Title:
HYDROSILYLATION REACTION CATALYST
Document Type and Number:
WIPO Patent Application WO/2016/024611
Kind Code:
A1
Abstract:
A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc; and a ligand comprising a carbine compound such as 1,3-dimesitylimidazol-2-ylidene, etc.. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.
Inventors:
NAGASHIMA HIDEO (JP)
SUNADA YUSUKE (JP)
TAHARA ATSUSHI (JP)
NODA DAISUKE (JP)
SOEJIMA HIROE (JP)
SAKUTA KOJI (JP)
SUNADA YUSUKE (JP)
TAHARA ATSUSHI (JP)
NODA DAISUKE (JP)
SOEJIMA HIROE (JP)
SAKUTA KOJI (JP)
Application Number:
PCT/JP2015/072839
Publication Date:
February 18, 2016
Filing Date:
August 12, 2015
Export Citation:
Assignee:
UNIV KYUSHU NAT UNIV CORP (JP)
SHINETSU CHEMICAL CO (JP)
SHINETSU CHEMICAL CO (JP)
International Classes:
B01J31/22; C07F7/08; C07B61/00
Foreign References:
| JP2003516230A | 2003-05-13 | |||
| US20040236054A1 | 2004-11-25 |
Other References:
MO ZHENBO ET AL.: "Anchoring of Silyl Donors on a N-Heterocyclic Carbene through the Cobalt- Mediated Silylation of Benzylic C-H Bonds", ANGEWANDTE CHEMIE . INTERNATIONAL EDITION, vol. 52, 2013, pages 10845 - 10849, XP055399235, ISSN: 1433-7851
JUNQUERA LOURDES BENITEZ ET AL.: "R-Allyl Nickel(II) Complexes with Chelating N- Heterocyclic Carbenes: Synthesis, Structural Characterization, and Catalytic Activity", ORGANOMETALLICS, vol. 31, 2012, pages 2175 - 2183, XP055399242, ISSN: 0276-7333
See also references of EP 3181226A4
JUNQUERA LOURDES BENITEZ ET AL.: "R-Allyl Nickel(II) Complexes with Chelating N- Heterocyclic Carbenes: Synthesis, Structural Characterization, and Catalytic Activity", ORGANOMETALLICS, vol. 31, 2012, pages 2175 - 2183, XP055399242, ISSN: 0276-7333
See also references of EP 3181226A4
Attorney, Agent or Firm:
KOJIMA Takashi et al. (JP)
Takashi Kojima (JP)
Takashi Kojima (JP)
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