Title:
LIGAND, METAL COMPLEX CONTAINING LIGAND, AND REACTION USING METAL COMPLEX CONTAINING LIGAND
Document Type and Number:
WIPO Patent Application WO/2014/136795
Kind Code:
A1
Abstract:
A hydrogen transfer reaction can be more efficiently promoted by using a metal complex that is represented by general formula (2). Specifically, a hydrogenation reaction can be caused to proceed with respect to various base materials which have a stable carbonyl group or the like under mild conditions with high yield.
(In the formula, R1-R8 may be the same as or different from each other, and each represents a hydrogen atom, a substituted or unsubstituted alkyl group or the like, or alternatively, R1 and R2, R2 and R3, R3 and R4, R4 and R5, and R5 and R6 may respectively combine together to form a divalent hydrocarbon group; R9 moieties may be the same as or different from each other, and each represents an alkyl group or a cycloalkyl group; M represents a ruthenium (Ru) atom or the like; X represents a ligand; and n represents 0, 1 or 2.)
Inventors:
SAITO SUSUMU (JP)
NOYORI RYOJI (JP)
MIURA TAKASHI (JP)
NARUTO MASAYUKI (JP)
IIDA KAZUKI (JP)
TAKADA YUKI (JP)
TODA KATSUAKI (JP)
NIMURA SOTA (JP)
AGRAWAL SANTOSH (JP)
LEE SUNKOOK (JP)
NOYORI RYOJI (JP)
MIURA TAKASHI (JP)
NARUTO MASAYUKI (JP)
IIDA KAZUKI (JP)
TAKADA YUKI (JP)
TODA KATSUAKI (JP)
NIMURA SOTA (JP)
AGRAWAL SANTOSH (JP)
LEE SUNKOOK (JP)
Application Number:
PCT/JP2014/055510
Publication Date:
September 12, 2014
Filing Date:
March 04, 2014
Export Citation:
Assignee:
UNIV NAGOYA NAT UNIV CORP (JP)
International Classes:
C07F9/58; B01J31/24; C07C29/145; C07C29/149; C07C31/04; C07C31/20; C07C33/20; C07C33/22; C07C33/24; C07C209/50; C07C211/27; C07C213/02; C07C215/08; C07F9/6561; C07B61/00; C07F15/00; C07F15/02; C07F15/04
Domestic Patent References:
| WO2012102247A1 | 2012-08-02 | |||
| WO2012102247A1 | 2012-08-02 | |||
| WO2012102247A1 | 2012-08-02 |
Foreign References:
| JP2011037809A | 2011-02-24 | |||
| JP2010215604A | 2010-09-30 | |||
| US20120253042A1 | 2012-10-04 |
Other References:
ZIESSEL, R.: "A new family of aromatic polyimine chelates substituted with two diphenylphosphines", TETRAHEDRON LETTERS, vol. 30, no. 4, 1989, pages 463 - 466, XP055279844
LANGER, R. ET AL.: "Stepwise metal-ligand cooperation by a reversible aromatization/ deconjugation sequence in ruthenium complexes with a tetradentate phenanthroline-based ligand", CHEMISTRY - A EUROPEAN JOURNAL, vol. 19, no. 10, 29 January 2013 (2013-01-29), pages 3407 - 3414, XP055279846
LIU, X. ET AL.: "Flexible Redox-Active Binuclear Macrocycles Formed via the Weak-Link Approach and Novel Hemilabile Ligands with N,N,N',N'- Tetramethyl-1,4-phenylenediamine Units", INORGANIC CHEMISTRY, vol. 40, no. 13, 2001, pages 2940 - 2941, XP055279847
See also references of EP 2966081A4
LANGER, R. ET AL.: "Stepwise metal-ligand cooperation by a reversible aromatization/ deconjugation sequence in ruthenium complexes with a tetradentate phenanthroline-based ligand", CHEMISTRY - A EUROPEAN JOURNAL, vol. 19, no. 10, 29 January 2013 (2013-01-29), pages 3407 - 3414, XP055279846
LIU, X. ET AL.: "Flexible Redox-Active Binuclear Macrocycles Formed via the Weak-Link Approach and Novel Hemilabile Ligands with N,N,N',N'- Tetramethyl-1,4-phenylenediamine Units", INORGANIC CHEMISTRY, vol. 40, no. 13, 2001, pages 2940 - 2941, XP055279847
See also references of EP 2966081A4
Attorney, Agent or Firm:
SAEGUSA & PARTNERS (JP)
Patent business corporation 3 Edakuni [Hajime] patent firm (JP)
Patent business corporation 3 Edakuni [Hajime] patent firm (JP)
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