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Title:
MODIFIED NANOSTRUCTURED SILICA MATERIALS FOR HEAVY METAL REMOVAL FROM CONTAMINATED WATER AND THE METHODS OF PRODUCTION THEREOF
Document Type and Number:
WIPO Patent Application WO/2021/101394
Kind Code:
A4
Abstract:
This invention discloses the methods of preparing Iron-modified nanostructured silica beads and iron-modified nanosilica powder. The resulting composition is used as heavy metal adsorbents in the removal of arsenic from contaminated water. These materials allow the remediation of arsenic contaminated groundwater using low-cost, locally available, and sustainable nanomaterials.

Inventors:
PERALTA MILAGROS (PH)
MAGALONA MARITESS (PH)
ESCOBEDO ERICSON (PH)
Application Number:
PCT/PH2020/050015
Publication Date:
September 23, 2021
Filing Date:
November 20, 2020
Export Citation:
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Assignee:
UNIV OF THE PHILIPPINES LOS BANOS (PH)
International Classes:
B01J20/10; B01D39/20; B01J20/28; B09C1/08; C02F1/28; C02F1/62
Attorney, Agent or Firm:
AVISO, Aldrex (PH)
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Claims:
AMENDED CLAIMS received by the International Bureau on 26 July 2021 (26.07.2021)

[Claim 1] [Amended] Nano structured filter beads and nano structured filter powder comprising of a nanosilica component with block copoly merization characteristics uniformly modified and incorporated with iron as ferric sulfate or ferric chloride, wherein: the nano structured filter beads have a particle size of 8.0 nm, pore radius of 17.0 angstroms, surface area of 349 m2/g, dry bulk density of 0.78-0.81 g/cm3, hardness of 1.02-1.71 kg/g; and the nano structured filter powder has a particle size of 36.0 nm, pore radius of 91.0 angstroms, and surface area of 110 m2/g.

[Claim 2] [Cancelled] [Claim 3] [Cancelled] [Claim 4] [Unchanged] A method of preparing nanostructured powder according to Claim 1 comprising the steps of: a. dissolving the nanosilica in 2.5 N NaOH at a ratio of 1:4 (wt. of nanosilica: vol. of base to obtain the silica sol); b. filtering the silica sol to remove the undissolved particles; c. dissolving the iron source (ferric sulfate or ferric chloride) in 2.5 N NaOH; d. filtering the excess iron using a funnel; e. adding the purified nanosilica to the alkaline solution of the iron salt; f. stirring the sol for ten hours; g. titrating the sol with 5 N H2S04 to reduce the pH to 7.5-8.5; h. washing the residue with deionized water; i. air-drying the residue; and j. oven drying the residue at 120-150 °C for three to twelve hours.

[Claim 5] [Unchanged] A method of preparing nanostructured beads according to Claim 1 comprising the steps of: a. dissolving the nanosilica powder in 2.5 N NaOH solution; b. titrating the resulting sodium silicate to glacial acetic acid with stirring until pH 3.5-4.0; c. adding the iron source to the solution and aging the resulting solution for 2-4 hours until a viscosity of 2750 to 3250 cP is achieved; d. dropping the solution of iron modified silica sol slowly to form beads in a column containing ammonium hydroxide with surfactant as the aqueous layer and hexane as the organic layer; e. aging the beads in ammonium hydroxide for at least two hours; f. collecting the iron modified silica beads; g. washing the iron modified silica beads; h. washing the beads with deionized water while undergoing sonication at 50-60 Hz, then with acetone or isopropyl alcohol; i. air-drying the beads; and j. oven-drying the beads at 150-200 °C for three to six hours.

[Claim 6] [Cancelled] [Claim 7] [Cancelled] [Claim 8] [Cancelled] [Claim 9] [Cancelled] [Claim 10] [Cancelled] [Claim 11] [Cancelled] [Claim 12] [Amended] The nanostructured filter powder according to Claim 1, wherein the allowed flow rate is 9.0 mL/min and the adsorption capacity is 0.99-1.02 mg As(III)/g adsorbent.

[Claim 13] [Amended] The nanostructured filter beads according to Claim 1 wherein the allowed flow rate is 600 mL/min and the adsorption capacity is 0.82-0.96 mg As(III)/g adsorbent.

[Claim 14] [Cancelled] [Claim 15] [Cancelled]