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Title:
(METH)ACRYLATE ESTERS, STARTING ALCOHOLS FOR THE PREPARATION THEREOF, PROCESSES FOR PREPARING BOTH, POLYMERS OF THE ESTERS, CHEMICALLY AMPLIFIABLE RESIST COMPOSITIONS, AND METHOD FOR FORMING PATTERNS
Document Type and Number:
WIPO Patent Application WO/2002/046179
Kind Code:
A1
Abstract:
(Meth)acrylate esters represented by the general formula (1). These esters can be prepared by preparing a product of addition of a 1,3-diene with maleic anhydride by Diels-Alder reaction, reducing this product into a lactone, hydrating this lactone into an alcohol, and esterifying this alcohol with (meth)acrylic acid. The (co)polymers produced by (co)- polymerizing monomer compositions containing the (meth)- acrylate esters are excellent in transparency, dry-etching resistance, and solubility in organic solvents, and useful as resins for chemically amplifiable resist compositions. (1) (In the general formula (1), R?1¿, R?2¿, R?3¿, and R?4¿ are each hydrogen, methyl, or ethyl; one of X?1¿ and X?2¿ is (meth)acryloyloxy and the other is hydrogen; and both A?1¿ and A?2¿ are hydrogen, or alternatively A?1¿ and A?2¿ are united to form -O-, -CH¿2?-, or -CH¿2?CH¿2?-.)

Inventors:
KAMON YOSHIHIRO (JP)
FUJIWARA TADAYUKI (JP)
KUWANO HIDEAKI (JP)
MOMOSE HIKARU (JP)
KOIZUMI ATSUSHI (JP)
Application Number:
PCT/JP2001/010628
Publication Date:
June 13, 2002
Filing Date:
December 05, 2001
Export Citation:
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Assignee:
MITSUBISHI RAYON CO (JP)
KAMON YOSHIHIRO (JP)
FUJIWARA TADAYUKI (JP)
KUWANO HIDEAKI (JP)
MOMOSE HIKARU (JP)
KOIZUMI ATSUSHI (JP)
International Classes:
C07D307/88; C07D307/93; C07D493/18; C08F220/18; C08F220/28; G03F7/039; (IPC1-7): C07D307/93; C07D307/77; C07D307/88; C07D493/18
Foreign References:
US4187236A1980-02-05
JP2002006502A2002-01-09
Other References:
MORI, K. ET AL.: "Synthetic microbial chemistry. XXV. synthesis of the enantiomers of differolide (4-(2',5'-dihydro-2'-oxo-3'-furanyl)-3a,4,5,6-tetrahydro-1(3H)-isobenzofuranone), a microbial bioregulators for the formation of aerial mycelium and spores of streptomyces.....", LIEBIGS ANN. CHEM., no. 6, 1993, pages 671 - 681, XP002909332
NUMATA, A. ET AL.: "Synthesis of pyrolysis products of bisdehydrodihydroenmein. I. synthesis of 6-hydroxy-7-methylphthalide and 2-(hydroxymethyl)-6,6-dimethyl-5-oxo-1-cyclohexenecarboxylic acid lactone", YAKUGAKU ZASSHI, vol. 88, no. 9, 1968, pages 1151 - 1162, XP002909340
See also references of EP 1352904A4
Attorney, Agent or Firm:
Kaneda, Nobuyuki (16th Kowa Bldg. 9-20 Akasaka 1-chome Minato-ku, Tokyo, JP)
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