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Title:
METHOD FOR PRODUCING ALKYLATED AROMATIC AMIDE DERIVATIVE
Document Type and Number:
WIPO Patent Application WO/2013/150988
Kind Code:
A1
Abstract:
Provided is a method for producing an aromatic amide derivative represented by general formula (4), which comprises a step wherein an aromatic amide derivative represented by general formula (1) and a haloalkyl compound represented by general formula (3) are reacted with each other in the presence of a base and a metal or metal salt. In the general formulae, each of X and Y represents a hydrogen atom, a halogen atom or the like; A represents a hydrogen atom, an alkyl group, a group represented by general formula (2) or the like; each of G1 and G2 represents an oxygen atom or the like; Q1 represents a phenyl group or the like; R1 represents a hydrogen atom, an alkyl group or the like; Z1 represents a haloalkyl group or the like; Xa represents an iodine atom or the like; m represents a number of 1-4; n1 represents a number of 1-5; and n2 represents a number of 1-4.

Inventors:
OKURA HIRONARI (JP)
Application Number:
PCT/JP2013/059695
Publication Date:
October 10, 2013
Filing Date:
March 29, 2013
Export Citation:
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Assignee:
MITSUI CHEMICALS AGRO INC (JP)
International Classes:
C07C231/12; C07C237/42
Domestic Patent References:
WO2006137376A12006-12-28
WO2011118759A12011-09-29
WO2003103654A12003-12-18
WO2005073165A12005-08-11
WO2006137376A12006-12-28
WO2010018714A12010-02-18
WO2010018857A12010-02-18
Foreign References:
CN102206172A2011-10-05
JP2004502749A2004-01-29
JP2010072101A2010-04-02
JP2001122836A2001-05-08
JP2012085053A2012-04-26
Other References:
GRAMMATICAKIS,P.: "Preparation and ultraviolet absorption of some m-(amino- and m-(acylaminobenzoyl)aryl amines, Comptes Rendus des Seances de l'Academie des Sciences, Serie C", SCIENCES CHIMIQUES, vol. 263, no. 21, 1966, pages 1306 - 1309, XP009137899
FUCHIKAMI T. ET AL.: "DIRECT PERFLUOROALKYLATION OF FUNCTIONALIZED BENZENES WITH PERFLUOROALKYL HALIDES AND COPPER BRONZE", JOURNAL OF FLUORINE CHEMISTRY, vol. 22, no. ISSUE, 1983, pages 541 - 556, XP001187569
"CSJ: The Chemical Society of Japan, Shin Jikken Kagaku Koza 14 Yuki Kagobutsu no Gosei to Hanno I", vol. 14, no. 1ST ED, 1977, pages 62, XP008175145
See also references of EP 2835366A4
JOURNAL OF FLUORINE CHEMISTRY, vol. 22, 1983, pages 541 - 556
BIOORGANIC & MEDICINAL CHEMISTRY, vol. 15, no. 3, 2007, pages 1212 - 1228
Attorney, Agent or Firm:
NAKAJIMA, Jun et al. (JP)
Nakajima 淳 (JP)
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