* * * * * * The present invention relates to an industrial proc- ess, a so-called oxido-destruction process, for con- veniently recycling every type of waste of any origin.

Materials obtained thereof have several interesting possibilities of use in the industrial field. Said process is preferably carried out continuously, in a suitable mobile or stationary system, by subjecting said waste to an oxidative demolition-depolymerization reaction, followed if necessary by a repolymerization reaction depending on the desired end product. In the first case biologically stable, sterile, fluid and solid materials are obtained, whereas in the second case a sterile stable expanded polymer is obtained, having a polyurethane structure. The oxidative demoli- tion-depolymerization reaction is preferably carried out by mixing intensively waste with a suitable super- oxidizing mixture in the presence of a mixture of suitable catalysts. The repolymerization reaction is carried out in its turn by subjecting the product de- riving from demolition-oxidation depolymerization di- rectly to the action of a suitable repolymerizing mix-

ture, in the presence of a mixture of suitable cata- lysts.

BACKGROUND Waste disposal gives rise to several problems for both technical and environmental reasons. Most of all, waste is disposed of in dumps and is only partially recycled and/or destroyed with thermal processes.

For instance, the humid and/or green fraction deriving from separate waste collection is biostabilized, though never completely, through aerobic or anaerobic processes requiring long times, about 4-6 months.

On the other hand, the recycling of post-consumables or scrap materials is characterized by a difficult re- use due to the loss of original properties; indeed, recycled products often do not find reliable applica- tions since they cannot ensure the same performances of originally manufactured items.

For wood processing scraps most shavings and powders are placed in dumps or are thermally destroyed. Unfor- tunately, during combustion powders and shavings gen- erate polluting gas compounds, beyond ash pollution.

The same applies for rubbers in generals and for tires, most of which are thermally destroyed, with well known pollution problems, and few of them are recycled.

On the other hand, polyurethane scraps are placed in dumps or thermally destroyed, such as other plastic post-consumables.

Also animal waste is burnt or used for producing ani- mal feed. Burning results in gas emissions with a high presence of NOX and a considerable ash generation.

Animal meals can then be only burnt today. However, ashes can contain unburnt residues infected by BSE (Bovine Spongiform Encephalopathy) and/or by other types of ESTs (Transmitted Spongiform Encephalo- pathies).

Household solid waste (RSU in Italian, which stands for Rifiuti Solidi Urbani) contain on average 40% by weight and 60% by volume of packaging, made of cellu- lose, plastic, polystyrene, metals, glass. The sepa- rate recycling of these materials, beyond being expen- sive, is difficult and sometimes impossible. Beyond being stocked in dumps, eventually they are thermally destroyed, with well known pollution problems.

Thermal destruction enables a partial recovery of thermal energy, but does not ensure zero pollution emissions; as a matter of fact, despite the post- combustion of exhaust gases and the presence of pro- gressive filters, at dump sites there are still pow- ders, dioxins deriving from plastic materials, sulfur

dioxide, carbon oxide, nitrogen oxide. Waste then is not completely burnt ; residual combustion ashes, about 40% by weight of initial waste, are sent to dumps as unburnable materials. Said disposal of unburnable ma- terials, however, results in further pollution prob- lems, since under the effect of winds ashes are taken away from the dump site, whereas from a chemical point of view rains cause serious ecologic problems, because sulfur and chlorine compounds build highly corrosive acids. Moreover, since much burnt waste has toxic properties, residual ashes are a concentrate of nox- ious substances. That is why ashes cannot be disposed of in dumps for household solid waste, but should be sent to special dumps. In recent times, in order to avoid thermal destruction or placing loosely in dumps, waste is packed up in blocks kept together by plastic films or nets, which are then placed in dumps. Said disposal, however, does not modify waste at all, which in absence of oxygen undergoes a subsequent rotting process,-which is also polluting.

Other treatments, developed as alternatives to the two treatments described above, have proved as unsatisfac- tory. Among them, physical treatment for instance based on humid heat (generally at 100°C for one hour), freezing, UV and/or ionizing radiations have not

proved particularly useful for finally solving the problems disclosed above.

Recently it has been suggested (Italian patent appli- cation TP2001A000001) to recycle a certain amount of waste of various origin by subjecting it to a combined process of oxidation with hydrogen peroxide and subse- quent trimerization with trimerized isocyanate. This process, however, is only a preliminary feasibility study and as such has not proved able to solve effi- ciently the problem of an environmentally friendly and industrially competitive recycling/disposal of waste of any origin.

DESCRIPTION Thanks to the present invention every possible type of waste can be recycled and reconverted in an efficient and economic way into useful materials, with several interesting possibilities of use.

By mere way of non-limiting example, the process ac- cording to the present invention has proved to per- fectly apply on an industrial level to: - household solid waste (RSU) from non-separate col- lection; - upper grain and lower grain fractions; - humid and/or green fractions from separate collec- tion;

- dung ; - hospital waste ; - agroindustrial waste, deriving from farms, slaugh- terhouses, fish or agricultural industries ; - industrial scraps, such as rubber, plastic, wood, organic and inorganic fibers (including for in- stance mineral wools and asbestos); - disposal residues in the automotive field ; - purging sludge ; - ashes ; - products recycled from post-consumables or scraps.

Therefore, one of the objects of the present invention is a process for recycling and converting, in an in- dustrially feasible and competitive way, all possible waste made of materials used in several market branches.

A second preferred object of the invention is a spe- cific system for implementing the process as referred to above. Said system basically comprises means for waste volumetric reduction and compacting and a multi- stage reactor, where the oxido-destruction process takes place. Preferably, said system also comprises means for collecting, isolating and separating prod- ucts resulting from oxido-destruction treatment. Said system is most preferably combined with two turbo-

electrophotolytic reactors for on-site preparation and metering of the super-oxidizing mixture for waste oxi- dative demolition-depolymerization.

Moreover, an object of the invention is also repre- sented by the mixtures of reagents activating the oxi- dative demolition-depolymerization reaction (super- oxidizing mixture) and the repolymerization reaction (repolymerizing mixture) of waste undergoing said process.

Other objects of the invention are the products ob- tained with said process and the use thereof.

An additional object of the invention is the use of the process and system as specified above for recy- cling and converting every type of waste into indus- trially useful products.

DESCRIPTION OF THE FIGURES Figure 1 shows by way of example the general structure of one of the preferred embodiments of the oxido- destruction system according to the present invention (a stationary system).

It shows in particular: (1) the waste pit ; (2) a belt conveyor for transferring waste from (1) to a crusher; (3) a breaker, equipped with a system for breaking

bags, boxes and coarse materials, if present ; (4) a belt conveyor, onto which an electromagnetic system for separating metal parts is located.

Said belt conveys said waste broken in (3) to a crusher ; (5) a crusher, where waste is reduced to a size of about 10 cm; (6) a belt conveyor, which transfers waste crushed in (5) to a refiner ; (7) a refiner, which can reduce waste to an average size of few centimeters ; (8) a belt conveyor, preferably with variable speed, which supplies the oxido-destruction reactor with waste refined in (7); (9) a multistage reactor with variable section, where waste oxido-destruction process occurs ; (10) is the reactor exit, where means for collecting and conveying processed waste are placed.

Figure 2 shows schematically one of the preferred em- bodiments of the multistage reactor where waste oxido- destruction process occurs.

It shows in particular (I) the first reactor chamber, whose section is shaped like a cylinder and a frustum of cone ; (II) the second reactor chamber, whose section is

shaped like a cylinder and a frustum of cone ; (III) the third reactor chamber, with cylindrical section; (11) a hydraulic speed variator; (12) a feeding hopper; (13) a first cylindrical-conical rotary spiral ; (14) a second cylindrical-conical rotary spiral ; (15) a third cylindrical rotary spiral ; (16) the entry of the super-oxidizing mixture into the first reactor chamber ; (17) the discharge of the super-oxidizing bath ; (18) the electric pump feeding the super-oxidizing mixture; (19) the intake of the super-oxidizing mixture ; (20) the entry of the repolymerizing mixture into the second reactor chamber ; (21) the discharge of the repolymerizing bath ; (22) the electric pump feeding the repolymerizing mixture ; (12) the intake of the repolymerizing mixture; (24) a hydraulic positioner ; (25) is the reactor exit.

Figure 3 shows schematically one of the specific turbo-electrophotolytic reactors generating on-site the super-oxidizing mixture.

It shows in particular: (26) the entry of the fluid to be treated ; (27) UV lamps ; (28) the transparent Teflon cylinder containing UV lamps ; (29) the spiral-shaped anode; (30) the spiral-shaped cathode; (31) the exit of processed fluid; (32) closing flanges and counter-flanges ; (33) current positive pole ; (34) current negative pole.

DETAILED DESCRIPTION The main object of the present invention is therefore an oxido-destruction process, comprising the following steps: a) physical preliminary treatment for waste volumetric reduction and compacting, so as to obtain a homoge- nous refined mixture free of ferrous/metal and/or too large residues ; b) feeding said mixture deriving from step a) into a first chamber of a multistage reactor, in which the mixture undergoes an oxidative demolition- depolymerization process ; c) feeding said oxidized mixture deriving from step b) into a solid-liquid extractor, in which the mixture

is separated into its components ; or d) feeding said oxidized mixture deriving from step b) into a second chamber of said multistage reactor, in which the mixture is activated to a repolymeri- zation process; e) feeding said activated mixture deriving from step d) into a third chamber of said multistage reactor, in which said repolymerization develops, and then into suitable collection or conveying means, in which said repolymerization reaction is completed, so as to obtain a sterile stable expanded polymer ; said process being characterized in that: - said oxidative demolition-depolymerization reaction as in step b) is carried out by intensively mixing the refined waste mixture with a super-oxidizing mixture, in the presence of catalysts ; - said repolymerization reaction as in step d) is car- ried out by intensively mixing said oxidized mixture with a repolymerizing mixture, in the presence of catalysts.

The steps of said process are preferably carried out continuously.

The physical preliminary treatment for waste volumet- ric reduction as in step a) preferably includes a se- ries of consecutive operations involving breaking, re-

moval of ferrous and/or metallic residues, crushing, refining, which lead to compacting and homogenization of the initial mass, with subsequent cost reduction.

The series of operations for waste physical prelimi- nary treatment as listed above is shown in accompany- ing Figure 1.

Said Figure 1 shows a stationary system. However, a mobile system, for instance on wheels, leaving aside its smaller size, will have a sequence of basically identical or equivalent components.

Said physical preliminary treatment also enables to carry out a preliminary selection and helps the subse- quent oxidative demolition-depolymerization reaction, by favoring the intensive mixing of the refined mix- ture thus obtained with the super-oxidizing mixture and the catalysts.

During step b) the refined mixture referred to above is fed continuously into the first chamber of. a multi- stage reactor.

A preferred structure of said multistage reactor is shown in cross section in accompanying Figure 2.

It shows the first chamber, whose section is shaped like a cylinder and a frustum of cone, the second chamber, whose section is also shaped like a cylinder and a frustum of cone, and the third chamber, with cy-

lindrical shape, connected in series one to the other.

Inside'said three chambers there is also the shaft- free double blade rotary spiral, having the same pro- file as said chambers, which continuously mixes waste and reagents.

Passing through said first chamber, said refined mix- ture undergoes the oxidative demolition- depolymerization reaction by intensive mixing with a super-oxidizing mixture in the presence of catalysts.

Said super-oxidizing mixture is preferably prepared and metered on-site by using two turbo- electrophotolytic twin reactors combined with the sys- tem.

The preferred structure of one of said turbo- electrophotolytic reactors is shown in cross section in accompanying Figure 3.

These reactors are characterized in that they combine into the same appliance the function of an electro- lytic cell and of a photolytic reactor.

As a matter of fact, said reactors are characterized in that they comprise the combination into one reactor body of: - an electrolytic cell ; and - a photolytic reactor.

Moreover, they use spiral-shaped instead of flat sur-

face electrodes ; said electrode shape enables to re- duce electrolytic cell volume, electrode surface and the electric energy applied to said electrodes.

In particular, the reactors are characterized by the following innovative features: they comprise an outer cylindrical body made of stainless steel, closed on both ends by flanges and counter-flanges. On one side UV lamps, housed inside a transparent Teflon cylinder, and on the other side the electrodes wound as spirals around the aforesaid Tef- lon cylinder, are fitted onto said flanges and. counter-flanges. Preferably, of the two electrodes the cathode is made of copper and the anode of iron. The fluid to be subjected to the combined electrochemical and photolytic treatment (turbo-electrophotolytic treatment) flows between the negative electrode (cath- ode) and the positive electrode (anode), while at the same time it is bombed by UV rays emitted by the lamps. The electrolytic action develops thanks to the direct current the two spiral-shaped electrodes are supplied with. On the other side, the photolytic ac- tion is obtained by using special mercury-vapor lamps designed to emit maximum energy at a frequency of 253. 7 nanometers, which proves particularly efficient for photochemical transformations.

In the first reactor an acid mixture A) undergoes a turbo-electrophotolytic treatment, which mixture pref- erably comprises : peroxides (50-80% by weight), acetic acid (7-15%), citric acid (5-13%), stabilizers (1%).

Said acid mixture A) (conventionally designed by the Applicant"peroacetric acid") is added with sodium hy- droxide so as to neutralize acetic acid. During treat- ment, within said mixture A) (or"peroacetric acid") a certain amount of highly reactive oxidizing species is generated, such as in particular oxygen °2, radicals OH and ozone 03. As a result, at the end of the com- bined electrolytic and photolytic treatment, a strongly oxidizing mixture is obtained, which is al- ready able as such to attack organic substances.

In the second reactor mixture B) undergoes a turbo- electrophotolytic treatment, which mixture comprises an aqueous phase (preferably recycled from oxido- destruction process) added with brine (containing on average 5-10% by weight of NaCl), preferably in amount of about 10-20% by weight with respect to the recycled solution. During treatment, within said mixture B) highly oxidizing species are generated, such as 02, chlorine, which further reacts so as to obtain sodium hypochlorite (NaClO), and 03. Also the mixture ob- tained at the end of this treatment is thus strongly

oxidizing.

Both mixtures, after treatment in the two turbo- electrophotolytic reactors, are united so as to obtain the final super-oxidizing mixture according to the present invention. In other words, after the turbo- electrophotolytic treatment, the two solutions A) and B) are mixed together and suitably metered in variable ratios depending on the type of waste to be treated and on the desired end product.

Said super-oxidizing mixture is then fed into the first chamber of the multistage reactor so as to per- form the oxidative demolition-depolymerization reac- tion as in step b) previously described.

The super-oxidizing mixture thus prepared is extremely rich in strongly reactive oxidizing species. In par- Iticular hydroxyl radicals OH, having an oxidative po- tential of 2.74, versus 1.76 of hydrogen peroxide, 1.36 of chlorine and 1. 23 of oxygen, are super- oxidizing and, in combination with ozone, can attack and destroy any organic substance. Moreover, hydrogen peroxide inside the mixture can react with hypochlo- rite, thus developing large amounts of oxygen, which improve the oxidizing and disinfecting power of said mixture Preferably, therefore, the super-oxidizing mixture ac-

cording to the present invention is prepared by suita- bly mixing the two oxidizing solutions (deriving from mixture A) and from mixture B), respectively) prepared in the two turbo-electrophotolytic reactors previously described, and is characterized in that it comprises a large amount of highly reactive oxidizing species such as hydroxyl radicals OH, ozone 03, oxygen 02, sodium hypochlorite NaClO, peroxides. The amount of these species can be suitably varied by changing for in- stance operating parameters applied to the turbo- electrophotolytic reactors, such as temperature and/or process duration.

In mixture A),"peroacetric acid", as referred to above, hydrogen peroxide can also be replaced by so- dium peroxide, Na202. In such a case an aqueous 20% solution of Na202 and magnesia in the presence of catalysts, such as copper, cobalt, nickel, manganese salts, is preferably used.

Another substance to be used instead of hydrogen per- oxide is sodium bicarbonate NaHCO3.

Catalysts accelerating the oxidative demolition- depolymerization process as in step b) basically com- prise a mixture of molecular sieves, kaolin, clay, so- dium aluminum silicates. By way of non-limiting exam- ple, one of the preferred compositions of said mixture

comprises : 75% of molecular sieves, 10% of kaolin, 8% of clay, 7% of sodium aluminum silicate blue powder (percentages refer to weight).

These catalysts have proved particularly useful, since they have a large surface area and thus enable to treat up to one hundred times the amount of molecules that can be absorbed onto a conventional amorphous catalyst. Moreover, they also act as molecular sieves and allow to trap in channels and cavities of their structure a series of molecules and toxic residues such as cations of alkali or alkaline-earth metals. On average, they are characterized by the following chemical-physical properties: - chabazite-phillipsite concentration ; - gravimetric analysis (chabazite + phillipsite) : 79% by weight ; - absolute density: 2.10 g/cm3 ; - apparent density: 0.70-1. 05 g/cm3 ; - max. humidity: 7% ; - max. tolerable temperature: 350°C ; - absorption selectivity for some cations: chabazite : K+>Ag+>Rb+>NH4+>Pb2+>Na+ Ba2+>Sr2+>Ca2+; phillipsite : Cs+ Rb+ K+>Na+>Li+ Ba2+>Ca2+ Sr2 ; - chemical composition (percentage of oxides) : Si02 51. 80% ; A1203 18. 34% ; Fe203 3. 40% ; MgO 0. 96% ;

CaO 4. 73% ; BaO 0. 35% ; SrO 0. 04% ; Na20 0. 60%; K2O 4. 91%.

Possible substitutes of molecular sieves can be chosen among bikitaite, Li2 [Al2Si4O12]#H2O ; heulandite, Ca4 [AlsSi28072]'24H20, as well as faujasite, (Na2, Ca, Mg) 29 [Al5sSii340384]-24H20.

The preferable amount. of molecular sieves varies from about 1% by weight with respect to the weight of waste entering the reactor and about 4% by weight for metal ion absorption.

Molecular sieves absorb small molecules such as for instance formic acid and methanol, remove SO2 and re- duce dramatically nitrogen load and ammonium nitrates.

They further remove Pb, Cr and other heavy metals, also in the presence of possible interfering elements such as NaCl. They also have a good affinity for Cd and Cu.

Kaolin inside the catalyst mixture belongs to hy- drosilicates and has the following chemical composi- tion: A1203 x Si02 x 2H20, where alumina is about 38% and silica about 48%. Before being added to the cata- lyst mixture kaolin is activated by heating at 1200°C.

Together with clay it has the following functions: -absorbing function: 20 to 50% by weight; - filtering function: towards toxic impurities;

- sanitizing function: it helps sterilization; - catalytic function: it accelerates chemical and biological reactions.

Sodium aluminum silicate activates clay functions as polymerization catalyst.

Basically, therefore, in the demolition-oxidative po- lymerization reaction these catalysts have a double effect : they accelerate the action of the super- oxidizing mixture and trap various toxic residues, represented for instance by heavy metals and various polluting elements, such as iron, chrome, chlorides, oils, fats. Advantageously, said trapping action en- ables to reduce dramatically or even cancel the con- tent of said polluting elements in end products.

Step c) is used when sterile, biologically stable re- cycled products are required. In this case, the oxi- dized mixture getting out of the first reactor chamber is sent and collected in a solid-liquid extractor where the liquid phase is separated from the solid phase.

Said mixture fed into said solid-liquid extractor is then separated into a sterile, liquid or fluid-dense organic phase and into a sterile solid dry phase.

The first sterile, liquid or fluid-dense organic phase has unexpectedly shown excellent amending and fertil-

izing properties. It is thus very conveniently used as fertilizing compost, absolutely non-polluting, com- pletely stable and free of any kind of bacteria, therefore also ecologically competitive.

The second phase, a sterile dry biostable solid (in practice it is a dry biomass), is particularly useful for instance as non-polluting fuel. This solid residue has indeed an excellent caloric yield and excellent non-polluting properties, since it does not give rise to smokes, ashes or other particulate residues. An- other useful field of application for the use of this bistable non-polluting mass has been identified in the reclamation, for instance by covering, of tradi- tional dumps. As a consequence, also this recycled ma- terial has proved conveniently useful and ecologically compatible.

Step c) is then preferably used for rapid composting of humid and green fractions and of dung.

Another particularly preferred application relates to the stabilization and oxidative saturation of sludge deriving from purging systems.

On the other hand, step d) is used as an alternative to step c) when the waste mixture has to be turned into another type of product, i. e. into an expanded polymer with elastic skeleton and intercommunicating

cells, which can be used for other applications in different technical fields.

In this case, the oxidized mixture getting out of the first chamber of the multistage reactor is sent as such, i. e. still impregnated with residual super- oxidizing mixture, directly into a second chamber of said multistage reactor. As shown in Figure 2, said second chamber is connected in series to the first one and contains the repolymerization reacting mixture. In this second chamber the oxidized mixture coming from the first chamber gets intensively impregnated with the repolymerization mixture, and is then sent con- tinuously into a third chamber placed in series with respect to the second one. In said third chamber of the multistage reactor, the repolymerization reaction of the components of the oxidized mixture takes place.

The repolymerization reacting mixture according to the present invention preferably comprises: - a mixture of diphenyl-methane-4, 4'-diisocyanate and/or isomers and homologues thereof (for instance 4, 4'-diisocyanate-bis (1, 4-isocyanatephenyl) metha- ne), containing about 25% to 35% of NCO groups, preferably about 30 to 32% ; said mixture is dis- persed into an isomer mixture of xilenes in a con- centration of 50-60% by weight;

- diazabicyclooctane (DABCO), in a percentage of 1% ; -additives, such as N, N-dimethyl-acetylamine (or N, N-dimethyl-aminoethanol), in a percentage of 1% ; - catalysts, in a percentage of 1 to 6% by weight.

Preferably, the same mixture of catalysts also used in the previous oxidative demolition-depolymerization re- action is used. In this case sodium aluminum silicate in blue powder is preferably. metered in a concentra- tion of 6.5 to 16. 5%, so as to help the catalyzing ac- tion of kaolin and clay towards polymerization proc- ess.

In said repolymerizing mixture, DABCO can be conven- iently replaced by substances having the same power to help the attack onto isocyanate as products deriving from the degradation-oxidative depolymerization reac- tion. For instance, methylene-bis-dimethyl-cycloamine is particularly preferred.

Eventually, in step e) the raw product impregnated with the repolymerization mixture gets through the third chamber of the multistage reactor and is sent to suitable collection means, when the repolymerization reaction is completed in short times, so as to obtain the desired expanded polymer. Said collection means vary depending on the shape to be given to the poly- mer. Particularly preferred are formworks for obtain-

ing blocks of expanded polymer having a desired shape and density ; the same preference goes to the use of a belt conveyor with lifted edges for obtaining continu- ously blocks or plates of expanded polymer.

The product thus obtained is a sterile stable polymer, characterized by a polyurethane structure with elastic skeleton, heterogeneous flexibility, intercommunicat- ing cells and density to be adjusted depending on ap- plied repolymerization conditions, basically affected by the composition of the repolymerization mixture.

Said expanded polymer has proved excellent as thermo- acoustic insulating material, and can thus be widely used for instance in the building field. Thanks to its long lifetime and'high inertia, it has proved as in- teresting for an economic and ecologic reclamation of caves and dumps as well as for various applications in road engineering and in industry in general. Another interesting application is its possible use as sup- porting band for out-of-soil cultures. Moreover, it is also perfectly recyclable through the process accord- ing to the present invention and is therefore a versa- tile, economic, environmentally friendly, recyclable material.

The oxido-destruction process is very fast (its aver- age duration is of 10 minutes, preferably even less)

and strongly exothermic. It starts at room temperature and develops until it reaches a temperature of about 95-97 °C.

The process according to the present invention is car- ried out in a suitable multicomponent system, shown by way of example in Figure 1, which can be mobile or stationary depending on needs.

Said system comprises at least: - a first section, for waste volumetric reduction, comprising one or more modules, connected one to the other, in which waste is crushed, compacted, homogenized (volumetric reduction and refining step); - a second section, basically comprising a single stage or multistage reactor and its functional ac- cessories, in which said refined waste undergoes the oxidative demolition-depolymerization process, followed or not by the subsequent repolymerization process (oxide-destruction step).

Said first section preferably comprises means for breaking (Fig. 1, (2) ), eliminating metal residues (Fig. 1, (3) ), crushing (Fig. 1, (4) ), refining and compacting (Fig. 1, (6) ) waste. Preferably, said means are connected in series one to the other by means of belt conveyors and/or belt separators (Fig. 1, (3),

(5) (7)), for instance electromagnetic belts, and re- lated loading devices, such as suitable hoppers.

Said second section comprises a reactor, preferably a multistage reactor (Fig. 1, (9) ), including in its turn (Fig. 2) : - a device for loading refined waste; - a first chamber, whose section is preferably shaped like a cylinder and a frustum of cone, in which the oxidative demolition-depolymerization process takes place ; - a second chamber, whose section is preferably shaped like a cylinder and a frustum of cone, in which the repolymerization process is activated ; - a third chamber, preferably with cylindrical sec- tion, in which the repolymerization process devel- ops while the mixture travels towards the reactor discharge Said chambers are preferably connected in series one to the other and are equipped with means for mixing and conveying the waste mass to be transformed, as well as with means for metering, restoring, recovering and recycling reagents and catalysts. Said means for mixing and conveying the waste mass to be transformed preferably comprise a shaft-free double blade rotary spiral, having the same profile as the reactor cham-

bers.

In case the refined waste mixture should undergo only step b) of oxidative-demolition-depolymerization, so as to obtain the products as in step c), it is also possible to use a reactor having only one chamber shaped like a cylinder and a frustum of cone. In its turn, said chamber shaped like a cylinder and a frus- tum of cone can be connected in series, if necessary, to a chamber with cylindrical section, for a more con- venient discharge of end products.

Preferably, said second section further comprises: - tanks for storing reagents ; - two twin turbo-electrophotolytic reactors, as pre- viously described and shown schematically in Figure 3, for producing on-site and feeding the super- oxidizing mixture; - devices for controlling and managing, automatically or not, said system.

Preferably, the system further comprises a third sec- tion, for collection, in which end products obtained from the oxido-destruction process are isolated and separated (collection step).

Said third section preferably includes means for sepa- rating and collecting end products, such as for in- stance a solid-liquid separator, preferably a conical

spiral continuous extractor, if fertilizing fluid products and dry biomass have to separated, or collec- tion and repolymerization means, such as for instance formworks, if expanded polymers have to be produced.

The oxide-destruction process according to the present invention basically causes a series of complex, abrupt and extremely fast changes in the materials and waste components undergoing said process. The super- oxidizing mixture is formulated so as to obtain in this step the molecular demolition of all substances.

By mere way of non-limiting example, the following can be mentioned : proteins, cellulose, organic colorants containing chromophores such as >C=O or-C=C-, lipids, amino acids, polymers of any type.

In particular, products based on cellulose, i. e. pa- per, cardboard and above all the residues of cellulose processing and recycling, which cannot be further processed and are destined to thermal destruction, are excellent substrates for the production of expanded polymer.

As far lipids are concerned, the depolymerization re- sulting from the oxido-destruction process turns them into glycerol and fatty acids.

On the other hand, amino groups of amino acids are turned into ammonia reacting with acetic acid to ob-

tain acetamid. The latter can act as catalyst in the subsequent repolymerization process.

Molecular demolition reactions aim at completely de- stroying and depolymerizing the materials undergoing the process, with the production of polyols or poly- glycols basically comprising OH and CH2 groups, which are strictly necessary for obtaining the expanded polymer in the subsequent steps.

Also microorganisms are attacked by the strong oxidiz- ing action : hydrogen peroxide and hypochlorite seri- ously danage the membrane of the bacterium and cause its death.

Depolymerization and subsequent repolymerization to obtain ari expanded polymer cause the complete demoli- tion of all pre-existing structures: prions, pro- teins, viruses, bacteria, microorganisms in general.

The molecular demolition caused by oxidative demoli- tion-depolymerization thus contributes in a decisive way to the complete sterilization of the materials subjected to the process.

Oxidation produces among other things also carbon di- oxide and water. The latter can be conveniently recov- ered, thus obtaining a bacterially pure product to be used as such for watering fields.

Depolymerizations of the substances are carried out

sequentially, so as to demolish completely the exist- ing chemical-physical structure and enable the subse- quent repolymerization of demolished substances.

The oxidation of organic materials, and of flesh in particular, causes the reaction of fats and unsatu- rated fatty acids and their depolymerization. Said de- polymerization gives rise to the formation of ethers and esters having a dense-fluid structure, known as polyglycols. After suitable purging processes, the po- lyglycols thus obtained as first step of flesh oxido- destruction can be used for producing polyols or other substances, to be used in the production of plastic materials, or dried and used as fuel or amending agents. In fleshes, then, water is present in an amount of 75%. In the exothermic process of oxidative demolition-depolymerization, said water is evaporated partially, but as was already mentioned before, it can be recovered obtaining bacterially pure water to be used for instance for watering fields.

As further example, the depolymerization of biomasses, which are widely present in waste and processing scraps, occurs by means of oxygen released by the oxi- dizing reaction. Glucose present in biomass structure depolymerizes in contact with oxygen generated by de- composition of peroxide and releases carbon dioxide

and water, which are necessary to build the cells of the expanded polymer.

Oxygen generated by decomposition of the super- oxidizing mixture (React. 1 below): 2 H202 + catalyst = 2 H2O + 02 (1) activates repolymerization reaction. Oxygen easily binds to carbon : the amount of oxygen in the process is suitably formulated both for the depolymerization of materials and for their subsequent repolymeriza- tion.

Beyond activating the production of carbon dioxide, which is strictly necessary for building the cells of the expanded polymer, oxygen is thus also the drive behind the repolymerization of the products deriving from waste decomposition.

This is due to the fact that oxygen released by perox- ides present in the super-oxidizing mixture has an ex- cess of electrons and thus gives a pair of said elec- trons to diisocyanate carbon, which has few electrons, or of its isomers present in the repolymerizing mix- ture. This step initiates the repolymerization process involving two electronegative elements: oxygen and ni- trogen. As a result of electron transfer from oxygen to carbon, the following bond between DABCO, glycol and isocyanate group is obtained (React. 2 below) :

Carbon of isocyanate groups still has few electrons ; oxygen, which has a partial negative charge, dis- charges a flow of electrons and remains with a posi- tive charge, whereas nitrogen still has a negative charge. Oxidative demolition-depolymerization, as de- scribed before, gives rise to ethers and esters with dense-fluid structure. Repolymerization to obtain an expanded polymer can be carried out with one scrap or with a plurality of materials, as in the case of household solid or recyclable waste, but it keeps es- sential chemical-physical properties unchanged. The reason is that the reaction occurs between the reagent diisocyanate of the repolymerizing mixture and OH groups of polyols obtained from the depolymerization of starting materials (React. 3 below) : #-i "OH"groups of polyols from Diisocysma. te depolymerization liquid I (3)

Oxygen, beyond taking part directly to almost all de- polymerization reactions, then catalyzes the repoly- merization process to obtain an expanded polymer of all materials to be recycled present in the process.

This is basically related to the excess of electrons characterizing it, and to its high amount, which makes it possible to exploit the whole electronegative en- ergy it is charged with.

Electronegativity, in particular, enables oxygen to take electrons away from other atoms. For instance, in the process step shown below, it takes electrons away from hydrogen atom, thus unbalancing the charge of its nucleus. In hydrogen rebalance through electrons is impossible, since they have been carried away by oxy- gen. Hydrogen is thus left with a weak charge and is saturated by the electron doublet of nitrogen atom of DABCO (React. 4 below) : kl Va-He, < . . T.. :- :'' :'..' ,,. (

The reaction for building the expanded polymer is pro- gressive; as a matter of fact, it develops gradually as OH groups obtained by depolymerization of bio- masses, fatty acids, plastic materials, natural or ar- tificial fibers, become available. As was already pointed out, the active element of the reaction is oxygen, which is always ready to combine depending on reaction needs, thus ensuring the complete transforma- tion during repolymerization (React. 5 below).

On the other hand, the dimer can react with dimers, trimers, oligomers. The reaction gradually completes uniting all oligomers until an expanded polymer with high molecular weight is obtained. Carbon in isocy- anate group is closed between two electronegative at- oms, oxygen and nitrogen. Electronegative atoms can attract the electrons belonging to other atoms. Thus, nitrogen and oxygen leave carbon partially electron- deficient. Water gives carbon a pair of electrons as shown in reaction (6) below.

Oxygen, after giving electrons to carbon, generates a negative charge. The nitrogen atom with negative charges is instable and thus balances its charge by taking a hydrogen atom from water (React. 6 below).

Nitrogen then takes another hydrogen atom. The reac- tion eventually generates a terminal amine on the oli- gomer and releases a COs molecule (React. 7 below).

Carbon dioxide, which is built through reaction (7) during repolymerization, expands the fluidized mass as a result of oxido-destructive depolymerization of pre- existing chemical structures, until the polycondensa- tion process is over, which releases all water mole- cules in form of vapor, leaving the new polymer anhy- drous.

Finally, the recycling of heterogeneous materials has enabled the formation of the desired expanded polymer, with elastic skeleton, heterogenous flexibility, in- tercommunicating cells (React. 8 below).

The transformation of most various materials thus per- formed allows to recycle, also without a substantial

preliminary selection, scraps and waste, without re- leasing fumes in the atmosphere, without residual ashes, in other words with no environmental impact.

The product thus obtained can be used as a long-life item in building and industry as a thermo-acoustic in- sulating material or for cave reclamation. The super- oxidizing mixture and the subsequent repolymerizing mixture enable to obtain an expanded polymer, per- fectly sterile and stable in time, also using as raw material for generating the OH groups required in the process highly rotting fleshes and household solid waste, whose microbial content is of hundreds of thou- sands of germs. The mixture of peroxides stabilizes all reducing compounds that might be present in house- hold solid waste, in purging sludge, in agricultural and industrial scraps to be stabilized or recycled.

The oxide-destruction reaction, whatever the chemical- physical structures of the materials to be treated, results in an automatic destruction and stabilization of organic and inorganic compounds that might be pre- sent, i. e. for instance: sulfides, cyanides, bivalent iron and manganese, phenols, aldehydes, aromatic amines, sulfurated compounds, carbohydrates, ketones, esters, aliphatic acids and amines, as well as aro- matic compounds with acryl, nitro or unsaturated alkyl

groups, and eventually also poorly reactive compounds, such as benzene, halogenated hydrocarbons and satu- rated aliphatic compounds. The formulation of oxidiz- ing agents is metered for destruction, and thus en- ables the transformation and complete saturation of all aforesaid compounds, allowing to stabilize compost in very short times and not to dispose of reducing compounds. Even more important is for instance the ac- tion of deactivation of infective agents from EST or BSE. Said agents do not survive after oxide- destruction. In particular, as far as flesh destruc- tion is concerned, the microbial load of mesophiles during the first treatment step is of 6. 0 x 109, whereas it is < 1 after depolymerization and repoly- merization process. In other words, the end product is perfectly sterile and therefore suitable for an envi- ronmentally friendly disposal, or it can be used di- rectly also in food-related fields, for instance as substrate for cultivating edible mushrooms, instead of sterilized straw. Expanded polymers have a high chemi- cal stability ; as reticulated polymers they have an excellent resistance to solvents and chemicals in gen- eral. Biological stability has been proved by tests showing how said expanded polymers inoculated with mi- croorganisms present in the soil (Aspergillus, A. fla-

vus, chetomiun globosum) are not characterized by col- ony growth after 28 days. Still said expanded poly- mers, subjected to the action of percolate, have given non-degradation analytical results, as well as those directly buried in dumps and controlled after 18 months have shown no degradation or development of mi- croorganisms. On the basis of said results, as an al- ternative to the use as thermo-acoustic insulating ma- terial, the expanded polymer according to the inven- tion can be produced at high density (1,000 kg/m3) and used for environmental reclamations.

By way of conclusion, in one case the strong super- oxidative reaction causes for instance the demolition- depolymerization of humid and/or green waste and its complete sterilization and stabilization.

In the other case, the repolymerization reaction turns all materials into one expanded polymer with polyure- thane elastic structure and with intercommunicating cells.

The oxide-destruction process according to the present invention therefore sets itself as an environmentally friendly and cheap alternative to traditional thermal destruction and biostabilization carried out with at- mospheric ai-r ; as a matter of fact, it enables the sterilization and biostabilization of waste without

air addition, and the recycling of all waste frac- tions, none being excluded, turning them into sterile biostabilized products and/or expanded polymers.

A brief summary of the advantages of the present in- vention with respect to the prior art of waste dis- posal and recycling is hereinafter displayed by way of example, not binding for the person skilled in the art.

-Oxido-destruction applies to household solid waste, special waste, hospital waste, scrap materials, so as to produce an expanded polymer to be used for environ- mental reclamation (if it is a high-density polymer) or as thermo-acoustic insulating material (if it is a low-density polymer).

- Oxide-reduction applies to animals'carcasses and to slaughtering scraps and scraps of fish industries, with the recovery of biologically sterile water and/or the production of sterile stabile inert substances or of polyglycols for industrial applications, thus avoiding burning or transformation into animals' meals.

- The process is carried out. in a dedicated reactor, either stationary or mobile, with fully automated cy- cle and without polluting emissions of any kind: gas, solid or liquids.

- It is possible to install mobile systems on wheels directly in dumps, slaughterhouses or in firms produc- ing scraps, so as to prevent environmental pollution related to the transfer of materials to be disposed of.

- The oxide-destruction process is fast: the whole automatic continuous cycle lasts for about 10 minutes, preferably even less, including crushing, refining and transformation into a time-stable sterile non- polluting expanded polymer or into a stable sterile biostabilized product.

-Polymer materials obtained after repolymerization can be re-used to building, road engineering and in- dustrial purposes, thanks to their mechanical stabil- ity, sterility and non-rottenness.

- It is possible to reclaim sites polluted by asbestos powders by spraying onto the polluted area the super- oxidizing mixture and then the repolymerizing mixture, generating on-site the oxido-destruction process with the formation of cellular material free of toxic fi- bers.

- It is possible to remove ammoniacal nitrogen, which is present for instance in the urines of the animals to be transformed, in sludge, in waste, etc. by break- point, after a suitable metering of sodium hypochlo-

rite.

- The oxide-destruction treatment in a continuous re- actor applies to all fractions of solid waste, also to those commonly destined to dumps, without preliminary selection, washing, drying etc. , with the preferential production of expanded polymers at low (-50-200 kg/m3), medium (-200-500 kg/m3) or high (-500-1000 kg/m3) density depending on the destination of the de- sired end product.

- It is possible to carry out a sterile biostabiliza- tion of household solid waste and processing scraps as such, or of the humid and green fraction, via depoly- merization through the super-oxidizing mixture accord- ing to the invention, with the instantaneous produc- tion both of combustible dry sterile biomass and of humid-fraction, or of fresh fertilizing compost to be used as amending material or for recovering dumps.

- It is possible to carry out an instantaneous sterile biostabilizati-on of reducing substances, sludge, nox- ious waste, ashes from burners, drains from tan indus- tries, thanks to the super-oxidizing action catalyzed by the micronized molecular sieves, which further act as trappers for toxic materials, in particular heavy metals.

- It is possible to carry out a convenient recycling

process for rubber, which can be used in the produc- tion of road or sports grounds or anti-vibration sub- strates. After treatment with super-oxidizing mixture and repolymerizing mixture, rubber granules and powder are vulcanized and then laid and rolled ; the substrate thus obtained can be walked on after 120 minutes.

SCHEMATIC EXAMPLE OF SOME PREFERRED APPLICATIONS OF THE INVENTION - Treatment of slaughtering and fish-processing scraps to as to obtain expanded polymer Process steps: -Collecting the animal, animal residues or meals with a suitable box in disinfecting bath, however not com- pulsory though preferable so as to prevent the diffu- sion of stinking polluting substances.

- Introducing the animal or its residues into a crusher, which reduces them to a size below 10 cm.

- A refiner downstream from the crusher further re- duces flesh and bones into small fragments, below one centimeter, practically a mush, so as to make oxida- tive attack easier in the following step inside the process reactor.

- The mush made of flesh and bones is fed into the oxide-destruction reactor. Said reactor comprises two chambers whose section is shaped like a cylinder and a

frustum of cone, containing the reacting mixtures and the catalysts, and one with cylindrical section, as described above. Moreover, the reactor houses inside a mixing and continuous transfer system, comprising a double blade spiral with wear-preventing insert having a decreasing cone-shaped section.

- The mush of flesh and bones, as soon as it gets in contact with the super-oxidizing mixture of the first reactor chamber, undergoes the oxidative demolition- depolymerization process which ends up in 50 seconds.

The time spent inside the first chamber is adjusted so as to enable the complete transformation of flesh into polyglycol.

- Polyglycol is fed into the second reactor chamber, containing the repolymerizing mixture, and here it is mixed intensively with said mixture. The residual oxi- dizing mixture, still present in polyglycol, immedi- ately initiates, and therefore catalyzes, the repoly- merization reaction.

- The mixture undergoing repolymerization is conveyed continuously through the third reactor chamber and discharged into suitable formworks, where the step of repolymerization of the desired expanded polymer is completed and blocks of said polymer having the de- sired shapes are obtained.

The process last on the whole 5 to 15 minutes.

-Biostabilization and/or polymerization of untreated waste or of humid and green fraction Process steps - Material crushing as described above.

- Separation of iron materials and refining.

- Identical super-oxidizing treatment both for materi- als to be depolymerized and biostabilized only, and for those to be converted into expanded polymer; i. e. introduction of. the refined materials into the super- oxidizing bath present in the first reactor chamber shaped like a cylinder and a frustum of cone, equipped inside with a double blade spiral shaped like a frus- tum of cone with wear-preventing insert so as to mix and transfer the material.

- Only for waste to be biostabilized : feeding the oxi- dizing materials inside the first reactor chamber to a two-stage continuous screw press, in order to recycle the super-oxidizing reagent and recover water released during oxidative depolymerization.

-Only for waste to be polymerized: continuous trans- fer and introduction of the oxidative materials into the subsequent repolymerizing reacting bath contained in the second reactor chamber.

- Beginning of repolymerization reaction in the third

cylindrical chamber of the continuous reactor, inside which a double blade cylindrical spiral with wear- preventing insert is operating.

- Discharge into formworks for the formation of blocks of expanded polymer with the desired density, or onto a belt platform with lateral walls for the continuous formation of blocks or plates of said polymer.

- Treatment of household solid and assimilable waste The same processing steps as described above basically apply also to the oxido-destructive treatment of household solid and assimilable waste.

The same treatment can apply to other types of waste.

The materials present in most waste, which can there- fore be treated with the process and system according to the present invention, are generally: Plastic materials in the most different forms and formulations ; # Paper and cardboard not conveyed to separate col- lection because together with. other waste; Processing scraps which cannot be separated from the remaining waste ; Organic substances ; # Inorganic substances ; Iron materials (for sterilization only) ; 'Non-iron materials (for sterilization only) ;

Wood fragments; * Asbestos.

Obviously, the person skilled in the art should regard the list above as purely indicative. The application of the process according to the invention to other types of waste materials should in fact be considered as clearly manifest by such a skilled person.