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Title:
RARE EARTH METAL COMPLEX
Document Type and Number:
WIPO Patent Application WO/2012/070420
Kind Code:
A1
Abstract:
A rare earth metal complex comprising a rare earth metal atom and a β-diketone compound which is represented by formula (1) and is coordinated to the rare earth metal atom. In formula (1), R1 represents a hydrogen atom, a halogen atom, an alkyl group, a perfluoroalkyl group, an alkoxy group, a perfluoroalkoxy group, a nitro group, an amino group, a sulfonyl group, a cyano group, a silyl group, a phosphone group, a diazo group, a mercapto group, an aryl group, an aralkyl group, an aryloxy group, an aryloxycarbonyl group, an allyl group, an acyl group, or an acyloxy group.

Inventors:
YAMASHITA TAKESHI (JP)
Application Number:
PCT/JP2011/076198
Publication Date:
May 31, 2012
Filing Date:
November 14, 2011
Export Citation:
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Assignee:
HITACHI CHEMICAL CO LTD (JP)
YAMASHITA TAKESHI (JP)
International Classes:
C07D333/16; C09K11/06; C07F5/00
Foreign References:
JP2005252250A2005-09-15
JPH11255700A1999-09-21
JP2005035902A2005-02-10
JP2009046577A2009-03-05
JP2011043500A2011-03-03
Other References:
SUN Y. ET AL.: "High luminescence quantum yields and long luminescence lifetime from Eu(III) complex containing two crystal water based on a new BETA-diketonate ligand", SPECTROCHIMICA ACTA PART A: MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol. 64, no. 4, 2006, pages 977 - 980, XP028036469
LIU X. ET AL.: "Synthesis and luminescence properties of rare earth ternary complexes consisting of Tb(III), beta-diketones and 1,10- phenanthroline (phen)", RARE METALS, vol. 27, no. 6, 2008, pages 612 - 616, XP025847378
ZHENG H. ET AL.: "Stabilization of Nondiscoid Columnar Liquid Crystals: Studies of Unsymmetrical Copper Bis-beta-diketonates", CHEMISTRY OF MATERIALS, vol. 8, no. 4, 1996, pages 907 - 911, XP055086067
DEOLANKAR, D. S. ET AL.: "La(III), Pr(III), Gd (III), Tb(III) & Dy(III) complex of aryl furyl and aryl thienyl beta-diketones", INDIAN JOURNAL OF CHEMISTRY, SECTION A: INORGANIC, PHYSICAL, THEORETICAL & ANALYTICAL, vol. 26A, no. 1, 1987, pages 68 - 69, XP008170576
See also references of EP 2644606A4
Attorney, Agent or Firm:
HIZATATE, Shoji et al. (JP)
膝舘 Yoshiharu (JP)
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Claims: