Title:
INTEGRATED SYSTEM COMPRISING ELECTROCATALYSIS DEVICE OF GLYCEROL AND CHEMICAL CATALYSIS DEVICE OF BIOMASS
Document Type and Number:
WIPO Patent Application WO/2018/012847
Kind Code:
A1
Abstract:
The present invention provides an integrated system comprising: an electrocatalysis device for producing hydrogen by carrying out an oxidation reaction at an anode and a reduction reaction at a cathode through an electrocatalysis of glycerol; and a chemical catalysis device for producing a butene oligomer from lignocellulosic biomass through a hydrogenation reaction process, wherein the hydrogen produced by the electrocatalysis device is used for the production of the butene oligomer by the chemical catalysis device, and the thermal energy of the electrocatalysis device and the chemical catalysis device is exchanged with each other. According to the present invention, the integrated system can reduce the cost of materials of a process for preparing a butene oligomer by using hydrogen, which is a by-product of a process for preparing a glycerol derivative, as a material of a process for preparing the butene oligomer through the integration of materials and energy from the processes for preparing the glycerol derivative and the butene oligomer, and can obtain an effect of reducing energy costs by greatly reducing energy required in an integrated process by supplying, as a part of the thermal energy required at the process for preparing the glycerol derivative, the waste heat of the process for preparing the butene oligomer through the construction of a thermal energy integration network.
Inventors:
KIM HYUNG JU (KR)
HAN JEEHOON (KR)
CHAE HO JEONG (KR)
KIM JEONG-RANG (KR)
JEONG SOON YONG (KR)
KIM BEOM SIK (KR)
HAN JEEHOON (KR)
CHAE HO JEONG (KR)
KIM JEONG-RANG (KR)
JEONG SOON YONG (KR)
KIM BEOM SIK (KR)
Application Number:
PCT/KR2017/007404
Publication Date:
January 18, 2018
Filing Date:
July 11, 2017
Export Citation:
Assignee:
KOREA RES INST CHEMICAL TECH (KR)
International Classes:
C07C2/08; C25B3/23; B01J19/08; C07C11/02; C07C45/38; C07C47/19; C07C51/21; C07C59/10; C07C59/185; C25B1/02
Foreign References:
| KR20070095176A | 2007-09-28 |
Other References:
LEE, SEONHWA ET AL.: "Highly Selective Transformation of Glycerol to Dihydroxyacetone without Using Oxidants by a PtSb/C-Catalyzed Electrooxidation Process", GREEN CHEMISTRY, vol. 18, no. 9, 29 January 2016 (2016-01-29), pages 2877 - 2887, XP 055548222
BYUN, JAEWON ET AL.: "Techno Economic Feasibility Study for Catalytic Butene Oligomers Production from Lignocellulosic Biomass using 2-sec-Butylphenol Solvents", ! 2TH INTERNATIONAL CONFERENCE ON HEAT TRANSFER, FLUID MECHANICS AND THERMODYNAMICS, 11 July 2016 (2016-07-11), Costa de Sol, Spain, pages 1226 - 1231, XP 055548219
SEN, S. MURAT ET AL.: "Production of Butene Oligomers as Transportation Fuels using Butene for Esterification of Levulinic Acid from Lignocellulosic Biomass: Process Synthesis and Teclmoeconomic Evaluation", GREEN CHEMISTRY, vol. 14, no. 12, 2012, pages 3289 - 3294, XP 055548227
BYEON, JAE WON ET AL.: "Process Design for Catalytic Production of Wood Biomass-based butene oligomers and tetrabydrofurfuryl alcohol", 2016 KICHE SPRING MEETING, vol. 22, no. 1, 27 April 2016 (2016-04-27), BEXCO, Busan, Republic of Korea, pages 183, XP009511512
ZHANG, ZHIYONG ET AL.: "Electrocatalytic Oxidation of Glycerol on Pt/C in Anion-exchange Membrane Fuel Cell : Cogeneration of Electricity and Valuable Chemicals", APPLIED CATALYSIS B: ENVIRONMENTAL, vol. 119, no. 120, 17 February 2012 (2012-02-17), pages 40 - 48, XP 028481490
CATAL. TODAY, vol. 37, 1997, pages 405
BYUN, JAEWON ET AL.: "Techno Economic Feasibility Study for Catalytic Butene Oligomers Production from Lignocellulosic Biomass using 2-sec-Butylphenol Solvents", ! 2TH INTERNATIONAL CONFERENCE ON HEAT TRANSFER, FLUID MECHANICS AND THERMODYNAMICS, 11 July 2016 (2016-07-11), Costa de Sol, Spain, pages 1226 - 1231, XP 055548219
SEN, S. MURAT ET AL.: "Production of Butene Oligomers as Transportation Fuels using Butene for Esterification of Levulinic Acid from Lignocellulosic Biomass: Process Synthesis and Teclmoeconomic Evaluation", GREEN CHEMISTRY, vol. 14, no. 12, 2012, pages 3289 - 3294, XP 055548227
BYEON, JAE WON ET AL.: "Process Design for Catalytic Production of Wood Biomass-based butene oligomers and tetrabydrofurfuryl alcohol", 2016 KICHE SPRING MEETING, vol. 22, no. 1, 27 April 2016 (2016-04-27), BEXCO, Busan, Republic of Korea, pages 183, XP009511512
ZHANG, ZHIYONG ET AL.: "Electrocatalytic Oxidation of Glycerol on Pt/C in Anion-exchange Membrane Fuel Cell : Cogeneration of Electricity and Valuable Chemicals", APPLIED CATALYSIS B: ENVIRONMENTAL, vol. 119, no. 120, 17 February 2012 (2012-02-17), pages 40 - 48, XP 028481490
CATAL. TODAY, vol. 37, 1997, pages 405
Attorney, Agent or Firm:
LEE, Won Hee (KR)
Download PDF: