Title:
Α-OLEFIN OLIGOMER AND PRODUCTION METHOD THEREOF
Document Type and Number:
WIPO Patent Application WO/2013/024701
Kind Code:
A1
Abstract:
Provided are: an α-olefin oligomer fulfilling (1)-(6) below; an α-olefin oligomer which is produced with an α-olefin oligomer production method using a specific double-cross-linked meso-type complex and which has a low amount of dimer components while having a low viscosity without following the Schulz-Flory distribution; and a production method of said α-olefin oligomers. (1) The trimer component proportion C3 (mass%) is higher than the theoretical value found by means of the S-F distribution. (2) The hexamer component proportion C6 (mass%) is lower than the theoretical value found by means of the S-F distribution. (3) 100°C kinematic viscosity is 20mm2/s or less. (4) The mesotriad fraction [mm] measured by 13C-NMR is 40 mol% or less. (5) There are 0.2-1.0 vinylidene groups per 1 molecule. (6) The average carbon number of monomer units is 6-30. Here, the aforementioned S-F distribution is computed on the basis of chain growth probability α calculated from the dimer component proportion C2 (mass%).
Inventors:
TSUJI MINAKO (JP)
OKAMOTO TAKUJI (JP)
FUJIMURA TAKENORI (JP)
MINAMI YUTAKA (JP)
OKAMOTO TAKUJI (JP)
FUJIMURA TAKENORI (JP)
MINAMI YUTAKA (JP)
Application Number:
PCT/JP2012/069511
Publication Date:
February 21, 2013
Filing Date:
July 31, 2012
Export Citation:
Assignee:
IDEMITSU KOSAN CO (JP)
TSUJI MINAKO (JP)
OKAMOTO TAKUJI (JP)
FUJIMURA TAKENORI (JP)
MINAMI YUTAKA (JP)
TSUJI MINAKO (JP)
OKAMOTO TAKUJI (JP)
FUJIMURA TAKENORI (JP)
MINAMI YUTAKA (JP)
International Classes:
C08F10/14; C07C2/24; C07C11/02; C07F17/00; C08F4/6592
Domestic Patent References:
| WO2010117028A1 | 2010-10-14 | |||
| WO2012035710A1 | 2012-03-22 | |||
| WO2003070790A1 | 2003-08-28 | |||
| WO2010053022A1 | 2010-05-14 | |||
| WO2010117028A1 | 2010-10-14 |
Foreign References:
| JP2001335607A | 2001-12-04 | |||
| JP2009057573A | 2009-03-19 | |||
| JP2000095808A | 2000-04-04 | |||
| JPH10259207A | 1998-09-29 | |||
| JP2001335607A | 2001-12-04 | |||
| JP2009501836A | 2009-01-22 |
Other References:
J. AM. CHEM. SOC., vol. 62, no. 6, 1940, pages 1561 - 1565
ADV. POLYMER. SCI, vol. 15, no. 1, 1974, pages 1 - 30
J. AM. CHEM. SOC., vol. 126, 2004, pages 10701 - 10712
MACROMOLECULES, vol. 24, 1991, pages 2334
POLYMER, vol. 30, 1989, pages 1350
ADV. POLYMER. SCI, vol. 15, no. 1, 1974, pages 1 - 30
J. AM. CHEM. SOC., vol. 126, 2004, pages 10701 - 10712
MACROMOLECULES, vol. 24, 1991, pages 2334
POLYMER, vol. 30, 1989, pages 1350
Attorney, Agent or Firm:
OHTANI, Tamotsu et al. (JP)
Tamotsu Otani (JP)
Tamotsu Otani (JP)
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