Title:
METAL COMPLEX AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2008/072758
Kind Code:
A1
Abstract:
Disclosed is a metal complex represented by the formula (A-1) or (B-1) below. This metal complex is excellent in heat resistance and acid resistance, and useful for redox reaction catalysts and the like.
Inventors:
MATSUNAGA TADAFUMI (JP)
KOSHINO NOBUYOSHI (JP)
HIGASHIMURA HIDEYUKI (JP)
KOSHINO NOBUYOSHI (JP)
HIGASHIMURA HIDEYUKI (JP)
Application Number:
PCT/JP2007/074191
Publication Date:
June 19, 2008
Filing Date:
December 11, 2007
Export Citation:
Assignee:
SUMITOMO CHEMICAL CO (JP)
MATSUNAGA TADAFUMI (JP)
KOSHINO NOBUYOSHI (JP)
HIGASHIMURA HIDEYUKI (JP)
MATSUNAGA TADAFUMI (JP)
KOSHINO NOBUYOSHI (JP)
HIGASHIMURA HIDEYUKI (JP)
International Classes:
C07D257/10; B01J31/22; C07D487/18; C08G85/00; C07F15/06
Other References:
KUMAR D.S. ET AL.: "Macrocyclic complexes of lanthanides in identical ligand frameworks. Part 1. Synthesis of lanthanide(III) and yttrium(III) complexes of an 18-membered dioxatetraaza macrocycle", INORGANICA CHIMICA ACTA, vol. 238, no. 1-2, 1995, pages 63 - 71
ROZNYATOVSKY V. ET AL.: "Dinuclear and polynuclear transition metal complexes with macrocyclic ligands. 6. New dinuclear copper(II) complexes with macroyclic Schiff bases derived from 4-tert-butyl-2,6-diformylphenol", RUSSIAN CHEMICAL BULLETIN, vol. 53, no. 6, 2004, pages 1208 - 1217, XP019224306, DOI: doi:10.1023/B:RUCB.0000042275.94158.b6
USTYNYUK Y.A. ET AL.: "Binuclear and polynuclear transition metal complexes with macrocyclic ligands. 2. New macrocyclic Schiff's base in the reaction of 4-tert-butyl-2,6-diformylphenol with 1,2-diaminobenzene. Synthesis and structural, spectroscopic, and theoretical study", RUSSIAN CHEMICAL BULLETIN, vol. 51, no. 3, 2002, pages 488 - 498, XP019224164, DOI: doi:10.1023/A:1015564403703
KISHORE M.J.L. ET AL.: "An alumina-supported homonuclear macrocyclic zirconium complex for reformation of n-hexane", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 216, no. 1, 2004, pages 157 - 163
BRYCHCY K. ET AL.: "Complexes with macrocyclic ligands. III. Mono- and dinuclear macrocyclic transition metal complexes of ligands of Schiff base type: syntheses, structures, electro- and magnetochemical properties", CHEMISCHE BERICHTE, vol. 127, no. 10, 1994, pages 1817 - 1826
CASELLATO U. ET AL.: "Mononuclear, homo- and heteropolynuclear complexes with acyclic compartmental Schiff bases", INORGANICA CHIMICA ACTA, vol. 207, no. 1, 1993, pages 39 - 58
AGUIARI A. ET AL.: "Macrocyclic and macrocyclic compartmental Schiff bases: synthesis, characterization, X-ray structure and interaction with metal ions", INORGANICA CHIMICA ACTA, vol. 202, no. 2, 1992, pages 157 - 171
LAM F. ET AL.: "Synthesis of Dinucleating Phenanthroline-Based Ligands", TETRAHEDRON, vol. 55, no. 28, 1999, pages 8377 - 8384, XP004170003, DOI: doi:10.1016/S0040-4020(99)00428-7
ROZNYATOVSKY V. ET AL.: "Dinuclear and polynuclear transition metal complexes with macrocyclic ligands. 6. New dinuclear copper(II) complexes with macroyclic Schiff bases derived from 4-tert-butyl-2,6-diformylphenol", RUSSIAN CHEMICAL BULLETIN, vol. 53, no. 6, 2004, pages 1208 - 1217, XP019224306, DOI: doi:10.1023/B:RUCB.0000042275.94158.b6
USTYNYUK Y.A. ET AL.: "Binuclear and polynuclear transition metal complexes with macrocyclic ligands. 2. New macrocyclic Schiff's base in the reaction of 4-tert-butyl-2,6-diformylphenol with 1,2-diaminobenzene. Synthesis and structural, spectroscopic, and theoretical study", RUSSIAN CHEMICAL BULLETIN, vol. 51, no. 3, 2002, pages 488 - 498, XP019224164, DOI: doi:10.1023/A:1015564403703
KISHORE M.J.L. ET AL.: "An alumina-supported homonuclear macrocyclic zirconium complex for reformation of n-hexane", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 216, no. 1, 2004, pages 157 - 163
BRYCHCY K. ET AL.: "Complexes with macrocyclic ligands. III. Mono- and dinuclear macrocyclic transition metal complexes of ligands of Schiff base type: syntheses, structures, electro- and magnetochemical properties", CHEMISCHE BERICHTE, vol. 127, no. 10, 1994, pages 1817 - 1826
CASELLATO U. ET AL.: "Mononuclear, homo- and heteropolynuclear complexes with acyclic compartmental Schiff bases", INORGANICA CHIMICA ACTA, vol. 207, no. 1, 1993, pages 39 - 58
AGUIARI A. ET AL.: "Macrocyclic and macrocyclic compartmental Schiff bases: synthesis, characterization, X-ray structure and interaction with metal ions", INORGANICA CHIMICA ACTA, vol. 202, no. 2, 1992, pages 157 - 171
LAM F. ET AL.: "Synthesis of Dinucleating Phenanthroline-Based Ligands", TETRAHEDRON, vol. 55, no. 28, 1999, pages 8377 - 8384, XP004170003, DOI: doi:10.1016/S0040-4020(99)00428-7
Attorney, Agent or Firm:
ENOMOTO, Masayuki et al. (Limited 5-33, Kitahama 4-chome, Chuo-ku, Osaka-sh, Osaka 50, JP)
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