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Title:
METHOD FOR PRODUCING ACETAL COMPOUND
Document Type and Number:
WIPO Patent Application WO/2017/204155
Kind Code:
A1
Abstract:
A method for producing an acetal compound, the method comprising: a step (A) for oxidizing a compound represented by general formula (1) (R1 represents an alkyl group having 1-6 carbon atoms) to obtain a compound represented by general formula (2) (R1 is as defined above); and a step (B) for acetalizing the compound represented by general formula(2) obtained in step (A), in the presence of an acid, to obtain a compound represented by general formula (3) (R1 is as defined above, R2 and R3 each independently represent an alkyl group having 1-6 carbon atoms, or are linked together to represent an alkylene group having 2-6 carbon atoms).

Inventors:
MINAMOTO NAOYA (JP)
SHIMIZU RYOSUKE (JP)
TSURUTA TAKUO (JP)
Application Number:
PCT/JP2017/019014
Publication Date:
November 30, 2017
Filing Date:
May 22, 2017
Export Citation:
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Assignee:
KURARAY CO (JP)
International Classes:
C07D317/12; C07B61/00
Domestic Patent References:
WO2016013220A12016-01-28
WO2016013221A12016-01-28
WO2016104332A12016-06-30
Foreign References:
JPS62283945A1987-12-09
Other References:
KRITCHEVSKY,D. ET AL., JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 65, 1943, pages 487
NARKUNAN,K., SYNLETT, vol. 9, 2000, pages 13 00 - 1302
LEE,T.V.: "THE CERIUM (III) MEDIATED REACTION OF TRIMETHYLSILYLMETHYL MAGNESIUMCHLORIDE WITH ESTERS AND LACTONES: THE EFFICIJWI’ SYNTHESIS OF SQMEFUNCTIONALISED ALLYLSILANES OF USE IN ANNULATION REACTIONS", TETRAHEDRON, vol. 45, no. 18, 1989, pages 5877 - 5886, XP055444458
TSUNODA,T., TETRANEDRON LETTERS, vol. 21, no. 14, 1980, pages 1357 - 1358, XP055444461
LI,BIN: "Asymmetric Syntheses of 8-Oxabicyclo[3,2,1]octanes: A CationicCascade Cyclization", ANGEWANDE CHEMIE INTERNATIONAL EDITION, vol. 51, 2012, pages 8041 - 8045, XP055444466
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