Title:
METHOD FOR PRODUCING 1,3-BUTADIENE AND/OR 3-BUTEN-2-OL
Document Type and Number:
WIPO Patent Application WO/2015/037556
Kind Code:
A1
Abstract:
Disclosed is a method for producing 1,3-butadiene and/or 3-buten-2-ol from 2,3-butanediol with high selectivity without requiring the use of a radioactive substance. The method for producing 1,3-butadiene and/or 3-buten-2-ol comprises a step of dehydrating 2,3-butanediol in the presence of scandium oxide. The method enables the production of 1,3-butadiene and/or 3-buten-2-ol from 2,3-butanediol with high selectivity without requiring the use of a radioactive substance.
Inventors:
SAKAMI SATOSHI (JP)
YAMADA KATSUSHIGE (JP)
SATO SATOSHI (JP)
DUAN HAILING (JP)
YAMADA KATSUSHIGE (JP)
SATO SATOSHI (JP)
DUAN HAILING (JP)
Application Number:
PCT/JP2014/073648
Publication Date:
March 19, 2015
Filing Date:
September 08, 2014
Export Citation:
Assignee:
TORAY INDUSTRIES (JP)
UNIV CHIBA NAT UNIV CORP (JP)
UNIV CHIBA NAT UNIV CORP (JP)
International Classes:
C07C1/20; C07C11/167; C07C29/60; C07C33/025; C07B61/00
Domestic Patent References:
| WO2014118484A1 | 2014-08-07 | |||
| WO2007094178A1 | 2007-08-23 | |||
| WO2009151342A1 | 2009-12-17 | |||
| WO2013054874A1 | 2013-04-18 |
Foreign References:
| US2527120A | 1950-10-24 | |||
| KR20120096125A | 2012-08-30 | |||
| KR20120099818A | 2012-09-12 | |||
| KR20120107353A | 2012-10-02 | |||
| JP2010047505A | 2010-03-04 | |||
| JPS4028569B | ||||
| JP2014172883A | 2014-09-22 | |||
| JPS63222135A | 1988-09-16 | |||
| KR20120099818A | 2012-09-12 | |||
| KR20120107353A | 2012-10-02 | |||
| JP2010150248A | 2010-07-08 |
Other References:
NAOKI ICHIKAWA ET AL.: "Catalytic reaction of 1,3-butanediol over solid acids", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 256, 2006, pages 106 - 112, XP028015648
SATOSHI SATO ET AL.: "Dehydration of diols catalyzed by Ce02", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 221, 2004, pages 177 - 183, XP004570925
ALLAN J. LUNDEEN ET AL.: "Selective Catalytic Dehydration. Thoria-Catalyzed Dehydration of Alcohols", J. ORG. CHEM., vol. 32, 1967, pages 3386 - 3389, XP055325395
FUMIYA SATO ET AL.: "Dehydration of 1,5- pentanediol over rare earth oxides", APPLIED CATALYSIS A: GENERAL, vol. 419-420, 2012, pages 41 - 48, XP028402762
HAILING DUAN ET AL.: "Dehydration of 2,3- butanediol into 3-buten-2-ol catalyzed by Zr02", CATALYSIS COMMUNICATIONS, vol. 48, 24 January 2014 (2014-01-24), pages 1 - 4, XP055161382
K.WEISSERMEL; H.-J.ARPE: "Industrial Organic Chemistry - Important Raw Materials and Intermediates", 16 December 2004, TOKYO KAGAKU DOJIN, pages: 114 - 119
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 256, no. 1-2, 2006, pages 106 - 112
JOURNAL OF MEDICINAL CHEMISTRY, vol. 40, no. 17, 1997, pages 2762 - 2769
JOURNAL OF MEDICINAL CHEMISTRY, vol. 33, no. 3, 1990, pages 999 - 1009
"Chemical Encyclopedia", vol. 9, 1962, KYORITSU SHUPPAN, pages: 183
BIOTECHNOLOGY ADVANCES, vol. 27, 2009, pages 715 - 725
JOURNAL OF THE COUNCIL OF INDUSTRIAL RESEARCH, vol. 18, 1945, pages 412 - 423
INDUSTRIAL AND ENGINEERING CHEMISTRY, vol. 37, no. 9, 1945, pages 905 - 908
JOURNAL OF ORGANIC CHEMISTRY, vol. 32, no. 11, 1967, pages 3386 - 3389
APPLIED MICROBIOLGY AND BIOTECHNOLOGY, vol. 87, no. 6, 2010, pages 2001 - 2009
SATOSHI SATO ET AL.: "Dehydration of diols catalyzed by Ce02", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 221, 2004, pages 177 - 183, XP004570925
ALLAN J. LUNDEEN ET AL.: "Selective Catalytic Dehydration. Thoria-Catalyzed Dehydration of Alcohols", J. ORG. CHEM., vol. 32, 1967, pages 3386 - 3389, XP055325395
FUMIYA SATO ET AL.: "Dehydration of 1,5- pentanediol over rare earth oxides", APPLIED CATALYSIS A: GENERAL, vol. 419-420, 2012, pages 41 - 48, XP028402762
HAILING DUAN ET AL.: "Dehydration of 2,3- butanediol into 3-buten-2-ol catalyzed by Zr02", CATALYSIS COMMUNICATIONS, vol. 48, 24 January 2014 (2014-01-24), pages 1 - 4, XP055161382
K.WEISSERMEL; H.-J.ARPE: "Industrial Organic Chemistry - Important Raw Materials and Intermediates", 16 December 2004, TOKYO KAGAKU DOJIN, pages: 114 - 119
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 256, no. 1-2, 2006, pages 106 - 112
JOURNAL OF MEDICINAL CHEMISTRY, vol. 40, no. 17, 1997, pages 2762 - 2769
JOURNAL OF MEDICINAL CHEMISTRY, vol. 33, no. 3, 1990, pages 999 - 1009
"Chemical Encyclopedia", vol. 9, 1962, KYORITSU SHUPPAN, pages: 183
BIOTECHNOLOGY ADVANCES, vol. 27, 2009, pages 715 - 725
JOURNAL OF THE COUNCIL OF INDUSTRIAL RESEARCH, vol. 18, 1945, pages 412 - 423
INDUSTRIAL AND ENGINEERING CHEMISTRY, vol. 37, no. 9, 1945, pages 905 - 908
JOURNAL OF ORGANIC CHEMISTRY, vol. 32, no. 11, 1967, pages 3386 - 3389
APPLIED MICROBIOLGY AND BIOTECHNOLOGY, vol. 87, no. 6, 2010, pages 2001 - 2009
Attorney, Agent or Firm:
TANIGAWA AND PARTNERS, PATENT FIRM (JP)
Patent business corporation mountain stream international patent firm (JP)
Patent business corporation mountain stream international patent firm (JP)
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