Title:
PROCESS FOR PRODUCING DIALKYL CARBONATE
Document Type and Number:
WIPO Patent Application WO/2010/074256
Kind Code:
A1
Abstract:
Disclosed is a process for industrially advantageously producing a symmetric dialkyl carbonate and an asymmetric dialkyl carbonate simultaneously by a transesterification reaction of an alkylene carbonate with two or more alcohols. Also disclosed is a process for efficiently producing high-purity diethyl carbonate by transesterification of ethylene carbonate or propylene carbonate with ethanol. Specifically disclosed is a process for producing a symmetric dialkyl carbonate and an asymmetric dialkyl carbonate simultaneously by subjecting an alkylene carbonate and two or more alcohols to a transesterification reaction in the same reactor. Also specifically disclosed is a process for producing diethyl carbonate by subjecting ethylene carbonate or propylene carbonate and ethanol to a transesterification reaction, wherein the process includes a step of performing separation by distillation of a fraction containing an ether compound by performing extractive distillation of a reaction product obtained by the transesterification reaction using ethylene glycol or propylene glycol as an extraction solvent.
Inventors:
SHIMIZU SATOSHI (JP)
Application Number:
PCT/JP2009/071654
Publication Date:
July 01, 2010
Filing Date:
December 25, 2009
Export Citation:
Assignee:
MITSUBISHI CHEM CORP (JP)
SHIMIZU SATOSHI (JP)
SHIMIZU SATOSHI (JP)
International Classes:
C07C68/06; C07C68/08; C07C69/96; C07B61/00
Foreign References:
JP2007534674A | 2007-11-29 | |||
JP2003089675A | 2003-03-28 | |||
JPH06166660A | 1994-06-14 | |||
JP2003300917A | 2003-10-21 | |||
JP2002371037A | 2002-12-26 | |||
JP2008333601A | 2008-12-26 | |||
JP2009290722A | 2009-12-22 |
Other References:
See also references of EP 2380868A4
Attorney, Agent or Firm:
OGURI Shohei et al. (JP)
Shohei Oguri (JP)
Shohei Oguri (JP)
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