Title:
PRODUCTION METHOD FOR CELLULOSE AND/OR HEMICELLULOSE
Document Type and Number:
WIPO Patent Application WO/2020/080557
Kind Code:
A1
Abstract:
The purpose of the present invention is to provide a method for obtaining cellulose and/or hemicellulose from a woody material under mild conditions. This production method for cellulose and/or hemicellulose comprises subjecting a woody material to an oxidation treatment using a metal complex and an oxidizing agent to separate and obtain cellulose and/or hemicellulose, and is characterized in that: the metal complex contains a metal and at least one nitrogen-containing compound selected from the group consisting of imides and amides as a ligand; the metal is at least one selected from the group consisting of iron group metals and platinum group metals; and the nitrogen-containing compound contains, as a substituent, at least one selected from the group consisting of sulfonyl groups having an electron-withdrawing group and sulfonyl groups having an aromatic group.
Inventors:
TAKAYA HIKARU (JP)
NAKAMURA MASAHARU (JP)
SHANOH TAKAFUMI (JP)
KITAYAMA KENJI (JP)
NAKAMURA MASAHARU (JP)
SHANOH TAKAFUMI (JP)
KITAYAMA KENJI (JP)
Application Number:
PCT/JP2019/042231
Publication Date:
April 23, 2020
Filing Date:
October 15, 2019
Export Citation:
Assignee:
UNIV KYOTO (JP)
DAICEL CORP (JP)
DAICEL CORP (JP)
International Classes:
C08B15/08; B01J31/22; C08B37/14; C08H7/00; C07F15/02
Domestic Patent References:
| WO2019172184A1 | 2019-09-12 |
Foreign References:
| JP2013198424A | 2013-10-03 | |||
| JP2016520565A | 2016-07-14 | |||
| JP2004531492A | 2004-10-14 |
Other References:
DEVARI, SHEKARAIAH ET AL.: "Osmium (VI) catalyzed chemoselective oxidation of allylic and benzylic alcohols", TETRAHEDRON LETTERS, vol. 54, no. 48, 2013, pages 6407 - 6410, XP028751808, DOI: 10.1016/j.tetlet.2013.09.036
DAYAN, SERKAN ET AL.: "Synthesis, characterization and catalytic properties of novel palladium(II) complexes containing aromatic sulfonamides: effective catalysts for the oxidation of benzyl alcohol", APPLIED ORGANOMETALLIC CHEMISTRY, vol. 27, no. 1, 2013, pages 52 - 58, XP055704153, DOI: 10.1002/aoc.2938
VINOD, K. N. ET AL.: "Os (VIII) as an Efficient Homogeneous Catalyst for the Oxidative Decolorization of Methylene Blue Dye with Alkaline Chloramine-T: Kinetic, Mechanistic, and Platinum Metal Ions Reactivity Studies", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, vol. 49, no. 7, 2010, pages 3137 - 3145, XP002678430, DOI: 10.1021/IE900628R
COOK, SARAH A. ET AL.: "Iron (II) Complexes Supported by Sulfonamido Tripodal Ligands: Endogenous versus Exogenous Substrate Oxidation", INORGANIC CHEMISTRY, vol. 53, no. 20, 2014, pages 11029 - 11035, XP055704154, DOI: 10.1021/ic501531g
DAYAN, SERKAN ET AL.: "Synthesis, characterization and catalytic properties of novel palladium(II) complexes containing aromatic sulfonamides: effective catalysts for the oxidation of benzyl alcohol", APPLIED ORGANOMETALLIC CHEMISTRY, vol. 27, no. 1, 2013, pages 52 - 58, XP055704153, DOI: 10.1002/aoc.2938
VINOD, K. N. ET AL.: "Os (VIII) as an Efficient Homogeneous Catalyst for the Oxidative Decolorization of Methylene Blue Dye with Alkaline Chloramine-T: Kinetic, Mechanistic, and Platinum Metal Ions Reactivity Studies", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, vol. 49, no. 7, 2010, pages 3137 - 3145, XP002678430, DOI: 10.1021/IE900628R
COOK, SARAH A. ET AL.: "Iron (II) Complexes Supported by Sulfonamido Tripodal Ligands: Endogenous versus Exogenous Substrate Oxidation", INORGANIC CHEMISTRY, vol. 53, no. 20, 2014, pages 11029 - 11035, XP055704154, DOI: 10.1021/ic501531g
Attorney, Agent or Firm:
GOTO & CO. (JP)
Download PDF: