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Title:
ORGANIC METAL COMPLEX, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC EQUIPMENT, AND ILLUMINATION APPARATUS
Document Type and Number:
WIPO Patent Application WO/2023/156886
Kind Code:
A1
Abstract:
Provided is a new organic metal complex that improves the light emission efficiency of a light-emitting device. The present invention provides an organic metal complex represented by general formula (G1). In the formula, X represents carbon or nitrogen, and the carbon is bonded to hydrogen (including deuterium), a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, or a substituted or unsubstituted aryl group. In addition, R1-R3 each independently represent hydrogen (including deuterium), a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, or a substituted or unsubstituted aryl group. Further, n represents an integer of 1-4. The respective borate ligands may be the same or different from each other. Each n may be the same or different from the others. When n is equal to or more than 2, X, R1, and R2 may each be the same or different from the others. When n is equal to or less than 2, each R3 may be the same or different from the others.

Inventors:
TSUNOI TOSHIAKI (JP)
YAMAGUCHI TOMOYA (JP)
YOSHIZUMI HIDEKO (JP)
SEO SATOSHI (JP)
Application Number:
PCT/IB2023/051143
Publication Date:
August 24, 2023
Filing Date:
February 09, 2023
Export Citation:
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Assignee:
SEMICONDUCTOR ENERGY LAB (JP)
International Classes:
C07F5/02; C09K11/06; H10K50/00; C07D231/12; C07F5/00; C07F19/00
Domestic Patent References:
WO2021159918A12021-08-19
Foreign References:
JP2012246230A2012-12-13
CN114057780A2022-02-18
Other References:
FANG, PEIYU ET AL.: "Lanthanide Cerium(III) Tris(pyrazolyl)borate Complexes: Efficient Blue Emitters for Doublet Organic Light-Emitting Diodes", ACS APPLIED MATERIALS AND INTERFACES, vol. 13, no. 38, 2021, pages 45686 - 45695, XP055964855, DOI: 10.1021/acsami.1c09718
CARVALHO, ADELAIDE ET AL.: "Dihydrobis(3,5-dimethylpyrazolyl)borate derivatives of f elements", POLYHEDRON, vol. 11, no. 12, 1992, pages 1481 - 1488, XP093085212, DOI: 10.1016/S0277-5387(00)83141-1
WANG LIDING, ZHAO ZIFENG, ZHAN GE, FANG HUAYI, YANG HANNAN, HUANG TIANYU, ZHANG YUEWEI, JIANG NAN, DUAN LIAN, LIU ZHIWEI, BIAN ZUQ: "Deep-blue organic light-emitting diodes based on a doublet d–f transition cerium(III) complex with 100% exciton utilization efficiency", LIGHT: SCIENCE & APPLICATIONS, vol. 9, no. 1, 1 December 2020 (2020-12-01), XP055964819, DOI: 10.1038/s41377-020-00395-4
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