Title:
METHOD FOR PRODUCING PERFLUOROALKYLATED COMPOUND
Document Type and Number:
WIPO Patent Application WO/2017/104589
Kind Code:
A1
Abstract:
Provided is a method for producing a perfluoroalkylated compound at low cost, safely and with high efficiency.
A method for producing a perfluoroalkylated compound, comprising reacting a bis(perfluoroalkanoyl)peroxide with a compound that contains a carbon-carbon unsaturated bond and/or an aromatic ring having a hydrogen atom bonded thereto in the presence of a copper catalyst.
More Like This:
Inventors:
SODEOKA MIKIKO (JP)
KAWAMURA SHINTARO (JP)
KAWAMURA SHINTARO (JP)
Application Number:
PCT/JP2016/086837
Publication Date:
June 22, 2017
Filing Date:
December 12, 2016
Export Citation:
Assignee:
RIKEN (JP)
International Classes:
C07B37/04; C07B37/08; C07B47/00; C07C17/263; C07C21/18; C07C22/00; C07C22/08; C07C29/32; C07C31/38; C07C41/30; C07C43/205; C07C45/68; C07C49/167; C07C67/293; C07C69/78; C07C303/40; C07C311/16; C07D203/24; C07D207/444; C07D209/34; C07D279/02; C07B61/00
Foreign References:
| JP2008137992A | 2008-06-19 | |||
| JP2012211208A | 2012-11-01 |
Other References:
ZHONG,S. ET AL.: "Metal-free radical perfluoroalkylation of (hetero)arenes", RSC ADVANCES, vol. 5, no. 9, 2015, pages 6255 - 6258, XP055490531
HAYAKAWA,Y. ET AL.: "Trifluoromethylation by bis(trifluoroacetyl) peroxide of polymers bearing benzene rings", POLYMER, vol. 42, no. 9, 2001, pages 4081 - 4086, XP055490535
SAWADA,H. ET AL.: "Trifluoromethylation of aromatic compounds with bis(trifluoroacetyl) peroxide", JOURNAL OF FLUORINE CHEMISTRY, vol. 46, no. 3, 1990, pages 423 - 431, XP026648078
R. W. WINTER ET AL., EXP PARASITOL., vol. 118, 2008, pages 487
A. TOGNI ET AL., CHEM. REV., vol. 115, 2014, pages 650
S. BRAESE ET AL., RSC ADV., vol. 5, 2015, pages 6255
See also references of EP 3392228A4
HAYAKAWA,Y. ET AL.: "Trifluoromethylation by bis(trifluoroacetyl) peroxide of polymers bearing benzene rings", POLYMER, vol. 42, no. 9, 2001, pages 4081 - 4086, XP055490535
SAWADA,H. ET AL.: "Trifluoromethylation of aromatic compounds with bis(trifluoroacetyl) peroxide", JOURNAL OF FLUORINE CHEMISTRY, vol. 46, no. 3, 1990, pages 423 - 431, XP026648078
R. W. WINTER ET AL., EXP PARASITOL., vol. 118, 2008, pages 487
A. TOGNI ET AL., CHEM. REV., vol. 115, 2014, pages 650
S. BRAESE ET AL., RSC ADV., vol. 5, 2015, pages 6255
See also references of EP 3392228A4
Attorney, Agent or Firm:
HIRAKI Yusuke et al. (JP)
Download PDF:
Previous Patent: VEHICLE AIR CONDITIONER
Next Patent: GAS DETECTION METHOD AND GAS DENSITY MEASUREMENT DEVICE
Next Patent: GAS DETECTION METHOD AND GAS DENSITY MEASUREMENT DEVICE