Title:
PREPARATION METHOD FOR AROMATIC AMIDE FRAGMENT EMBEDDED HYDROPHILIC AND HYDROPHOBIC MOLECULE SELF-ASSEMBLED MICELLE, AND PREPARATION METHOD FOR SUPRAMOLECULAR PHOTOCATALYTIC ASSEMBLY
Document Type and Number:
WIPO Patent Application WO/2021/088310
Kind Code:
A1
Abstract:
A construction unit head-body-tail three-section amphiphilic molecule of an aromatic amide fragment embedded hydrophilic and hydrophobic molecule self-assembled micelle, a preparation method for forming a water-phase ultra-uniform round micelle assembly by the construction unit, and a preparation method for a supramolecular photocatalytic assembly. According to the three-section amphiphilic molecule, an aromatic amide oligomer fragment is embedded into a conventional hydrophilic and hydrophobic molecule. The supramolecular photocatalytic assembly is prepared by carrying out a reaction on the prepared aromatic amide fragment embedded hydrophilic and hydrophobic molecule self-assembled micelle and a catalyst in a water-phase sacrificial reagent. The aromatic amide fragment embedded hydrophilic and hydrophobic molecule self-assembled micelle has extremely high chemical and structural stability in water, is ultra-uniform and monodisperse and has controllable particle size. The supramolecular photocatalytic assembly is suitable for producing hydrogen by reducing water phase protons under atmospheric atmosphere at normal temperature and normal pressure and selectively reducing carbon dioxide to prepare CO and CH4 under normal temperature and normal pressure in a carbon dioxide atmosphere, and does not contain noble metals.
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Inventors:
TIAN JIA (CN)
XIANG DECHENG (CN)
ZHANG YIFAN (CN)
XIANG DECHENG (CN)
ZHANG YIFAN (CN)
Application Number:
PCT/CN2020/083725
Publication Date:
May 14, 2021
Filing Date:
April 08, 2020
Export Citation:
Assignee:
THINKDO TECH LTD (CN)
International Classes:
C08G69/12; B01J31/22; C08G69/00
Domestic Patent References:
| WO2014093675A1 | 2014-06-19 |
Foreign References:
| CN102757437A | 2012-10-31 | |||
| CN107375927A | 2017-11-24 |
Other References:
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SCHENNING A. P. H. J., HUBERT D. H. W., FEITERS M. C., NOLTE R. J. M.: "Control of Aggregation and Tuning of the Location of Porphyrins in Synthetic Membranes as Mimics for Cytochrome P450", LANGMUIR, AMERICAN CHEMICAL SOCIETY, US, vol. 12, no. 6, 1 January 1996 (1996-01-01), US, pages 1572 - 1577, XP055809878, ISSN: 0743-7463, DOI: 10.1021/la950486a
D. AMILAN JOSE, STEFAN STADLBAUER, BURKHARD KÖNIG: "Polydiacetylene-Based Colorimetric Self-Assembled Vesicular Receptors for Biological Phosphate Ion Recognition", CHEMISTRY - A EUROPEAN JOURNAL, JOHN WILEY & SONS, INC, vol. 15, no. 30, 27 July 2009 (2009-07-27), pages 7404 - 7412, XP055604314, ISSN: 0947-6539, DOI: 10.1002/chem.200900339
KUMAR, DALIP ET AL.: "Cationic Porphyrin–Quinoxaline Conjugate as a Photochemically Triggered Novel Cytotoxic Agent", BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, vol. 23, 6 April 2013 (2013-04-06), XP028535176, DOI: 10.1016/j.bmcl.2013.03.126
ZOU QIANLI, ABBAS MANZAR, ZHAO LUYANG, LI SHUKUN, SHEN GUIZHI, YAN XUEHAI: "Biological Photothermal Nanodots Based on Self-Assembly of Peptide–Porphyrin Conjugates for Antitumor Therapy", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, US, vol. 139, no. 5, 8 February 2017 (2017-02-08), US, pages 1921 - 1927, XP055809876, ISSN: 0002-7863, DOI: 10.1021/jacs.6b11382
Attorney, Agent or Firm:
DONGGUAN ZHONG YE INTELLECTUAL PROPERTY FIRM (CN)
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