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Title:
METHOD FOR PRODUCING ESTER COMPOUND AND PALLADIUM CATALYST USED IN METHOD FOR PRODUCING ESTER COMPOUND
Document Type and Number:
WIPO Patent Application WO/2014/050810
Kind Code:
A1
Abstract:
A method for producing an ester compound, wherein an ester compound is obtained by reacting a compound having at least one cyclic structure, namely a norbornene ring and/or a norbornadiene ring, with an alcohol and carbon monoxide with use of a palladium catalyst and an oxidant so as to introduce an ester group to a carbon atom that constitutes a double bond in the cyclic structure. This method for producing an ester compound is characterized in that the palladium catalyst contains palladium acetate having a nitrite ligand represented by general formula (1) in an amount of 10% by mole or more in terms of metal. Pd3(CH3COO)5(NO2) (1)

Inventors:
KOMATSU SHINICHI (JP)
SHIIBASHI AKIRA (JP)
MATSUMOTO TAKAYA (JP)
Application Number:
PCT/JP2013/075693
Publication Date:
April 03, 2014
Filing Date:
September 24, 2013
Export Citation:
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Assignee:
JX NIPPON OIL & ENERGY CORP (JP)
International Classes:
C07C67/36; B01J31/22; C07C69/753; C07B61/00
Domestic Patent References:
WO2011099518A12011-08-18
Foreign References:
JPH07138205A1995-05-30
JPH07179400A1995-07-18
Other References:
VLADIMIR I. BAKHMUTOV ET AL.: "Non-trivial behavior of palladium(II) acetate", DALTON TRANSACTIONS, vol. 11, 2005, pages 1989 - 1992
R.F.MULAGALEEV ET AL.: "Palladium(II) Acetates: Synthesis and Molecular Transformation Scheme", RUSSIAN JOURNAL OF APPLIED CHEMISTRY, vol. 83, no. 12, 2010, pages 2065 - 2075
Attorney, Agent or Firm:
CENTCREST IP ATTORNEYS (JP)
Patent business corporation cent Crest international patent firm (JP)
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