Title:
PALLADIUM CATALYST AND PROCESS FOR PRODUCTION OF BISARYL COMPOUND USING SAME
Document Type and Number:
WIPO Patent Application WO/2011/062109
Kind Code:
A1
Abstract:
Disclosed are: a novel palladium catalyst which does not undergo leakage, can be recycled, does not require the use of any phosphorus-containing ligand, and has a high catalytic activity; and a process for producing a novel bisaryl compound using the palladium catalyst. In the production of a bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of a palladium catalyst and a base, the palladium catalyst comprises a dendrimer containing a silica particle as a core and a palladium compound dissolved in an ionic liquid and supported on the dendrimer.
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Inventors:
HAGIWARA HISAHIRO (JP)
TSUBOKAWA NORIO (JP)
TSUBOKAWA NORIO (JP)
Application Number:
PCT/JP2010/070101
Publication Date:
May 26, 2011
Filing Date:
November 11, 2010
Export Citation:
Assignee:
UNIV NIIGATA (JP)
HAGIWARA HISAHIRO (JP)
TSUBOKAWA NORIO (JP)
HAGIWARA HISAHIRO (JP)
TSUBOKAWA NORIO (JP)
International Classes:
C07C1/32; B01J31/04; C07C15/14; C07C41/30; C07C43/205; C07C45/68; C07C49/784; C07C49/84; C07B61/00; C07F7/18; C07F15/00
Domestic Patent References:
| WO2008118097A1 | 2008-10-02 |
Foreign References:
| JP2008184418A | 2008-08-14 |
Other References:
HAGIWARA, H. ET AL.: "Nano-silica PAMAM Dendrimer as a Novel Catalyst for Knoevenagel Reactions", CHEM. LETT., vol. 38, no. 9, September 2009 (2009-09-01), pages 926 - 927
ALPER, H. ET AL.: "Heck reaction using palladium complexed to dendrimers on silica", CAN. J. CHEM., vol. 78, no. 6, June 2000 (2000-06-01), pages 920 - 924
LI, Y. ET AL.: "The Effect of Stabilizers on the Catalytic Activity and Stability of Pd Colloidal Nanoparticles in the Suzuki Reactions in Aqueous Solution", J. PHYS. CHEM. B, vol. 105, no. 37, September 2001 (2001-09-01), pages 8938 - 8943
"90th Annual Meeting of Chemical Society of Japan in Spring (2010) Koen Yokoshu IV", March 2010, article HISAHIRO HAGIWARA ET AL.: "Nano Silica Dendrimer Koteika Pd Shokubai no Kaihatsu to Suzuki-Miyaura Hanno eno Tenkai", pages: 1557
ALPER, H. ET AL.: "Heck reaction using palladium complexed to dendrimers on silica", CAN. J. CHEM., vol. 78, no. 6, June 2000 (2000-06-01), pages 920 - 924
LI, Y. ET AL.: "The Effect of Stabilizers on the Catalytic Activity and Stability of Pd Colloidal Nanoparticles in the Suzuki Reactions in Aqueous Solution", J. PHYS. CHEM. B, vol. 105, no. 37, September 2001 (2001-09-01), pages 8938 - 8943
"90th Annual Meeting of Chemical Society of Japan in Spring (2010) Koen Yokoshu IV", March 2010, article HISAHIRO HAGIWARA ET AL.: "Nano Silica Dendrimer Koteika Pd Shokubai no Kaihatsu to Suzuki-Miyaura Hanno eno Tenkai", pages: 1557
Attorney, Agent or Firm:
USHIKI, Mamoru (JP)
牛木 護 (JP)
牛木 護 (JP)
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