Title:
ORGANOPOLYSILOXANE AND ACTIVE-ENERGY-RAY CURABLE COMPOSITION CONTAINING SAME
Document Type and Number:
WIPO Patent Application WO/2020/246312
Kind Code:
A1
Abstract:
[Problem] To provide: an organopolysiloxane that has a superior compatibility with various polymerizable unsaturated compounds and that has a high refractive index; and an active-energy-ray curable composition that contains said organopolysiloxane and that could generate a cured product that has superior adhesion with respect to a base material and superior flex resistance. [Solution] An organopolysiloxane has at least one siloxane unit represented by formula (I). Formula (I) (In the formula, R1 is a group that is represented, independently of each other, by formula (II); R2 is, independently of each other, a hydrogen atom or a group that is selected from a C1-8 alkyl group that is optionally substituted by a halogen atom, a C6-12 aryl group that is optionally substituted by a halogen atom, a (meth)acryloyloxypropyl group, and a glycydoxypropyl group; X is a single bond or a C1-6 divalent hydrocarbon group; Z is a C1-6 divalent hydrocarbon group; n is an integer of 1-3; and r is an integer of 1-3) Formula (II) (In the formula, R3 is a hydrogen atom, a C1-8 alkyl group that is optionally substituted by a halogen atom, a C2-8 alkenyl group, or a C6-12 aryl group that is optionally substituted by a halogen atom)
Inventors:
UCHIDA SAKI (JP)
GOTO YUTA (JP)
FUJIMOTO TAKUYA (JP)
GOTO YUTA (JP)
FUJIMOTO TAKUYA (JP)
Application Number:
PCT/JP2020/020729
Publication Date:
December 10, 2020
Filing Date:
May 26, 2020
Export Citation:
Assignee:
SHINETSU CHEMICAL CO (JP)
International Classes:
C08F299/08; C08G77/20; C08G77/28
Foreign References:
| JP2015151405A | 2015-08-24 | |||
| JPH0253844A | 1990-02-22 | |||
| CN101649052A | 2010-02-17 |
Other References:
PÉRINEAU FABIEN, PENSEC SANDRINE, SANCHEZ CLÉMENT, CRETON COSTANTINO, ROZES LAURENCE, BOUTEILLER LAURENT: "Supramolecular design for polymer/titanium oxo-cluster hybrids: an open door to new organic-inorganic dynamers", POLYMER CHEMISTRY, vol. 2, no. 12, 2011, pages 2785 - 2788, XP055769283, ISSN: 1759-9962
CHEN, HUNG-TING: "Urea and Thiourea-Functionalized Mesoporous Silica Nanoparticle Catalysts with Enhanced Catalytic Activity for Diels-Alder Reaction", TOPICS IN CATALYSIS, vol. 53, no. 3-4, 2010, pages 187 - 191, XP019795731, ISSN: 1022-5528
BORONI ERMETE, PREDIERI GIOVANNI, TIRIPICCHIO ANTONIO, TIRIPICCHIO CAMELLINI MARISA: "Reactivity of double thioureas towards metal complexes . Synthesis and crystal structure of ruthenium cluster H)Ru3(CO)9}2{SC(NPh)N(Et)( CH 2)2NH(PhN) CS", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 451, no. I-2, 1993, pages 163 - 168, XP055769286, ISSN: 0022-328X
ZUB YU L, MELNYK I. V, CHUIKO A. A, CAUZZI D, PREDIERI G: "Design of functionalized polysiloxanes: synthesis and study on sulfur-containing xerogels with mono- and bifunctional surface layer", KHIMIYA, FIZIKA TA TEKHNOLOGIYA POVERKHNI, 2002, pages 35 - 45, XP055769046
CAUZZI, DANIELE: "Anchoring rhodium(I) on thiourea-functionalized silica xerogels and silsesquioxanes. Part II. matrix effects on the selectivity in the hydroformylation of styrene", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 541, no. 1-2, 1997, pages 377 - 389, XP004093737, ISSN: 0022-328X, DOI: 10.1016/S0022-328X(97)00089-2
ZUB, YU. L.: "Single-step template synthesis of mesoporous silicas containing thiourea functional groups", FUNCTIONAL MATERIALS, vol. 13, no. 2, 2006, pages 274 - 279, XP055769034, ISSN: 1027-5495
BAIGOZHIN, A.: "Reaction of 3-(triethoxysilyl)propylamine with allyl and phenyl isothiocyanates", JOURNAL OF GENERAL CHEMISTRY OF THE USSR, vol. 43, no. 6, 1973, pages 1396
CHEN, HUNG-TING: "Urea and Thiourea-Functionalized Mesoporous Silica Nanoparticle Catalysts with Enhanced Catalytic Activity for Diels-Alder Reaction", TOPICS IN CATALYSIS, vol. 53, no. 3-4, 2010, pages 187 - 191, XP019795731, ISSN: 1022-5528
BORONI ERMETE, PREDIERI GIOVANNI, TIRIPICCHIO ANTONIO, TIRIPICCHIO CAMELLINI MARISA: "Reactivity of double thioureas towards metal complexes . Synthesis and crystal structure of ruthenium cluster H)Ru3(CO)9}2{SC(NPh)N(Et)( CH 2)2NH(PhN) CS", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 451, no. I-2, 1993, pages 163 - 168, XP055769286, ISSN: 0022-328X
ZUB YU L, MELNYK I. V, CHUIKO A. A, CAUZZI D, PREDIERI G: "Design of functionalized polysiloxanes: synthesis and study on sulfur-containing xerogels with mono- and bifunctional surface layer", KHIMIYA, FIZIKA TA TEKHNOLOGIYA POVERKHNI, 2002, pages 35 - 45, XP055769046
CAUZZI, DANIELE: "Anchoring rhodium(I) on thiourea-functionalized silica xerogels and silsesquioxanes. Part II. matrix effects on the selectivity in the hydroformylation of styrene", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 541, no. 1-2, 1997, pages 377 - 389, XP004093737, ISSN: 0022-328X, DOI: 10.1016/S0022-328X(97)00089-2
ZUB, YU. L.: "Single-step template synthesis of mesoporous silicas containing thiourea functional groups", FUNCTIONAL MATERIALS, vol. 13, no. 2, 2006, pages 274 - 279, XP055769034, ISSN: 1027-5495
BAIGOZHIN, A.: "Reaction of 3-(triethoxysilyl)propylamine with allyl and phenyl isothiocyanates", JOURNAL OF GENERAL CHEMISTRY OF THE USSR, vol. 43, no. 6, 1973, pages 1396
Attorney, Agent or Firm:
MATSUI Mitsuo et al. (JP)
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