Title:
PRODUCTION METHOD FOR CIS-3-HEXENE-1-OL
Document Type and Number:
WIPO Patent Application WO/2014/156781
Kind Code:
A1
Abstract:
The present invention provides a production method for cis-3-hexene-1-ol, said production method being characterized in that 3-hexyne-1-ol is subjected to a partial hydrogenation reaction in the presence of a palladium catalyst, in the absence of a solvent, and under conditions in which the hydrogen gauge pressure in a reaction vessel is in the range 10-1000 kPa. According to the present invention, highly pure cis-3-hexene-1-ol can be produced in an industrially advantageous manner by using a palladium catalyst to partially hydrogenate 3-hexyne-1-ol.
Inventors:
ENDOU MASAHIRO (JP)
Application Number:
PCT/JP2014/057180
Publication Date:
October 02, 2014
Filing Date:
March 17, 2014
Export Citation:
Assignee:
ZEON CORP (JP)
International Classes:
C07C29/17; C07C33/025; C07B61/00
Foreign References:
| JPS5564527A | 1980-05-15 | |||
| JPS5612326A | 1981-02-06 | |||
| JPS61118328A | 1986-06-05 | |||
| JPS6383031A | 1988-04-13 | |||
| CN1762941A | 2006-04-26 |
Other References:
CARMEN MORENO MARRODAN ET AL.: "In situ generation of resin-supported Pd nanoparticles under mild catalytic conditions: a green route to highly efficient, reusable hydrogenation catalysts", CATALYSIS SCIENCE & TECHNOLOGY, vol. 2, no. 11, 2012, pages 2279 - 2290
ALEXANDER SACHSE ET AL.: "Selective hydrogenation over Pd nanoparticles supported on a pore-flow-through silica monolith microreactor with hierarchical porosity", DALTON TRANSACTIONS, vol. 42, no. 5, pages 1378 - 1384
H. BONNEMANN: "Surfactant stabilized palladium colloids as precursors for cis-selective alkyne hydrogenation catalysts", APPLIED ORGANOMETALLIC CHEMISTRY, vol. 11, 1997, pages 783 - 796
ALEXANDER SACHSE ET AL.: "Selective hydrogenation over Pd nanoparticles supported on a pore-flow-through silica monolith microreactor with hierarchical porosity", DALTON TRANSACTIONS, vol. 42, no. 5, pages 1378 - 1384
H. BONNEMANN: "Surfactant stabilized palladium colloids as precursors for cis-selective alkyne hydrogenation catalysts", APPLIED ORGANOMETALLIC CHEMISTRY, vol. 11, 1997, pages 783 - 796
Attorney, Agent or Firm:
OHISHI HARUHITO (JP)
Haruhito Oishi (JP)
Haruhito Oishi (JP)
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