Title:
POROUS NETWORK COMPLEX, NETWORK COMPLEX ENCAPSULATING GUEST MOLECULE, AND METHOD FOR SEPARATING GUEST MOLECULE
Document Type and Number:
WIPO Patent Application WO/2011/062260
Kind Code:
A1
Abstract:
Disclosed are a porous network complex comprising, as a structural unit, an M6L4 structure being constituted in a self-assembled manner by six transition metal ions (M) and four substantially planar tridentate organic ligands (L) and having an octahedral three-dimensional shape in which the transition metal ions (M) are positioned at six vertices thereof, wherein said M6L4 structures are consecutively arranged sharing the transition metal ions (M) positioned at the individual vertices thereof; a network complex encapsulating a guest molecule wherein a guest molecule is encapsulated in a pore of said porous network complex; and a method for separating a guest molecule such as fullerene C70 or the like using said porous network structure. Thus, a novel porous network complex encapsulating various chemicals in pores, a network complex encapsulating a guest molecule wherein a chemical is encapsulated in said network complex, and a method for separating a guest molecule, whereby a specific guest molecule is separated from a mixture of guest molecules, can be provided.
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Inventors:
FUJITA MAKOTO (JP)
INOKUMA YASUHIDE (JP)
ARAI TATSUHIKO (JP)
INOKUMA YASUHIDE (JP)
ARAI TATSUHIKO (JP)
Application Number:
PCT/JP2010/070696
Publication Date:
May 26, 2011
Filing Date:
November 19, 2010
Export Citation:
Assignee:
UNIV TOKYO (JP)
FUJITA MAKOTO (JP)
INOKUMA YASUHIDE (JP)
ARAI TATSUHIKO (JP)
FUJITA MAKOTO (JP)
INOKUMA YASUHIDE (JP)
ARAI TATSUHIKO (JP)
International Classes:
C07D213/24; C07B63/02; C07C7/13; C07C7/152; C07C15/20; C07C15/30; C07D401/14; C07F17/02; B01D15/00; B01J20/22; C07F15/06
Foreign References:
| JP2006188560A | 2006-07-20 | |||
| JP2008214318A | 2008-09-18 | |||
| JP2000086682A | 2000-03-28 |
Other References:
BRENDAN F. ABRAHAMS, ET AL.: "A Cubic (3,4)-Connected Net with Large Cavities in Solvated [Cu3(tpt)4](ClO4)3 (tpt = 2,4,6-Tri(4-pyridyl)-1,3,5-triazine)", ANGEWANDTE CHEMIE, INTERNATIONAL EDITION IN ENGLISH, vol. 35, no. 15, August 1996 (1996-08-01), pages 1690 - 1692
HEE K. CHAE, ET AL.: "A route to high surface area, porosity and inclusion of large molecules in crystals", NATURE, vol. 427, 5 February 2004 (2004-02-05), pages 523 - 527, XP002392827
DANIL N. DYBTSEV, HYUNGPHIL CHUN AND KIMOON KIM: "Three-dimensional metal-organic framework with (3,4)-connected net, synthesized from an ionic liquid medium", CHEMICAL COMMUNICATIONS, no. 14, 2004, pages 1594 - 1595
STUART R. BATTEN, BERNARD F. HOSKINS, RICHARD ROBSON: "Two Interpenetrating 3D Networks Which Generate Spacious Sealed-Off Compartments Enclosing of the Order of 20 Solvent Molecules in the Structures of Zn(CN)(NO3)(tpt)2/3.cntdot.solv (tpt = 2,4,6-tri(4-pyridyl)-1,3,5-triazine, solv = .apprx.3/4C2H2Cl4.cntdot.3/4CH3OH or .apprx.3/2CHCl3.cntdot.1/3CH3OH", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 117, no. 19, May 1995 (1995-05-01), pages 5385 - 5386
BRENDAN F. ABRAHAMS, ET AL.: "A wellsian 'three-dimensional' racemate: eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed", CHEMICAL COMMUNICATIONS, no. 11, 1996, pages 1313 - 1314
HEE K. CHAE, ET AL.: "A route to high surface area, porosity and inclusion of large molecules in crystals", NATURE, vol. 427, 5 February 2004 (2004-02-05), pages 523 - 527, XP002392827
DANIL N. DYBTSEV, HYUNGPHIL CHUN AND KIMOON KIM: "Three-dimensional metal-organic framework with (3,4)-connected net, synthesized from an ionic liquid medium", CHEMICAL COMMUNICATIONS, no. 14, 2004, pages 1594 - 1595
STUART R. BATTEN, BERNARD F. HOSKINS, RICHARD ROBSON: "Two Interpenetrating 3D Networks Which Generate Spacious Sealed-Off Compartments Enclosing of the Order of 20 Solvent Molecules in the Structures of Zn(CN)(NO3)(tpt)2/3.cntdot.solv (tpt = 2,4,6-tri(4-pyridyl)-1,3,5-triazine, solv = .apprx.3/4C2H2Cl4.cntdot.3/4CH3OH or .apprx.3/2CHCl3.cntdot.1/3CH3OH", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 117, no. 19, May 1995 (1995-05-01), pages 5385 - 5386
BRENDAN F. ABRAHAMS, ET AL.: "A wellsian 'three-dimensional' racemate: eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed", CHEMICAL COMMUNICATIONS, no. 11, 1996, pages 1313 - 1314
Attorney, Agent or Firm:
OHISHI HARUHITO (JP)
Haruhito Oishi (JP)
Haruhito Oishi (JP)
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