Title:
METHOD FOR PRODUCING GLYCERIC ACID ESTER
Document Type and Number:
WIPO Patent Application WO/2018/124148
Kind Code:
A1
Abstract:
The purpose of the present invention relates to providing a novel glyceric acid ester which can be produced at a high yield and for which use as a synthesis intermediate can be expected, and a method for producing same. The purpose of the present invention also relates to providing a novel glyceric acid ester for which the recovery rate in a water washing step following a reaction is high, for which there are few additional operations during manufacture, and for which use as a synthesis intermediate can be expected, and a method for producing same. Provided is a method for producing a compound represented by formula (II), which has a step for oxidatively esterifying a compound represented by formula (I). (In formula (I) and formula (II), R1 and R2 each independently denote a hydrogen atom or a monovalent hydrocarbon group, or R1 and R2 denote divalent hydrocarbon groups that bond to each other to form a ring structure. However, it is not possible for both R1 and R2 to be methyl groups.)
Inventors:
AOKI TAKASHI (JP)
Application Number:
PCT/JP2017/046814
Publication Date:
July 05, 2018
Filing Date:
December 26, 2017
Export Citation:
Assignee:
KAO CORP (JP)
International Classes:
C07D317/32; C07C45/65; C07C49/17; C07C213/00; C07C215/10; C07D319/06; C07B61/00
Domestic Patent References:
| WO2016097840A1 | 2016-06-23 | |||
| WO2012041845A1 | 2012-04-05 |
Foreign References:
| JP2006219406A | 2006-08-24 |
Other References:
ABRAMOVICH ADI ET AL.: "Organocatalytic oxidative dimerization of alcohols to esters", SYNLETT, vol. 23, no. 15, 20 August 2012 (2012-08-20), pages 2261 - 2265, XP055605168, ISSN: 0936-5214, DOI: 10.1055/s-0032-1317018
MERBOUH NABYL ET AL.: "Oxoammonium Salts. 9. Oxidative Dimerization of Polyfunctional Primary Alcohols to Esters. An Int eresting beta Oxygen Effect", JOURNAL OF ORGANIC CHEMISTRY, vol. 69, no. 15, 26 June 2004 (2004-06-26), pages 5116 - 5119, XP055605169, ISSN: 0022-3263, DOI: 10.1021/jo049461j
HON YUNG-SON ET AL.: "Tishchenko reactions of aldehydes promoted by diisobutylaluminum hydride and its application to th e macrocyclic lactone formation", TETRAHEDRON, vol. 63, no. 4, 29 August 2007 (2007-08-29) - 4 October 2007 (2007-10-04), pages 11325 - 11340, XP022284165, ISSN: 0040-4020, DOI: 10.1016/j.tet.2007.08.074
ERMOLENKO LUDMILA ET AL.: "An expedient one-step preparation of (S)-2,3-0-isopropylideneglyceraldehyde", SYNLETT, vol. 10, 2001, pages 1565 - 1566, XP002274843
HON YUNG-SON ET AL.: "Tishchenko reactions and Oppenauer oxidation reactions of aldehydes promoted by diisobutylaluminum hydride", TETRAHEDRON LETTERS, vol. 45, no. 16, 4 December 2004 (2004-12-04), pages 3313 - 331, XP004499005, ISSN: 0040-4039, DOI: 10.1016/j.tetlet.2004.02.145
SYNLETT, vol. 10, 2001, pages 1565 - 1566
THE JOURNAL OF ORGANIC CHEMISTRY, vol. 69, 2004, pages 5116 - 5119
TETRAHEDRON, vol. 63, 2007, pages 11325 - 11340
SYNLETT, vol. 23, 2012, pages 2261 - 2265
JOURNAL OF CATALYSIS, vol. 245, 2007, pages 428 - 435
TETRAHEDRON, vol. 71, no. 20, 2015, pages 3032 - 3038
GREEN CHEMISTRY, vol. 12, 2010, pages 2225 - 2231
See also references of EP 3564226A4
MERBOUH NABYL ET AL.: "Oxoammonium Salts. 9. Oxidative Dimerization of Polyfunctional Primary Alcohols to Esters. An Int eresting beta Oxygen Effect", JOURNAL OF ORGANIC CHEMISTRY, vol. 69, no. 15, 26 June 2004 (2004-06-26), pages 5116 - 5119, XP055605169, ISSN: 0022-3263, DOI: 10.1021/jo049461j
HON YUNG-SON ET AL.: "Tishchenko reactions of aldehydes promoted by diisobutylaluminum hydride and its application to th e macrocyclic lactone formation", TETRAHEDRON, vol. 63, no. 4, 29 August 2007 (2007-08-29) - 4 October 2007 (2007-10-04), pages 11325 - 11340, XP022284165, ISSN: 0040-4020, DOI: 10.1016/j.tet.2007.08.074
ERMOLENKO LUDMILA ET AL.: "An expedient one-step preparation of (S)-2,3-0-isopropylideneglyceraldehyde", SYNLETT, vol. 10, 2001, pages 1565 - 1566, XP002274843
HON YUNG-SON ET AL.: "Tishchenko reactions and Oppenauer oxidation reactions of aldehydes promoted by diisobutylaluminum hydride", TETRAHEDRON LETTERS, vol. 45, no. 16, 4 December 2004 (2004-12-04), pages 3313 - 331, XP004499005, ISSN: 0040-4039, DOI: 10.1016/j.tetlet.2004.02.145
SYNLETT, vol. 10, 2001, pages 1565 - 1566
THE JOURNAL OF ORGANIC CHEMISTRY, vol. 69, 2004, pages 5116 - 5119
TETRAHEDRON, vol. 63, 2007, pages 11325 - 11340
SYNLETT, vol. 23, 2012, pages 2261 - 2265
JOURNAL OF CATALYSIS, vol. 245, 2007, pages 428 - 435
TETRAHEDRON, vol. 71, no. 20, 2015, pages 3032 - 3038
GREEN CHEMISTRY, vol. 12, 2010, pages 2225 - 2231
See also references of EP 3564226A4
Attorney, Agent or Firm:
KATAOKA, Makoto et al. (JP)
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