Title:
METHOD FOR PREPARING CARBON DIOXIDE-BASED QUATERNARY COPOLYMER
Document Type and Number:
WIPO Patent Application WO/2023/045887
Kind Code:
A1
Abstract:
The present invention belongs to the technical field of IPC C08G64/16, and specifically relates to a method for preparing a carbon dioxide-based quaternary copolymer. The method for preparing a carbon dioxide-based quaternary copolymer comprises the following steps: 1) adding preparation raw materials to a high-pressure reactor, then adding a catalyst, and heating same for a quaternary ring-opening copolymerization reaction; and 2) after the reaction is finished, carrying out a post-treatment to obtain the carbon dioxide-based quaternary copolymer. According to the carbon dioxide-based quaternary copolymer provided in the present invention, by means of adding ethylene oxide and the catalysts of triethylborane or tributylborane and tetra-n-butylammonium fluoride, tetra-n-butylammonium chloride, tetra-n-butylammonium bromide, tetra-n-butylammonium iodide, tetra-n-propylammonium fluoride, tetra-n-propylammonium chloride, tetra-n-propylammonium bromide or tetra-n-propylammonium iodide, the reaction activity can be changed, the time for preparing the high-molecular-weight polymer can be shortened, the energy consumption can be reduced, and the carbon dioxide-based quaternary copolymer has a relatively high reference value when applied to large-scale industrial production.
Inventors:
WEI HUAIJIAN (CN)
LI HONGGUO (CN)
LI YIGE (CN)
GAO YUFEI (CN)
FU HAI (CN)
DONG LIANG (CN)
LI HONGGUO (CN)
LI YIGE (CN)
GAO YUFEI (CN)
FU HAI (CN)
DONG LIANG (CN)
Application Number:
PCT/CN2022/119737
Publication Date:
March 30, 2023
Filing Date:
September 20, 2022
Export Citation:
Assignee:
SHANDONG LECSIN GREEN TECH CO LTD (CN)
International Classes:
C08G64/16; C08G64/18; C08G64/34
Foreign References:
| CN114524929A | 2022-05-24 | |||
| CN111333825A | 2020-06-26 | |||
| CN111378101A | 2020-07-07 | |||
| CN103403060A | 2013-11-20 | |||
| CN106083907A | 2016-11-09 | |||
| CN110092900A | 2019-08-06 | |||
| CA2810559A1 | 2012-03-15 | |||
| CN112126053A | 2020-12-25 | |||
| JP2008280399A | 2008-11-20 |
Other References:
TAKAZO AIDA, MASAHIDE ISHIKAWA, SHOHEI INOUE: "Alternating copolymerization of carbon dioxide and epoxide catalyzed by the aluminum porphyrin-quaternary organic salt or -triphenylphosphine system. Synthesis of polycarbonate with well-controlled molecular weight", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, US, vol. 19, no. 1, 1 January 1986 (1986-01-01), US , pages 8 - 13, XP055296565, ISSN: 0024-9297, DOI: 10.1021/ma00155a002
LIU, YULEI ET AL.: "Mechanism Studies of Terpolymerization of Phthalic Anhydride, Propylene Epoxide, and Carbon Dioxide Catalyzed by ZnGA", RSC ADVANCES, vol. 4, no. 19, 19 March 2014 (2014-03-19), XP093053558, ISSN: 2046-2069, DOI: 10.1039/C3RA46343E
YE SHUXIAN, WANG WENJING, LIANG JIAXIN, WANG SHUANJIN, XIAO MIN, MENG YUEZHONG: "Metal-Free Approach for a One-Pot Construction of Biodegradable Block Copolymers from Epoxides, Phthalic Anhydride, and CO 2", ACS SUSTAINABLE CHEMISTRY & ENGINEERING, AMERICAN CHEMICAL SOCIETY, US, vol. 8, no. 48, 7 December 2020 (2020-12-07), US , pages 17860 - 17867, XP093054888, ISSN: 2168-0485, DOI: 10.1021/acssuschemeng.0c07283
JONG YEOB JEON ET AL.: "Copolymerization and Terpolymerization of Carbon Dioxide/Propylene Oxide/Phthalic Anhydride Using a (salen)Co(III) Complex Tethering Four Quaternary Ammonium Salts", BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 10, 5 August 2014 (2014-08-05), XP055888017, ISSN: 1860-5397, DOI: 10.3762/bjoc.10.187
YAJUN ZHAO; SHUAISHUAI ZHU; CAN LIAO; YONG WANG; JACKY W. Y. LAM; XINGPING ZHOU; XIANHONG WANG; XIAOLIN XIE; BEN ZHONG TANG: "Cobalt‐Mediated Switchable Catalysis for the One‐Pot Synthesis of Cyclic Polymers", ANGEWANDTE CHEMIE, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 133, no. 31, 24 June 2021 (2021-06-24), DE , pages 17111 - 17116, XP071384123, ISSN: 0044-8249, DOI: 10.1002/ange.202106285
LIU, YULEI ET AL.: "Mechanism Studies of Terpolymerization of Phthalic Anhydride, Propylene Epoxide, and Carbon Dioxide Catalyzed by ZnGA", RSC ADVANCES, vol. 4, no. 19, 19 March 2014 (2014-03-19), XP093053558, ISSN: 2046-2069, DOI: 10.1039/C3RA46343E
YE SHUXIAN, WANG WENJING, LIANG JIAXIN, WANG SHUANJIN, XIAO MIN, MENG YUEZHONG: "Metal-Free Approach for a One-Pot Construction of Biodegradable Block Copolymers from Epoxides, Phthalic Anhydride, and CO 2", ACS SUSTAINABLE CHEMISTRY & ENGINEERING, AMERICAN CHEMICAL SOCIETY, US, vol. 8, no. 48, 7 December 2020 (2020-12-07), US , pages 17860 - 17867, XP093054888, ISSN: 2168-0485, DOI: 10.1021/acssuschemeng.0c07283
JONG YEOB JEON ET AL.: "Copolymerization and Terpolymerization of Carbon Dioxide/Propylene Oxide/Phthalic Anhydride Using a (salen)Co(III) Complex Tethering Four Quaternary Ammonium Salts", BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 10, 5 August 2014 (2014-08-05), XP055888017, ISSN: 1860-5397, DOI: 10.3762/bjoc.10.187
YAJUN ZHAO; SHUAISHUAI ZHU; CAN LIAO; YONG WANG; JACKY W. Y. LAM; XINGPING ZHOU; XIANHONG WANG; XIAOLIN XIE; BEN ZHONG TANG: "Cobalt‐Mediated Switchable Catalysis for the One‐Pot Synthesis of Cyclic Polymers", ANGEWANDTE CHEMIE, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 133, no. 31, 24 June 2021 (2021-06-24), DE , pages 17111 - 17116, XP071384123, ISSN: 0044-8249, DOI: 10.1002/ange.202106285
Attorney, Agent or Firm:
BEIJING GAOWO LAW FIRM (CN)
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