Title:
FOUR-MEMBERED RING FUEL MOLECULE AND PHOTOCHEMICAL PREPARATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2019/080016
Kind Code:
A1
Abstract:
Disclosed is a four-membered ring structure fuel molecule and photochemical preparation method therefor. The structure of the fuel molecule is shown as (I), wherein n=1 or 2, and R1, R2, R3, R4, R5 and R6 are independently H or -CH3 or -CH2CH3. The described fuel molecule has the excellent properties of high density, high heat value and low ice point; the described preparation method features a high yield and mild reaction conditions, and no solvent is needed.
Inventors:
ZOU JIJUN (CN)
XIE JUNJIAN (CN)
PAN LUN (CN)
ZHANG XIANGWEN (CN)
WANG LI (CN)
XIE JUNJIAN (CN)
PAN LUN (CN)
ZHANG XIANGWEN (CN)
WANG LI (CN)
Application Number:
PCT/CN2017/107696
Publication Date:
May 02, 2019
Filing Date:
October 25, 2017
Export Citation:
Assignee:
UNIV TIANJIN (CN)
International Classes:
C07C13/547; C07C2/42; C10L1/04
Foreign References:
| CN102010764A | 2011-04-13 | |||
| US5220085A | 1993-06-15 | |||
| US5545790A | 1996-08-13 |
Other References:
HILL,E. ALEXANDER: "Ring Cleavage Rearrangements of 2- Bicyclo[3.2.0]heptyl and Related Grignard Reagents", J. ORG. CHEM., vol. 41, no. 7, 31 December 1976 (1976-12-31), pages 1191 - 1199, XP055594295, ISSN: 0022-3263, DOI: 10.1021/jo00869a024
HEATHCOCK, CLAYTON H.: "Photochemistry of 1, 6-Cyclodecadienes. I. 1-Me- thyl-(E, E)-I, 6-cyclodecadiene", J. ORG. CHEM., vol. 37, no. 23, 1 November 1972 (1972-11-01) - 31 December 1972 (1972-12-31), pages 3754, XP055594298, ISSN: 0022-3263, DOI: 10.1021/jo00796a918
BALDWIN, JOHN E.: "Thermal Isomerization of cis, anti, cis- Tricyclo[6.3. 0. 0]undec-3-ene to endo-Tricyclo[5. 2. 2. 0]undec-8-ene", ORG. LETT., vol. 7, no. 23, 19 October 2005 (2005-10-19) - 10 November 2005 (2005-11-10), pages 5195 - 5197, XP055594300, ISSN: 1523-7060, DOI: 10.1021/ol052004k
RANU,BRINDABAN C.: "Two-carbon Ring Expansion through Free Cyclo butylcar- binyl Radical Fragmentation", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 1,, vol. 8, 31 December 1994 (1994-12-31), pages 921 - 922, XP009063217, ISSN: 0300-922X, DOI: 10.1039/p19940000921
ZOU JIJUN ET AL.: "High Density Liquid Hydrocarbon Fuels for Aerospace Propulsion : Synthesis and Application", JOURNAL OF PROPULSION TECHNOLOGY, vol. 35, no. 10, 31 October 2014 (2014-10-31), pages 1419 - 1425, XP055594307, DOI: 10.13675/j.cnki.tjjs.2014.10.018
PAN LUN ET AL.: "Synthesis Chemistry of High-Density Fuels for Aviation and Aerospace Propulsion", PROGRESS IN CHEMISTRY, vol. 27, no. 11, 3 November 2015 (2015-11-03), pages 1531 - 1541, XP055594311, DOI: 10.7536/PC150531
HEATHCOCK, CLAYTON H.: "Photochemistry of 1, 6-Cyclodecadienes. I. 1-Me- thyl-(E, E)-I, 6-cyclodecadiene", J. ORG. CHEM., vol. 37, no. 23, 1 November 1972 (1972-11-01) - 31 December 1972 (1972-12-31), pages 3754, XP055594298, ISSN: 0022-3263, DOI: 10.1021/jo00796a918
BALDWIN, JOHN E.: "Thermal Isomerization of cis, anti, cis- Tricyclo[6.3. 0. 0]undec-3-ene to endo-Tricyclo[5. 2. 2. 0]undec-8-ene", ORG. LETT., vol. 7, no. 23, 19 October 2005 (2005-10-19) - 10 November 2005 (2005-11-10), pages 5195 - 5197, XP055594300, ISSN: 1523-7060, DOI: 10.1021/ol052004k
RANU,BRINDABAN C.: "Two-carbon Ring Expansion through Free Cyclo butylcar- binyl Radical Fragmentation", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 1,, vol. 8, 31 December 1994 (1994-12-31), pages 921 - 922, XP009063217, ISSN: 0300-922X, DOI: 10.1039/p19940000921
ZOU JIJUN ET AL.: "High Density Liquid Hydrocarbon Fuels for Aerospace Propulsion : Synthesis and Application", JOURNAL OF PROPULSION TECHNOLOGY, vol. 35, no. 10, 31 October 2014 (2014-10-31), pages 1419 - 1425, XP055594307, DOI: 10.13675/j.cnki.tjjs.2014.10.018
PAN LUN ET AL.: "Synthesis Chemistry of High-Density Fuels for Aviation and Aerospace Propulsion", PROGRESS IN CHEMISTRY, vol. 27, no. 11, 3 November 2015 (2015-11-03), pages 1531 - 1541, XP055594311, DOI: 10.7536/PC150531
Attorney, Agent or Firm:
BEIJING LINGZHUAN INTELLECTUAL PROPERTY AGENCY CO., LTD (CN)
Download PDF: