Title:
PHENYL ANHYDRIDE-ETHYLENE OXIDE QUATERNARY COPOLYMER
Document Type and Number:
WIPO Patent Application WO/2023/045898
Kind Code:
A1
Abstract:
The present invention relates to a phenyl anhydride-ethylene oxide quaternary copolymer. For the phenyl anhydride-ethylene oxide quaternary copolymer, preparation raw materials comprise copolymer monomers and a catalyst; the copolymer monomers are selected from ethylene oxide, propylene oxide, phenyl anhydride, and carbon dioxide. Under the control of the preparation raw materials and conditions of this system, it can be ensured that the prepared copolymer is of an irregular structure or a block structure, thereby ensuring that ethylene oxide exists in the middle of phenyl anhydride, then ensuring that a prepared material have a high internal plasticization effect, and ensuring that the molecular weight can reach 1.0×105 g/mol and the reaction time is shortened. The application prospect of the prepared material in the plastic field is increased while ensuring that the prepared material has good degradation performance.
Inventors:
WEI HUAIJIAN (CN)
LI HONGGUO (CN)
LI YIGE (CN)
GAO YUFEI (CN)
WANG BO (CN)
DONG LIANG (CN)
LI HONGGUO (CN)
LI YIGE (CN)
GAO YUFEI (CN)
WANG BO (CN)
DONG LIANG (CN)
Application Number:
PCT/CN2022/119766
Publication Date:
March 30, 2023
Filing Date:
September 20, 2022
Export Citation:
Assignee:
SHANDONG LECSIN GREEN TECH CO LTD (CN)
International Classes:
C08G64/34; C08G63/00; C08G63/64; C08G64/00; C08G64/18
Foreign References:
| CN114524930A | 2022-05-24 | |||
| CN114524929A | 2022-05-24 | |||
| CN114539743A | 2022-05-27 | |||
| CN114525025A | 2022-05-24 | |||
| CN1831029A | 2006-09-13 | |||
| CN111378101A | 2020-07-07 | |||
| CN111333825A | 2020-06-26 | |||
| US4851507A | 1989-07-25 |
Other References:
TAKAZO AIDA, MASAHIDE ISHIKAWA, SHOHEI INOUE: "Alternating copolymerization of carbon dioxide and epoxide catalyzed by the aluminum porphyrin-quaternary organic salt or -triphenylphosphine system. Synthesis of polycarbonate with well-controlled molecular weight", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, US, vol. 19, no. 1, 1 January 1986 (1986-01-01), US , pages 8 - 13, XP055296565, ISSN: 0024-9297, DOI: 10.1021/ma00155a002
ZOU YINGNAN, WANG SHUAN-JIN, XIAO MIN, MENG YAOZHONG: "Synthesis and Characterization of Terpolymer Polycarbonates from Propylene Oxide and Ethylene Oxide with Carbonate Dioxide", GAOFENZI-CAILIAO-KEXUE-YU-GONGCHENG = POLYMER MATERIALS SCIENCE AND ENGINEERING, CHENGDU KEJI DAXUE GAOFENZI YANJIUSUO, CN, vol. 23, no. 2, 30 March 2007 (2007-03-30), CN , pages 120 - 123, XP093055116, ISSN: 1000-7555, DOI: 10.16865/j.cnki.1000-7555.2007.02.030
LIU, YULEI ET AL.: "Mechanism studies of terpolymerization of phthalic anhydride, propylene epoxide, and carbon dioxide catalyzed by ZnGA", RSC ADVANCES, vol. 4, no. 19, 19 March 2014 (2014-03-19), XP093053558, ISSN: 2046-2069, DOI: 10.1039/C3RA46343E
ZOU YINGNAN, WANG SHUAN-JIN, XIAO MIN, MENG YAOZHONG: "Synthesis and Characterization of Terpolymer Polycarbonates from Propylene Oxide and Ethylene Oxide with Carbonate Dioxide", GAOFENZI-CAILIAO-KEXUE-YU-GONGCHENG = POLYMER MATERIALS SCIENCE AND ENGINEERING, CHENGDU KEJI DAXUE GAOFENZI YANJIUSUO, CN, vol. 23, no. 2, 30 March 2007 (2007-03-30), CN , pages 120 - 123, XP093055116, ISSN: 1000-7555, DOI: 10.16865/j.cnki.1000-7555.2007.02.030
LIU, YULEI ET AL.: "Mechanism studies of terpolymerization of phthalic anhydride, propylene epoxide, and carbon dioxide catalyzed by ZnGA", RSC ADVANCES, vol. 4, no. 19, 19 March 2014 (2014-03-19), XP093053558, ISSN: 2046-2069, DOI: 10.1039/C3RA46343E
Attorney, Agent or Firm:
BEIJING GAOWO LAW FIRM (CN)
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