Title:
METHOD FOR PRODUCING FLUORINATED SULFONIUM ALKYLFLUOROPHOSPHATE
Document Type and Number:
WIPO Patent Application WO/2007/061024
Kind Code:
A1
Abstract:
Disclosed is a method for efficiently producing a fluorinated alkylfluorophosphoric acid salt of an aryl sulfonium at low cost without requiring an extremely excessive amount of acid. Specifically disclosed is a method for producing a sulfonium salt represented by the formula (3) below wherein an aryl compound Ar-H and a compound represented by the formula (1) below (wherein R1 and R2 respectively represent an optionally substituted hydrocarbon group or a heterocyclic group, or alternatively R1 and R2 are bonded together directly or via -O-, -S-, -SO-, -SO2-, -NH-, -NR’-, -CO-, -COO-, -CONH-, an alkylene having 1-3 carbon atoms or a phenylene and form an optionally substituted ring structure with R’ being a C1-5 alkyl or a C6-10 aryl) are reacted with each other in the presence of an acid represented by the formula (2) below (wherein Rf represents an alkyl in which 80% or more of hydrogen atoms are substituted by fluorine atoms, and a represents a number of 1-5) and a dehydrating agent.
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Inventors:
KIMURA HIDEKI (JP)
YAMAMOTO JIRO (JP)
YAMASHITA SHINJI (JP)
YAMAMOTO JIRO (JP)
YAMASHITA SHINJI (JP)
Application Number:
PCT/JP2006/323386
Publication Date:
May 31, 2007
Filing Date:
November 24, 2006
Export Citation:
Assignee:
SAN APRO LTD (JP)
KIMURA HIDEKI (JP)
YAMAMOTO JIRO (JP)
YAMASHITA SHINJI (JP)
KIMURA HIDEKI (JP)
YAMAMOTO JIRO (JP)
YAMASHITA SHINJI (JP)
International Classes:
C07C381/12
Domestic Patent References:
WO2002048101A1 | 2002-06-20 | |||
WO2005000801A1 | 2005-01-06 | |||
WO2005116037A1 | 2005-12-08 |
Foreign References:
JPS61100557A | 1986-05-19 | |||
JPH0782244A | 1995-03-28 | |||
JPH0782245A | 1995-03-28 | |||
JP2004159921A | 2004-06-10 | |||
JPS61212554A | 1986-09-20 | |||
JPS61100557A | 1986-05-19 | |||
JPH0782244A | 1995-03-28 | |||
JP2002241363A | 2002-08-28 |
Other References:
See also references of EP 1953139A4
Attorney, Agent or Firm:
HAYASAKA, Takumi (2nd Fl. Kitahama-heiwa Bldg., 5-13, Kitahama 2-chome, Chuo-k, Osaka-shi Osaka 41, JP)
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