Title:
METHOD FOR PRODUCING ENANTIOMERS, METHOD FOR IMPROVING ENANTIOSELECTIVITY, METHOD FOR CONTROLLING SYNTHESIS OF ENANTIOMER SPECIES, AGENT FOR IMPROVING ENANTIOSELECTIVITY, ENANTIOSELECTIVITY-VARIABLE MATERIAL, ENANTIOSELECTION CONTROLLING MATERIAL, ASYMMETRIC SYNTHESIS REACTION DEVICE, COMPLEX, AND METHOD FOR SEPARATELY PRODUCING R-ISOMER AND S-ISOMER
Document Type and Number:
WIPO Patent Application WO/2017/051856
Kind Code:
A1
Abstract:
A method for producing a specific enantiomer in a larger amount than the other enantiomer, said method comprising reacting a reaction substrate in the presence of cellulose nanofiber or a derivative thereof and a catalyst so as to improve the yield. The present invention makes it possible to improve the yield and enantioselectivity in an asymmetric synthesis reaction.
Inventors:
JIN XIN (JP)
TATEBAYASHI NAOKO (JP)
KITAOKA TAKUYA (JP)
TATEBAYASHI NAOKO (JP)
KITAOKA TAKUYA (JP)
Application Number:
PCT/JP2016/077984
Publication Date:
March 30, 2017
Filing Date:
September 23, 2016
Export Citation:
Assignee:
UNIV KYUSHU NAT UNIV CORP (JP)
DAICEL CORP (JP)
DAICEL CORP (JP)
International Classes:
C07C45/72; C07B53/00; C07C49/245; C07C201/12; C07C205/45; B01J31/04; C07B61/00
Foreign References:
| JP2002275118A | 2002-09-25 |
Other References:
KAUSHIK, MADHU ET AL.: "Cellulose Nanocrystals as Chiral Inducers: Enantioselective Catalysis and Transmission Electron Microscopy 3D Characterization", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 137, no. 19, 27 April 2015 (2015-04-27), pages 6124 - 6127, XP055370583
YASUKAWA, TOMOHIRO ET AL.: "Cellulose-supported chiral rhodium nanoparticles as sustainable heterogeneous catalysts for asymmetric carbon- carbon bond-forming reactions", CHEMICAL SCIENCE, vol. 6, no. 11, 12 August 2015 (2015-08-12), pages 6224 - 6229, XP055370590
MOSCHETTA, ERIC G. ET AL.: "Composite Polymer/Oxide Hollow Fiber Contactors: Versatile and Scalable Flow Reactors for Heterogeneous Catalytic Reactions in Organic Synthesis", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 54, no. 22, 13 April 2015 (2015-04-13), pages 6470 - 6474, XP055370988
SAITO, TSUGUYUKI ET AL.: "Homogeneous Suspensions of Individualized Microfibrils from TEMPO-Catalyzed Oxidation of Native Cellulose", BIOMACROMOLECULES, vol. 7, no. 6, 12 June 2006 (2006-06-12), pages 1687 - 1691, XP002675845
YASUKAWA, TOMOHIRO ET AL.: "Cellulose-supported chiral rhodium nanoparticles as sustainable heterogeneous catalysts for asymmetric carbon- carbon bond-forming reactions", CHEMICAL SCIENCE, vol. 6, no. 11, 12 August 2015 (2015-08-12), pages 6224 - 6229, XP055370590
MOSCHETTA, ERIC G. ET AL.: "Composite Polymer/Oxide Hollow Fiber Contactors: Versatile and Scalable Flow Reactors for Heterogeneous Catalytic Reactions in Organic Synthesis", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 54, no. 22, 13 April 2015 (2015-04-13), pages 6470 - 6474, XP055370988
SAITO, TSUGUYUKI ET AL.: "Homogeneous Suspensions of Individualized Microfibrils from TEMPO-Catalyzed Oxidation of Native Cellulose", BIOMACROMOLECULES, vol. 7, no. 6, 12 June 2006 (2006-06-12), pages 1687 - 1691, XP002675845
Attorney, Agent or Firm:
SIKS & CO. (JP)
Download PDF: