Description The present invention relates to surface functionalized titanium dioxide nanoparticles, a method for its production, a coating composition, comprising the surface functionalized titanium dioxide nanoparticles and the use of the coating composition for coating holo ^¬ grams, wave guides and solar panels. Holograms are bright and visible from any angle, when printed with the coating composition, comprising the surface functionalized tita- nium dioxide nanoparticles.

EP0707051 relates to treated inorganic solid comprising particulate titanium dioxide or zinc oxide, the particles of which are coated with a composition consisting essentially of an organophosphorus compound selected from the group consisting of alkylphosphonic acids and esters of alkylphosphonic acids wherein the alkylphosphonic acid contains from 8 to 22 carbon atoms. The titanium dioxide particles have an average primary particle size in the range of 10 to 150 nm.

H. Weller et al. J. Amer. Chem. Soc. 125 (2003) 14539 describe the synthesis of high as- pect ration anastase T1O2 nanorods by hydrolysis of titanium tetraisopropoxide in oleic acid at a tempertature as low as 80 °C. Typically the T1O2 nanorods have uniform lengths up to 40nm and a diameter of 3 to 4 nm.

B. Wang et al., Macromolecules 24 (1991) 3449 describe the preparation of high refractive index organic/inorganic hybrid materials from sol-gel processing.

R. Himmelhuber et al., Optical Materials Express 1 (2011) 252 describe titanium oxide sol gel films with tunable refractive index. US2012276683 describes the preparation of titania pastes. Hydrochloric acid as a catalyst and distilled water as a dispersing medium are mixed at room temperature of about 20 °C to 25 °C at a molar ratio of hydrochloric acid to distilled water of 0.5:351.3. Next, one mole of titanium tetraisopropoxide as a titanium precursor is added to the solution under continuous stirring, forming a thick, white precipitate. Finally, the sol is peptized for about two hours to form a clear titania sol. The titania nanoparticles exhibit a narrow size distri ^¬ bution ranging from about 10 nm to about 27 nm with an average particle size of 19 nm. During experimentation, it was found that the titania sol was stable for at least seven months. US2005164876 relates to the preparation of photocatalysts. 10 g of titanium isopropoxide (TTI P, Acros) was slowly added at room temperature to a solution of absolute ethanol (EtOH) in a breaker under vigorously stirred for 0.5 h to prevent a local concentration of the TTI P solution. EtOH mixed with nitric acid was added to the solution to promote hy ^¬ drolysis. Polyethylene glycol (PEG, Acros) 600 was added to the solution and stirred for 1 h. The solution was then ultra sounded for 0.5 h and left for 24 h before being used. The molar ratio of TTI P:EtOH:PEG was 1:15:10, corresponding to 5 weight percent of T1O2 in order to compare the photodegradation using P25. Photocatalyst T1 was immobilized on glass fiber by dip-coating. The glass fiber was loaded into the solution for 30 min and re ^¬ tracted at a rate of 10 mm/s. The glass fiber was dried at 100 °C for 2 h and then calci ^¬ nated at 450 °C for 2 h at a heating rate of 5.5 °C /min in air. The average crystallite size of T1 deposited on glass fiber was 9.8 nm.

WO200 nanoparticles coated with phosphonates of for-

mula (I) . The process of production of the metal oxide nanoparticles coated with phosphonates of formula (I) involves mixing the metal oxides with the phosphonates of formula (I) in an organic solvent at elevated temperature. In Ex ^¬ ample 17 of WO2006094915 titanium dioxide P25 (0 ca. 21 nm, available from DEGUSSA) was coated with the phosphonate compounds.

US2011226321 relates to titanium dioxide nano particles capped with a surface stabilizer represented by any one of Chemical Formulae 1 to 3:

The method for preparing the titanium dioxide nano particles comprises: mixing and re ^¬ acting titanium isopropoxide with a surface stabilizer represented by any one of Chemical Formulae 1 to 3 in a solvent; and evaporating the solvent from thus produced titanium dioxide colloid.

G. J. Ruitencamp et al. J. Nanopart,. Res. 2011, 13, 2779 reports the surface functionaliza- tion of rutile titanium dioxide with 1-decylphosponic acid and diethyl undec-10-enyl phos ^¬ phonate in a two-stage process. The dual-functionalized particles possessed a uniform size of around 13 nm. Transparent nanocomposites were formed by introducing the func- tionalized nanoparticles into a poly(benzyl acrylate) matrix. A polymer containing 14.0 vol.% T1O2 had a refractive index of 1.63 at λ = 586 nm.

For many optical applications, high refractive index materials are highly desirable. However, those materials consist of metal oxides e.g Z 0 ₂ (Rl (Refractive Index) ca. 2.13) or T1O2 (Rl ca. 2.59) which are not easy to process in printing lacquers and are incompatible with merely organic carrier materials or organic overcoats. A number of methods for compati- bilizing e.g. TiCVsurfaces have been described (D. Geldof et al. Surface Science, 2017, 655, 31). However, carboxylate ligands or siloxane ligands - which always give high amounts of unwanted homocondensation by-products - although easily prepared are not stable to ^¬ ward hydrolysis. Highly stable surface coatings may be achieved with phosphonate ligands (WO 2006/094915). The Ti-O-P bonding is highly stable and forms the required colorless coats (R. Luschtinetz et al. J. Phys. Chem. C 2009, 113, 5730). The adsorption and chemical stable bonding also takes place rapidly. The stability of phosphonate ligands is based on the specific binding mode of the phosphonate (phosphate) moiety on TiCVsurfaces. Po- tentially, three oxygen atoms can attach to the metal surface resulting in enhanced surface binding.

I n addition, besides being cheap and non-toxic T1O2 nanoparticles can be prepared in var ^¬ ious core sizes. The preferred particle size however, should be < 40 nm, in order to avoid the Rayleigh' s scattering in the visible spectrum range (W. Casari et al. Chem. Eng. Com- mun. 2009, 196, 549) and thus forming a transparent material.

There is however a problem associated with T1O2 nanoparticles prepared by the sol-gel method. These particles - as known from any nano-particle preparation - tend to agglom ^¬ erate and subsequently precipitate from aqueous or organic solutions, so appropriate treating (protection) of the TiCVnano-particles is a necessity for storage and applications in printing lacquers. However, when coated with organic material the refractive index of the T1O2 nanocrystals gets 'diluted' as the molar fraction is reduced according the equa ^¬ tion:

(l -L)-t? _W;P

n

! -¾ _P j _^ : i -L)-fl _W! p ^ L _wp

fim i½i¾ ^' ft ⁷

wherein Θ _ν ηο2 is the volume fraction of TiCVmaterial, 0 _w,p is weight fraction functionalized particle in nano-composite, L weight fraction (loss) of volatiles e.g. alcohols or water, ρ ο2 density of T1O2, p _m density of coating matrix, pf density of functionalization layer on parti ^¬ cles (G. J. Ruitencamp et al. J. Nanopart,. Res. 2011, 13, 2779). So, keeping up a high refrac ^¬ tive index and achieving the desired stability of the hybrid particles necessitates a well- balanced ratio of inorganic and organic surface treatment. According the equation the low refractive organics should be kept at such a minimum, only rendering the particles soluble and processable and not 'diluting' the refractive index of the particles too much. This can be achieved following the inventive description given below.

One aspect of the present invention relates to the preparation of transparent, redissolva- ble storage stable T1O2 nanoparticles via a so-called sol-gel process resulting in high re ^¬ fractive index material.

The process for preparing titanium dioxide nanoparticles comprises

(a) adding a solution of concentrated hydrogen chloride (33% in water) diluting this solu ^¬ tion with half volume of distilled water (60 - 29.8 / volume-volume) diluting this solution with additional ethanol (90 - 1910 / volume-volume) (resulting in solution I) to a solution of titanium-tetra-/ 0-propoxide first stirred in (absolute) ethanol (10 - 90 / weight-vol ^¬ ume) resulting in a solution I I, both volumes I and I I being equal,

(b) stirring the obtained clear solution for 5 days at room temperature, and (c) evaporating the clear solution at 20 - 30°C/20mm until a constant weight is achieved to obtain titanium dioxide nanoparticles.

The titanium dioxide nanoparticles obtainable by the above process have a particle size from 1 nm to 40 nm, preferably from 1 nm to 10 nm, more preferably from 1 nm to 5 nm. They are storable at 4 °C for at least 3 months and can be redissolved in methanol, etha ^¬ nol, propanol, 2-methoxy ethanol, /io-propanol, 2 -/ 0- pro poxy ethanol, butanol, N-me- thyl pyrrolidone, dimethyl formamide, ethyl acetate, propyl acetate, butyl acetate and di ^¬ methyl acetamide. A film of the titanium dioxide nanoparticles which is dried at 25 °C shows a refractive index of greater than 1.70 (589 nm), especially of greater than 1.75, very especially of greater than 1.80. The refractive index may be even 1.95, when the film of the titanium dioxide nanoparticles is dried at 120 °C.

The TiCVcontent of the titanium dioxide nanoparticles is at least 40 % (w) (% by weight), preferably at least 45 % (w) and most preferably al least 50 % (w) confirmed by differen ^¬ tial scanning colorimetry (DSC).

I n another aspect, the present invention relates to the surface functionalization of the T1O2 nanoparticles by both phosphonates and alkoxides. Preferably, either the alkoxides or pref- erably the phosphonates bear a polymerizable moiety, preferably an olefinic double bond polymerizable via photo initiation and/or radical initiation. The coating of the T1 O2 nano ^¬ particles by phosphonates and alkoxides can be performed subsequently or stepwise in either order or simultaneously. The process for the production of the surface functionalized titanium dioxide nanoparticles comprises the following steps:

a) dissolving the titanium dioxide nanoparticles in a solvent, such as, for example, ethanol, or isopropanol,

b) adding the phosphonate of formula (I) and optionally the alcohol of formula

(c) stirring the mixture obtained in step (b) until a transparent solution is obtained, and

(d) evaporating the mixture until the weight remains constant.

The titanium dioxide nanoparticles employed in the process for the production of the sur face functionalized titanium dioxide nanoparticles are prefereably the titanium dioxide na noparticles obtained according to the process of the present invention.

Accordingly, the present invention relates to surface functionalized titanium dioxide na ^¬ noparticles coated with

a) a phosphonate of formula (I), or a mixture of phosphonates of formula (I), wherein

R ¹ and R ² are independently of each other hydrogen, or a Cr 4alkyl group,

R ³ is a group CH ₂ =CH-, or a group of formula -[CH ₂ ] _n -R ⁴ , wherein

n is an integer of 1 to 12,

when n > 3 one -CH ₂ - may be replaced by -S- with the proviso that S is not

linked to P, or R ⁴ ,

R ⁴ is hydrogen, or a group of formula or

R ⁵ is hydrogen, or a group,

R ⁶ is hydrogen, or a group,

X ¹ is 0, or NH, and

b) bonded with an alkoxide of formula R ⁷ 0 ^~ (II) and/or

(III), wherein

R ⁷ is a CrCsalkyl group, which may be interrupted one or more times by -O- and/or sub ^¬ stituted one or more times by -OH,

R ⁸ is hydrogen, or a 0-C ₄ alkyl group,

R ⁹ is hydrogen, -CH ₂ OH, -CH ₂ SPh, -CH ₂ OPh, or a group of formula R ¹⁰ -[CH ₂ OH-O-

CH ₂ ] n1 ^" ,

n1 is an integer of 1 to 5,

X ² is O, or NH,

R ¹⁰ is a group of formula -CH ₂ -X ³ -CH ₂ -C(=0)-CR ¹¹ =CH ₂ ,

X ³ is 0, or NH, and

R ¹¹ hydrogen, or a 0-C ₄ alkyl group.

The surface functionalized titanium dioxide nanoparticles have a size from 1 nm to 40 nm, preferably from 1 nm to 10 nm, more preferably from 1 nm to 5 nm.

The surface functionalized titanium dioxide nanoparticles exhibit a refractive index of greater than 1.70 (589 nm), especially of greater than 1.75, very especially of greater than 1.80, when coated on a glass plate and dried at 60 °C.

The surface functionalized titanium dioxide nanoparticles are dissolved in ethanol, or iso- propanol and spin-coated on float-glass substrates. The coated glass substrates are dried at temperatures of from 60 to 120 °C until weight constancy and the Refractive In- dex (Rl) of the coatings (layer thickness ca. 400 nm) is determined by white-light reflec- tometry using a Filmetrics F10-RTA-UV photospectrometer with an internal fitting algo ^¬ rithm (Cauchy fit). From the fitting the refractive indices were calculated for a wavelength of 589 nm.

The weight ratio of titanium dioxide nanoparticles to phosphonate(s) of formula (I) and alkoxide(s) of formula (II) and (III) is in the range of from 99 - 1 to 50 - 50, preferably 80 - 20 to 50 - 50, more preferably 70 - 30 to 50 - 50 and most preferably from 65 - 35 to 50 -50.

The weight ratio of phosphonate(s) of formula (I) and alkoxide(s) of formula (II) and (III) is in the range of from 1 - 99 to 50 - 50, preferably 10 - 90 to 50 - 50, more preferably 5 - 95 to 50 - 50, and most preferably 3 - 97 to 50 - 50.

The phosphonate is preferably a phosphonate of formula (I), wherein

R ¹ and R ² are hydrogen,

R ³ is a group CH ₂ =CH-, or a group of formula -[CH ₂ ] _n -R ⁴ , wherein

n is an integer of 1 to 4,

R (A-2),

(A-3), (A-4), ^{H H} (A-5), (A-6), or

Among the groups of formula (A-1) to (A-7) groups of formula (A-1) and (A-2) are pre ^¬ ferred.

I n one embodiment of the present invention phosphonates of formula

(I) are more preferred, wherein

R ¹ and R ² are hydrogen,

R ³ is a group of formula -[CH ₂ ] _n -R ⁴ , wherein

n is an integer of 1 to 12,

R ⁴ is hydrogen. This embodiment has the advantage of low refractive index dilution and rapid coating.

I n another embodiment of the present invention phosphonates of formula (I) are more preferred, wherein

R ¹ and R ² are hydrogen,

R ³ is a group of formula -[CH ₂ ] _n -R ⁴ , wherein

n is an integer of 1 to 12,

when n > 3 one -CH ₂ - may be replaced by -S- with the proviso that S is not directly linked to P, or R ⁴ ,

R ⁴ is a group of formula , R ⁵ is hydrogen, or a methyl group and

X ¹ is 0, or NH, especially 0. This embodiment offers the advantage of more stable at ^¬ tachment of olefinic groups to T1O2 surface.

Examples of the phosphonate of fo rmula (I) are

i) a compound of formula (B1; n is 1 to 8), such as, for example,

ample, (B2a), or (B2b);

(B2' , n is 1 to 5), such as, for example,

iii) a compound of formula (B3, n is 1 to 5), such as, for exam-

iv) a compound of for such as, for example,

v) For n is 3 to 5 in compounds B2, B2' , B3 and B4 one -CH ₂ - may be replaced by sulfur

resulting, for example, in a compound of formula

Compounds of formula (B3) are less preferred than compounds of formula (B2). I n the alkoxide of formula R ⁷ 0 ^~ (II) R ⁷ is a CrCsalkyl group, which may be interrupted one or more times by -0- and/or substituted one or more times by -OH. Examples of the alkoxide of formula (II) are CH ₃ 0-(D-1), CH ₃ CH ₂ 0-(D-2), CH ₃ CH ₂ CH ₂ 0-(D-3), (CH ₃ ) ₂ CHO- (D-4), CH ₃ CH ₂ CH ₂ CH ₂ 0-(D-5), (CH ₃ ) ₂ CHCH ₂ 0-(D-6), (CH ₃ ) ₂ CHOCH ₂ CH ₂ 0-(D-7), (CH3)2CHOCHCH ₂ OH)(CH2CH ₂ 0-) (D-8), (CH ₃ )2CHOCH ₂ CH(OH)(CH ₂ 0-) (D-9). Preferred alkoxides of formula (II) are CH3CH2O (D-2) and (CH ₃ )2CHO ^_ (D-4), because organic sol ^¬ vents used in the printing industries comprise preferably volatile primary and/or second ^¬ ary alcohols.

The alkoxide of formula III is referabl derived from the followin alcohols:

(C-4),

(C-19) or

(C-20). Among the alcohols of formula (C-1) to (C-20) alcohols of for ^¬ mula (C-9), (C-10), (C-13) and (C-14) are preferred. A single phosphonate or a mixture of up to three different phosphonates, preferably two phosphonates with weight ratios of 1 - 99 to 99 -1 may be used, according the specific application parameters. Usually at least two different alkoxides are present.

Examples of surface functionalized T1O2 particles are shown in the table below:

At present the-surface functionalized T1O2 particles (T-1), (T-4) and (T-7) are most preferred.

The surface functionalized T1O2 nanoparticles having high refractive index and stability are soluble in organic solvents or aqueous mixtures of organic solvents used in the printing industries; those solvents preferably comprise volatile primary or secondary alcohols e.g as ethanol, / 0-propanol and the like as known in the art.

Accordingly, the present invention is directed to a coating composition, comprising the surface functionalized titanium dioxide nanoparticles of the present invention and a sol- vent. The solvent is preferably selected from water, alcohols (such as methanol, ethanol, 1-pro- panol, 2-propanol, 1-butanol, 2-butanol, isobutanol, tert-butanol, tert-pentanol), cyclic or acyclic ethers (such as diethyl ether, tetrahydrofuran and 2-methyltetrahydrofurane), ke ^¬ tones (such as acetone, 2-butanone, 3-pentanone), ether-alcohols (such as 2-methoxy- ethanol, 1-methoxy-2-propanol, ethylene glycol monobutyl ether, diethylene glycol mo- noethyl ether, diethylene glycol monopropyl ether, and diethylene glycol monobutyl ether), esters (such as ethyl acetate, ethyl propionate, and ethyl 3-ethoxypropionate) and mixtures thereof. Volatile primary or secondary alcohols, like ethanol and / 0-propanol are most preferred.

The amount of solvent in the (coating or printing ink) composition is dependent on the coating process, printing process etc. For gravure printing the solvent may be present in the printing ink composition in an amount of from 80 to 97 % by weight of the printing ink composition, preferably 90 to 95 % by weight.

The compositions, preferably printing ink compositions may comprise a binder. Generally, the binder is a high-molecular-weight organic compound conventionally used in coating compositions. High molecular weight organic materials usually have molecular weights of about from 10 ³ to 10 ⁸ g/mol or even more. They may be, for example, natural resins, dry ^¬ ing oils, rubber or casein, or natural substances derived therefrom, such as chlorinated rubber, oil-modified alkyd resins, viscose, cellulose ethers or esters, such as ethylcellulose, cellulose acetate, cellulose propionate, cellulose acetobutyrate or nitrocellulose, but espe ^¬ cially totally synthetic organic polymers (thermosetting plastics and thermoplastics), as are obtained by polymerisation, polycondensation or polyaddition. From the class of the polymerisation resins there may be mentioned, especially, polyolefins, such as polyeth ^¬ ylene, polypropylene or polyisobutylene, and also substituted polyolefins, such as polymerisation products of vinyl chloride, vinyl acetate, styrene, acrylonitrile, acrylic acid esters, methacrylic acid esters or butadiene, and also copolymerisation products of the said monomers, such as especially ABS or EVA.

With respect to the binder resin, a thermoplastic resin may be used, examples of which include, polyethylene based polymers [polyethylene (PE), ethylene-vinyl acetate copoly ^¬ mer (EVA), vinyl chloride-vinyl acetate copolymer, vinyl alcohol-vinyl acetate copolymer, polypropylene (PP), vinyl based polymers [polyvinyl chloride) (PVC), polyvinyl butyral) (PVB), polyvinyl alcohol) (PVA), poly(vinylidene chloride) (PVdC), polyvinyl acetate) (PVAc), polyvinyl formal) (PVF)], polystyrene based polymers [polystyrene (PS), styrene- acrylonitrile copolymer (AS), acrylonitrile-butadiene-styrene copolymer (ABS)], acrylic based polymers [poly(methyl methacrylate) (PM MA), MMA-styrene copolymer], polycar- bonate (PC), celluloses [ethyl cellulose (EC), cellulose acetate (CA), propyl cellulose (CP), cellulose acetate butyrate (CAB), cellulose nitrate (CN), also known as nitrocellulose], fluo- rin based polymers [polychlorofluoroethylene (PCTFE), polytetrafluoroethylene (PTFE), tetrafluoroethylene-hexafluoroethylene copolymer (FEP), poly(vinylidene fluoride) (PVdF)], urethane based polymers (PU), nylons [type 6, type 66, type 610, type 11], polyesters (al- kyl) [polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polycyclohexane terephthalate (PCT)], novolac type phenolic resins, or the like. I n addition, thermosetting resins such as resol type phenolic resin, a urea resin, a melamine resin, a polyurethane resin, an epoxy resin, an unsaturated polyester and the like, and natural resins such as protein, gum, shellac, copal, starch and rosin may also be used. The binder preferably comprises nitrocellulose, ethyl cellulose, cellulose acetate, cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), alcohol soluble propionate (ASP), vinyl chloride, vinyl ace ^¬ tate copolymers, vinyl acetate, vinyl, acrylic, polyurethane, polyamide, rosin ester, hydro ^¬ carbon, aldehyde, ketone, urethane, polythyleneterephthalate, terpene phenol, polyolefin, silicone, cellulose, polyamide, polyester, rosin ester resins, shellac and mixtures thereof, most preferred are soluble cellulose derivatives such as hydroxylethyl cellulose, hydroxy- propyl cellulose, nitrocellulose, carboxymethylcellulose as well as chitosan and agarose, in particular hydroxyethyl cellulose and hydroxypropyl cellulose. The (coating or printing ink) compositions may also comprise an additional colorant. Ex ^¬ amples for suitable dyes and pigments are given subsequently.

The (printing ink or coating) composition may also contain a surfactant. I n general surfac ^¬ tants change the surface tension of the composition. Typical surfactants are known to the skilled person, they are for example, anionic or non-ionic surfactants. Examples of anionic surfactants can be, for example, a sulfate, sulfonate or carboxylate surfactant or a mixture thereof. Preference is given to alkylbenzenesulfonates, alkyl sulfates, alkyl ether sulfates, olefin sulfonates, fatty acid salts, alkyl and alkenyl ether carboxylates or to an a-sulfonic fatty acid salt or an ester thereof.

Preferred sulfonates are, for example, alkylbenzenesulfonates having from 10 to 20 car ^¬ bon atoms in the alkyl radical, alkyl sulfates having from 8 to 18 carbon atoms in the alkyl radical, alkyl ether sulfates having from 8 to 18 carbon atoms in the alkyl radical, and fatty acid salts derived from palm oil or tallow and having from 8 to 18 carbon atoms in the al- kyl moiety. The average molar number of ethylene oxide units added to the alkyl ether sulfates is from 1 to 20, preferably from 1 to 10. The cation in the anionic surfactants is preferably an alkaline metal cation, especially sodium or potassium, more especially so ^¬ dium. Preferred carboxylates are alkali metal sarcosinates of formula Rg- CON (Rio)CH ₂ COOMi wherein R ₉ is or Cg-Cizalkenyl, R ₁₀ is and Μ _Ί is an alkali metal such as lithium, sodium, potassium, especially sodium.

Cg-Ci7alkyl means n-, i-nonyl, n-, i-decyl, n-, i-undecyl, n-, i-dodecyl, n-, i-tridecyl, n-, i- tetradecyl, n-, i-pentadecyl, n-, i-hexadecyl, n-, i-heptadecyl. Cg-Ci7al kenyl means n-, i-nonenyl, n-, i-decenyl, n-, i-undecenyl, n-, i-dodecenyl, n-, i- tridecenyl, n-, i-tetradecenyl, n-, i-pentadecenyl, n-, i-hexadecenyl, n-, i-heptadecenyl.

The non-ionic surfactants may be, for example, a primary or secondary alcohol ethox- ylate, especially a Cs-C2oaliphatic alcohol ethoxylated with an average of from 1 to 20 mol of ethylene oxide per alcohol group. Preference is given to primary and secondary Cio- Ci5 aliphatic alcohols ethoxylated with an average of from 1 to 10 mol of ethylene oxide per alcohol group. Non-ethoxylated non-ionic surfactants, for example alkylpolyglyco- sides, glycerol monoethers and polyhydroxyamides (glucamide), may likewise be used. Further in addition, an auxiliary agent including a variety of reactive agents for improving drying property, viscosity, and dispersibility, may suitably be added. The auxiliary agents are to adjust the performance of the ink, and for example, a compound that improves the abrasion resistance of the ink surface and a drying agent that accelerates the drying of the ink and the like may be employed.

Furthermore, a plasticizer for stabilizing the flexibility and strength of the print film may be added according to the needs therefor.

The (coating or printing ink) composition may further contain a dispersant. The disper- sant may be any polymer which prevents agglomeration or aggregation of the spherical and shaped particles formed after heating step D). The dispersant may be a non-ionic, anionic or cationic polymer having a weight average molecular weight of from 500 to

2,000,000 g/mol, preferably from 1,500,000 to 1,000,000 g/mol, which forms a solution or emulsion in the aqueous mixture. Typically, the polymers may contain polar groups. Suit ^¬ able polymeric dispersants often possess a two-component structure comprising a poly ^¬ meric chain and an anchoring group. The particular combination of these leads to their effectiveness.

Suitable commercially available polymeric dispersants are, for example, EFKA ^® 4046, 4047, 4060, 4300, 4330, 4580, 4585, 8512, Disperbyk ^® 161, 162, 163, 164, 165, 166, 168, 169, 170, 2000, 2001, 2050, 2090, 2091, 2095, 2096, 2105, 2150, Ajinomoto Fine Techno' s PB ^® 711, 821, 822, 823, 824, 827, Lubrizol' s Solsperse ^® 24000, 31845, 32500, 32550, 32600, 33500, 34750, 36000, 36600, 37500, 39000, 41090, 44000, 53095, ALBRITECT ^® CP30 (a copolymer of acrylic acid and acrylphosphonate) and combinations thereof.

Preference is given to polymers derived from hydroxyalkyl(meth)acrylates and/or polygly- col (meth)acrylates, such as hydroxyethyl and hydroxypropyl (meth)acrylate, polyethylene glycol (meth)acrylates, (meth)acrylates having amine functionality, for example, N-[3-(di- methylamino)propyl](meth)acrylamide or 2-(N,N-dimethylamino)ethyl(meth)acrylate.

I n particular, non-ionic copolymer dispersants having amine functionality are preferred. Such dispersants are commercially available, for example as EFKA ® 4300, EFKA ® 4580 or EFKA 4585. The polymeric dispersants may be used alone or in admixture of two or more.

The coating composition of the present invention may be used for coating holograms, wave guides and solar panels.

The coating or printing ink composition of the present invention can be used in the man ^¬ ufacture of surface relief microstructures, such as, for example, an optically variable de ^¬ vices (OVD), such as, for example, a hologram). The method for forming a surface relief microstructure on a substrate comprising the steps of:

a) forming a surface relief microstructure on a discrete portion of the substrate; and b) depositing the coating composition according to the present invention on at least a portion of the surface relief microstructure.

A further specific embodiment of the invention concerns a preferred method for forming a surface relief microstructure on a substrate, wherein step a) comprises

a1) applying a curable compound to at least a portion of the substrate;

a2) contacting at least a portion of the curable compound with surface relief microstruc ^¬ ture forming means; and

a3) curing the curable compound.

The composition of the present invention may be applied to the substrate by means of conventional printing press such as gravure, flexographic, lithographic, offset, letterpress intaglio and/or screen process, or other printing process.

I n another embodiment the composition may be applied by coating techniques, such as spraying, dipping, casting or spin-coating.

Preferably the printing process is carried out by flexographic, offset or by gravure print ^¬ ing.

The resulting coatings, comprising the surface functionalized T1O2 nanoparticles, are trans- parent in the visible region. The transparent surface functionalized T1O2 nanoparticles con ^¬ taining layer has a thickness from 50 nm to 500 nm after drying. The surface functionalized T1O2 nanoparticles containing coating is dried at below 120°C to avoid damage of organic substrates and/coating layers. I n another aspect the invention relates to the use of the surface functionalized T1O2 nano ^¬ particles in UV-curable printable curing inks preferably processed via gravure printing re ^¬ sulting in flexible hybrid layers.

The resulting products may be coated with a protective coating. The protective coating is preferably transparent or translucent. Examples for such coatings are known to the skilled person. For example, water borne coatings, UV-cured coatings or laminated coatings may be used. Examples for typical coating resins will be given below.

The surface functionalized T1O2 nanoparticles may be coated onto organic foils via gravure printing followed by a transparent overcoat subsequently being UV-cured (e.g. I rgacure 819 ^® , I rgacure 184 ^® and Lumogen OVD Primer 301 ^® ). That way ligands, i.e. phosphonates (I) and/or alkoxides (ll)/(l l l), carrying olefinic moieties are arrested in the coating impeding subsequent migration and aggregation of the particles which would result in severe loss of transparency. The (security, or decorative) product obtainable by using the above method forms a fur ^¬ ther subject of the present invention.

Accordingly, the present invention is directed to a security, or decorative element, com- prising a substrate, which may contain indicia or other visible features in or on its surface, and on at least part of the said substrate surface, a coating according to the present in ^¬ vention.

Typically the security product includes banknotes, credit cards, identification documents like passports, identification cards, driver licenses, or other verification documents, phar ^¬ maceutical apparel, software, compact discs, tobacco packaging and other products or packaging prone to counterfeiting or forgery.

The substrate may comprise any sheet material. The substrate may be opaque, substan- tially transparent or translucent, wherein the method described in WO08/061930 is espe ^¬ cially suited for substrates, which are opaque to UV light (non-transparent). The substrate may comprise paper, leather, fabric such as silk, cotton, tyvac, filmic material or metal, such as aluminium. The substrate may be in the form of one or more sheets or a web. The substrate may be mould made, woven, non-woven, cast, calendared, blown, ex- truded and/or biaxially extruded. The substrate may comprise paper, fabric, man made fibres and polymeric compounds. The substrate may comprise any one or more selected from the group comprising paper, papers made from wood pulp or cotton or synthetic wood free fibres and board. The paper/board may be coated, calendared or machine glazed; coated, uncoated, mould made with cotton or denim content, Tyvac, linen, cot- ton, silk, leather, polythyleneterephthalate, polypropylene propafilm, polyvinylchloride, rigid PVC, cellulose, tri-acetate, acetate polystyrene, polyethylene, nylon, acrylic and poly- therimide board. The polythyleneterephthalate substrate may be Melinex type film orien ^¬ tated polypropylene (obtainable from DuPont Films Willimington Delaware product I D Melinex HS-2).

The substrates being transparent films or non-transparent substrates like opaque plastic, paper including but not limited to banknote, voucher, passport, and any other security or fiduciary documents, self adhesive stamp and excise seals, card, tobacco, pharmaceutical, computer software packaging and certificates of authentication, aluminium, and the like.

I n a preferred embodiment of the present invention the substrate is a non-transparent (opaque) sheet material, such as, for example, paper. Advantageously, the paper may be precoated with an UV curable lacquer. Suitable UV curable lacquers and coating methods are described, for example, WO2015/049262 and WO2016/156286.

I n another preferred embodiment of the present invention the substrate is a transparent or translucent sheet material, such as, for example, polyethylene terephthalate, polyeth ^¬ ylene naphthalate, polyvinyl butyral, polyvinyl chloride, flexible polyvinyl chloride, polyme- thyl methacrylate, poly(ethylene-co-vinyl acetate), polycarbonate, cellulose triacetate, polyether sulfone, polyester, polyamide, polyolefins, such as, for example, polypropylene, and acrylic resins. Among these, polyethylene terephthalate and polypropylene are pre ^¬ ferred. The flexible substrate is preferably biaxial ly oriented.

The forming of an optically variable image on the substrate may comprise depositing a curable composition on at least a portion of the substrate, as described above. The cura- ble composition, generally a coating or lacquer may be deposited by means of gravure, flexographic, ink jet and screen process printing. The curable lacquer may be cured by actinic radiations, preferably ultraviolet (UV) light or electron beam. Preferably, the cura ^¬ ble lacquer is UV cured. UV curing lacquers are well known and can be obtained from e.g. BASF SE. The lacquers exposed to actinic radiations or electron beam used in the present invention are required to reach a solidified stage when they separate again from the imaging shim in order to keep the record in their upper layer of the sub-microscopic, holographic diffraction grating image or pattern (optically variable image, OVI). Particu ^¬ larly suitable for the lacquer compositions are mixtures of typical well-known components (such as photoinitiators, monomers, oligomers, levelling agents etc.) used in the radiation curable industrial coatings and graphic arts. Particularly suitable are compositions con ^¬ taining one or several photo-latent catalysts that will initiate polymerization of the ex ^¬ posed lacquer layer to actinic radiations. Particularly suitable for fast curing and conver ^¬ sion to a solid state are compositions comprising one or several monomers and oligo ^¬ mers sensitive to free-radical polymerization, such as acrylates, methacrylates or mono- mers or/and oligomers, containing at least one ethylenically unsaturated group, examples have already been given above. Further reference is made to pages 8 to 35 of

WO2008/061930.

The UV lacquer may comprise an epoxy-acrylate from the CRAYNOR ® Sartomer Europe range (10 to 60%) and one or several acrylates (monofunctional and multifunctional), monomers which are available from Sartomer Europe (20 to 90%) and one, or several photoinitiators (1 to 15%) such as Darocure ® 1173 and a levelling agent such as BYK® 361 (0.01 to 1%) from BYK Chemie. The epoxy-acrylate is selected from aromatic glycidyl ethers aliphatic glycidyl ethers. Aro ^¬ matic glycidyl ethers are, for example, bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, bisphenol B diglycidyl ether, bisphenol S diglycidyl ether, hydroquinone diglycidyl ether, alkylation products of phenol/dicyclopentadiene, e.g., 2,5-bis[(2,3-epoxypro- poxy)phenyl]octahydro-4,7-methano-5H-indene (CAS No. [13446-85-0]), tris[4-(2,3- epoxypropoxy)phenyl] methane isomers (CAS No. [66072-39-7]), phenol-based epoxy no- volaks (CAS No. [9003-35-4]), and cresol-based epoxy novolaks (CAS No. [37382-79-9]). Examples of aliphatic glycidyl ethers include 1,4-butanediol diglycidyl ether, 1,6-hex- anediol diglycidyl ether, trimethylolpropane triglycidyl ether, pentaerythritol tetraglycidyl ether, 1,1,2,2-tetrakis[4-(2,3-epoxypropoxy)phenyl]ethane (CAS No. [27043-37-4]), diglyc- idyl ether of polypropylene glycol (oc,co-bis(2,3-epoxypropoxy)poly(oxypropylene), CAS No. [16096-30-3]) and of hydrogenated bisphenol A (2,2-bis[4-(2,3-epoxypropoxy)cyclo- hexy propane, CAS No. [13410-58-7]).

The one or several acrylates are preferably multifunctional monomers which are selected from trimethylolpropane triacrylate, trimethylolethane triacrylate, trimethylolpropane tri- methacry-. late, trimethylolethane trimethacrylate, tetramethylene glycol dimethacrylate, triethylene gly-.col dimethacrylate, tetraethylene glycol diacrylate, tripropylene glycol di ^¬ acrylate (TPGDA), dipropylene glycol diacrylate (DPGDA), pentaerythritol diacrylate, pen- taerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol diacrylate, dipentae- rythritol triacry-. late, dipentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, di- pentaerythritol hexa -.acrylate, tripentaerythritol octaacrylate, pentaerythritol dimethacry ^¬ late, pentaerythritol trimeth-.acrylate, dipentaerythritol dimethacrylate, dipentaerythritol tetramethacrylate, tripenta -.erythritol octamethacrylate, pentaerythritol diitaconate, di ^¬ pentaerythritol tris-itaconate, dipen-.taerythritol pentaitaconate, dipentaerythritol hex- aitaconate, ethylene glycol diacrylate, 1,3-bu-.tanediol diacrylate, 1,3-butanediol di- methacrylate, 1,4-butanediol diitaconate, sorbitol triacry ate, sorbitol tetraacrylate, pen- taerythritol-modified triacrylate, sorbitol tetra methacrylate, sorbitol pentaacrylate, sorbi ^¬ tol hexaacrylate, oligoester acrylates and methacrylates, glycerol diacrylate and triacrylate, 1,4-cyclohexane diacrylate, bisacrylates and bismethacrylates of polyethylene glycol with a molecular weight of from 200 to 1500, triacrylate of singly to vigintuply alkoxylated, more preferably singly to vigintuply ethoxylated trimethylolpropane, singly to vigintuply propoxylated glycerol or singly to vigintuply ethoxylated and/or propoxylated pentae ^¬ rythritol, such as, for example, ethoxylated trimethylol propane triacrylate (TM EOPTA) and or mixtures thereof. The photoinitiator is preferably a blend of an alpha-hydroxy ketone, alpha-alkoxyketone or alpha-aminoketone compound and a benzophenone compound; or a blend of an al ^¬ pha-hydroxy ketone, alpha-alkoxyketone or alpha-aminoketone compound, a benzophe ^¬ none compound and an acylphosphine oxide compound. The curable composition is preferably deposited by means of gravure or flexographic printing.

The curable composition can be coloured. A filmic substrate is printed conventionally with a number of coloured inks, using, for ex ^¬ ample, a Cerutti R950 printer (available from Cerrutti UK Long Hanborough Oxon.). The substrate is then printed with an ultra violet curable lacquer. An OVD is cast into the sur ^¬ face of the curable composition with a shim having the OVD thereon, the holographic image is imparted into the lacquer and instantly cured via a UV lamp, becoming a facsim- ile of the OVD disposed on the shim.

The diffraction grating may be formed using any methods known to the skilled man such as those described in US4,913,858, US5,164,227, WO2005/051675 and WO2008/061930. The curable coating composition may be applied to the substrate by means of conven ^¬ tional printing press such as gravure, rotogravure, flexographic, lithographic, offset, letter ^¬ press intaglio and/or screen process, or other printing process.

Preferably, when the substrate carrying the enhanced diffractive image or pattern is sub- sequently over-laid onto printed pictures and/or text, or the substrate is pre-printed with pictures and/or text and the enhanced diffractive image or pattern is deposited thereon, those printed features are visible through the substrate, provided that the substrate itself is at least opaque, translucent or transparent. Preferably the T1O2 layer which is printed over the OVD, for example the diffraction grating is also sufficiently thin as to allow view ^¬ ing in transmission and reflectance. I n other words the whole security element on the substrate allows a viewing in transmission and reflectance.

I n another preferred embodiment the security element comprises a mutlilayer structure capable of interference, wherein the multilayer structure capable of interference has a re ^¬ flection layer, a dielectric layer, and a partially transparent layer (EP1504923,

WO01/03945, WO01/53113, WO05/38136, W016173696), wherein the dielectric layer is ar ^¬ ranged between the reflection layer and the partially transparent layer and the absorber layer is formed by a layer, containing the surface functionalized T1O2 nanoparticles of the present invention. Suitable materials for the reflective layer include aluminum, silver, copper mixtures or al ^¬ loys thereof. Suitable materials for the dielectric layer include silicium dioxide, zinc sulfide, zinc oxide, zirconium oxide, zirconium dioxide, titanium dioxide, diamond-like carbon, in ^¬ dium oxide, indium-tin-oxide, tantalum pentoxide, cerium oxide, yttrium oxide, europium oxide, iron oxides, hafnium nitride, hafnium carbide, hafnium oxide, lanthanum oxide, magnesium oxide, magnesium fluoride, neodymium oxide, praseodymium oxide, samar ^¬ ium oxide, antimony trioxide, silicon monoxide, selenium trioxide, tin oxide, tungsten tri- oxide and combinations thereof as well as organic polymer acrylates.

The absorber layer is preferably an aluminum or silver layer and the dielectric layer is preferably formed of S1O2.

The curable composition may further comprise modifying additives, for example color ^¬ ants and/or suitable solvent(s). Preferably, the resin maintains adhesion of the composition to the surface of the diffrac ^¬ tion grating.

Specific additives can be added to the composition to modify its chemicals and/or physi ^¬ cal properties. Polychromatic effects can be achieved by the introduction of (colored) in- organic and/or organic pigments and/or solvent soluble dyestuffs into the ink, to achieve a range of coloured shades. By addition of a dye the transmission colour can be influ ^¬ enced. By the addition of fluorescent or phosphorescent materials the transmission and/or the reflection colour can be influenced. Suitable colored pigments especially include organic pigments selected from the group consisting of azo, azomethine, methine, anthraquinone, phthalocyanine, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine iminoisoindoline, dioxazine, imi- noisoindolinone, quinacridone, flavanthrone, indanthrone, anthrapyrimidine and quinophthalone pigments, or a mixture or solid solution thereof; especially a dioxazine, diketopyrrolopyrrole, quinacridone, phthalocyanine, indanthrone or iminoisoindolinone pigment, or a mixture or solid solution thereof. Colored organic pigments of particular interest include C.I. Pigment Red 202, C.I. Pigment Red 122, C.I. Pigment Red 179, C.I. Pigment Red 170, C.I. Pigment Red 144, C.I. Pigment Red 177, C.I. Pigment Red 254, C.I. Pigment Red 255, C.I. Pigment Red 264, C.I. Pigment Brown 23, C.I. Pigment Yellow 109, C.I. Pigment Yellow 110, C.I. Pigment Yellow 147, C.I. Pigment Orange 61, C.I. Pigment Orange 71, C.I. Pigment Orange 73, C.I. Pigment Or ^¬ ange 48, C.I. Pigment Orange 49, C.I. Pigment Blue 15, C.I. Pigment Blue 60, C.I. Pigment Violet 23, C.I. Pigment Violet 37, C.I. Pigment Violet 19, C.I. Pigment Green 7, C.I. Pigment Green 36, the 2,9-dichloro-quinacridone in platelet form described in WO08/055807, or a mixture or solid solution thereof.

Plateletlike organic pigments, such as plateletlike quinacridones, phthalocyanine, fluo- rorubine, dioxazines, red perylenes or diketopyrrolopyrroles can advantageously be used. Suitable colored pigments also include conventional inorganic pigments; especially those selected from the group consisting of metal oxides, antimony yellow, lead chromate, lead chromate sulfate, lead molybdate, ultramarine blue, cobalt blue, manganese blue, chrome oxide green, hydrated chrome oxide green, cobalt green and metal sulfides, such as cerium or cadmium sulfide, cadmium sulfoselenides, zinc ferrite, bismuth vanadate, Prussian blue, Fe304, carbon black and mixed metal oxides.

Examples of dyes, which can be used to color the curable composition, are selected from the group consisting of azo, azomethine, methine, anthraquinone, phthalocyanine, dioxa- zine, flavanthrone, indanthrone, anthrapyrimidine and metal complex dyes. Monoazo dyes, cobalt complex dyes, chrome complex dyes, anthraquinone dyes and copper phthalocyanine dyes are preferred.

The surface relief microstructur is, for example, an optically variable device (OVD), which is, for example, a diffractive optical variable image (DOVI). The term "diffractive optical variable image" as used herein may refer to any type of holograms including, for exam ^¬ ple, but not limited to a multiple plane hologram (e.g., 2-dimensional hologram, 3-di- mensional hologram, etc.), a stereogram, and a grating image (e.g., dot-matrix, pix- elgram, exelgram, kinegram, etc.). Examples of an optically variable device are holograms or diffraction gratings, moire grat ^¬ ing, lenses etc. These optical microstructured devices (or images) are composed of a se ^¬ ries of structured surfaces. These surfaces may have straight or curved profiles, with con ^¬ stant or random spacing, and may even vary from microns to millimetres in dimension. Patterns may be circular, linear, or have no uniform pattern. For example a Fresnel lens has a microstructured surface on one side and a pano surface on the other. The micro- structured surface consists of a series of grooves with changing slope angles as the dis ^¬ tance from the optical axis increases. The draft facets located between the slope facets usually do not affect the optical performance of the Fresnel lens. A further aspect of the present invention is the use of the element as described above for the prevention of counterfeit or reproduction, on a document of value, right, identity, a security label or a branded good. Various aspects and features of the present invention will be further discussed in terms of the examples. The following examples are intended to illustrate various aspects and fea ^¬ tures of the present invention.

The refractive indices of the HRI coatings (layer thickness ca. 400 nm) on float-glass sub- strates are determined by white-light reflectometry using a Filmetrics F10-RTA-UV pho- tospectrometer with an internal fitting algorithm (Cauchy fit). From the fitting the refrac ^¬ tive indices were calculated for a wavelength of 589 nm.

The size of the functionalized titanium dioxide nanoparticles is measured using a Trans- mission Electron Microscope (TEM).

Examples

Example 1

Preparation of phosphonates:

Phosphonate acrylamide and acrylate precursors have been synthesized according WO2006/094915 unless otherwise stated or are used as commercially available. All ¹ H-NMR taken at 300.13 MHz and ³¹ P-N MR at 121.5 M Hz.

1.1

Methyl phosphonate of formula (I) (R ⁴ , R ¹ and R ² = H; n = 1):

50.0 g commercial dimethyl methyl phosphonic ester (Aldrich) are dissolved in 400 ml ac- etonitrile at room temperature and treated with 135.7 g trimethylsilyl bromide at 40°C for 20 h. Then the mixture is evaporated and the residue treated with an excess of methanol to hydrolyze the silyl ester for 48 h at room temperature. Evaporation leaves 38.0 g of the methyl phosphonic acid (B1a) ready for further use.

1H-N MR(DOCD ₃ ): 1.42 ppm (d). ³¹ P-N MR (DOCD ₃ ): + 28.4 ppm.

Example 1.2

Butyl phosphonate of formula (I) (R ⁴ , R ¹ and R ² = H; n = 4):

According the procedure given for example 1.1, 35.0 g of butyl phosphonate (Bid) is ob ^¬ tained from 50.0 g of diethylbutyl phosphonic ester ready for further use.

1H-N MR(CDCI ₃ ): 0.94 ppm (t, 3 H); 1.48 ppm (m, 2 H); 1.61 ppm (m, 2 H); 1.76 ppm (m, 2 H). ³¹ P-N MR (CDCI ₃ ): + 36.6 ppm.

Example 1.3

Octyl phosphonate of formula (I) (R ⁴ , R ¹ and R ² = H; n = 8):

According the procedure given for example 1.1, 11.0 g of octyl phosphonate (B1e) is ob- tained from 15.0 g of diethyloctyl phosphonic ester ready for further use.

¹ H-N MR(CDCI ₃ ): 0.90 ppm (t, 3 H); 1.28 - 1.41 ppm (m, 8 H); 1.57 - 1.82 (m, 6 H). ³¹ P-NM R

Example 1.4

4-acryloylamido-butyl phosphonate of formula (I) (R ⁴ = acryloylamido-, R ¹ and R ² = H, n = 4):

112.0 g of Diethyl-4-amino butyl phosphonic ester (WO2006/094915) are reacted with 75.0 g of 2-chloro acetic acid chloride (Aldrich) in 600 ml dichloromethane in the presence of 59.7 g triethyl amine at 0°C to room temperature for 24 h. The mixture is then subsequently extracted with 1 N hydrogen chloride solution, water and brine and dried over sodium sul- fate, filtered and evaporated to leave 111.1 g of a syrupy mass which is used in the next step. The product is dissolved in 450 ml of acetone containing 62.0 g of DBU (diaza-bicyclo- undecane) and 20 mg methoxy phenol and stirred at room temperature for 24 h. Subse ^¬ quent evaporation leaves a residue which is extracted with 1 N hydrogen chloride, sat. sodium hydrogencarbonate solution and brine to give after removal of solvent 67.2 g of the phosphonic ester. The ester is treated according the procedure given in example 1 with 85.5 g trimethyl silylbromide in 475 ml acetonitrile to give 47.3 g of the title compound (B3b). ¹ H-N MR(DOCD ₃ ): 1.44 - 1.80 ppm (m, 6 H); 3.30 ppm (t, 2 H); 5.67 ppm (dd, 1 H); 6.24 ppm (dd, 2 H). ³¹ P-N MR (DOCD ₃ ): + 30.4 ppm.

Example 1.5

4- vinyl butyl phosphonate of formula (I) (R ⁴ = vinyl-, R ¹ and R ² = H, n = 4):

4.8 g of the starting diethyl phosphonate (R ⁴ = vinyl, R ¹ = R ² = Et, n = 4) obtained according (WO2006/094915) are treated according the procedure in example 1.1 with 6.7 g trime- thylsilyl bromide in acetonitrile to give 3.0 g of the title compound (B4b).

1H-N MR(CDCI ₃ ): 1.55 ppm (m, 2 H); 1.68 ppm (m, 2 H); 1.81 ppm (m, 2 H); 2.12 ppm (m, 2 H); 5.00 ppm (m, 2 H); 5.81 ppm (m, 1 H). ³¹ P-N MR (CDCI ₃ ): + 30.2 ppm

Example 1.6

2-methacroyloxy-butyl phosphonate of formula (I) (R ⁴ = methacroyloxy -, R ¹ and R ² = H, n = 2):

The starting dimethyl 2-methacroyloxy derivative (R ⁴ = methacroyloxy, R ¹ = R ² = Me, n = 2) is obtained according literature (K. Rajalakshmi et al. Polym. Sci. Ser. B, 2015, 57 (5), 408). 28.0 g of this material is then treated with 41.0 g of trimethyl siliyl bromide in 120 ml ace ^¬ tonitrile according the procedure given in example 1.1 to give 24 g of the title compound (B2a) ready for further use.

¹ H-N MR(CDCI ₃ ): 2.01 ppm (s, 3 H); 2.22 ppm (m, 2 H); 4.38 ppm (m, 2 H); 5.58 ppm (s, 1 H), 6.12 ppm (s, 1 H). ³¹ P-N MR (CDCI ₃ ): + 28.3 ppm.

Example 1.7

5- methacryolyloxy-3 thia pentyl phosphonate of formula (I) (R ⁴ = 5-methacryolyloxy-3 thia pentyl -, R ¹ and R ² = H, n = 5):

32.8 g of commercial diethyl vinylphosphonic ester are reacted with 15.6 g of 2-mercapto ethanol and 0.5 mg of sodium ethanolate (in 1.5 ml abs. ethanol) for 32 h at 107°C. After cooling down to room temperature the mixture is dissolved in dichloromethane and washed with water and dried over sodium sulfate. Filtration and evaporation leaves a resi ^¬ due which is purified by silica gel column chromatography (eluent: dichloromethane - methanol: 40 - 1) to give 38.2 g of the intermediate alcohol (R ⁴ = 5 hydroxy- 3-thia pentyl, R = Et, n = 5).

34.9 g of this material is dissolved in 300 ml dichloromethane containing 22.6 g triethyl amine and 4-methoxy phenol as stabilizer and cooled to -10°C. Then 27 g of methacrylic acid chloride are added and the mixture stirred for 20 h. Subsequent extraction with 1 N hydrogen chloride, sat. hydrogen carbonate solution and brine and evaporation leaves a residue which is purified over silica gel column chromatography (eluent: dichloromethane - methanol: 40 - 1) to give 38.7 g of the title compound (B5a).

¹ H-N MR(CDCI ₃ ): 1.97 ppm (s, 3 H; 2.16 ppm (m, 2 H); 2.87 ppm (m, 4 H); 4.35 ppm (t, 2 H); 5.63 ppm (s, 1 H); 6.16 ppm (s, 1 H). ³¹ P-N MR (CDCI ₃ ): + 28.5 ppm.

Example 2

Ti(O ⁱ Prop) ₄

(idealized with one potential ligand each only) Preparation of transparent, soluble and storable TiOg-nanoparticles (idealized with one po ^¬ tential liqand each only):

A 5 I flask is first charged with 200 g (0.70 mol) commercial titanium-tetra-/ 0-propoxide (Aldrich) and filled up to a total volume of 2 I with dry absolute ethanol (Merck). This mixture is stirred smoothly (200 rpm) at room temperature. To this solution is subsequently fun- neled a second solution havinq been prepared from 60 ml of 33% hydroqen chloride (Al ^¬ drich) and 29.8 ml of distilled water filled up to a total volume of 2 I with ethanol. The resultinq clear solution is stirred for 5 days at room temperature and then smoothly evap ^¬ orated at 20° - 30°C/20mm until a constant weiqht is achieved.

A transparent foamy material (118.9 q) is obtained which can be crushed to a solid when dry. This material can be stored at least over three months at 4°C without any visible chanqe and can be redissolved clearly in e.q. methanol, ethanol, propanol, 2-methoxy ethanol, iso- propanol, 2 -/ θ- pro poxy ethanol, butanol, N-methyl pyrrolidone, dimethyl formamide, di ^¬ methyl acetamide and the like. A TGA (thermoqravimetric analysis) of this material up to 450°C shows a weiqht loss of about 42 %, which leaves a total T1O2 contents of at least 58%. A TEM (transmission electron microscopy) shows particle sizes < 5 nm. A film of this material dried at 25 °C shows a refractive index (Rl) (589 nm) of 1.72 and when dried at 120°C an Rl of 1.95, accordinqly.

The titanium dioxide nanoparticles are dissolved in ethanol, or isopropanol and spin- coated on float-glass substrates. The coated glass substrates are dried at temperatures of 25, or 120 °C until weight constancy and the Refractive I ndex (Rl) of the coatings (layer thickness ca. 400 nm) is determined by white-light reflectometry using a Filmetrics F10- RTA-UV photospectrometer with an internal fitting algorithm (Cauchy fit). From the fitting the refractive indices were calculated for a wavelength of 589 nm.

Example 3

Coating of soluble & storable TiOg-nanoparticles:

Example 3.1

Coating of TiOg-nanoparticles of example 2 with phosphonate of formula (I) of example 1.1 (R ⁴ , R ¹ and R ² = H; n = 1):

1.00 g of dried TiCVnanoparticles are dissolved at room temperature in 10 ml of ethanol together with various amounts from 0.01 g to 0.75 g (1 % to 75 %) of phosphonate of example 1.1 dissolved in 2 ml ethanol and stirred 18 h - 24 h. All solutions are clear after being stirred for 1 h. The 1 % sample stays clear as a 7% w/v solution in ethanol or as a 20 % w/v in 2 / 0-propoxy ethanol (R' -OH). The 1 % sample e. g. gives a film after drying at 40°C with thickness ca. 875 nm and Rl = 1.8240.

Example 3.2

Coating of TiOg-nanoparticles of example 2 with phosphonate of formula (I) of example 1.1

cr ^ph o

(R ⁴ , R ¹ and R ² = H; n = 1) and (C-10):

10.00 g of dried TiCVnanoparticles are dissolved at room temperature in 4.20 ml of ethanol to form a transparent solution; to this mixture a solution of 0.108 g of phosphonate of example 1.1, dissolved in 0.30 ml ethanol is added at room temperature and stirred for 3.5 h. Thereafter 0.96 g of compound (C-10), dissolved in 0.50 ml ethanol is added and the transparent mixture stirred for 24 h and subseguently evaporated until the weight remains constant to give a yellowish syrupy mass.

Example 3.3

Coating of TiOg-nanoparticles of example 2 with with phosphonate of formula (I) of exam ^¬ ple 1.1 (R ⁴ , R ¹ and R ² = H; n = 1) and phosphonate of formula (I) of example 1.4 (R ⁴ = acryloylamido-, R ¹ and R ² = H, n = 4):

10.00 g of dried TiCVnanoparticles are dissolved at room temperature in 50 ml of ethanol together with 0.20 g of phosphonate of example 1.1 to form a transparent solution and stirred for 2.5 h; to this mixture a solution of 0.800 g of phosphonate of example 1.4, dis ^¬ solved in 20 ml ethanol is added at room temperature and stirred for an additional 18.5 h. Thereafter the transparent mixture evaporated until the weight remains constant to give a yellowish syrupy mass. This material shows an Rl of 1.70 when dried at room temperature and an Rl of 1.81 when dried at 80°C.

Example 3.4

Coating of TiOg-nanoparticles of example 2 with with phosphonate of formula (I) of ex ^¬ ample 1.1 (R ⁴ , R ¹ and R ² = H; n = 1) and phosphonate of formula (I) of example 1.6 (R ⁴ = methacryloxy, R ¹ and R ² = H, n = 2):

Coating of TiCVnanoparticles of example 2 with phosphonate of example 1.1 methyl phos ^¬ phonate of example 1.1 and phosphonic acid I (R^ = methacryloxy, R = H, n = 2):

160.00 g of dried TiCVnanoparticles are dissolved at room temperature in 60 ml of ethanol, to this mixture are added 3.20 g of phosphonate of example 1.6 dissolved in 5 ml ethanol and stirred for 3 h to form a transparent solution; to this mixture a solution of 12.60 g of phosphonate of example 1.1, dissolved in 5 ml ethanol is added at room temperature and stirred for an additional 18.5 h. Fines are filtered off and the transparent mixture is evapo- rated until the weight remains constant to give a yellowish syrupy mass. This material shows an Rl of 1.76 when dried at 80°C.

Example 3.5

Coating of TiOg-nanoparticles of example 2 with with phosphonate of formula (I) of ex ^¬ ample 1.1 (R ⁴ , R ¹ and R ² = H; n = 1) and phosphonate of formula (I) of example 1.7 (R ⁴ = 5-methacryolyloxy-3 thia pentyl -, R ¹ and R ² = H, n = 5):

1.00 g of dried Ti02-nanoparticles are dissolved at room temperature in 3.00 ml of ethanol, to this mixture are added 0.275 g of phosphonate of example 1.7 dissolved in 2 ml ethanol and stirred for 7 h to form a transparent solution; to this mixture a solution of 0.02 g of phosphonate of example 1.1, dissolved in 2 ml ethanol is added at room temperature and stirred for an additional 18.5 h. The transparent mixture is evaporated until the weight re ^¬ mains constant to give a yellowish syrupy mass.

Example 3.6

Coating of TiOg-nanoparticles of example 2 with with phosphonate of formula (I) of exam ^¬ ple 1.3 (R ⁴ , R ¹ and R ² = H; n = 8) and phosphonate of formula (I) of example 1.7 (R ⁴ = 5- methacryolyloxy-3 thia pentyl -, R ¹ and R ² = H, n = 5):

2.00 g of dried TiCVnanoparticles are dissolved at room temperature in 20.00 ml of etha- nol, to this mixture are added 0.100 g of phosphonate of example 1.3 and 0.50 g phospho ^¬ nate of example 1.7 dissolved in 4 ml ethanol and stirred for 24 h to form a transparent solution. The transparent mixture is evaporated until the weight remains constant to give a white foamy mass which forms transparent solutions in ethanol.

Example 3.7

Coating of TiOg-nanoparticles of example 2 with phosphonate of formula (I) of example 1.6 (R4 = vinyl- i _a nd R? = H, n = 4) and alcohol (C-10):

10.00 g of dried TiCVnanoparticles are dissolved at room temperature in 4.20 ml of etha ^¬ nol, to this mixture are added 0.300 g of phosphonic acid of example 1.6 dissolved in 0.30 ml ethanol and stirred for 3 h; thereafter 0.96 g of alcohol (C-10) dissolved in 0.50 ml eth- anol are added and stirred for an additional 24 h. The transparent mixture is evaporated until the weight remains constant to give a yellowish syrupy mass which forms transparent solutions in ethanol.

Example 4

Measuring of RI and film thickness of titanium nanoparticles containing films

The titanium nanoparticles are diluted at a ratio 1:10 in ethanol. The solution is mixed at room temperature with a magnetic stirrer at low regime (roughly 50 rpm). Glass plates are cleaned with ethanol and wiped without leaving any fibers or contamination. Then the glass plates are Corona-treated twice (power 300W). The glass plates are fixed on a spin coater by vacuum. The solution is visually transparent. After mixing, the solution, an amount of 0.1, resp. 0.2g is taken with a pipette and applied on the center of the glass plate. The spin coater is turned on and runs at a rotational speed of 150 rpm during 10 seconds then immediately 10000 rpm during 4 seconds. A visual examination ensures that the coatings are transparent. The coated glass plates are dried at temperatures of from 60 to 120 °C until weight con ^¬ stancy and the Refractive Index (RI) of the coatings (layer thickness ca. 400 nm) are deter ^¬ mined by white-light reflectometry using a Filmetrics F10-RTA-UV photospectrometer with an internal fitting algorithm (Cauchy fit). From the fitting the refractive indices were calculated for a wavelength of 589 nm.

The results are summarized in the table below:

Example Phosphonate (I) Alkoxide (ll)/(lll) Refractive Index (T1O2 nanop.) (RI)

3.1 0 EtO ^" (D-2), iPropCr RI of 1.82 when

H ₃ C— p-OH

(T-1) (D-4) dried at 120°C

^N ° ^H (B1a) 3.2 0 EtO ^" (D-2), iPropO- Rl of 1.82 when (T-2) H ₃ C— Ρ-ΟΗ

(D-4), dried at 120°C

' ^0Η (Bla) 0' 0 o II

(C-10' )

3.3 0 EtO ^" (D-2), iPropO- Rl of 1.81 when (T-3) H ₃ C— P-OH (D-4)- dried at 80°C

^Χ ° ^Η (Blal

(B3b)

3.4 0 EtO ^" (D-2), iPropO- Rl of 1.76 when (Τ-4) H ₃ C— P-OH

(D-4) dried at 80°C

^X ° ^H (Blal

(B2' a)

3.5 EtO ^" (D-2), iPropO- Rl of 1.76 when (Τ-5) (D-4) dried at 60°C

(

3.6 EtO ^" (D-2), iPropO- Rl of 1.75 when (Τ-6) (D-4)- dried at 60°C

(B5b)

3.7 EtO ^" (D-2), iPropO- Rl of 1.75 when (Τ-7) o- ^Ph O dried at 60°C

(B2' a) (D-4), ⁰ "

(C-10' ) coated glass plates are then stored in closed petri-dishes at room temperatu

Example 5

Gravure printing The titanium nanoparticles containing products of examples 3.1 to 3.7 (40% to 70% (w (weight)/v(volume)) solids in ethanol) are diluted to a final 6.5% (w/v) concentration (of solids: surface-treated T1O2 particles) with ethanol. The resulting ink is printed by gravure on PET foil containing holograms and no holograms using a 70l/cm gravure cylinder at printing speed 10 - 90m/min, heating 90°C.

any angle, after overcoating the printed foil with 10 micron UV varnish, holographic struc ^¬ tures remain visible.