Title:
METHOD FOR PRODUCING SATURATED ALCOHOLS, KETONES, ALDEHYDES AND CARBOXYLIC ACIDS
Document Type and Number:
WIPO Patent Application WO2003004447
Kind Code:
A3
Abstract:
The invention relates to a method for catalytically oxidizing unsaturated hydrocarbons to form oxidation products, and to the production of saturated alcohols, ketones, aldehydes or carboxylic acids by subsequently hydrogenating the oxidation product. A compound of formula (I) is used as a catalyst during oxidizing in which: R<1>, R<2> = H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 carbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R<1> and R<2> signify identical or different radicals or R<1> and R<2> can be coupled to one another via a covalent bond, with Q<1>, Q<2> = the same or different, C, CH, N; X, Z = C, S or CH2; Y = O or OH; k = 0, 1 or 2; l = 0, 1 or 2; m = 1 to 100 in the presence of a radical initiator. Peroxy compounds or azo compounds can be used as radical initiators. Preferred substrates are cyclic aliphatic or aromatic compounds.
Inventors:
KUEHNLE ADOLF (DE)
JOST CARSTEN (DE)
SHELDON ROGER ARTHUR (NL)
CHATEL SANDRINE M M (NL)
ARENDS ISABELLA W C E (NL)
JOST CARSTEN (DE)
SHELDON ROGER ARTHUR (NL)
CHATEL SANDRINE M M (NL)
ARENDS ISABELLA W C E (NL)
Application Number:
PCT/EP2002/006411
Publication Date:
November 20, 2003
Filing Date:
June 12, 2002
Export Citation:
Assignee:
DEGUSSA (DE)
KUEHNLE ADOLF (DE)
JOST CARSTEN (DE)
SHELDON ROGER ARTHUR (NL)
CHATEL SANDRINE M M (NL)
ARENDS ISABELLA W C E (NL)
KUEHNLE ADOLF (DE)
JOST CARSTEN (DE)
SHELDON ROGER ARTHUR (NL)
CHATEL SANDRINE M M (NL)
ARENDS ISABELLA W C E (NL)
International Classes:
C07B41/00; C07B61/00; C07C29/17; C07C29/50; C07C31/02; C07C31/133; C07C45/34; C07C47/02; C07C47/28; C07C49/04; C07C49/29; C07C51/25; C07C53/00; C07C53/134; (IPC1-7): C07C29/50; C07C45/34; C07C51/25; C07B41/00
Foreign References:
| US5030739A | 1991-07-09 | |||
| EP0858835A1 | 1998-08-19 |
Other References:
Y. ISHII: "A novel catalysis of N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen", JOURNAL OF ORGANIC CHEMISTRY, vol. 60, no. 13, 1995, EASTON US, pages 3934 - 3935, XP000512054
A. HORINAKA: "Photosensitized oxygenation of unconjugated cyclic dienes", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 48, no. 7, 1975, TOKYO JP, pages 2095 - 2098, XP002253156
A. HORINAKA: "Photosensitized oxygenation of unconjugated cyclic dienes", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 48, no. 7, 1975, TOKYO JP, pages 2095 - 2098, XP002253156
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