Title:
METHOD FOR MANUFACTURING FLUORINE-CONTAINING CYCLO OLEFIN
Document Type and Number:
WIPO Patent Application WO/2016/129607
Kind Code:
A1
Abstract:
An objective of the present invention is to provide a method for manufacturing a fluorine-containing cyclo olefin compound in which a compound having a fluorine atom bonded directly to each carbon forming a carbon-carbon double bond therein, and a linear diene compound having a fluorine atom bonded to the carbon at the allylic site therein serve as source materials. The present invention pertains to a method for manufacturing a fluorine-containing cyclo olefin compound represented by at least one of formulas (64)-(67), by reacting a fluorine-containing diene compound represented by at least one of formulas (44)-(47) in the presence of a metal-carbene complex compound exhibiting olefin metathesis activity.
Inventors:
TAKAHIRA YUSUKE (JP)
USUDA TSUKASA (JP)
JOMUTA DAISUKE (JP)
USUDA TSUKASA (JP)
JOMUTA DAISUKE (JP)
Application Number:
PCT/JP2016/053868
Publication Date:
August 18, 2016
Filing Date:
February 09, 2016
Export Citation:
Assignee:
ASAHI GLASS CO LTD (JP)
International Classes:
C07C17/361; C07C23/10; C07D307/30; B01J31/22; C07B61/00
Foreign References:
| JP2013522351A | 2013-06-13 | |||
| JP2009533215A | 2009-09-17 |
Other References:
MARHOLD, MICHAEL ET AL.: "Ring-Closing Metathesis of Vinyl Fluorides towards alpha- Fluorinated alpha,beta-Unsaturated Lactams and Lactones", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 2014, no. 16, 2014, pages 5777 - 5785
NIHEI, TAKASHI ET AL.: "Highly regioselective SN2' reaction of beta-fluoroallylic phosphates with organocopper reagents and its application to the synthesis of fluorine-containing carbocycles", JOURNAL OF FLUORINE CHEMISTRY, vol. 167, 2014, pages 110 - 121
DE MATTEIS, VALERIA ET AL.: "A ring-closing metathesis pathway to fluorovinyl-containing nitrogen heterocycles", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 5, 2006, pages 1166 - 1176
MUNEMORI, DAISUKE ET AL.: "Synthesis of gem- Difluoromethylene Building Blocks through Regioselective Allylation of gem- Difluorocyclopropanes", ORGANIC LETTERS, vol. 16, no. 10, 2014, pages 2638 - 2641
AUDOUARD, CHRISTOPHE ET AL.: "Synthesis of 4,4- difluoro-glycosides using ring-closing metathesis", ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 2, no. 4, 2004, pages 528 - 541
NIHEI, TAKASHI ET AL.: "Highly regioselective SN2' reaction of beta-fluoroallylic phosphates with organocopper reagents and its application to the synthesis of fluorine-containing carbocycles", JOURNAL OF FLUORINE CHEMISTRY, vol. 167, 2014, pages 110 - 121
DE MATTEIS, VALERIA ET AL.: "A ring-closing metathesis pathway to fluorovinyl-containing nitrogen heterocycles", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 5, 2006, pages 1166 - 1176
MUNEMORI, DAISUKE ET AL.: "Synthesis of gem- Difluoromethylene Building Blocks through Regioselective Allylation of gem- Difluorocyclopropanes", ORGANIC LETTERS, vol. 16, no. 10, 2014, pages 2638 - 2641
AUDOUARD, CHRISTOPHE ET AL.: "Synthesis of 4,4- difluoro-glycosides using ring-closing metathesis", ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 2, no. 4, 2004, pages 528 - 541
Attorney, Agent or Firm:
EIKOH PATENT FIRM, P. C. (JP)
Patent business corporation glory patent firm (JP)
Patent business corporation glory patent firm (JP)
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