Title:
METHOD FOR OXIDIZING HYDROCARBON TO OXYGEN COMPOUND
Document Type and Number:
WIPO Patent Application WO/2021/002477
Kind Code:
A1
Abstract:
[Problem] To provide a novel method for obtaining an oxygen compound, e.g., dimethyl ether, by oxidizing a hydrocarbon, e.g., methane, in a vapor phase under simple and relatively mild conditions. [Solution] A method for oxidizing a hydrocarbon to an oxygen compound, the method comprising a step in which the hydrocarbon is brought into contact with a mixture gas comprising NO gas, NO2 gas, and O2 gas, in the presence of a catalyst.
Inventors:
OYAMA SHIGEO (JP)
VARGHEESE VIBIN (JP)
GHAMPSON ISAAC TYRONE (JP)
YUN GWANG-NAM (JP)
KUSHIDA HIROFUMI (JP)
KOBAYASHI YASUKAZU (JP)
TAKAGAKI ATSUSHI (JP)
YOZA MASAAKI (JP)
LI XIAOHONG (JP)
SONG YANG (JP)
VARGHEESE VIBIN (JP)
GHAMPSON ISAAC TYRONE (JP)
YUN GWANG-NAM (JP)
KUSHIDA HIROFUMI (JP)
KOBAYASHI YASUKAZU (JP)
TAKAGAKI ATSUSHI (JP)
YOZA MASAAKI (JP)
LI XIAOHONG (JP)
SONG YANG (JP)
Application Number:
PCT/JP2020/026407
Publication Date:
January 07, 2021
Filing Date:
July 06, 2020
Export Citation:
Assignee:
UNIV TOKYO (JP)
THE UNIV OF KITAKYUSHU (JP)
THE UNIV OF KITAKYUSHU (JP)
International Classes:
C07C41/01; B01J23/42; B01J23/44; B01J23/46; B01J23/63; B01J23/656; B01J23/72; B01J23/89; B01J27/185; C07C43/04; C07C47/04; C07B61/00
Foreign References:
| US20160340283A1 | 2016-11-24 | |||
| CN104447249A | 2015-03-25 |
Other References:
CHOI, B. ET AL., TRANSACTIONS OF THE JAPAN SOCIETY OF MECHANICAL ENGINEERS. B, vol. 59, no. 562, 1993, pages 2078 - 2083
TETSUYA TAKEMOTO, KENJI TABATA, YONGHONG TENG, LIAN-XIN DAI, EIJI SUZUKI: "Selective oxidation of methane in CH4–O2–NO2 over MoO3", CATALYSIS TODAY, vol. 71, 2001, pages 47 - 53, XP055783919
BARBERO J. A., ALVAREZ M. C., BAÑARES M. A., PEÑA M. A., FIERRO J. L. G.: "Breakthrough in the direct conversion of methane into c1-oxygenates", CHEMICAL COMMUNICATIONS, no. 11, 2002, pages 1184 - 1185, XP055783923
BANARES, M. A. ET AL.: "SELECTIVE OXIDATION OF METHANE TO METHANOL AND FORMALDEHYDE OVER V2O5/SIO2 CATALYSTS. ROLE OF NO IN THE GAS PHASE", CATALYSIS LETTERS, vol. 56, 1998, pages 149 - 153, XP000802189
J.A. BARBERO, M.A. BAÑARES, M.A. PEÑA, J.L.G. FIERRO: "Partial oxidation of methane into C1-oxygenates:role of homogeneous reactions and catalyst surface area", CATALYSIS TODAY, vol. 71, no. 1-2, 2001, pages 11 - 19, XP055783929
MARUZEN INC., THE CHEMICAL SOCIETY OFJAPAN, 4TH EXPERIMENTAL CHEMISTRY LECTURE 2: BASIC OPERATION II,, 1990, pages 171 - 176
VIBIN VARGHEESE, JUNICHI MURAKAMI, KYOKO K. BANDO, I. TYRONE GHAMPSON, GWANG-NAM YUN, YASUKAZU KOBAYASHI, S. TED OYAMA: "The direct molecular oxygen partial oxidation of CH4to dimethyl ether without methanol formation over a Pt/Y2O3 catalyst using an NO/NO2 oxygen atom shuttle", JOURNAL OF CATALYSIS, vol. 389, 26 May 2020 (2020-05-26), pages 352 - 365, XP055783940
VARGHEESE, V. ET AL., ANGEW.CHEM.INT.ED., vol. 59, no. 1, 15 June 2020 (2020-06-15), pages 2 - 9
TETSUYA TAKEMOTO, KENJI TABATA, YONGHONG TENG, LIAN-XIN DAI, EIJI SUZUKI: "Selective oxidation of methane in CH4–O2–NO2 over MoO3", CATALYSIS TODAY, vol. 71, 2001, pages 47 - 53, XP055783919
BARBERO J. A., ALVAREZ M. C., BAÑARES M. A., PEÑA M. A., FIERRO J. L. G.: "Breakthrough in the direct conversion of methane into c1-oxygenates", CHEMICAL COMMUNICATIONS, no. 11, 2002, pages 1184 - 1185, XP055783923
BANARES, M. A. ET AL.: "SELECTIVE OXIDATION OF METHANE TO METHANOL AND FORMALDEHYDE OVER V2O5/SIO2 CATALYSTS. ROLE OF NO IN THE GAS PHASE", CATALYSIS LETTERS, vol. 56, 1998, pages 149 - 153, XP000802189
J.A. BARBERO, M.A. BAÑARES, M.A. PEÑA, J.L.G. FIERRO: "Partial oxidation of methane into C1-oxygenates:role of homogeneous reactions and catalyst surface area", CATALYSIS TODAY, vol. 71, no. 1-2, 2001, pages 11 - 19, XP055783929
MARUZEN INC., THE CHEMICAL SOCIETY OFJAPAN, 4TH EXPERIMENTAL CHEMISTRY LECTURE 2: BASIC OPERATION II,, 1990, pages 171 - 176
VIBIN VARGHEESE, JUNICHI MURAKAMI, KYOKO K. BANDO, I. TYRONE GHAMPSON, GWANG-NAM YUN, YASUKAZU KOBAYASHI, S. TED OYAMA: "The direct molecular oxygen partial oxidation of CH4to dimethyl ether without methanol formation over a Pt/Y2O3 catalyst using an NO/NO2 oxygen atom shuttle", JOURNAL OF CATALYSIS, vol. 389, 26 May 2020 (2020-05-26), pages 352 - 365, XP055783940
VARGHEESE, V. ET AL., ANGEW.CHEM.INT.ED., vol. 59, no. 1, 15 June 2020 (2020-06-15), pages 2 - 9
Attorney, Agent or Firm:
ONO Makoto et al. (JP)
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