Title:
PROCESS FOR PRODUCTION OF GLYCIDYL ETHER COMPOUNDS, AND MONOALLYL MONOGLYCIDYL ETHER COMPOUND
Document Type and Number:
WIPO Patent Application WO/2011/078060
Kind Code:
A1
Abstract:
Provided are: a process by which a compound having an allyl ether linkage can be efficiently converted into the corresponding glycidyl ether compound under mild conditions using hydrogen peroxide as the oxidizing agent; and a novel monoallyl monoglycidyl ether compound having a biphenyl skeleton. Specifically provided are: a process for the production of glycidyl ether compounds which comprises reacting a compound having an allyl ether linkage with hydrogen peroxide to epoxidize the carbon-carbon double bond of the allyl group and thus form the corresponding glycidyl ether compound, characterized by using, as the reaction catalyst, a tungsten compound, a tertiary amine, and phenylphosphonic acid; and a monoallyl monoglycidyl ether compound having a biphenyl skeleton. The monoallyl monoglycidyl ether compound can be produced by the process.
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Inventors:
UCHIDA HIROSHI (JP)
ARAI YOSHIKAZU (JP)
SATO KAZUHIKO (JP)
CHISHIRO TAKEFUMI (JP)
ARAI YOSHIKAZU (JP)
SATO KAZUHIKO (JP)
CHISHIRO TAKEFUMI (JP)
Application Number:
PCT/JP2010/072715
Publication Date:
June 30, 2011
Filing Date:
December 16, 2010
Export Citation:
Assignee:
SHOWA DENKO KK (JP)
NAT INST OF ADVANCED IND SCIEN (JP)
UCHIDA HIROSHI (JP)
ARAI YOSHIKAZU (JP)
SATO KAZUHIKO (JP)
CHISHIRO TAKEFUMI (JP)
NAT INST OF ADVANCED IND SCIEN (JP)
UCHIDA HIROSHI (JP)
ARAI YOSHIKAZU (JP)
SATO KAZUHIKO (JP)
CHISHIRO TAKEFUMI (JP)
International Classes:
C07D301/12; C07D303/22; C07D303/27
Domestic Patent References:
| WO2009107754A1 | 2009-09-03 | |||
| WO2010110151A1 | 2010-09-30 | |||
| WO2010073960A1 | 2010-07-01 |
Foreign References:
| JP2009256217A | 2009-11-05 | |||
| DE4023741A1 | 1992-01-30 | |||
| JP2002517387A | 2002-06-18 | |||
| JPH10511721A | 1998-11-10 |
Other References:
QUENARD, M. ET AL.: "Epoxidation of olefins by hydrogen peroxide catalyzed by phosphonotungstic complexes", TETRAHEDRON LETTERS, vol. 28, no. 20, 1987, pages 2237 - 2238
QUENARD, M. ET AL.: "Epoxydation d'olefines par l'eau oxygenee en presence de catalyseurs a base de tungstene VI, et de ligands phosphores", NEW JOURNAL OF CHEMISTRY, vol. 13, no. 3, 1989, pages 183 - 191
KON, Y. ET AL.: "An effective catalytic epoxidation of terpenes with hydrogen peroxide under organic solvent-free conditions", SYNLETT, April 2009 (2009-04-01), pages 1095 - 1098
QUENARD, M. ET AL.: "Epoxydation d'olefines par l'eau oxygenee en presence de catalyseurs a base de tungstene VI, et de ligands phosphores", NEW JOURNAL OF CHEMISTRY, vol. 13, no. 3, 1989, pages 183 - 191
KON, Y. ET AL.: "An effective catalytic epoxidation of terpenes with hydrogen peroxide under organic solvent-free conditions", SYNLETT, April 2009 (2009-04-01), pages 1095 - 1098
Attorney, Agent or Firm:
AOKI, Atsushi et al. (JP)
Aoki 篤 (JP)
Aoki 篤 (JP)
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