Title:
OSMIUM OXIDE DEPOSITED ON HYDROPHILIC POLYMER SUPPORT
Document Type and Number:
WIPO Patent Application WO/2002/072259
Kind Code:
A1
Abstract:
A support for osmium oxide supporting which comprises an aromatic polyolefin having a group represented by the general formula [1] -A'-O(-A-O)¿n?-R [1] (wherein A represents alkylene; A' represents a bond or alkylene; R represents aryl; and n is an integer of 1 to 10); osmium oxide deposited on the support; and a process for producing the osmium oxide. Since the osmium oxide has been deposited on the support having a hydrophilic group, it enables a diol compound to be easily produced in a high optical yield through oxidation or asymmetric oxidation especially in a heterogeneous system. It is usable safely and effectively also in the reactions of compounds including those which have been difficult to react in a nonaqueous solvent system.
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Inventors:
KOBAYASHI SHU (JP)
Application Number:
PCT/JP2002/002179
Publication Date:
September 19, 2002
Filing Date:
March 08, 2002
Export Citation:
Assignee:
WAKO PURE CHEM IND LTD (JP)
KOBAYASHI SHU (JP)
KOBAYASHI SHU (JP)
International Classes:
B01J13/02; B01J23/46; B01J31/06; B01J31/28; C07B53/00; C07C29/48; C07C45/30; C07F15/00; (IPC1-7): B01J31/06; B01J32/00; C07B53/00; C07C29/48; C07C33/26; C08F8/00
Foreign References:
| EP0252254A1 | 1988-01-13 |
Other References:
KOBAYASHI S. ET AL.: "Catalytic asymmetric dihydroxylation using phenoxyethoxymethyl-polystyrene (PEM)-based novel microencapsulated osmium tetroxide (PEM-MC OSO4)", ORG. LETT., vol. 3, no. 17, 23 August 2001 (2001-08-23), pages 2649 - 2652, XP002951803
ISHIDA TASUKU ET AL.: "Shinki micro capsule-ka yonsanka osmium o michiiru fusei dihydroxyl-ka hanno no kaihatsu", CSJ: THE CHEMICAL SOCIETY OF JAPAN, 69TH SHUNKI NENKAI KOEN YOKOSHU, vol. 79, no. 2, 15 March 2001 (2001-03-15), pages 1141, XP002951804
CAINELLI G. ET AL.: "Cleavage of olefins by polymer-supported osmium tetroxide and sodium periodate", SYNTHESIS, no. 1, 1989, pages 47 - 48, XP000020883
KOBAYASHI S. ET AL.: "Catalytic asymmetric dihydroxylation of olefins using a recoverable and reusable polymer-supported osmium catalyst", J. AM. CHEM. SOC., vol. 121, no. 48, 1999, pages 11229 - 11230, XP002951805
See also references of EP 1366814A4
ISHIDA TASUKU ET AL.: "Shinki micro capsule-ka yonsanka osmium o michiiru fusei dihydroxyl-ka hanno no kaihatsu", CSJ: THE CHEMICAL SOCIETY OF JAPAN, 69TH SHUNKI NENKAI KOEN YOKOSHU, vol. 79, no. 2, 15 March 2001 (2001-03-15), pages 1141, XP002951804
CAINELLI G. ET AL.: "Cleavage of olefins by polymer-supported osmium tetroxide and sodium periodate", SYNTHESIS, no. 1, 1989, pages 47 - 48, XP000020883
KOBAYASHI S. ET AL.: "Catalytic asymmetric dihydroxylation of olefins using a recoverable and reusable polymer-supported osmium catalyst", J. AM. CHEM. SOC., vol. 121, no. 48, 1999, pages 11229 - 11230, XP002951805
See also references of EP 1366814A4
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