Login| Sign Up| Help| Contact|

Patent Searching and Data


Title:
METHOD AND APPARATUS FOR CONTROLLING A STABLE EMULSION
Document Type and Number:
WIPO Patent Application WO/2010/134821
Kind Code:
A1
Abstract:
An emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil comprises a generally horizontal and elongate vessel (10) constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet (12), an oil outlet (22), a water outlet (24), and at least one coalescer element (16, 18) supported within the vessel (10). At least one electrostatic element (26) is electrically connected to a power supply and control unit (42) and supported within the vessel (10) such that the electrostatic element (26) is immersed in oil and at a distance from an interface (I) between the oil and water (W) which occurs in the vessel when the apparatus is in use, said water (W) providing an electrical ground component whereby an electrostatic field is induced between the electrostatic element (26) and the water (W). The electrostatic element (26) may comprise a generally horizontal electrostatic grid.

Inventors:
SMUIN DONALD R (CA)
D SOUZA LOUIS (CA)
MULVEY J STEWART (CA)
Application Number:
PCT/NO2010/000179
Publication Date:
November 25, 2010
Filing Date:
May 14, 2010
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
AKER PROCESS SYSTEMS AS (NO)
SMUIN DONALD R (CA)
D SOUZA LOUIS (CA)
MULVEY J STEWART (CA)
International Classes:
B03C11/00; C10G33/02
Foreign References:
US4252631A1981-02-24
US4329159A1982-05-11
US4469582A1984-09-04
Attorney, Agent or Firm:
ONSAGERS AS et al. (Oslo, NO)
Download PDF:
Claims:
CLAIMS

1. An emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, comprising a generally horizontal and elongate vessel (10) constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet (12), an oil outlet (22), a water outlet (24), and at least one coalescer element (16, 18) supported within the vessel (10), characterized by a device for controlling or preventing the formation of a rag layer emulsion (R) in the emulsion treating apparatus, comprising at least one electrostatic element (26) electrically connected to a power supply and control unit (42) and supported within the vessel (10) such that the electrostatic element (26) is immersed in oil and at a distance from an interface (I) between the oil and water (W) which occurs in the vessel when the apparatus is in use, said water (W) providing an electrical ground component whereby an electrostatic field is induced between the electrostatic element (26) and the water (W), and wherein the power supply and control unit (42) comprises a self-controlling and short-circuit proof transformer unit, whereby the formation of a rag layer emulsion in the vessel (10) may be controlled or prevented.

2. The emulsion treating apparatus of claim 1, wherein the electrostatic element (26) comprises a generally horizontal electrostatic grid. 3. The emulsion treating apparatus of claim 1 or claim 2, wherein the electrostatic element (26) is supported downstream of the at least one coalescer element (16, 18).

4. The emulsion treating apparatus of any one of claims 1 to 3, wherein the electrostatic element (26) is supported between about 4 inches and about 12 inches from the interface (I).

5. The emulsion treating apparatus of any one of claims 1 to 4, further comprising one or more baffle elements (14, 15) for flow distribution, supported within the vessel.

6. The emulsion treating apparatus of any one of claims 1 to 5, wherein the at least one coalescer element (16, 18) comprises at least one electrostatic grid pair

(16) and at least one matrix pack (18), sequentially spaced within the vessel along the vessel longitudinal direction.

7. The emulsion treating apparatus of any one of claims 1 to 5, wherein the at least one coalescer element comprises vertically oriented electrostatic grid pairs (16), sequentially spaced within the vessel.

8. The emulsion treating apparatus of any one of claims 1 to 5, wherein the at least one coalescer element (18) comprises vertically oriented matrix packs (18), sequentially spaced within the vessel.

9. The emulsion treating apparatus of any one of claims 1 to 8, further comprising a transverse baffle (15), supported upstream of the at least one coalescer element (16, 18).

10. The emulsion treating apparatus of any one of the preceding claims, further comprising at least one heating element (28) supported within the vessel at or near the interface (I), whereby the temperature at or near the interface (I) may be controllably increased to a level above the temperature in the surrounding emulsion, oil and water.

11. The emulsion treating apparatus of claim 10, wherein the heating element (28) comprises at least any one of a selection of a heating coil, a bare or a finned tube through which a high-temperature heating fluid from an external source is circulated.

12. The emulsion treating apparatus of claim 11, further comprising a heating fluid re-cycle line (24a) for feeding water (W) separated from the emulsion to the heating element (28), where is circulated though the heating element as a high- temperature heating fluid. 13. The emulsion treating apparatus of claim 10, wherein the heating element (28) comprises an electrically powered heating element.

14. The emulsion treating apparatus of any one of claims 10 to 14, wherein the heating element (28) is supported downstream of the at least one coalescer element (16, 18). 15. A method of controlling or preventing the formation of a rag layer emulsion (R) forming in or near an interface (I) between oil and water (W) in an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, said treating apparatus comprising a generally horizontal and elongate vessel (10) constructed and arranged for longitudinal flow of emulsion therethrough and further comprising an emulsion inlet (12), an oil outlet (22), a water outlet (24), and at least one coalescer element (16, 18) supported within the vessel (10), said method being characterized by generating an electrostatic field in the vessel (10) between a position within the oil and the interface (I) and the rag layer emulsion (R); and electrically grounding the interface (I) and the rag layer emulsion (R); whereby an electrical field is induced through the rag layer emulsion (R) thereby promoting coalescing within the rag layer emulsion.

16. The method of claim 15, further comprising adjustment of the electrostatic field and adjustment of said distance.

17. The method of claim 16, wherein the distance is adjusted to a distance between about 4 inches and about 12 inches. 18. The method of any one of claims 15 to 17, wherein the electrostatic field is generated in a region within the vessel (10) downstream of the at least one coalescer element (16, 18).

19. The method of any one of claims 15 - 18, further heating the region of the interface (I) and the rag layer emulsion (R) to a temperature which is higher than the surrounding emulsion.

20. The method of claim 19, wherein said temperature is about 5 0C higher than the surrounding emulsion.

21. The method of claim 19 or claim 20, wherein the heating is performed in a region within the vessel (10) downstream of the at least one coalescer element (16, 18).

Description:
Method and apparatus for controlling a stable emulsion

Field of the Invention

The invention relates generally to emulsion treating, and more particularly to a coalescer for separating emulsified water and solids from oil during longitudinal flow through a horizontally extending tank. More specifically, the invention relates to a method and a device for controlling the thickness of, and/or substantially preventing the formation of, a stable emulsion layer in an emulsion treating apparatus. The invention applies to all horizontally flowing gas-liquid-liquid gravity separation devices and horizontally flowing liquid-liquid gravity separation devices, comprising devices such as 3 -Phase Separators, FWKOs, Heater-Treaters, Treaters, Electrical Treaters and Desalters.

Background of the Invention It is well known that petroleum as it is naturally produced from a subterranean formation (commonly referred to as "crude") must be treated so as to separate and remove entrained gas, produced water or solids, in order to render the oil in a condition where it can be further transported (e.g. in a pipeline) and processed. Various techniques and processes have heretofore been employed in order to minimize treatment time and avoid high-energy consumption. The produced water may be either connate water, or water that has been injected for enhanced oil recovery purposes, and can be either fresh or saline (brine) in nature.

The produced water and solids are separated from the oil by gravity. One widely used process is to flow the produced crude though an elongated horizontal separation vessel (commonly referred to as a "treater"), wherein the oil, gas, produced water and solids constituents are separated. In some cases it is necessary to pre-heat the crude prior to separation, and a heater section is then added upstream of the treater. In such case the heater section and the treater are commonly incorporated into one vessel (commonly referred to as a "heater treater"). Gravity separation of oil and water is governed by Stoke's Law, which states that the settling velocity is proportional to the square of the water particle size. In practical design of separation vessels, this principle is used in order to speed up the separation process in the treater and thereby (among other benefits) permitting the use of smaller separation vessels. For example, doubling the size of the water particles to be separated out will increase the settling velocity by 4 times, thus allowing a 75% reduction of treater size. It is known in the art to use mechanical devices (such as matrix packs) and/or electrostatic grids- separately or in pairs, in order to grow such larger water particles and thus enhancing the separation process and allowing smaller separation vessels.

United States Patent No. 4 329 159, entitled "Energy Saving Heavy Crude Oil Emulsion Treating Method and Apparatus for Use Therewith", describes a method and apparatus comprising an elongated horizontal cylindrical tank, divided by internal partitions, into compartments through which the petroleum will sequentially flow. Burner-fired heaters are normally included in an upstream heater section for heating the emulsion to a desired temperature, during which most of the entrained gas and some of the produced water will separate from the emulsion. The partially de-emulsified produced water then flows into a coalescing section, encountering a series of baffles adapted to encourage even flow of fluids and to avoid the formation of flow channels within the fluid body. Additionally, high-potential electrostatic fields are applied by energizing grids with high voltage potential. The grids are adjacent to each grounded baffle, which creates the fields between each grid and grounded baffle.

Canadian Patent No. 2 329 224, entitled "Energy- Saving Heavy Crude Oil Emulsion- Treating Apparatus", describes a treater for electrostatically separating emulsified produced water from oil during longitudinal flow through a horizontally elongated coalescing section. The treater has a number of baffles with adjacent electrostatic wing grids therein. The electrostatic wing grids are externally connected to one or more transformers so that a higher voltage may be applied to subsequent grids along the coalescing section. Each of the electrostatic wing grids includes a front face and perpendicular side edges and a perpendicular bottom edge to extend the electrostatic field out beyond the front face, so as to enhance the electrostatic action and more efficiently remove water from the emulsion. The baffles preferably extend downwardly to a water/oil interface, so as to increase the coalescing efficiency of the emulsion flowing through the coalescing section and ensure that the electrostatic field is applied to the emulsion.

United States Patent No. 6 207 032, entitled "Electrostatic/Mechanical Emulsion Treating Method and Apparatus", describes a treater for electrostatically and/or mechanically separating emulsified produced water from oil during longitudinal flow through a horizontally elongated metal tank. Adjustable distributor elements are provided for enhancement of the de-emulsification process. The adjustable distributor elements may be externally operated to more closely control the diffusion and distribution of the flowing emulsion across the transverse area of the treater. The emulsion may be first directed through electrical fields, upstream of the distributor elements, where the produced water droplets take on an electrical charge, then move through the distributor elements to electrically grounded coalescing elements. De-emulsified oil is removed in a stream separate from the produced water stream. The treater also operates mechanically, with reduced efficiency, when electrostatic operation is unavailable, and can also be operated if coalescing elements are not used. The externally-adjustable, louvered baffles may be accompanied by fixed, non-adjustable louvers at intermediate spacing between the externally-adjustable louvers to provide additional coalescing and flow direction that will enhance dehydration of the process stream, and become an integral extension component thereof.

Equipment for processing oils is subject to a phenomenon referred to as a "rag layer", in some contexts also referred to as a "cuff layer" or a "pad layer"; i.e. the formation of a stable oil-water-solids emulsion. The solids components may consist of small sized and oil- wet solids (like clay) and precipitated high mole weight hydrocarbons (like asphaltenes). These are the building blocks for rag. The oil- water-solids rag composition results in a mixture that is heavier than oil but floats on water. It is caused by flow channeling (or stagnant zones) and thermal cooling primarily under process upsets or turn down conditions. The cooling leads to a change in viscosity, as well as a change in the densities of the oil and water preventing separation of the emulsion in these localized areas. This denser emulsion promotes the capture of the solids components creating a very stable oil-water-solids mixture that will continue to increase in density. With horizontal fluid flow, the rag layer migrates in the direction of fluid flow to the outlet end, becoming thicker and thicker with time, in this non-flowing zone.

The rag layer problem is normally experienced with oil having an API gravity below approximately 30. The term "heavy oils" is commonly used for oil having an API gravity of < approximately 20, "extra heavy oil" as having an API gravity < approximately 12, while oil sands bitumen normally has an API gravity < approximately 9. The heavier the oil, the more stable the rag layer will be once it is formed, and thus more difficult to break up. The rag layer build-up is therefore a particular problem in equipment for processing heavy oils, extra heavy oils and oil sands bitumen.

There are a variety of processes for producing bitumen from oil sands. One such process is termed "SAGD" (Steam Assisted Gravity Drainage), in which steam is injected from a pipe above an oil collector pipe. The steam melts the bitumen and it flows by gravity to the oil collection pipe below. Another process is termed "cyclic steam", where steam first is injected into a pipe, and then after a time the produced bitumen and condensed water is pumped out of the same pipe. A third process is "THAI" (or "Toe to Heel Air Injection"), which is a fire flood where air is injected into the reservoir and the bitumen is burnt as fuel. The heat front melts the bitumen which is collected from a separate well. In addition, there are new experimental systems where petroleum solvents are injected into the oil sands with steam to help dissolve the bitumen. Bitumen produced either by the SAGD, cyclic steam or THAI methods is normally sufficiently hot for separation when it emerges from the reservoir. It may therefore be flowed directlyϊnto the treater, and a heater section is not required. With the production of bitumen, as compared to conventional heavy oil, there is often a need to add a diluent (lighter petroleum oils or naphtha), which causes asphaltenes to precipitate out. In addition, the oil sand production also yields a considerable amount of fine clay. This fine clay bonds with the water and asphaltenes and makes the rag layer with the oil sand production very difficult to break down.

In the treatment of conventional heavy oils, generally referred to as Cold Heavy Oil Production (or CHOP's) since the oil is fluid enough to flow naturally out of the well bore, the processing or separation of the oil-water-solids is done using fired equipment or "heater treaters". Here the usual practice is to draw off (blow-down) the rag layer to a slop tank and then recycle it back to the inlet of the treater and reheat it with the normal production fluids.

With the bitumen production associated with the oil sands using the existing thermal extraction technologies (SAGD 3 Cyclic Steam, THAI) the process heat is input into the reservoir in order to get the bitumen to flow. No additional processing heat is incorporated into the separation equipment. Here, treating the rag layer by conventional recycle from a slop tank, or by direct recycle from the process vessel into the hot well head or inlet production fluids has been unsuccessful.

When using the SAGD process to produce oil sands bitumen, asphaltenes tend to precipitate out of the bitumen and bond with clays suspended in the produced water, thus creating the rag layer. The asphaltenes/clays tend bond or adhere to internal instrumentation surfaces used to control the oil water interface and detect the rag layer. This build up renders the instrumentation ineffective leading to off- specification production in both the oil and water phases, as eventually the rag will be carried over in either or both these product streams.

Therefore, there exists a need for a method and an apparatus for effectively preventing and controlling the formation of a rag layer.

Summary of the Invention The present invention meets that need, in that it provides an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, characterized by at least one electrostatic element electrically connected to a power supply and control unit and supported within the vessel such that the electrostatic element is immersed in oil and at a distance from an interface between the oil and water which occurs in the vessel when the apparatus is in use, said water providing an electrical ground component whereby an electrostatic field is induced between the electrostatic element and the water.

In an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, there is provided a device for controlling the thickness of a stable emulsion layer forming in or near an interface between the oil and water in the vessel when the apparatus is in use, comprising at least one electrostatic element electrically connected to a power supply and control unit and supported within the vessel such that it is immersed in oil and at a distance from the interface and the stable emulsion layer, said stable emulsion layer and/or water providing an electrical ground component whereby an electrical field is induced between the electrostatic element, the stable emulsion layer and the water, thus promoting coalescing of water droplets within the stable emulsion layer.

The electrostatic element may comprise a generally horizontal electrostatic grid. The electrostatic element may be supported downstream of the at least one coalescer element, and in one embodiment between about 4 inches and about 12 inches from the interface.

In one embodiment, one or more baffle elements for flow distribution, are supported within the vessel. In one embodiment, the at least one coalescer element comprises at least one electrostatic grid pair and at least one matrix pack, sequentially spaced within the vessel along the vessel longitudinal direction. The at least one coalescer element may comprise vertically oriented electrostatic grid pairs, sequentially spaced within the vessel. The at least one coalescer element may comprise vertically oriented matrix packs, sequentially spaced within the vessel. A transverse baffle may be supported upstream of the at least one coalescer element.

It is also provided an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, characterized by at least one heating element supported within the vessel at or near an interface between the emulsion or oil and water which occurs in the vessel when the apparatus is in use, whereby the temperature at or near the interface may be controllably increased to a level above the temperature in the surrounding emulsion, oil and water.

In an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, there is provided a device for controlling and substantially preventing the formation of a stable emulsion layer in or near an interface between the emulsion or oil and water in the vessel when the apparatus is in use, comprising at least one heating element supported within the vessel at or near the interface, whereby the temperature at or near the interface may be controllably increased to a level above the temperature in the surrounding emulsion, oil and water. The heating element may comprise at least any one of a selection of a heating coil, a bare or a finned tube through which a high-temperature heating fluid from an external source is circulated.

In one embodiment, the emulsion treating apparatus further comprises a heating fluid re-cycle line for feeding water separated from the emulsion to the heating element, where is circulated though the heating element as a high-temperature heating fluid. The heating element may comprise an electrically powered heating element. The heating element is in one embodiment supported downstream of the at least one coalescer element.

In one embodiment, one or more baffle elements for flow distribution, are supported within the vessel. The at least one coalescer element may comprise at least one electrostatic grid pair and at least one matrix pack, sequentially spaced within the vessel along the vessel longitudinal direction.

The coalescer elements may in one embodiment comprise vertically oriented electrostatic grid pairs, sequentially spaced within the vessel. The at least one coalescer element may comprise vertically oriented matrix packs, sequentially spaced within the vessel.

The flow distribution devices may comprise a transverse baffle, supported upstream of the at least one coalescer element.

It is also provided an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, characterized in that it comprises at least one electrostatic element according to the invention as described above and at least one heating element according to the invention as described above. There is also provided a method of controlling the thickness of a stable emulsion layer forming in or near an interface between oil and water in an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, said treating apparatus comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and further comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, the method being characterized by generating an electrostatic field in the vessel between a position within the oil and the interface and the stable emulsion layer; and electrically grounding the interface and the stable emulsion layer; whereby an electrical field is induced through the stable emulsion layer thereby promoting coalescing within the stable emulsion layer.

The method may also comprise adjustment of the electrostatic field and adjustment of said distance. In one embodiment, the distance is adjusted to a distance between about 4 inches and about 12 inches. In an embodiment, the electrostatic field is generated in a region within the vessel downstream of the at least one coalescer element.

There is also provided a method of controlling and substantially preventing the formation of a stable emulsion layer in or near an interface between oil and water in an emulsion treating apparatus for separating an emulsion of emulsified produced water droplets and oil, said treating apparatus comprising a generally horizontal and elongate vessel constructed and arranged for longitudinal flow of emulsion therethrough and further comprising an emulsion inlet, an oil outlet, a water outlet, and at least one coalescer element supported within the vessel, the method being characterized by heating the region of the interface and the stable emulsion layer to a temperature which is higher than the surrounding emulsion.

In one embodiment, said temperature is about 5 0 C higher than the surrounding emulsion. In one embodiment, the heating is performed in a region within the vessel downstream of the at least one coalescer element.

Brief description of the drawings

These and other characteristics of the invention will be clear from the following description of embodiment of the invention, given as non-restrictive examples, with reference to the attached drawings, wherein:

Fig. 1 and Fig. 2 are schematic side elevation views of the coalescing section of respective horizontally- extending tank oil treaters in the form of elongated, horizontally flowing gas-liquid-liquid separation devices, illustrating an embodiment of the invention; Fig. 3 is a schematic side elevation view of the coalescing section of a horizontally- extending tank oil treater in the form of an elongated, horizontally flowing gas- liquid-liquid separation device, illustrating a second embodiment of the invention;

Fig. 4 is a schematic side elevation view of the coalescing section of a horizontally- extending tank oil treater in the form of an elongated, horizontally flowing gas- liquid-liquid separation device, illustrating a third embodiment of the invention; and

Fig. 5 is a schematic side elevation view of the coalescing section of a horizontally- extending tank oil treater in the form of an elongated, horizontally flowing gas- liquid-liquid separation device, illustrating a fourth embodiment of the invention. Fig. 6 and Fig. 7 are schematic side elevation views of the coalescing section of respective horizontally- extending tank oil treaters in the form of elongated, horizontally flowing gas-liquid-liquid separation devices, illustrating embodiments similar to those of Figs. 2 and 3, respectively, in a process configuration where the density of the bitumen is greater than the density of the produced water.

Detailed description of preferred embodiments

Fig. 1 shows a horizontally extending elongated treater vessel 10, having an inlet 12 through which crude (emulsion) to be separated is fed, an oil outlet 22, a water outlet 24, a gas outlet 20, a weir 19 defining an upstream sand dam, and a transverse baffle 15. Crude in this context comprises an emulsion of emulsified produced water droplets, solids and semi-solids and oil, hereinafter referred to as emulsion E. A transverse baffle 15 and a plurality of diffusion baffles 14 are supported at intervals in the treater vessel 10. There is a need to establish a uniform plug flow through the treater; any velocity channelling, resulting in differential cooling of the crude, is undesirable. Thus, the transverse baffle 15 is an initial flow distribution device (or bulk separation device) in which the water W is forced down under the baffle, while the inlet emulsion E is feed through a distribution channel in the transverse baffle in the centre of the oil emulsion layer. The diffusion baffles 14 serve a similar purpose, i.e. providing a uniform flow distribution and thus preventing flow channelling.

Fig. 1 also shows a plurality of matrix packs 18, which are mechanical coalescing devices as described in the Background of the Invention, and well known in the art. Although Fig. 1 shows a plurality of matrix packs, the skilled person knows that only one matrix pack may be sufficient, depending on the specific crude application.

When the treater Υessel 10 is in operation, emulsion E enters the treater vessel 10 through the inlet 12. The emulsion may have been subjected to a pre-heating, either by virtue of the method of extraction from the reservoir (e.g. the SAGD method, as described above) or in a heater section upstream of the treater vessel. In the latter case, the heater section and the treater section are normally integrated into one vessel commonly referred to as a "heater treater", and the emulsion flows into the treater section from the upstream heater section.

As the emulsion flows through the matrix packs 18, water W is separated from the emulsion due to gravity, as explained above. The separated water W is discarded from the vessel 10 via the water outlet 24. Any gas G released from the emulsion is discarded from the vessel via the gas outlet 20, and the treated oil is flowed out of the vessel via the oil outlet 22.

In order to control the thickness of the stable emulsion (i.e. the rag layer) R which tends to build up in the oil/water interface as explained above, the vessel 10 also comprises an electrostatic grid 26, which is an element supported within the vessel 10 such that it is immersed in the oil and at a distance from the oil/water interface I which occurs when the vessel is in normal operation. The electrostatic grid is supported such that it is substantially parallel with the interface I. Under normal operating conditions, the electrostatic grid is thus substantially horizontal and extends in the vessel's horizontal plane. The electrostatic grid 26 is electrically connected to a power supply and control unit 42, whereas the water W, and any stable emulsion (rag layer) R, provide an electrical ground component, whereby an electrostatic field is induced through the rag layer R and electrostatic coalescing takes place in the rag layer. It is this (intense) electrical field between the high voltage energised grid 26 and ground that performs the coalescing of the stable emulsion R. It the rag layer grows in thickness, the space between the electrostatic grid 26 and the rag layer R (electrical ground) decreases, resulting in an increased electrostatic coalescing within the rag layer R. The rag layer R may thus be kept to a minimum desired thickness, by controlling the electrostatic field, the electrostatic grid distance from the interface I, or both. The electrostatic grid 26 must be positioned in the relatively non-conductive oil phase and a distance from the interface I and the rag layer R which is sufficient so as to avoid a short circuit. Preferably, the electrostatic grid distance from the interface I is between 4 inches and 12 inches. The skilled person knows that this distance is determined by the voltage applied to the electrostatic grid. As Fig. 1 indicates, the electrostatic grid 26 is preferably positioned in the region of the downstream end of the vessel (also downstream of the matrix packs) where the rag layer formation becomes the thickest.

The skilled individual knows that a process upset could lift the emulsion layer up into the grids 26, creating a dead short situation for the power supply. With the normal power supply system for the conventional electrostatic grids, consisting of a conventional step up transformer 17 (described below with reference to figure 2) this requires the need for current monitoring devices to shut down the power supply upon detection of a high current draw. Ultimate protection in the event of a failure of the monitoring devices is provided by the power breaker feeding the transformer and the design of the transformer itself to be able handle a short circuit. The latter requires the transformer to be of a 100% reactive type. With this conventional control system the power breaker would have to be manually reset once the process upset is cleared, resulting in additional processing down time.

However, the power supply and control unit 42 that would provide power to the rag layer treating grids 26 is a dynamic magnetically controllable transformer unit which is short circuit proof. This is a proprietary system, described by the following patents: US 6 933 822 and US 7 193 495 (basic MCI technology); US 7 026 905 B2 and US 7 256 678 (improved MCI technology); NO 322 439 (MCT power supply); and patent application No. US 2005/076293 Al. This proprietary system is based on the principle that an orthogonal magnetic field can control the relative permeability in a magnetic material such as the coil in a transformer, and hence control the energy (current) transferred to the secondary or output side.

By controlling the relative (electric) permeability in the orthogonal direction in the transformer coil material, it controls the amount of flux in the rolling direction. As the magnetic domains in a magnetisable material can only be magnetized in one direction, by magnetizing orthogonally (transverse direction) the domains are not able to be magnetized in the rolling direction and thus the relative permeability in the rolling direction is reduced. This means that more current may flow through the coil main winding as the relative permeability is reduced. Altering, or adjusting the orthogonal magnetic field, controls the transformer coil as a linear electric valve.

This orthogonal magnetic field is controlled by monitoring the current that flows through the main winding. If the current increases due to a very fast load such as in the case of an electric short on the output or secondary side, the driving voltage on the transverse field will collapse until the short is gone. The short will be gone when the voltage collapses. This means that the device is self controlling due to its patented design. The response on a short is almost immediate as this is based on the design and physics of the core, and the relative permeability in the core material at the moment as governed by the transverse magnetic field. Hence the device does not measure the current with an external control system and control loop, the control system simply controls the output voltage that is required in the normal operation mode.

Fig. 2 illustrates a configuration similar to that of Fig. 1, but the matrix packs 18 are supplemented by a plurality of conventional electrostatic grid pairs 16 (however, the skilled person knows that only a single grid or a single grid pair may be involved, depending on the specific crude application). As the skilled person knows, the electrostatic grid pairs 16 promote separation by electrostatic coalescing, by one grid being energized and controlled e.g. by transformer grid banks 17, and the other being electrically grounded. Coalescing takes place between the two grids in each grid pair 16. As in Fig.l, the vessel 10 also comprises an electrostatic grid 26 supported within the vessel 10 such that it is immersed in the oil and at a distance from the oil/water interface I which occurs when the vessel is in normal operation. Other aspects of the electrostatic grid are as described above with reference to Fig. 1. Although the schematic figures, for the sake of clarity of illustration, show the transformer grid banks 17 and the power supply and control unit 42 as being mounted on top of the vessels with their cables extending down to the grid pairs 16 and the electrostatic grid 26, respectively, the skilled person will understand that in a practical application the transformer grid banks 17 and the power supply and control unit 42 are mounted such that their respective high tension electrical cables are immersed in oil and not run through the gas phase G.

Fig. 2 is in other respects similar to Fig. 1. The invention is thus not restricted to the types of conventional coalescing means, i.e. matrix packs and/or electrostatic grid pairs, but applies in general to all horizontally flowing liquid-liquid gravity separation devices used for emulsion treating, and comprises devices such as 3- Phase Separators, FWKOs, Heater- Treaters, Treaters, Electrical Treaters and Desalters.

Fig. 3 illustrates a second embodiment of the invention. As in Fig. 2, the matrix packs 18 are supplemented by a conventional electrostatic grid pairs 16. Only those features which are different from those of Fig. 2 will be described in the following description of Fig. 3. In this second embodiment illustrated by Fig. 3, the rag layer control is achieved not by a horizontal electrostatic grid, but by a heating element 28 is supported within the vessel 10 at or near the oil/water interface I. The heating element 28 may be a heating coil, a bare tube or a finned tube or similar heat exchanger connected to a heating source (not shown in Fig. 3) in a closed circuit in a conventional manner. The heating fluid may be externally supplied steam, oil, glycol, or similar.

Instead of a separate heating source, separated water W may also be used as heating fluid. This embodiment is illustrated in Fig. 4, schematically showing a recycle line 24a feeding separated water to the heating element 28. Fig. 4 is in other respects similar to Fig. 3. Necessary pumps and valves, etc. have been omitted in Fig. 4 for the sake of clarity of illustration, and as these features are obvious for the skilled person. The heating element 28 may also be heated by other means, such as an electrically powered heater, or similar. With the heating element 28, illustrated by Figs. 3 and 4, an amount of heat is added into the rag layer R development zone, thus substantially preventing the rag layer from forming. Only a small temperature difference is required in order to achieve this objective. In one embodiment the temperature difference between the heating element 28 and the rag layer R is in the order of 5 °C. The heating element 28 may be dimensioned both in the horizontal and the vertical plane to extend in a suitable region in or near the interface I.

Fig. 5 illustrates an embodiment of the invention which essentially combines the first embodiment (as illustrated by Fig. 2) and the second or third embodiments (illustrated by Figs. 3 or 4), in that the vessel 10 comprises the horizontal electrostatic grid 26 and the heating element 28 in a combined arrangement. Otherwise, the components of Fig. 5 are similar to those described above with reference to Figs. 1 — 4. The same distance control and electrical field control of the electrostatic grid 26 as that described with reference to Figs. 1 and 2 apply to this embodiment, as do the heating means and sources of the heating element 28 described with reference to Figs. 3 and 4. The heating element 28 and the electrostatic grid 26 will both contribute to breaking down the rag layer R, and the two components may be operated in a manner yielding the optimum control and removal of the stable emulsion R, such operation depending on the processing situation.

In some production scenarios, bitumen production is processed without the addition of a diluent. However, depending on how heavy the bitumen is (i.e. how low the API gravity is) and on the production or processing temperatures, the density of the bitumen may be heavier than that of the produced water. In this case the fluid separation takes place inverted, compared to what is described above. Even though a diluent is not added, as processing temperatures for undiluted bitumen are much higher than those for diluted bitumen asphaltenes still precipitate out. Hence even with this inverted processing scenario there remains a need for a method and an apparatus for effectively preventing and controlling the formation of a rag layer. Thus, Figs. 6 and 7 illustrate such an inverted processing scenario. Fig. 6 illustrates the first embodiment in an inverted scenario, while Fig. 7 illustrates the second embodiment in an inverted scenario. Even in this inverted scenario, the horizontally extending elongated treater vessel 10 comprises an inlet 12 through which crude (emulsion) to be separated is fed, an oil outlet 22, a water outlet 24, a gas outlet 20, a weir 19 defining an upstream sand dam, and a transverse baffle 15, as otherwise described above with reference to Figs. 1 and 2.

The vessel 10 illustrated by Fig. 6 therefore also comprises an electrostatic grid 26 supported and controlled within the vessel 10 such that it is immersed in the oil and at a distance from the oil/water interface I which occurs when the vessel is in normal operation, and as furthermore explained with reference to Figs 1 and 2.

The vessel 10 illustrated by Fig. 7 therefore also comprises a heating element 28 supported within the vessel 10 at or near the oil/water interface I. The heating element 28 may be a heating coil, a bare tube or a finned tube or similar heat exchanger connected to a heating source, as furthermore explained above with reference to Figs. 3 and 4.

Therefore, the skilled person will understand that the invention is equally applicable to both processing scenarios described above. Although the invention has been described with reference to a treater vessel employing conventional coalescing means, i.e. matrix packs and/or electrostatic grid pairs, the skilled person will understand that the invention applies equally to all horizontally flowing liquid-liquid gravity separation devices used for emulsion treating, comprising devices such as 3-Phase Separators, FWKOs, Heater-Treaters, Treaters, Electrical Treaters and Desalters.

The skilled person will also understand that although the invention is particularly useful in the treatment of extra heavy oil and bitumen, the invention is also useful in the treatment of other oil/water emulsions, including conventional heavy oil.