US4836950A | 1989-06-06 | |||
US5098591A | 1992-03-24 | |||
US5011621A | 1991-04-30 | |||
JPH0341170A | 1991-02-21 | |||
JPH0337299A | 1991-02-18 |
1. | A nonaqueous, liquid composition comprising the following ingredients : a) dlimonene; b) ethyl lactate; c) NMP; and d) a surfactant . |
2. | A graphic ink remover nonaqueous composition comprising the following ingredients: a) dlimonene b) ethyl lactate c) NMP the dlimonene and the ethyl lactate each being at least 15% by weight of the composition. |
3. | A nonaqueous cleaning composition for removing graphic ink from screens comprising the following ingredients in approximate percent by weight: Ingredients % by weight 1. dlimonene 3080 2 ethyl lactate 1050 3 NMP 530. |
4. | surfactant 0.55 4 A composition as defined in claim 3 in which the following ingredients are present in approximate percent by weight:. |
5. | A composition as defined in claim 3 in which the following ingredients are present in approximate percent by weight:. |
6. | A composition as defined in claim 3 containing about 50 weight percent dlimonene, 30 weight percent ethyl lactate, and 15 weight cetyl NMP and effective amounts of a surfactant to form a homogenous mixture. |
7. | A composition as defined in claim 5 in which there is about 0.1 to 5 weight percent of ethoxylated undecyl alcohol. |
8. | A composition as defined in claim 2 in which the surfactant as an alkyl benzene sulfonate. |
9. | A composition as defined in claim 1 in which the dlimonene and ethyl lactate are the major components in the composition. |
10. | A composition as defined in claim 1 in which a portion of the ethyl lactate is substituted for by methyl lactate. |
11. | A composition as defined in claim 1 comprising about 50% by weight of dlimonene, about 2025% by weight of ethyl lactate, about 1520% by weight of NMP and, optionally, a surfactant. |
12. | A liquid nonaqueous cleaner composition as defined in claim 1, the composition comprising dlimonene, ethyl lactate, NMP and amine alkyl benzene sulfonate. |
13. | A composition as defined in claim 1 in which the following ingredients are present in approximate percent by weight: Ingredient % by weight dlimonene 59 ethyl lactate 25 Nmethyl pyrrolidone 15 amine alkylbenzene 1 sulfonate (surfactant) . |
14. | A method of removing a graphic ink on a screen or printing press surface, the method comprising: a) applying the cleaning composition defined in claim 1 to the ink on the screen or press; b) allowing the coated ink and composition to remain in contact for a time sufficient to loosen the coating from the screen or press surface; and c) separating the coating and the composition from the screen or printing press surface. |
GRAPHIC INK REMOVER SOLUTION FIELD OF THE INVENTION The present invention relates to a coating removal and all-purpose cleaning composition and, more particularly, to a one step graphic ink remover composition.
BACKGROUND OF THE INVENTION Conventional graphic ink remover solutions or compositions have drawbacks and are not always efficient enough to remove graphic ink from screens and printing equipment during color change over and at the end of the printing job. Material such as acetone, ethyl acetate and alcohol often have a disagreeable odor, irritates eyes and are flammable and combustible which can be harmful to the user.
OBJECTS OF THE INVENTION It is an object of the present invention to provide an easy-to-make, easy-to-use very efficient one step graphic ink remover compositions and methods of using the compositions.
It is a further object of the present invention is to provide a very effective, non-toxic, non-methylene chloride, acetone, ethyl acetate or alcohol containing graphic ink remover comprising d-limonene, ethyl lactate, NMP (n-methyl pyrrolidone) and a surfactant.
Still another object of the present invention to provide a non-aqueous liquid cleaning composition
especially adapted graphic ink from screens for removing graphic ink from screens, the composition comprising the following ingredients in approximate percent by weight: Ingredients % by weight 1. d-limonene 30-80
2. ethyl lactate 10-50
3. NMP 5-30
4. surfactant 0.5-5 These and other objects will be apparent from the specification and claims that follow.
SUMMARY OF THE INVENTION The present invention provides a liquid non-aqueous composition comprising the following ingredients:
1. d-1imonene;
2 . ethyl lactate;
3. NMP;
4. surfactant; and 5. optionally, gamma butyrolactone in place of 5 or
10 up to 50% of the NMP to provide benefits of a lower odor and a faster evaporation rate. The present invention provides an effective, non- toxic, non-aqueous liquid graphic ink remover, cleaner and remover composition comprising the following ingredients
in the general and preferred ranges set forth in approximate percent by weight:
Ingredients % by weight
General Preferred Ideal
1. d-limonene 30-80 50-68 59
2. ethyl lactate 10-50 17-32 25
3. NMP 5-30 10-20 15
4. surfactant 0.5-5 0.8-2 1
Optionally, gamma butrolactone and glycol ether can
be used as well as a surfactant such as ethoxylated
undecyl alcohol and preferably, amine alkyl benzene εulfonate (Stepa Ninate 411™) . These formulations are as follows in approximate % by weight:
Ingredient O timal General
The compositions of the present invention, while preferably used as a graphic ink remover for screens, also can be used as an all purpose cleaner and, in particular hard surface cleaners, blanket washes for use in the
printing industry, cleaners for brake linings, silk screens, and copier belts.
The easy to use, easy to make cleaning composition is
made by mixing generally the three liquid ingredients (d- limonene, ethyl lactate and NMP) with a surfactant to form a homogenized stable cleaning mixture having enhanced detergent and stripping powers. Ethyl lactate helps increase the speed of the cleaning action. This combination of NMP, d-limonene and ethyl lactate is necessary for the removal of most of the graphic ink encountered. The d-limonene component is a solvent or diluent that assists in penetrating and stripping or removing of the inks that coat the screens
The d-limonene helps to loosen or dissolve grease, fat or organic materials, and is described as an ingredient in a cleaner in U.S. Patent Nos. 4,790,951 and 5,031,648.
When N-methyl pyrrolidone (NMP) is used as a solvent in the composition, generally NMP is used in lower amounts than d-limonene and ethyl lactate. U.S. Patent No. 4,605,670 discloses a percutaneous (drug) absorption composition including NMP and other ingredients such as
alcohols or esters including cetyl acetate. U.S. Patent
No. 5,011,621 is directed to a paint stripper composition
and discloses the use of NMP, an oil, and a plurality of cosolvents including terpeneε. U.S. Patent No. 5,098,591 (Stevens) discloses a paint stripper composition that includes NMP, d-limonene and a surfactant, but there is no teaching of the use of ethyl lactate which helps provide
superior results.
As indicated, relatively large amounts of ethyl lactate can be used, say, about 10 to 20 up to 50 or 60% by weight. Preferably about 25 to 35 weight percent is used to obtain fast drying. Ethyl lactate is a solvent that is compatible with d-limonene, NMP, and the surfactant. Ethyl lactate enhances the compatibility, efficiency, miscibility, and the stability of the liquid, the speed of drying the non-aqueous d'limonene/NMP combination and enhances the removal time for the more difficult hard nail polish surfaces. Best results are obtained with about 25-32% by weight. As indicated, the total amount of d-limonene in the composition is preferably at least 25 or up to 30 - 35 percent by weight and more preferably at least about 45 or 55 percent by
weight. In some cases, methyl lactate can be used with the ethyl lactate, the methyl lactate being generally about 3 to 5 weight percent up to 50 to 55 weight percent of the combination of ethyl lactate and methyl lactate. The cleaner composition has an outstanding balance of properties including easy removal of ink coatings on screens on screen and hard surfaces, being non-irritating, having a pleasant order, being quick drying, having miscible ingredients, and leaving the cleaned surfaces free of surface film. The cleaner has the advantage of producing up to two-thirds less Volatile Organic Compounds (VOC) than other products currently in use, to perform the cleaning operation.
The preferred surfactant is amine alkyl benzene sulfonate surfactant. (Stepan Ninate 411™) . The alkyl group is generally 1-16 carbon atoms and preferably 4 or 6 up to 8 or 10 carbon atoms. Suitable surfactants are ethoxylated sulfate, phosphate esters and other surfactants mentioned in column 8 of U.S. Patent No. 5,098,591 (Stevens) .
The Stevens patent discloses a terpene (d-limonene) ; NMP, a surfactant and carbonates or glycol ethers. The
carbonates such as ethylene carbonate and propylene carbonates are necessary in the formulation and one of the main, thrusts of the Stevens patent. However, there is no suggestion or showing of the use of ethyl lactate or a graphic ink cleaner in Stevens.
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