Title:
NOVEL COMPOUND AND SYNTHESIS METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2017/170934
Kind Code:
A1
Abstract:
The present invention pertains to an acetylacetone derivative which is useful in trapping metal elements by complex formation, and a simple and highly versatile synthesis method therefor. More specifically, the present invention pertains to a compound represented by general formula (1).
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Inventors:
KATO TAKASHI (JP)
KAWATA KEN (JP)
KAWATA KEN (JP)
Application Number:
PCT/JP2017/013404
Publication Date:
October 05, 2017
Filing Date:
March 30, 2017
Export Citation:
Assignee:
UNIV TOKYO (JP)
International Classes:
C07C271/48; C07C45/68; C07C49/825; C07C49/92; C07C67/343; C07C69/716; C07C269/06; C07F9/53; C08F22/20; C08L101/00; C09K3/00
Foreign References:
| US4500601A | 1985-02-19 | |||
| JP2014504632A | 2014-02-24 | |||
| JPS5931768A | 1984-02-20 | |||
| JP2002138069A | 2002-05-14 | |||
| JPH11199855A | 1999-07-27 | |||
| JPH111625A | 1999-01-06 |
Other References:
LI, NAN-SHENG ET AL.: "Synthesis of 2-Acyl-1,4- diketones via the Diacylation of alpha,beta- Unsaturated Ketones", ORGANOMETALLICS, vol. 17, no. 17, 1998, pages 3815 - 3818, XP055431368
BARUAH, JUBARAJ B. ET AL.: "Copper(I) promoted allylic nucleophilic substitutions: a synthetic and mechanistic study", NEW JOURNAL OF CHEMISTRY, vol. 18, no. 8-9, 1994, pages 961 - 971
IBATA, TOSHIKAZU ET AL.: "Reaction of diazo ketones in the presence of metal chelates. Reaction with beta-diketones", CHEMISTRY LETTERS, 1976, pages 1267 - 1270
MENG, XU ET AL.: "Heterogeneous synthesis of 1,4-enediones and 1,4-diketones with manganese oxide molecular sieves OMS-2 as a recyclable catalyst", CATALYSIS COMMUNICATIONS, vol. 69, 2015, pages 239 - 242, XP055431374
KUMARI, NEETU ET AL.: "Synthesis of some novel beta-diketones and beta-ketoesters of 4-methyl sulphonyl benzoyl methylene bromide", CHEMICAL SCIENCE TRANSACTIONS, vol. 2, no. 1, 2013, pages 81 - 84, XP055432546
FAN, XUESEN ET AL.: "Tandem reaction of 1,2- allenic ketone with a-halo ketone or a-halo ester in water: an efficient and sustainable synthesis of 1,3,4'-tricarbonyl compounds", GREEN CHEMISTRY, vol. 13, no. 11, 2011, pages 3218 - 3223, XP055431402
MATANO, YOSHIHIRO ET AL.: "A novel synthesis of alkylbismuthonium salts and their reaction with some nucleophiles . First x-ray structural analysis of a stabilized alkylbismuthonium tetrafluoroborate", TETRAHEDRON LETTERS, vol. 34, no. 52, 1993, pages 8457 - 8460, XP055431407
STETTER, HERMANN ET AL.: "Addition of aldehydes to activated double bonds. XXV. Syntheses and reactions of branched tricarbonyl compounds", CHEMISCHE BERICHTE, vol. 114, no. 2, 1981, pages 564 - 580, XP002904299
BARUAH, JUBARAJ B. ET AL.: "Copper(I) promoted allylic nucleophilic substitutions: a synthetic and mechanistic study", NEW JOURNAL OF CHEMISTRY, vol. 18, no. 8-9, 1994, pages 961 - 971
IBATA, TOSHIKAZU ET AL.: "Reaction of diazo ketones in the presence of metal chelates. Reaction with beta-diketones", CHEMISTRY LETTERS, 1976, pages 1267 - 1270
MENG, XU ET AL.: "Heterogeneous synthesis of 1,4-enediones and 1,4-diketones with manganese oxide molecular sieves OMS-2 as a recyclable catalyst", CATALYSIS COMMUNICATIONS, vol. 69, 2015, pages 239 - 242, XP055431374
KUMARI, NEETU ET AL.: "Synthesis of some novel beta-diketones and beta-ketoesters of 4-methyl sulphonyl benzoyl methylene bromide", CHEMICAL SCIENCE TRANSACTIONS, vol. 2, no. 1, 2013, pages 81 - 84, XP055432546
FAN, XUESEN ET AL.: "Tandem reaction of 1,2- allenic ketone with a-halo ketone or a-halo ester in water: an efficient and sustainable synthesis of 1,3,4'-tricarbonyl compounds", GREEN CHEMISTRY, vol. 13, no. 11, 2011, pages 3218 - 3223, XP055431402
MATANO, YOSHIHIRO ET AL.: "A novel synthesis of alkylbismuthonium salts and their reaction with some nucleophiles . First x-ray structural analysis of a stabilized alkylbismuthonium tetrafluoroborate", TETRAHEDRON LETTERS, vol. 34, no. 52, 1993, pages 8457 - 8460, XP055431407
STETTER, HERMANN ET AL.: "Addition of aldehydes to activated double bonds. XXV. Syntheses and reactions of branched tricarbonyl compounds", CHEMISCHE BERICHTE, vol. 114, no. 2, 1981, pages 564 - 580, XP002904299
Attorney, Agent or Firm:
ONO Makoto et al. (JP)
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