JP2023151484 | LUBRICATING OIL COMPOSITION |
WO/2014/115603 | CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK |
JP2013087198 | SLIDING MECHANISM |
LIN THOMAS (US)
ARITAKE TAKASHI (JP)
KATOU GOU (JP)
MAEDA MAKOTO (JP)
MOGI YASUHIRO (JP)
MORISATO HIROSHI (JP)
SAITO HIROKAZU (JP)
JATCO LTD (JP)
US20130102511A1 | 2013-04-25 | |||
US2522590A | 1950-09-19 | |||
US6337309B1 | 2002-01-08 | |||
US5840663A | 1998-11-24 | |||
US202017062456A | 2020-10-02 | |||
US4873009A | 1989-10-10 | |||
US20120264665A1 | 2012-10-18 | |||
US3254025A | 1966-05-31 | |||
US3502677A | 1970-03-24 | |||
US4857214A | 1989-08-15 | |||
US2719125A | 1955-09-27 | |||
US2719126A | 1955-09-27 | |||
US3087937A | 1963-04-30 | |||
US2760933A | 1956-08-28 | |||
US2836564A | 1958-05-27 | |||
US3663561A | 1972-05-16 | |||
US5840663A | 1998-11-24 | |||
US20090005277A1 | 2009-01-01 |
C.V. SMALLHEERR. KENNEDY SMITH, LUBRICANT ADDITIVES, 1967, pages 1 - 11
CLAIMS What is claimed is: 1. A transmission fluid booster additive package composition comprising: (a) a mixture comprising: (i) two or more compounds of structures (I): ); wh s or alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage, provided that, in component (i), at least some of groups R1, R2 and R3 are alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage; and (ii) one or more compounds of structures (II): II) where groups R4 and 2 carbon atoms and R5 and R6 are independently alkyl linkages having 2 to 12 carbon atoms; (b) an ashless dispersant representing at least 20 mass% of the transmission fluid booster additive package composition; (c) an overbased calcium phenate detergent; (d) at least two friction modifiers, a first of which comprises a polyethylene polyamine succinimide derivative; (e) a corrosion inhibitor; and (f) a suspension-stabilizing amount of a lubricating oil basestock, wherein the transmission fluid booster additive package composition exhibits: a boron content from 0.04 mass% to 0.75 mass%, based on the total mass of the additive package composition; a calcium content from 0.3 mass% to 1.5 mass%, based on the total mass of the additive package composition; and a phosphorus content from 0.3 mass% to 1.5 mass%, based on the total mass of the additive package composition. 2. A booster additive package composition according to claim 1, wherein the compounds of component (i) and component (ii) are present in the composition in a mass ratio of from 2:1 to 1:2. 3. A booster additive package composition according to claim 1 or claim 2, wherein the ashless dispersant comprises a polyisobutenyl succinimide. 4. A booster additive package composition according to any one of the previous claims, wherein the polyethylene polyamine succinimide derivative has the following structure: where 5. A booster additive package composition according to any one of the previous claims, wherein a second friction modifier comprises an amide friction modifier, an amine friction modifier, or a mixture or combination thereof. 6. A booster additive package composition according to any one of the previous claims, wherein the corrosion inhibitor comprises a benzotriazole. 7. A booster additive package composition according to any one of the previous claims, wherein the transmission fluid booster additive package composition comprises substantially no additional antioxidants, other than any compounds that may function as antioxidants from components (a), (b), (c), (d), and (e). 8. A booster additive package composition according to any one of the previous claims, wherein the lubricating oil basestock comprises a Group II basestock, a Group III basestock, and/or a Group V basestock and is present in a suspension-stabilizing amount from 5.0 mass% to 40 mass%, based on the weight of the booster additive package composition. 9. A booster additive package composition according to any one of the previous claims, wherein one or more of the following is satisfied: (1) a fully formulated lubricating oil composition, which comprises the booster additive package composition and a lubricating oil basestock that is the same as or different from the lubricating oil basestock in the booster additive package composition (e.g., in a mass ratio of booster additive package composition to lubricating oil basestock of from 1:49 to 1:7), is formulated to exhibit an anti-shudder durability (ASD) lifetime under constant torque of at least 85 hours; (2) the booster additive package composition contributes at least an additional 40 hours of ASD lifetime under constant torque, when added to a fresh or used fully formulated lubricating oil composition comprising, or having comprised prior to use, at least an anti- wear additive, an ashless dispersant, a detergent, a friction modifier, at least one additional antioxidant, and a lubricating oil basestock, as compared to an ASD lifetime of the fresh or used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to fresh or used fully formulated lubricating oil composition is from 1:32 to 1:8); and (3) the booster additive package composition contributes at least a 60% increase in ASD lifetime under constant torque, when added to a fresh or used fully formulated lubricating oil composition comprising, or having comprised prior to use, at least an anti- wear additive, an ashless dispersant, a detergent, a friction modifier, at least one additional antioxidant, and a lubricating oil basestock, as compared to an ASD lifetime of the fresh or used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to fresh or used fully formulated lubricating oil composition is from 1:32 to 1:8). 10. A rejuvenated, used lubricating oil composition comprising an admixture of: a major amount of a fully formulated lubricating oil composition that has been previously used to lubricate a vehicle transmission for at least 25,000 kilometers, or a lubrication running time equivalent thereto, the fully formulated lubricating oil composition having comprised, prior to use, at least an anti-wear additive, an ashless dispersant, an overbased calcium detergent, a friction modifier, a corrosion inhibitor, at least two additional antioxidants, and a lubricating oil basestock; and a minor amount of a transmission fluid booster additive package composition that maintains suspension stability when added to the previously used formulated lubricating oil composition, which booster additive package composition may be according to any of the previous claims or comprises: (a) a mixture comprising: (i) two or more compounds of structures (I): ); wh s or alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage, provided that, in component (i), at least some of groups R1, R2 and R3 are alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage; and (ii) one or more compounds of structures (II): II) where groups R4 and 2 carbon atoms and R5 and R6 are independently alkyl linkages having 2 to 12 carbon atoms; (b) an ashless dispersant; (c) an overbased calcium phenate detergent; (d) at least two friction modifiers, a first of which comprises a polyethylene polyamine succinimide derivative; (e) a corrosion inhibitor; and (f) a suspension-stabilizing amount of a lubricating oil basestock wherein the rejuvenated, used lubricating oil composition exhibits: a boron content from 30 to 400 parts per million by mass, based on the total mass of the rejuvenated, used lubricating oil composition; a calcium content from 250 to 800 parts per million by mass, based on the total mass of the rejuvenated, used lubricating oil composition; and a phosphorus content from 250 to 800 parts per million by mass, based on the total mass of the rejuvenated, used lubricating oil composition. 11. A rejuvenated composition according to claim 10, wherein at least 20 mass% of the transmission fluid booster additive package composition is comprised of the ashless dispersant. 12. A rejuvenated composition according to claim 10 or claim 11, wherein the compounds of component (i) and component (ii) are each present in the composition in an amount from 0.05 to 1.2% by mass, based on the total mass of the composition. 13. A rejuvenated composition according to any one of claims 10 through 12, wherein the compounds of component (i) and component (ii) are present in the composition in a mass ratio of from 2:1 to 1:2. 14. A rejuvenated composition according to any one of claims 10 through 13, wherein the ashless dispersant comprises a polyisobutenyl succinimide and the corrosion inhibitor comprises a benzotriazole. 15. A rejuvenated composition according to any one of claims 10 through 14, wherein the polyethylene polyamine succinimide derivative has the following structure: where 16. A rejuvenated composition according to any one of claims 10 through 15, wherein a second friction modifier comprises an amide friction modifier, an amine friction modifier, or a mixture or combination thereof. 17. A rejuvenated composition according to any one of claims 10 through 16, wherein the transmission fluid booster additive package composition comprises substantially no additional antioxidants, other than any compounds that may function as antioxidants from components (a), (b), (c), (d), and (e). 18. A rejuvenated composition according to any one of claims 10 through 17, wherein a mass ratio of the booster additive package composition to the used fully formulated lubricating oil composition is from 1:49 to 1:5. 19. A rejuvenated composition according to any one of claims 10-18, wherein the lubricating oil basestock from the booster additive package composition comprises a Group II basestock, a Group III basestock, and/or a Group V basestock, and wherein the lubricating oil basestock from the fully formulated lubricating oil composition, prior to use, comprised a Group II basestock and/or a Group III basestock. 20. A rejuvenated composition according to any one of claims 10 through 19, wherein one or more of the following is satisfied: (1) the rejuvenated, used lubricating oil composition exhibits an anti-shudder durability (ASD) lifetime under constant torque of at least 80 hours; (2) the rejuvenated, used lubricating oil composition exhibits an anti-shudder durability (ASD) lifetime under constant torque of an additional 40 hours, as compared to an ASD lifetime of the used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to used fully formulated lubricating oil composition is from 1:32 to 1:8); and (3) the rejuvenated, used lubricating oil composition contributes at least a 60% increase in ASD lifetime under constant torque, as compared to an ASD lifetime of the used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to used fully formulated lubricating oil composition is from 1:32 to 1:8). 21. A rejuvenated composition according to any one of claims 10 through 20, which composition exhibits: (A) a coefficient of friction, μ, of at least 0.100 and not greater than 0.140 under LFW-1 standard test conditions at a sliding speed of about 0.125 m/s, a temperature of about 110℃, and at an applied load of about 1.1kN (~250 lbs); (B) a coefficient of friction, μ(5), that is no more than 40% below and no greater than 10% above a corresponding coefficient of friction, μ(5), of the rejuvenated, used lubricating oil composition without the transmission fluid booster additive package composition, in which μ(5) is measured according to constant-torque modified JASO M349 standard anti- shudder durability test conditions; or (C) both (A) and (B). 22. A method of rejuvenating a fully formulated lubricating oil composition that has been previously used to lubricate a vehicle transmission for at least 25,000 kilometers, or a lubrication running time equivalent thereto, the method comprising: admixing the suspension-stable transmission fluid booster additive package composition according to any one of claims 1 through 9 with the used, fully formulated lubricating oil composition to form a rejuvenated, used lubricating oil composition, the used, fully formulated lubricating oil composition having comprised, prior to use, at least an anti- wear additive, an ashless dispersant, an overbased calcium detergent, a friction modifier, a corrosion inhibitor, at least two additional antioxidants, and a lubricating oil basestock; and lubricating the vehicle transmission to enable operation for at least an additional 30,000 kilometers, or a lubrication running time equivalent thereto. 23. A method of rejuvenating a fully formulated lubricating oil composition that has been previously used to lubricate a vehicle transmission for at least 25,000 kilometers, or a lubrication running time equivalent thereto, the method comprising: admixing a suspension-stable transmission fluid booster additive package composition with the used, fully formulated lubricating oil composition to form the rejuvenated, used lubricating oil composition according to any one of claims 10 through 21, the used, fully formulated lubricating oil composition having comprised, prior to use, at least an anti-wear additive, an ashless dispersant, an overbased calcium detergent, a friction modifier, a corrosion inhibitor, at least two additional antioxidants, and a lubricating oil basestock; and lubricating the vehicle transmission to enable operation for at least an additional 30,000 kilometers, or a lubrication running time equivalent thereto. 24. Use of the suspension-stable transmission fluid booster additive package composition according to any one of claims 1 through 9 in combination with a fresh or used fully formulated lubricating oil composition to rejuvenate lubricant properties at least partially lost during previous operation of a vehicle transmission, in particular rejuvenating one or more of anti-shudder durability, friction modification, dynamic-static friction balance, anti-wear, soot dispersion capability, detergency, suspension stability, and corrosion inhibition. 25. Use of the rejuvenated, used lubricating oil composition according to any one of claims 10 through 21 to rejuvenate lubricant properties at least partially lost during previous operation of a vehicle transmission, in particular rejuvenating one or more of anti-shudder durability, friction modification, dynamic-static friction balance, anti-wear, soot dispersion capability, detergency, suspension stability, and corrosion inhibition. |
wherein ea , provided that R11 and R12 connected to the same succinimide ring are not both hydrogen; z may be an integer from 0 to 10, such as from 1 to 8; and each R13 may individually be hydrogen, an acetyl group, a –CH 2 -CH 2 -N(R 13 ) 2 group, or a branched succinimide of the formula: , or wherein two proximate R13 nitrogen atoms may connect together, e.g., using an ethylene bridge to form a piperazinyl group. [0051] In order to properly function as a dispersant, relative to a similar chemical structure that primarily functions as a friction modifier (as described below), the hydrocarbyl group on each succinimide ring (i.e., the relevant R 11 alone if R 12 is hydrogen, the relevant R12 alone if R11 is hydrogen, or a combination of the relevant R11 and R12) may advantageously comprise greater than 36 carbons, in particular greater than 40 carbon atoms, greater than 44 carbon atoms, or greater than 48 carbon atoms. When R 12 is hydrogen and R 11 is a polyisobutenyl chain, this structure describes the polyisobutenyl succinimides mentioned earlier. When R11 is a polyalphaolefin (PAO) chain, such as a metallocene- catalyzed polyalphaolefin (mPAO) made by polymerizing 1-octene, 1-decene, and/or 1- dodecene, this structure describes an analogous polyalphaolefin succinimide dispersant. Just as with polyisobutenyl chains, additional or alternative examples of ashless dispersants may include polyalphaolefin succinamides, mixed ester/amides/imides of polyalphaolefin- substituted succinic acid, and/or hydroxyesters of polyalphaolefin-substituted succinic acid, as well as variations with imidazoline and/or oxazoline linkages in lieu of or in addition to the succinimides shown in the formula above. Examples of such PAO dispersants can be seen, e.g., in U.S. Patent Application Publication No.2012/0264665. [0052] In particular, the ashless dispersant may include a polyisobutenyl succinimide formed from polyisobutenyl succinic anhydride and a polyalkylene polyamine such as tetraethylene pentamine or H-PAM. The polyisobutenyl group may be derived from polyisobutene and may exhibit a number average molecular weight (Mn) from about 750 to about 5000 Daltons, e.g., from about 900 to about 2500 Daltons. [0053] As is known in the art, dispersants may be post-treated (e.g., with a borating/boronating agent and/or with an inorganic acid of phosphorus). Suitable examples may be found, for instance, in U.S. Patent Nos.3,254,025, 3,502,677, and 4,857,214. [0054] When used, an ashless dispersant may be present in transmission fluid compositions according to the present disclosure in an amount of from 0.1 mass% to 10 mass%, based on the mass of the transmission fluid composition, in particular from 0.5 mass% to 5.0 mass%. Additionally or alternatively, when used, an ashless dispersant may be present in booster additive package concentrates according to the present disclosure in an amount of at least 15 mass%, based on the mass of the booster additive package concentrate, e.g., at least 20 mass%, at least 25 mass%, at least 30 mass%, at least 35 mass%, at least 40 mass%, from 15 mass% to 65 mass%, from 15 mass% to 60 mass%, from 15 mass% to 55 mass%, from 15 mass% to 50 mass%, from 15 mass% to 45 mass%, from 15 mass% to 40 mass%, from 20 mass% to 65 mass%, from 20 mass% to 60 mass%, from 20 mass% to 55 mass%, from 20 mass% to 50 mass%, from 20 mass% to 45 mass%, from 20 mass% to 40 mass%, from 25 mass% to 65 mass%, from 25 mass% to 60 mass%, from 25 mass% to 55 mass%, from 25 mass% to 50 mass%, from 25 mass% to 45 mass%, from 25 mass% to 40 mass%, from 30 mass% to 65 mass%, from 30 mass% to 60 mass%, from 30 mass% to 55 mass%, from 30 mass% to 50 mass%, from 30 mass% to 45 mass%, from 30 mass% to 40 mass%, from 35 mass% to 65 mass%, from 35 mass% to 60 mass%, from 35 mass% to 55 mass%, from 35 mass% to 50 mass%, from 35 mass% to 45 mass%, or from 35 mass% to 40 mass%, in particular at least 20 mass%, at least 30 mass%, from 20 mass% to 55 mass%, or from 30 mass% to 50 mass%. A mixture of more than one ashless dispersant may be included in the booster additive package concentrate and/or the transmission fluid composition in which case, the amounts given herein refer to the total amount of the mixture of dispersants used. Detergents [0055] The transmission fluid booster additive package compositions and/or transmission fluid compositions according to the present disclosure may further comprise a detergent, such as a calcium-containing detergent. These detergents are typically sufficiently oil-soluble or dispersible such as to remain dissolved or dispersed in an oil in order to be transported by the oil to their intended site of action. Calcium-containing detergents are known in the art and include neutral and overbased calcium salts with acidic substances such as salicylic acids, sulfonic acids, carboxylic acids, alkyl phenols, sulfurized alkyl phenols and mixtures of these substances. [0056] Neutral calcium-containing detergents are those detergents that contain stoichiometrically equivalent amounts of calcium in relation to the amount of (Lewis) acidic moieties present in the detergent. Thus, in general, neutral detergents can typically have a relatively low basicity, when compared to their overbased counterparts. [0057] The term "overbased," for example in connection with calcium detergents, is used to designate the fact that the calcium component is present in stoichiometrically larger amounts than the corresponding (Lewis) acid component. The commonly employed methods for preparing the overbased salts involve heating a mineral oil solution of an acid with a stoichiometric excess of a neutralizing agent at an appropriate temperature (in this case, a calcium neutralizing agent, such as an oxide, hydroxide, carbonate, bicarbonate, sulfide, or combination thereof, at a temperature of about 50℃) and filtering the resultant product. The use of a “promoter” in the neutralization step to aid the incorporation of a large excess of salt/base (in this case, calcium) likewise is known. Examples of compounds useful as a promoter may include, but are not necessarily limited to, phenolic substances such as phenol, naphthol, alkyl phenol, thiophenol, sulfurized alkylphenol, and condensation products of formaldehyde with a phenolic substance; alcohols such as methanol, 2-propanol, octanol, Cellosolve™ alcohol, Carbitol™ alcohol, ethylene glycol, stearyl alcohol, and cyclohexyl alcohol; amines such as aniline, phenylene diamine, phenothiazine, phenyl-β-naphthylamine, and dodecylamine; and combinations thereof. A particularly effective method for preparing the basic salts comprises mixing an acidic substance with an excess of calcium neutralizing agent and at least one alcohol promoter, and carbonating the mixture at an elevated temperature, such as from 60 to 200℃. [0058] Examples of calcium-containing detergents useful in the transmission fluid compositions of the present disclosure may include, but are not necessarily limited to, neutral and/or overbased salts of such substances as calcium phenates; sulfurized calcium phenates (e.g., wherein each aromatic group has one or more aliphatic groups to impart hydrocarbon solubility); calcium sulfonates (e.g., wherein each sulfonic acid moiety is attached to an aromatic nucleus, which in turn usually contains one or more aliphatic substituents to impart hydrocarbon solubility); calcium salicylates (e.g., wherein the aromatic moiety is usually substituted by one or more aliphatic substituents to impart hydrocarbon solubility); calcium salts of hydrolyzed phosphosulfurized olefins (e.g., having 10 to 2000 carbon atoms) and/or of hydrolyzed phosphosulfurized alcohols and/or aliphatic-substituted phenolic compounds (e.g., having 10 to 2000 carbon atoms); calcium salts of aliphatic carboxylic acids and/or aliphatic substituted cycloaliphatic carboxylic acids; and combinations and/or reaction products thereof; as well as many other similar calcium salts of oil-soluble organic acids. Mixtures of neutral and/or overbased salts of two or more different acids can be used, if desired (e.g., one or more overbased calcium phenates with one or more overbased calcium sulfonates and/or one or more overbased calcium salicylates). [0059] Methods for the production of oil-soluble neutral and overbased calcium detergents are well known to those skilled in the art and are extensively reported in the patent literature. Calcium-containing detergents may optionally be post-treated, e.g., borated/boronated. Methods for preparing borated/boronated detergents are well known to those skilled in the art, and are extensively reported in the patent literature. [0060] When present, a calcium-containing detergent may advantageously comprise, consist essentially of, or consist of a neutral or overbased calcium phenate detergent, optionally plus a neutral or overbased calcium sulfonate detergent and/or a neutral or overbased calcium salicylate detergent. Antioxidants [0061] Antioxidants are sometimes referred to as oxidation inhibitors and may increase the resistance (or decrease the susceptibility) of the transmission fluid composition to oxidation. They may work by combining with and modifying oxidative agents, such as peroxides and other free radical-forming compounds, to render them harmless, e.g., by decomposing them or by rendering inert a catalyst or facilitator of oxidation. Oxidative deterioration can be evidenced by sludge in the fluid with increased use, by varnish-like deposits on metal surfaces, and sometimes by viscosity increase. [0062] Examples of suitable antioxidants may include, but are not limited to, copper- containing antioxidants, sulfur-containing antioxidants, aromatic amine-containing and/or amide-containing antioxidants, hindered phenolic antioxidants, dithiophosphates and derivatives, and the like, as well as combinations and certain reaction products thereof. Some anti-oxidants may be ashless (i.e., may contain few, if any, metal atoms other than trace or contaminants). In most embodiments, one or more antioxidants (in particular, at least a combination of an aromatic amine antioxidant and a hindered phenolic antioxidant) is/are present in new (and fully formulated) vehicle transmission lubricant fluids and typically remains present in used vehicle transmission lubricant fluids. Because of that, when a transmission fluid booster additive package composition according to the present disclosure is added to a used vehicle transmission lubricant fluid to form a transmission fluid composition according to the present disclosure, the transmission fluid composition may typically comprise one or more antioxidants, but in some embodiments only from the used vehicle transmission lubricating fluid; in such embodiments, transmission fluid booster additive package compositions according to the present disclosure may comprise substantially no additional antioxidants (that are not subsumed within another additive having a different enumerated function – for example, phosphorus-containing anti-wear agents may have antioxidant character but do not qualify as additional antioxidants because of the anti-wear primary function of enumerated component (i)). Corrosion inhibitors [0063] Corrosion inhibitors may be used to reduce the corrosion of metals and are often alternatively referred to as metal deactivators or metal passivators. Some corrosion inhibitors may alternatively be characterized as antioxidants. [0064] Suitable corrosion inhibitors may include nitrogen and/or sulfur containing heterocyclic compounds such as triazoles (e.g., benzotriazoles), substituted thiadiazoles, imidazoles, thiazoles, tetrazoles, hydroxyquinolines, oxazolines, imidazolines, thiophenes, indoles, indazoles, quinolines, benzoxazines, dithiols, oxazoles, oxatriazoles, pyridines, piperazines, triazines and derivatives of any one or more thereof. A particular corrosion inhibitor is a benzotriazole represented by the structure: wherein R 8 is absent or is a C 1 to C 20 ubstituted hydrocarbyl group which may be linear or branched, saturated or unsaturated. It may contain ring structures that are alkyl or aromatic in nature and/or contain heteroatoms such as N, O, or S. Examples of suitable compounds may include benzotriazole, alkyl-substituted benzotriazoles (e.g., tolyltriazole, ethylbenzotriazole, hexylbenzotriazole, octylbenzotriazole, etc.), aryl substituted benzotriazole, alkylaryl- or arylalkyl-substituted benzotriazoles, and the like, as well as combinations thereof. For instance, the triazole may comprise or be a benzotriazole and/or an alkylbenzotriazole in which the alkyl group contains from 1 to about 20 carbon atoms or from 1 to about 8 carbon atoms. A preferred corrosion inhibitor may comprise or be benzotriazole and/or tolyltriazole. [0065] Additionally or alternatively, the corrosion inhibitor may include a substituted thiadiazoles represented by the structure: wherein R 9 and R 10 are indepen arbon group, which group may be aliphatic or aromatic, including cyclic, alicyclic, aralkyl, aryl and alkaryl. These substituted thiadiazoles are derived from the 2,5-dimercapto-1,3,4-thiadiazole (DMTD) molecule. Many derivatives of DMTD have been described in the art, and any such compounds can be included in the transmission fluid used in the present disclosure. For example, U.S. Patent Nos. 2,719,125, 2,719,126, and 3,087,937 describe the preparation of various 2, 5-bis-(hydrocarbon dithio)-1,3,4-thiadiazoles. [0066] Further additionally or alternatively, the corrosion inhibitor may include one or more other derivatives of DMTD, such as a carboxylic ester in which R 9 and R 10 may be joined to the sulfide sulfur atom through a carbonyl group. Preparation of these thioester containing DMTD derivatives is described, for example, in U.S. Patent No.2,760,933. DMTD derivatives produced by condensation of DMTD with alpha-halogenated aliphatic monocarboxylic acids having at least 10 carbon atoms are described, for example, in U.S. Patent No.2,836,564. This process produces DMTD derivatives wherein R 9 and R 10 are HOOC-CH(R 19 )- (R 19 being a hydrocarbyl group). DMTD derivatives further produced by amidation or esterification of these terminal carboxylic acid groups may also be useful. [0067] The preparation of 2-hydrocarbyldithio-5-mercapto-1,3,4-thiadiazoles is described, for example, in U.S. Patent No.3,663,561. [0068] A particular class of DMTD derivatives may include mixtures of a 2- hydrocarbyldithio-5-mercapto-1,3,4-thiadiazole and a 2,5-bis-hydrocarbyldithio-1,3,4- thiadiazole. Such mixtures may be sold under the tradename HiTEC ® 4313 and are commercially available from Afton Chemical. [0069] When used, corrosion inhibitors may be present in any effective amount, but may typically be used in transmission fluid compositions in amounts from about 0.001 mass% to 3.0 mass%, based on the mass of the transmission fluid composition, e.g., from 0.003 mass% to 1.0 mass% or from 0.005 mass% to 0.5 mass%. Additionally or alternatively, when used, corrosion inhibitors may be present in booster additive package concentrates in amounts from about 0.01 mass% to 10 mass%, based on the mass of the booster additive package concentrate, e.g., from 0.03 mass% to 5.0 mass% or from 0.05 mass% to 2.0 mass%. Friction modifiers [0070] Friction modifiers may include derivatives of polyethylene polyamines and/or ethoxylated long chain amines. The derivatives of polyethylene polyamines may advantageously include succinimides of a defined structure or may be simple amides. [0071] Suitable succinimides derived from polyethylene polyamines may include those of the following structure: where particular wherein x + y may be from 11 to 15 (e.g., 13) and z may be from 1 to 3. Preparation of such friction modifiers is described, for example, in U.S. Patent No.5,840,663. [0072] The above succinimides may be post-reacted with acetic anhydride to form friction modifiers exemplified by the following structure (in which z = 1): [0073] Preparation of this friction modifier is known and can be found, e.g., in U.S. Patent Application Publication No.2009/0005277. Post reaction with other reagents, e.g., borating/boronating agents, is also known in the art. [0074] When present, such succinimide friction modifiers may be used in any effective amount. Typically, in transmission fluid compositions, they may be used in amounts from 0.1 mass% to 10 mass%, based on the mass of the transmission fluid composition, e.g., from 0.3 mass% to 6.0 mass% or from 0.5 mass% to 3.0 mass%. Additionally or alternatively, when used, succinimide friction modifiers may be present in booster additive package concentrates in amounts from about 0.5 mass% to 50 mass%, based on the mass of the booster additive package concentrate, e.g., from 1.0 mass% to 40 mass% or from 3.0 mass% to 30 mass%. [0075] An example of an alternative simple amide may have the following structure: wherein R 1 and R 2 may be the sa ups. For example, R 1 and R 2 may be C14 to C20 alkyl groups, which may be linear or branched, and m can be an integer from 1 to 5. In particular, R 1 and R 2 may both be derived from iso-stearic acid, and m may be 4. [0076] When present, such simple amide friction modifiers may be used in any effective amount. Typically, in transmission fluid compositions, they may be used in amounts from 0.01 mass% to 5.0 mass%, based on the mass of the transmission fluid composition, e.g., from 0.03 mass% to 2.0 mass% or from 0.05 mass% to 1.0 mass%. Additionally or alternatively, when used, simple amide friction modifiers may be present in booster additive package concentrates in amounts from about 0.1 mass% to 15 mass%, based on the mass of the booster additive package concentrate, e.g., from 0.3 mass% to 8.0 mass% or from 0.5 mass% to 4.0 mass%. [0077] Suitable ethoxylated amine friction modifiers may include or be reaction products of primary amines and/or diamines with ethylene oxide. The reaction with ethylene oxide may be suitably carried out using a stoichiometry such that substantially all primary and secondary amines may be converted to tertiary amines. Such amines may have the exemplary structures: wherein R 3 and R ur or oxygen linkages, containing from about 10 to 20 carbon atoms. Exemplary ethoxylated amine friction modifiers may include materials in which R 3 and/or R 4 may contain from 16 to 20 carbon atoms, e.g., from 16 to 18 carbon atoms. Materials of this type may be commercially available and sold under the tradenames of Ethomeen ® and Ethoduomeen ® by Akzo Nobel. Suitable materials from Akzo Nobel may include Ethomeen ® T/12 and Ethoduomeen ® T/13, inter alia. [0078] When present, such ethoxylated amine friction modifiers may be used in any effective amount. Typically, in transmission fluid compositions, they may be used in amounts from 0.01 mass% to 4.0 mass%, based on the mass of the transmission fluid composition, e.g., from 0.02 mass% to 1.5 mass% or from 0.03 mass% to 0.8 mass%. Additionally or alternatively, when used, ethoxylated amine friction modifiers may be present in booster additive package concentrates in amounts from about 0.1 mass% to 10 mass%, based on the mass of the booster additive package concentrate, e.g., from 0.2 mass% to 6.0 mass% or from 0.3 mass% to 3.0 mass%. [0079] However, in some embodiments, particularly in embodiments in which the transmission fluid compositions are used in conjunction with hybrid or fully electric engines, the transmission fluid compositions may optionally contain substantially no friction modifiers, or alternatively substantially no friction modifiers of the type(s) described herein. Other Additives [0080] Other additives known in the art may optionally be added to the transmission fluids, such as but not limited to other anti-wear agents, extreme pressure additives, viscosity modifiers, and the like. They are typically disclosed in, for example, “Lubricant Additives” by C.V. Smallheer and R. Kennedy Smith, 1967, pp 1-11. Compositional Attributes [0081] The transmission fluid booster additive package compositions and the rejuvenated lubricating oil compositions according to the present disclosure may exhibit particular concentrations (contents) of different elements. [0082] For instance, transmission fluid booster additive package compositions according to the present disclosure may exhibit a boron content of at least 0.02 mass%, e.g., at least 0.03 mass%, at least 0.04 mass%, at least 0.05 mass%, at least 0.07 mass%, at least 0.1 mass%, at least 0.12 mass%, at least 0.15 mass%, at least 0.17 mass%, at least 0.2 mass%, at least 0.22 mass%, at least 0.25 mass%, at least 0.27 mass%, at least 0.3 mass%, from 0.02 mass% to 1.2 mass%, from 0.02 mass% to 1.0 mass%, from 0.02 mass% to 0.9 mass%, from 0.02 mass% to 0.8 mass%, from 0.02 mass% to 0.75 mass%, from 0.02 mass% to 0.7 mass%, from 0.02 mass% to 0.65 mass%, from 0.02 mass% to 0.6 mass%, from 0.02 mass% to 0.55 mass%, from 0.02 mass% to 0.5 mass%, from 0.02 mass% to 0.2 mass%, from 0.02 mass% to 0.1 mass%, from 0.03 mass% to 1.2 mass%, from 0.03 mass% to 1.0 mass%, from 0.03 mass% to 0.9 mass%, from 0.03 mass% to 0.8 mass%, from 0.03 mass% to 0.75 mass%, from 0.03 mass% to 0.7 mass%, from 0.03 mass% to 0.65 mass%, from 0.03 mass% to 0.6 mass%, from 0.03 mass% to 0.55 mass%, from 0.03 mass% to 0.5 mass%, from 0.03 mass% to 0.2 mass%, from 0.03 mass% to 0.1 mass%, from 0.04 mass% to 1.2 mass%, from 0.04 mass% to 1.0 mass%, from 0.04 mass% to 0.9 mass%, from 0.04 mass% to 0.8 mass%, from 0.04 mass% to 0.75 mass%, from 0.04 mass% to 0.7 mass%, from 0.04 mass% to 0.65 mass%, from 0.04 mass% to 0.6 mass%, from 0.04 mass% to 0.55 mass%, from 0.04 mass% to 0.5 mass%, from 0.04 mass% to 0.2 mass%, from 0.04 mass% to 0.1 mass%, from 0.05 mass% to 1.2 mass%, from 0.05 mass% to 1.0 mass%, from 0.05 mass% to 0.9 mass%, from 0.05 mass% to 0.8 mass%, from 0.05 mass% to 0.75 mass%, from 0.05 mass% to 0.7 mass%, from 0.05 mass% to 0.65 mass%, from 0.05 mass% to 0.6 mass%, from 0.05 mass% to 0.55 mass%, from 0.05 mass% to 0.5 mass%, from 0.05 mass% to 0.2 mass%, from 0.05 mass% to 0.1 mass%, from 0.07 mass% to 1.2 mass%, from 0.07 mass% to 1.0 mass%, from 0.07 mass% to 0.9 mass%, from 0.07 mass% to 0.8 mass%, from 0.07 mass% to 0.75 mass%, from 0.07 mass% to 0.7 mass%, from 0.07 mass% to 0.65 mass%, from 0.07 mass% to 0.6 mass%, from 0.07 mass% to 0.55 mass%, from 0.07 mass% to 0.5 mass%, from 0.07 mass% to 0.2 mass%, from 0.07 mass% to 0.1 mass%, from 0.1 mass% to 1.2 mass%, from 0.1 mass% to 1.0 mass%, from 0.1 mass% to 0.9 mass%, from 0.1 mass% to 0.8 mass%, from 0.1 mass% to 0.75 mass%, from 0.1 mass% to 0.7 mass%, from 0.1 mass% to 0.65 mass%, from 0.1 mass% to 0.6 mass%, from 0.1 mass% to 0.55 mass%, from 0.1 mass% to 0.5 mass%, from 0.15 mass% to 1.2 mass%, from 0.15 mass% to 1.0 mass%, from 0.15 mass% to 0.9 mass%, from 0.15 mass% to 0.8 mass%, from 0.15 mass% to 0.75 mass%, from 0.15 mass% to 0.7 mass%, from 0.15 mass% to 0.65 mass%, from 0.15 mass% to 0.6 mass%, from 0.15 mass% to 0.55 mass%, from 0.15 mass% to 0.5 mass%, from 0.2 mass% to 1.2 mass%, from 0.2 mass% to 1.0 mass%, from 0.2 mass% to 0.9 mass%, from 0.2 mass% to 0.8 mass%, from 0.2 mass% to 0.75 mass%, from 0.2 mass% to 0.7 mass%, from 0.2 mass% to 0.65 mass%, from 0.2 mass% to 0.6 mass%, from 0.2 mass% to 0.55 mass%, from 0.2 mass% to 0.5 mass%, from 0.25 mass% to 1.2 mass%, from 0.25 mass% to 1.0 mass%, from 0.25 mass% to 0.9 mass%, from 0.25 mass% to 0.8 mass%, from 0.25 mass% to 0.75 mass%, from 0.25 mass% to 0.7 mass%, from 0.25 mass% to 0.65 mass%, from 0.25 mass% to 0.6 mass%, from 0.25 mass% to 0.55 mass%, from 0.25 mass% to 0.5 mass%, from 0.3 mass% to 1.2 mass%, from 0.3 mass% to 1.0 mass%, from 0.3 mass% to 0.9 mass%, from 0.3 mass% to 0.8 mass%, from 0.3 mass% to 0.75 mass%, from 0.3 mass% to 0.7 mass%, from 0.3 mass% to 0.65 mass%, from 0.3 mass% to 0.6 mass%, from 0.3 mass% to 0.55 mass%, or from 0.3 mass% to 0.5 mass%, based on the total mass of the additive package composition, in particular at least 0.04 mass% or from 0.04 mass% to 0.75 mass%. [0083] Additionally or alternatively, rejuvenated lubricating oil compositions according to the present disclosure may exhibit a boron content of at least 30 parts per million by mass, e.g., at least 50 ppm, at least 70 ppm, at least 85 ppm, at least 100 ppm, at least 110 ppm, at least 120 ppm, at least 130 ppm, at least 140 ppm, at least 150 ppm, at least 160 ppm, at least 170 ppm, at least 180 ppm, at least 190 ppm, at least 200 ppm, from 30 ppm to 750 ppm, from 30 ppm to 600 ppm, from 30 ppm to 500 ppm, from 30 ppm to 450 ppm, from 30 ppm to 400 ppm, from 30 ppm to 350 ppm, from 30 ppm to 300 ppm, from 30 ppm to 270 ppm, from 30 ppm to 250 ppm, from 30 ppm to 220 ppm, from 30 ppm to 200 ppm, from 30 ppm to 150 ppm, from 50 ppm to 750 ppm, from 50 ppm to 600 ppm, from 50 ppm to 500 ppm, from 50 ppm to 450 ppm, from 50 ppm to 400 ppm, from 50 ppm to 350 ppm, from 50 ppm to 300 ppm, from 50 ppm to 270 ppm, from 50 ppm to 250 ppm, from 50 ppm to 220 ppm, from 50 ppm to 200 ppm, from 50 ppm to 150 ppm, from 70 ppm to 750 ppm, from 70 ppm to 600 ppm, from 70 ppm to 500 ppm, from 70 ppm to 450 ppm, from 70 ppm to 400 ppm, from 70 ppm to 350 ppm, from 70 ppm to 300 ppm, from 70 ppm to 270 ppm, from 70 ppm to 250 ppm, from 70 ppm to 220 ppm, from 70 ppm to 200 ppm, from 70 ppm to 150 ppm, from 85 ppm to 750 ppm, from 85 ppm to 600 ppm, from 85 ppm to 500 ppm, from 85 ppm to 450 ppm, from 85 ppm to 400 ppm, from 85 ppm to 350 ppm, from 85 ppm to 300 ppm, from 85 ppm to 270 ppm, from 85 ppm to 250 ppm, from 85 ppm to 220 ppm, from 85 ppm to 200 ppm, from 100 ppm to 750 ppm, from 100 ppm to 600 ppm, from 100 ppm to 500 ppm, from 100 ppm to 450 ppm, from 100 ppm to 400 ppm, from 100 ppm to 350 ppm, from 100 ppm to 300 ppm, from 100 ppm to 270 ppm, from 100 ppm to 250 ppm, from 100 ppm to 220 ppm, from 110 ppm to 200 ppm, from 110 ppm to 750 ppm, from 110 ppm to 600 ppm, from 110 ppm to 500 ppm, from 110 ppm to 450 ppm, from 110 ppm to 400 ppm, from 110 ppm to 350 ppm, from 110 ppm to 300 ppm, from 110 ppm to 270 ppm, from 110 ppm to 250 ppm, from 110 ppm to 220 ppm, from 110 ppm to 200 ppm, from 120 ppm to 750 ppm, from 120 ppm to 600 ppm, from 120 ppm to 500 ppm, from 120 ppm to 450 ppm, from 120 ppm to 400 ppm, from 120 ppm to 350 ppm, from 120 ppm to 300 ppm, from 120 ppm to 270 ppm, from 120 ppm to 250 ppm, from 120 ppm to 220 ppm, from 120 ppm to 200 ppm, from 130 ppm to 750 ppm, from 130 ppm to 600 ppm, from 130 ppm to 500 ppm, from 130 ppm to 450 ppm, from 130 ppm to 400 ppm, from 130 ppm to 350 ppm, from 130 ppm to 300 ppm, from 130 ppm to 270 ppm, from 130 ppm to 250 ppm, from 130 ppm to 220 ppm, from 130 ppm to 200 ppm, from 140 ppm to 750 ppm, from 140 ppm to 600 ppm, from 140 ppm to 500 ppm, from 140 ppm to 450 ppm, from 140 ppm to 400 ppm, from 140 ppm to 350 ppm, from 140 ppm to 300 ppm, from 140 ppm to 270 ppm, from 140 ppm to 250 ppm, from 140 ppm to 220 ppm, from 140 ppm to 200 ppm, from 150 ppm to 750 ppm, from 150 ppm to 600 ppm, from 150 ppm to 500 ppm, from 150 ppm to 450 ppm, from 150 ppm to 400 ppm, from 150 ppm to 350 ppm, from 150 ppm to 300 ppm, from 150 ppm to 270 ppm, from 150 ppm to 250 ppm, from 150 ppm to 220 ppm, or from 150 ppm to 200 ppm, based on the total mass of the rejuvenated lubricating oil composition, in particular at least 30 ppm, at least 85 ppm, from 30 ppm to 400 ppm, from 85 ppm to 300 ppm or from 30 ppm to 150 ppm. [0084] Further additionally or alternatively, transmission fluid booster additive package compositions according to the present disclosure may exhibit a calcium content (from at least the detergent(s) and/or optionally from any other calcium-containing component) from 0.1 mass% to 3.5 mass%, e.g., from 0.1 mass% to 3.0 mass%, from 0.1 mass% to 2.5 mass%, from 0.1 mass% to 2.3 mass%, from 0.1 mass% to 2.0 mass%, from 0.1 mass% to 1.8 mass%, from 0.1 mass% to 1.5 mass%, from 0.1 mass% to 1.3 mass%, from 0.1 mass% to 1.0 mass%, from 0.1 mass% to 0.9 mass%, from 0.1 mass% to 0.8 mass%, from 0.1 mass% to 0.7 mass%, from 0.2 mass% to 3.5 mass%, from 0.2 mass% to 3.0 mass%, from 0.2 mass% to 2.5 mass%, from 0.2 mass% to 2.3 mass%, from 0.2 mass% to 2.0 mass%, from 0.2 mass% to 1.8 mass%, from 0.2 mass% to 1.5 mass%, from 0.2 mass% to 1.3 mass%, from 0.2 mass% to 1.0 mass%, from 0.2 mass% to 0.9 mass%, from 0.2 mass% to 0.8 mass%, from 0.2 mass% to 0.7 mass%, from 0.3 mass% to 3.5 mass%, from 0.3 mass% to 3.0 mass%, from 0.3 mass% to 2.5 mass%, from 0.3 mass% to 2.3 mass%, from 0.3 mass% to 2.0 mass%, from 0.3 mass% to 1.8 mass%, from 0.3 mass% to 1.5 mass%, from 0.3 mass% to 1.3 mass%, from 0.3 mass% to 1.0 mass%, from 0.3 mass% to 0.9 mass%, from 0.3 mass% to 0.8 mass%, from 0.3 mass% to 0.7 mass%, from 0.4 mass% to 3.5 mass%, from 0.4 mass% to 3.0 mass%, from 0.4 mass% to 2.5 mass%, from 0.4 mass% to 2.3 mass%, from 0.4 mass% to 2.0 mass%, from 0.4 mass% to 1.8 mass%, from 0.4 mass% to 1.5 mass%, from 0.4 mass% to 1.3 mass%, from 0.4 mass% to 1.0 mass%, from 0.4 mass% to 0.9 mass%, from 0.4 mass% to 0.8 mass%, from 0.4 mass% to 0.7 mass%, from 0.5 mass% to 3.5 mass%, from 0.5 mass% to 3.0 mass%, from 0.5 mass% to 2.5 mass%, from 0.5 mass% to 2.3 mass%, from 0.5 mass% to 2.0 mass%, from 0.5 mass% to 1.8 mass%, from 0.5 mass% to 1.5 mass%, from 0.5 mass% to 1.3 mass%, from 0.5 mass% to 1.0 mass%, from 0.5 mass% to 0.9 mass%, from 0.5 mass% to 0.8 mass%, from 0.5 mass% to 0.7 mass%, from 0.6 mass% to 3.5 mass%, from 0.6 mass% to 3.0 mass%, from 0.6 mass% to 2.5 mass%, from 0.6 mass% to 2.3 mass%, from 0.6 mass% to 2.0 mass%, from 0.6 mass% to 1.8 mass%, from 0.6 mass% to 1.5 mass%, from 0.6 mass% to 1.3 mass%, from 0.6 mass% to 1.0 mass%, from 0.6 mass% to 0.9 mass%, from 0.6 mass% to 0.8 mass%, or from 0.6 mass% to 0.7 mass%, based on the total mass of the additive package composition, in particular from 0.2 mass% to 2.0 mass%, from 0.3 mass% to 1.5 mass%, or from 0.3 mass% to 1.0 mass%. [0085] Still further additionally or alternatively, rejuvenated lubricating oil compositions according to the present disclosure may exhibit a calcium content (from at least the detergent(s) and/or optionally from any other calcium-containing component) from 150 ppm to 7500 ppm (by mass), e.g., from 150 ppm to 6000 ppm, from 150 ppm to 5000 ppm, from 150 ppm to 4500 ppm, from 150 ppm to 4000 ppm, from 150 ppm to 3500 ppm, from 150 ppm to 3000 ppm, from 150 ppm to 2500 ppm, from 150 ppm to 2000 ppm, from 150 ppm to 1500 ppm, from 150 ppm to 1250 ppm, from 150 ppm to 1000 ppm, from 150 ppm to 800 ppm, from 150 ppm to 600 ppm, 250 ppm to 7500 ppm, from 250 ppm to 6000 ppm, from 250 ppm to 5000 ppm, from 250 ppm to 4500 ppm, from 250 ppm to 4000 ppm, from 250 ppm to 3500 ppm, from 250 ppm to 3000 ppm, from 250 ppm to 2500 ppm, from 250 ppm to 2000 ppm, from 250 ppm to 1500 ppm, from 250 ppm to 1250 ppm, from 250 ppm to 1000 ppm, from 250 ppm to 800 ppm, from 250 ppm to 600 ppm, from 300 ppm to 7500 ppm, from 300 ppm to 6000 ppm, from 300 ppm to 5000 ppm, from 300 ppm to 4500 ppm, from 300 ppm to 4000 ppm, from 300 ppm to 3500 ppm, from 300 ppm to 3000 ppm, from 300 ppm to 2500 ppm, from 300 ppm to 2000 ppm, from 300 ppm to 1500 ppm, from 300 ppm to 1250 ppm, from 300 ppm to 1000 ppm, from 300 ppm to 800 ppm, from 300 ppm to 600 ppm, from 350 ppm to 7500 ppm, from 350 ppm to 6000 ppm, from 350 ppm to 5000 ppm, from 350 ppm to 4500 ppm, from 350 ppm to 4000 ppm, from 350 ppm to 3500 ppm, from 350 ppm to 3000 ppm, from 350 ppm to 2500 ppm, from 350 ppm to 2000 ppm, from 350 ppm to 1500 ppm, from 350 ppm to 1250 ppm, from 350 ppm to 1000 ppm, from 350 ppm to 800 ppm, from 350 ppm to 600 ppm, from 400 ppm to 7500 ppm, from 400 ppm to 6000 ppm, from 400 ppm to 5000 ppm, from 400 ppm to 4500 ppm, from 400 ppm to 4000 ppm, from 400 ppm to 3500 ppm, from 400 ppm to 3000 ppm, from 400 ppm to 2500 ppm, from 400 ppm to 2000 ppm, from 400 ppm to 1500 ppm, from 400 ppm to 1250 ppm, from 400 ppm to 1000 ppm, from 400 ppm to 800 ppm, from 400 ppm to 600 ppm, from 450 ppm to 7500 ppm, from 450 ppm to 6000 ppm, from 450 ppm to 5000 ppm, from 450 ppm to 4500 ppm, from 450 ppm to 4000 ppm, from 450 ppm to 3500 ppm, from 450 ppm to 3000 ppm, from 450 ppm to 2500 ppm, from 450 ppm to 2000 ppm, from 450 ppm to 1500 ppm, from 450 ppm to 1250 ppm, from 450 ppm to 1000 ppm, from 450 ppm to 800 ppm, from 450 ppm to 600 ppm, from 500 ppm to 7500 ppm, from 500 ppm to 6000 ppm, from 500 ppm to 5000 ppm, from 500 ppm to 4500 ppm, from 500 ppm to 4000 ppm, from 500 ppm to 3500 ppm, from 500 ppm to 3000 ppm, from 500 ppm to 2500 ppm, from 500 ppm to 2000 ppm, from 500 ppm to 1500 ppm, from 500 ppm to 1250 ppm, from 500 ppm to 1000 ppm, from 500 ppm to 800 ppm, or from 500 ppm to 600 ppm, based on the total mass of the rejuvenated lubricating oil composition, in particular from 150 ppm to 2000 ppm, from 250 ppm to 800 ppm, from 300 ppm to 1250 ppm, or from 300 ppm to 1000 ppm. [0086] Yet further additionally or alternatively, transmission fluid booster additive package compositions according to the present disclosure may exhibit a phosphorus content (from at least compounds of structure (I) and structure (II), and/or optionally from any other phosphorus-containing component) from 0.1 mass% to 3.5 mass%, e.g., from 0.1 mass% to 3.0 mass%, from 0.1 mass% to 2.5 mass%, from 0.1 mass% to 2.3 mass%, from 0.1 mass% to 2.0 mass%, from 0.1 mass% to 1.8 mass%, from 0.1 mass% to 1.5 mass%, from 0.1 mass% to 1.3 mass%, from 0.1 mass% to 1.0 mass%, from 0.1 mass% to 0.9 mass%, from 0.1 mass% to 0.8 mass%, from 0.1 mass% to 0.7 mass%, from 0.2 mass% to 3.5 mass%, from 0.2 mass% to 3.0 mass%, from 0.2 mass% to 2.5 mass%, from 0.2 mass% to 2.3 mass%, from 0.2 mass% to 2.0 mass%, from 0.2 mass% to 1.8 mass%, from 0.2 mass% to 1.5 mass%, from 0.2 mass% to 1.3 mass%, from 0.2 mass% to 1.0 mass%, from 0.2 mass% to 0.9 mass%, from 0.2 mass% to 0.8 mass%, from 0.2 mass% to 0.7 mass%, from 0.3 mass% to 3.5 mass%, from 0.3 mass% to 3.0 mass%, from 0.3 mass% to 2.5 mass%, from 0.3 mass% to 2.3 mass%, from 0.3 mass% to 2.0 mass%, from 0.3 mass% to 1.8 mass%, from 0.3 mass% to 1.5 mass%, from 0.3 mass% to 1.3 mass%, from 0.3 mass% to 1.0 mass%, from 0.3 mass% to 0.9 mass%, from 0.3 mass% to 0.8 mass%, from 0.3 mass% to 0.7 mass%, from 0.4 mass% to 3.5 mass%, from 0.4 mass% to 3.0 mass%, from 0.4 mass% to 2.5 mass%, from 0.4 mass% to 2.3 mass%, from 0.4 mass% to 2.0 mass%, from 0.4 mass% to 1.8 mass%, from 0.4 mass% to 1.5 mass%, from 0.4 mass% to 1.3 mass%, from 0.4 mass% to 1.0 mass%, from 0.4 mass% to 0.9 mass%, from 0.4 mass% to 0.8 mass%, from 0.4 mass% to 0.7 mass%, from 0.5 mass% to 3.5 mass%, from 0.5 mass% to 3.0 mass%, from 0.5 mass% to 2.5 mass%, from 0.5 mass% to 2.3 mass%, from 0.5 mass% to 2.0 mass%, from 0.5 mass% to 1.8 mass%, from 0.5 mass% to 1.5 mass%, from 0.5 mass% to 1.3 mass%, from 0.5 mass% to 1.0 mass%, from 0.5 mass% to 0.9 mass%, from 0.5 mass% to 0.8 mass%, from 0.5 mass% to 0.7 mass%, from 0.6 mass% to 3.5 mass%, from 0.6 mass% to 3.0 mass%, from 0.6 mass% to 2.5 mass%, from 0.6 mass% to 2.3 mass%, from 0.6 mass% to 2.0 mass%, from 0.6 mass% to 1.8 mass%, from 0.6 mass% to 1.5 mass%, from 0.6 mass% to 1.3 mass%, from 0.6 mass% to 1.0 mass%, from 0.6 mass% to 0.9 mass%, from 0.6 mass% to 0.8 mass%, or from 0.6 mass% to 0.7 mass%, based on the total mass of the additive package composition, in particular from 0.2 mass% to 2.0 mass%, from 0.3 mass% to 1.5 mass%, or from 0.3 mass% to 1.0 mass%. [0087] Yet still further additionally or alternatively, rejuvenated lubricating oil compositions according to the present disclosure may exhibit a phosphorus content (from at least compounds of structure (I) and structure (II), and/or optionally from any other phosphorus-containing component) from 150 ppm to 7500 ppm (by mass), e.g., from 150 ppm to 6000 ppm, from 150 ppm to 5000 ppm, from 150 ppm to 4500 ppm, from 150 ppm to 4000 ppm, from 150 ppm to 3500 ppm, from 150 ppm to 3000 ppm, from 150 ppm to 2500 ppm, from 150 ppm to 2000 ppm, from 150 ppm to 1500 ppm, from 150 ppm to 1250 ppm, from 150 ppm to 1000 ppm, from 150 ppm to 800 ppm, from 150 ppm to 600 ppm, 250 ppm to 7500 ppm, from 250 ppm to 6000 ppm, from 250 ppm to 5000 ppm, from 250 ppm to 4500 ppm, from 250 ppm to 4000 ppm, from 250 ppm to 3500 ppm, from 250 ppm to 3000 ppm, from 250 ppm to 2500 ppm, from 250 ppm to 2000 ppm, from 250 ppm to 1500 ppm, from 250 ppm to 1250 ppm, from 250 ppm to 1000 ppm, from 250 ppm to 800 ppm, from 250 ppm to 600 ppm, from 300 ppm to 7500 ppm, from 300 ppm to 6000 ppm, from 300 ppm to 5000 ppm, from 300 ppm to 4500 ppm, from 300 ppm to 4000 ppm, from 300 ppm to 3500 ppm, from 300 ppm to 3000 ppm, from 300 ppm to 2500 ppm, from 300 ppm to 2000 ppm, from 300 ppm to 1500 ppm, from 300 ppm to 1250 ppm, from 300 ppm to 1000 ppm, from 300 ppm to 800 ppm, from 300 ppm to 600 ppm, from 350 ppm to 7500 ppm, from 350 ppm to 6000 ppm, from 350 ppm to 5000 ppm, from 350 ppm to 4500 ppm, from 350 ppm to 4000 ppm, from 350 ppm to 3500 ppm, from 350 ppm to 3000 ppm, from 350 ppm to 2500 ppm, from 350 ppm to 2000 ppm, from 350 ppm to 1500 ppm, from 350 ppm to 1250 ppm, from 350 ppm to 1000 ppm, from 350 ppm to 800 ppm, from 350 ppm to 600 ppm, from 400 ppm to 7500 ppm, from 400 ppm to 6000 ppm, from 400 ppm to 5000 ppm, from 400 ppm to 4500 ppm, from 400 ppm to 4000 ppm, from 400 ppm to 3500 ppm, from 400 ppm to 3000 ppm, from 400 ppm to 2500 ppm, from 400 ppm to 2000 ppm, from 400 ppm to 1500 ppm, from 400 ppm to 1250 ppm, from 400 ppm to 1000 ppm, from 400 ppm to 800 ppm, from 400 ppm to 600 ppm, from 450 ppm to 7500 ppm, from 450 ppm to 6000 ppm, from 450 ppm to 5000 ppm, from 450 ppm to 4500 ppm, from 450 ppm to 4000 ppm, from 450 ppm to 3500 ppm, from 450 ppm to 3000 ppm, from 450 ppm to 2500 ppm, from 450 ppm to 2000 ppm, from 450 ppm to 1500 ppm, from 450 ppm to 1250 ppm, from 450 ppm to 1000 ppm, from 450 ppm to 800 ppm, from 450 ppm to 600 ppm, from 500 ppm to 7500 ppm, from 500 ppm to 6000 ppm, from 500 ppm to 5000 ppm, from 500 ppm to 4500 ppm, from 500 ppm to 4000 ppm, from 500 ppm to 3500 ppm, from 500 ppm to 3000 ppm, from 500 ppm to 2500 ppm, from 500 ppm to 2000 ppm, from 500 ppm to 1500 ppm, from 500 ppm to 1250 ppm, from 500 ppm to 1000 ppm, from 500 ppm to 800 ppm, or from 500 ppm to 600 ppm, based on the total mass of the rejuvenated lubricating oil composition, in particular from 150 ppm to 2000 ppm, from 250 ppm to 800 ppm, from 300 ppm to 1250 ppm, or from 300 ppm to 1000 ppm. Lubricant Fluid Composition Functional Characteristics [0088] Advantageously, lubricating oil compositions according to the present disclosure, and/or made by combining a fresh or used lubricating oil basestock (alone or with one or more other components, such as a viscosity modifier and/or the like) with a booster additive package composition according to the present disclosure, can desirably exhibit certain functional characteristics, which are typically linked with and/or inexorably tied to the particular application(s) in which the lubricating oil compositions are desired to be used. For the purposes of the present disclosure, such lubricating oil composition functional characteristics may include, but are not necessarily limited to, anti-shudder durability (ASD) lifetime, paper-on-metal static friction coefficient (μs), relatively low-velocity paper-on-metal dynamic friction coefficient (μ5; optionally as an alternative to/approximation of μs), miscibility/suspension-stability, and/or optionally other functional characteristics, as well as combinations thereof. [0089] As described in further detail below, ASD lifetime can be measured by constant pressure test methods (e.g., JASO M349), but it is believed that test methods utilizing constant torque measurements (e.g., modified JASO M349, as detailed in the Examples section herein) may provide an alternative/more accurate/more sensitive evaluation parameter. Thus, whether the booster additive package compositions according to the present disclosure are combined with one or more lubricating oil basestocks or with fresh (fully formulated) or used (actually or through simulated use) lubricating oil compositions containing a majority of lubricating oil basestock (including basestock mixtures), e.g., in a mass ratio of booster package to lubricating oil basestock(s)/(fresh/used)composition(s) of from 1:49 to 1:7, from 1:32 to 1:8, or from 1:24 to 1:9, the resulting rejuvenated lubricating oil composition (also according to the present disclosure) may advantageously exhibit one or more of the following: (1) an ASD lifetime under constant torque conditions (e.g., using modified JASO M349) of at least 80 hours (e.g., at least 85 hours, at least 90 hours, at least 95 hours, at least 100 hours, at least 110 hours, at least 120 hours, from 80 hours to 320 hours, from 80 hours to 300 hours, from 80 hours to 280 hours, from 80 hours to 260 hours, from 80 hours to 240 hours, from 80 hours to 220 hours, from 80 hours to 200 hours, from 80 hours to 180 hours, from 80 hours to 160 hours, from 80 hours to 140 hours, from 80 hours to 120 hours, from 85 hours to 320 hours, from 85 hours to 300 hours, from 85 hours to 280 hours, from 85 hours to 260 hours, from 85 hours to 240 hours, from 85 hours to 220 hours, from 85 hours to 200 hours, from 85 hours to 180 hours, from 85 hours to 160 hours, from 85 hours to 140 hours, from 85 hours to 120 hours, from 90 hours to 320 hours, from 90 hours to 300 hours, from 90 hours to 280 hours, from 90 hours to 260 hours, from 90 hours to 240 hours, from 90 hours to 220 hours, from 90 hours to 200 hours, from 90 hours to 180 hours, from 90 hours to 160 hours, from 90 hours to 140 hours, from 90 hours to 120 hours, from 95 hours to 320 hours, from 95 hours to 300 hours, from 95 hours to 280 hours, from 95 hours to 260 hours, from 95 hours to 240 hours, from 95 hours to 220 hours, from 95 hours to 200 hours, from 95 hours to 180 hours, from 95 hours to 160 hours, from 95 hours to 140 hours, from 95 hours to 120 hours, from 100 hours to 320 hours, from 100 hours to 300 hours, from 100 hours to 280 hours, from 100 hours to 260 hours, from 100 hours to 240 hours, from 100 hours to 220 hours, from 100 hours to 200 hours, from 100 hours to 180 hours, from 100 hours to 160 hours, from 100 hours to 140 hours, from 100 hours to 120 hours, from 110 hours to 320 hours, from 110 hours to 300 hours, from 100 hours to 280 hours, from 110 hours to 260 hours, from 110 hours to 240 hours, from 100 hours to 220 hours, from 110 hours to 200 hours, from 110 hours to 180 hours, from 100 hours to 160 hours, from 110 hours to 140 hours, from 120 hours to 320 hours, from 120 hours to 300 hours, from 120 hours to 280 hours, from 120 hours to 260 hours, from 120 hours to 240 hours, from 120 hours to 220 hours, from 120 hours to 200 hours, from 120 hours to 180 hours, or from 120 hours to 160 hours); (2) an increase in ASD lifetime under constant torque conditions (e.g., using modified JASO M349) of at least 35 hours, as compared to an ASD lifetime of the rejuvenated lubricating oil composition without the booster package (e.g., at least 40 hours, at least 45 hours, at least 50 hours, from 35 hours to 240 hours, from 35 hours to 220 hours, from 35 hours to 200 hours, from 35 hours to 180 hours, from 35 hours to 160 hours, from 35 hours to 140 hours, from 35 hours to 120 hours, from 35 hours to 100 hours, from 35 hours to 80 hours, from 35 hours to 60 hours, from 40 hours to 240 hours, from 40 hours to 220 hours, from 40 hours to 200 hours, from 40 hours to 180 hours, from 40 hours to 160 hours, from 40 hours to 140 hours, from 40 hours to 120 hours, from 40 hours to 100 hours, from 40 hours to 80 hours, from 40 hours to 60 hours, from 45 hours to 240 hours, from 45 hours to 220 hours, from 45 hours to 200 hours, from 45 hours to 180 hours, from 45 hours to 160 hours, from 45 hours to 140 hours, from 45 hours to 120 hours, from 45 hours to 100 hours, from 45 hours to 80 hours, from 45 hours to 60 hours, from 50 hours to 240 hours, from 50 hours to 220 hours, from 50 hours to 200 hours, from 50 hours to 180 hours, from 50 hours to 160 hours, from 50 hours to 140 hours, from 50 hours to 120 hours, from 50 hours to 100 hours, from 50 hours to 80 hours, or from 50 hours to 60 hours); and (3) an increase in ASD lifetime under constant torque conditions (e.g., using modified JASO M349) of at least 40%, as compared to an ASD lifetime of the rejuvenated lubricating oil composition without the booster package (e.g., at least 50%, at least 60%, at least 75%, at least 90%, from 40% to 300%, from 40% to 250%, from 40% to 200%, from 40% to 175%, from 40% to 150%, from 40% to 125%, from 40% to 100%, from 40% to 80%, from 40% to 60%, from 50% to 300%, from 50% to 250%, from 50% to 200%, from 50% to 175%, from 50% to 150%, from 50% to 125%, from 50% to 100%, from 50% to 80%, from 50% to 60%, from 60% to 300%, from 60% to 250%, from 60% to 200%, from 60% to 175%, from 60% to 150%, from 60% to 125%, from 60% to 100%, from 60% to 80%, from 75% to 300%, from 75% to 250%, from 75% to 200%, from 75% to 175%, from 75% to 150%, from 75% to 125%, from 75% to 100%, from 90% to 300%, from 90% to 250%, from 90% to 200%, from 40% to 175%, from 90% to 150%, from 90% to 125%, or from 90% to 100%). [0090] Additionally or alternatively, whether the booster additive package compositions according to the present disclosure are combined with one or more lubricating oil basestocks or with fresh (fully formulated) or used (actually or through simulated use) lubricating oil compositions containing a majority of lubricating oil basestock (including basestock mixtures), the resulting rejuvenated lubricating oil composition (also according to the present disclosure) may advantageously exhibit one or more of the following: (1) a coefficient of friction, μ, of at least 0.100 (e.g., at least 0.105, at least 0.110, at least 0.115, or at least 0.119, and optionally not greater than 0.140, not greater than 0.135, or not greater than 0.130), under LFW-1 standard test conditions (see, e.g., the JASO M358 (2005) standard test method) at a sliding speed of about 0.125 m/s, a temperature of about 110℃, and at an applied load of about 1.1kN (~250 lbs); (2) a coefficient of friction, μ(5), that is no more than 40% below (e.g., no more than 35% below, no more than 30% below, no more than 25% below, no more than 20% below, no more than 15% below, no more than 10% below, no more than 5% below, no more than 2% below, at or above, and optionally no greater than 2% above, no greater than 5% above, or no greater than 10% above) a corresponding coefficient of friction, μ(5), of the resulting rejuvenated lubricating oil composition without the booster package (e.g., as fresh fully formulated lubricating oil composition or as used/degraded formulated lubricating oil composition), in which μ(5) is measured according to the modified JASO M349 standard anti-shudder durability test conditions (constant torque) disclosed herein; and (3) where the rejuvenated lubricating oil composition comprises the booster package and a used version of a fully formulated (fresh) lubricating oil composition, a coefficient of friction, μ(5), that is no more than 30% below (e.g., no more than 25% below, no more than 20% below, no more than 15% below, no more than 10% below, no more than 5% below, no more than 2% below, at or above, and optionally no greater than 10% above, or no greater than 5% above) a corresponding coefficient of friction, μ(5), of the corresponding fresh (fully formulated) lubricating oil composition prior to use, in which μ(5) is measured according to the modified JASO M349 standard anti-shudder durability test conditions (constant torque) disclosed herein. Additional Embodiments [0091] Additionally or alternatively, the present disclosure may include one or more of the following embodiments. [0092] Embodiment 1. A transmission fluid booster additive package composition comprising: (a) a mixture comprising: (i) two or more compounds of structures (I): ); wh s or alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage, provided that, in component (i), at least some of groups R1, R2 and R3 are alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage; and (ii) one or more compounds of structures (II): II) where groups R4 and 2 carbon atoms and R5 and R6 are independently alkyl linkages having 2 to 12 carbon atoms; (b) an ashless dispersant representing at least 20 mass% of the transmission fluid booster additive package composition; (c) an overbased calcium phenate detergent; (d) at least two friction modifiers, a first of which comprises a polyethylene polyamine succinimide derivative; (e) a corrosion inhibitor; and (f) a suspension-stabilizing amount of a lubricating oil basestock, wherein the transmission fluid booster additive package composition exhibits: a boron content from 0.04 mass% to 0.75 mass%, based on the total mass of the additive package composition; a calcium content from 0.3 mass% to 1.5 mass%, based on the total mass of the additive package composition; and a phosphorus content from 0.3 mass% to 1.5 mass%, based on the total mass of the additive package composition. [0093] Embodiment 2. A booster additive package composition according to embodiment 1, wherein the compounds of component (i) and component (ii) are present in the composition in a mass ratio of from 2:1 to 1:2. [0094] Embodiment 3. A booster additive package composition according to embodiment 1 or embodiment 2, wherein the ashless dispersant comprises a polyisobutenyl succinimide. [0095] Embodiment 4. A booster additive package composition according to any one of the previous embodiments, wherein the polyethylene polyamine succinimide derivative has the following structure: wherei n x + y s rom 8 to 5 and z s 0 or an nteger rom to 5. [0096] Embodiment 5. A booster additive package composition according to any one of the previous embodiments, wherein a second friction modifier comprises an amide friction modifier, an amine friction modifier, or a mixture or combination thereof. [0097] Embodiment 6. A booster additive package composition according to any one of the previous embodiments, wherein the corrosion inhibitor comprises a benzotriazole. [0098] Embodiment 7. A booster additive package composition according to any one of the previous embodiments, wherein the transmission fluid booster additive package composition comprises substantially no additional antioxidants, other than any compounds that may function as antioxidants from components (a), (b), (c), (d), and (e). [0099] Embodiment 8. A booster additive package composition according to any one of the previous embodiments, wherein the lubricating oil basestock comprises a Group II basestock, a Group III basestock, and/or a Group V basestock and is present in a suspension- stabilizing amount from 5.0 mass% to 40 mass%, based on the weight of the booster additive package composition. [0100] Embodiment 9. A booster additive package composition according to any one of the previous embodiments, wherein one or more of the following is satisfied: (1) a fully formulated lubricating oil composition, which comprises the booster additive package composition and a lubricating oil basestock that is the same as or different from the lubricating oil basestock in the booster additive package composition (e.g., in a mass ratio of booster additive package composition to lubricating oil basestock of from 1:49 to 1:7), is formulated to exhibit an anti-shudder durability (ASD) lifetime under constant torque of at least 85 hours; (2) the booster additive package composition contributes at least an additional 40 hours of ASD lifetime under constant torque, when added to a fresh or used fully formulated lubricating oil composition comprising, or having comprised prior to use, at least an anti-wear additive, an ashless dispersant, a detergent, a friction modifier, at least one additional antioxidant, and a lubricating oil basestock, as compared to an ASD lifetime of the fresh or used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to fresh or used fully formulated lubricating oil composition is from 1:32 to 1:8); and (3) the booster additive package composition contributes at least a 60% increase in ASD lifetime under constant torque, when added to a fresh or used fully formulated lubricating oil composition comprising, or having comprised prior to use, at least an anti-wear additive, an ashless dispersant, a detergent, a friction modifier, at least one additional antioxidant, and a lubricating oil basestock, as compared to an ASD lifetime of the fresh or used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to fresh or used fully formulated lubricating oil composition is from 1:32 to 1:8). [0101] Embodiment 10. A rejuvenated, used lubricating oil composition comprising an admixture of: a major amount of a fully formulated lubricating oil composition that has been previously used to lubricate a vehicle transmission for at least 25,000 kilometers, or a lubrication running time equivalent thereto, the fully formulated lubricating oil composition having comprised, prior to use, at least an anti-wear additive, an ashless dispersant, an overbased calcium detergent, a friction modifier, a corrosion inhibitor, at least two additional antioxidants, and a lubricating oil basestock; and a minor amount of a transmission fluid booster additive package composition that maintains suspension stability when added to the previously used formulated lubricating oil composition, which booster additive package composition may be according to any of the previous embodiments or comprises: (a) a mixture comprising: (i) two or more compounds of structures (I): ); w s or alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage, provided that, in component (i), at least some of groups R 1 , R 2 and R 3 are alkyl groups having 1 to 18 carbon atoms where the alkyl chain is interrupted by a thioether linkage; and (ii) one or more compounds of structures (II): II) where groups R 4 and 2 carbon atoms and R 5 and R6 are independently alkyl linkages having 2 to 12 carbon atoms; (b) an ashless dispersant; (c) an overbased calcium phenate detergent; (d) at least two friction modifiers, a first of which comprises a polyethylene polyamine succinimide derivative; (e) a corrosion inhibitor; and (f) a suspension-stabilizing amount of a lubricating oil basestock wherein the rejuvenated, used lubricating oil composition exhibits: a boron content from 30 to 400 parts per million by mass, based on the total mass of the rejuvenated, used lubricating oil composition; a calcium content from 250 to 800 parts per million by mass, based on the total mass of the rejuvenated, used lubricating oil composition; and a phosphorus content from 250 to 800 parts per million by mass, based on the total mass of the rejuvenated, used lubricating oil composition. [0102] Embodiment 11. A rejuvenated composition according to embodiment 10, wherein at least 20 mass% of the transmission fluid booster additive package composition is comprised of the ashless dispersant. [0103] Embodiment 12. A rejuvenated composition according to embodiment 10 or embodiment 11, wherein the compounds of component (i) and component (ii) are each present in the composition in an amount from 0.05 to 1.2% by mass, based on the total mass of the composition. [0104] Embodiment 13. A rejuvenated composition according to any one of embodiments 10-12, wherein the compounds of component (i) and component (ii) are present in the composition in a mass ratio of from 2:1 to 1:2. [0105] Embodiment 14. A rejuvenated composition according to any one of embodiments 10-13, wherein the ashless dispersant comprises a polyisobutenyl succinimide and the corrosion inhibitor comprises a benzotriazole. [0106] Embodiment 15. A rejuvenated composition according to any one of embodiments 10-14, wherein the polyethylene polyamine succinimide derivative has the following structure: w eren x y s rom to an z s or an nteger rom to . [0107] Embodiment 16. A rejuvenated composition according to any one of embodiments 10-15, wherein a second friction modifier comprises an amide friction modifier, an amine friction modifier, or a mixture or combination thereof. [0108] Embodiment 17. A rejuvenated composition according to any one of embodiments 10-16, wherein the transmission fluid booster additive package composition comprises substantially no additional antioxidants, other than any compounds that may function as antioxidants from components (a), (b), (c), (d), and (e). [0109] Embodiment 18. A rejuvenated composition according to any one of embodiments 10-17, wherein a mass ratio of the booster additive package composition to the used fully formulated lubricating oil composition is from 1:49 to 1:5. [0110] Embodiment 19. A rejuvenated composition according to any one of embodiments 10-18, wherein the lubricating oil basestock from the booster additive package composition comprises a Group II basestock, a Group III basestock, and/or a Group V basestock, and wherein the lubricating oil basestock from the fully formulated lubricating oil composition, prior to use, comprised a Group II basestock and/or a Group III basestock. [0111] Embodiment 20. A rejuvenated composition according to any one of embodiments 10-19, wherein one or more of the following is satisfied: (1) the rejuvenated, used lubricating oil composition exhibits an anti-shudder durability (ASD) lifetime under constant torque of at least 80 hours; (2) the rejuvenated, used lubricating oil composition exhibits an anti-shudder durability (ASD) lifetime under constant torque of an additional 40 hours, as compared to an ASD lifetime of the used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to used fully formulated lubricating oil composition is from 1:32 to 1:8); and the rejuvenated, used lubricating oil composition contributes at least a 60% increase in ASD lifetime under constant torque, as compared to an ASD lifetime of the used fully formulated lubricating oil composition alone (e.g., wherein a mass ratio of the booster additive package composition to used fully formulated lubricating oil composition is from 1:32 to 1:8). [0112] Embodiment 21. A rejuvenated composition according to any one of embodiments 10-20, which composition exhibits: (A) a coefficient of friction, μ, of at least 0.100 and not greater than 0.140 under LFW-1 standard test conditions at a sliding speed of about 0.125 m/s, a temperature of about 110℃, and at an applied load of about 1.1kN (~250 lbs); (B) a coefficient of friction, μ(5), that is no more than 40% below and no greater than 10% above a corresponding coefficient of friction, μ(5), of the rejuvenated, used lubricating oil composition without the transmission fluid booster additive package composition, in which μ(5) is measured according to constant-torque modified JASO M349 standard anti- shudder durability test conditions; or (C) both (A) and (B). [0113] Embodiment 22. A method of rejuvenating a fully formulated lubricating oil composition that has been previously used to lubricate a vehicle transmission for at least 25,000 kilometers, or a lubrication running time equivalent thereto, the method comprising: admixing the suspension-stable transmission fluid booster additive package composition according to any one of embodiments 1-9 with the used, fully formulated lubricating oil composition to form a rejuvenated, used lubricating oil composition, the used, fully formulated lubricating oil composition having comprised, prior to use, at least an anti-wear additive, an ashless dispersant, an overbased calcium detergent, a friction modifier, a corrosion inhibitor, at least two additional antioxidants, and a lubricating oil basestock; and lubricating the vehicle transmission to enable operation for at least an additional 30,000 kilometers, or a lubrication running time equivalent thereto. [0114] Embodiment 23. A method of rejuvenating a fully formulated lubricating oil composition that has been previously used to lubricate a vehicle transmission for at least 25,000 kilometers, or a lubrication running time equivalent thereto, the method comprising: admixing a suspension-stable transmission fluid booster additive package composition with the used, fully formulated lubricating oil composition to form the rejuvenated, used lubricating oil composition according to any one of embodiments 10-21, the used, fully formulated lubricating oil composition having comprised, prior to use, at least an anti-wear additive, an ashless dispersant, an overbased calcium detergent, a friction modifier, a corrosion inhibitor, at least two additional antioxidants, and a lubricating oil basestock; and lubricating the vehicle transmission to enable operation for at least an additional 30,000 kilometers, or a lubrication running time equivalent thereto. [0115] Embodiment 24. Use of the suspension-stable transmission fluid booster additive package composition according to any one of embodiments 1-9 in combination with a fresh or used fully formulated lubricating oil composition to rejuvenate lubricant properties at least partially lost during previous operation of a vehicle transmission, in particular rejuvenating one or more of anti-shudder durability, friction modification, dynamic-static friction balance, anti-wear, soot dispersion capability, detergency, suspension stability, and corrosion inhibition. [0116] Embodiment 25. Use of the rejuvenated, used lubricating oil composition according to any one of embodiments 10-21 to rejuvenate lubricant properties at least partially lost during previous operation of a vehicle transmission, in particular rejuvenating one or more of anti-shudder durability, friction modification, dynamic-static friction balance, anti-wear, soot dispersion capability, detergency, suspension stability, and corrosion inhibition. Examples [0117] This invention may be further understood by reference to the following (non- limiting) examples. In the following Examples, the properties of certain components or the composition itself are described using certain terms of art, as defined below. In the Examples, all parts are parts by weight, unless otherwise noted. [0118] “Anti-shudder durability” lifetime (or ASD life) measures the ability of a lubricating composition, e.g., when lubricating a transmission such as a CVT or other portion of a drivetrain of a vehicle, to resist erratic stick/slip friction phenomena known as “shudder.” In transmissions with clutches and/or variators, for example, to prevent “shudder,” the lubricant can typically provide a positive friction gradient, i.e., increasing friction coefficient with increasing sliding speed, which is often alternatively referred to as a positive dµ/dv. Negative friction gradients (or negative dµ/dv values) can result in vehicle vibrations, which have been termed “shudder.” The standard method for evaluating anti- shudder (stick/slip friction) performance is JASO M349, which utilizes a low velocity friction apparatus (LVFA) to “age” the lubricant under constant-speed and constant-pressure rubbing of a steel plate against a friction plate under the conditions in Table 1. Table 1. JASO M349 Parameter Condition Lubricant tem erature (℃) 120 ± 5 every 24 hours to decide the failure point. The every-day μ-v measurement conditions are also done under constant pressure but at continuously-varying sliding speeds and under a variety of temperatures, as shown in Table 2 below. Table 2. Mu-V Testing Parameter Condition L b i t t t (℃) 40 80 d 120 h ± 5 when dµ/dv reaches its threshold failure value (i.e., becomes negative) at either the 0.3 m/s or the 0.9 m/s sliding speed (or, more accurately, at the point between successful and failing measurements in a least-squares curve-fit where the threshold value is reached). [0121] However, according to the present disclosure, the anti-shudder performance testing of JASO M349 has been adapted to apply constant torque to the friction plates, instead of constant pressure. While JASO M349 (standard) ASD performance testing is run under constant-pressure, the modified JASO M349 ASD performance testing may be run under variable pressure, so that torque applied may stay approximately constant. The modified JASO M349 ASD performance testing aims to keeps applied torque constant from the start of the test throughout the test by allowing applied pressure to vary. In this case, the constant applied torque value defined is equivalent to the “initial” torque measured during JASO M349 ASD performance testing (1.00 +/- 0.05 MPa constant pressure). In this case, using JASO M349 (constant pressure/standard) tests performed on an Automax™ LVFA rig (using RTF-1 reference fluid and A795.D0AK friction material, with the Automax™ software being prompted to collect data points at ~10-minute intervals), the “initial” torque value can be measured either as the zero-minute data point itself or as a numerical average of the first 20 minutes of data points (i.e., the average of the 0-minute, 10-minute, and 20- minute data points), with the latter (average) torque value measurement being preferred. The other modified parameters/conditions for the constant-torque “aging” adaptation are shown in Table 3 below. Table 3. Modified JASO M349 Parameter Condition Lubricant tem erature (℃) 120 ± 5 every 20 hours to decide the failure point. The every-20-hour μ-v measurement conditions are done under three different constant pressures (instead of a single constant torque) and involve a continuously-varying sweep sliding speed under a variety of temperatures, as shown in Table 4 below. Table 4. Mu-V Testing Parameter Condition L b i ℃ 40 80 d 120 h ± 5 [0123] In this latter Mu-V testing regimen, µ(5) or µ5 is the µ value at 5 rpm, µ(50) or µ50 is the µ value at 50 rpm, and µ(150) or µ150 is the µ value at 150 rpm; thus, the ratio of µ(5)/µ(50) can be a good representation of relatively low speed frictional behavior vis-à-vis shudder, and the ratio of µ(50)/µ(150) can be a good representation of relatively high speed frictional behavior vis-à-vis shudder. The anti-shudder durability (ASD) lifetime in this modified regimen is measured (also usually in hours) as being when either the ratio of µ(5)/µ(50) or the ratio of µ(50)/µ(150) reaches a threshold failure value (e.g., about 1.05) at any combination of temperature and applied pressure (or, more accurately, at the point between successful and failing measurements in a least-squares curve-fit where the threshold value is reached). The ASD lifetime values provided in the Examples below are determined based on µ(5), µ(50), and µ(150) values measured during the sweep sliding ramp procedure according to the modified/adapted conditions (see Table 4). Fresh Lubricant Sample A, Examples 1-4, and Comparative Examples 1-4 [0124] In these Examples, a fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A) had been factory-filled into a continuously-variable transmission (CVT) of a vehicle and run for (or simulated as if it had been run for the equivalent of) at least 25,000 kilometers (e.g., ~25,000 kilometers, ~50,000 kilometers, or ~85,000 kilometers). The fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A), as first- filled, contained the following components of an additive package (suspension-stable), with the remainder of the composition comprising mostly a Group III lubricating oil basestock, optionally with a minor amount (at most 10 mass%) of Group IV lubricating oil basestock and optionally with a minor amount (at most 10 mass%) of a viscosity modifier: an anti- wear additive, an ashless dispersant, an overbased calcium detergent, at least two friction modifiers (at least one of which being an anti-shudder durability (ASD) friction modifier), a corrosion inhibitor, at least two additional antioxidants (other than the components mentioned), and a diluent (e.g., a lubricating oil basestock of appropriate viscosity). The components of the fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A), as first-filled, were sufficient to yield: a phosphorus content (i.e., as measured in accordance with ASTM D5185) of from 200 to 500 parts per million by mass (ppm), based on the mass of the fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A); a calcium content (i.e., as measured in accordance with ASTM D5185) of from 170 to 480 parts per million by mass (ppm), based on the mass of the fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A); a boron content (i.e., as measured in accordance with ASTM D5185) of from 60 to 200 parts per million by mass (ppm), based on the mass of the fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A); and a phosphorus to calcium mass ratio of from 0.85:1.0 to 1.3:1.0. [0125] After being used, the phosphorus, calcium, and boron contents dropped to various levels, depending upon the extent and severity of use, which reductions may or may not have been uniform relative to each other (e.g., the same element ratios may or may not apply to the used lubricating oil composition(s)). After being used for (or simulating) the requisite mileage, various booster additive package compositions were added to the used lubricating oil composition(s) in the vehicle transmissions. Those booster additive package compositions are shown in Table 5 below, relative to the content of like components in the fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A). Table 5. Compar. Compar. Compar. Compar. Component Ex.1 Ex.2 Ex.3 Ex.4 Ex 1 Ex 2 Ex 3 Ex 4 [0126] Paper-on-steel friction characteristics for these samples were measured using a small-scale Low Velocity Friction Apparatus (ssLVFA) using a Dynax™ D0535-23H fiber plate and an SAE™ 1035 tumbled steel plate. Dynamic and static friction measurements were made on these apparatus after about 6, about 30, and about 60 minutes, under ~1 MPa applied pressure and at temperatures of ~40℃, ~80℃, and ~120℃. Figures 1-7 show graphs of the dynamic friction characteristics for a freshly-formulated (additized) lubricating oil composition (Figure 1) and for various rejuvenated lubricating oil compositions made from used lubricating oil composition and the booster additive package compositions of Comparative Examples 1 (Figure 2), 2 (Figure 3), 3 (Figure 4), and 4 (Figure 5), and of Examples 1 (Figure 6) and 2 (Figure 7). Figures 8-14 show the graphs of static friction characteristics, corresponding to Figures 1-7, for the freshly-formulated (additized) lubricating oil composition (Figure 8) and for a rejuvenated lubricating oil composition made from used lubricating oil composition and the booster additive package compositions of Comparative Examples 1 (Figure 9), 2 (Figure 10), 3 (Figure 11), and 4 (Figure 12), and of Examples 1 (Figure 13) and 2 (Figure 14). Though graphs of the dynamic Mu-V curves and static coefficients of friction are not provided herein for rejuvenated lubricating oil compositions made from used lubricating oil compositions and the booster additive package compositions of Examples 3 and 4, their characteristics are believed to be similar to and consistent with those of Example 2 (Figures 7 and 14). This Mu-V screening process highlighted that, when combined with used, fully formulated lubricating oil compositions, the booster additive package compositions of Comparative Examples 1-4 did not exhibit sufficiently “rejuvenated” dynamic friction characteristics, compared to the fresh version of the fully formulated lubricating oil compositions, whereas the booster additive package compositions of Examples 1-2 did. [0127] Furthermore, Figure 15 shows that the rejuvenated used lubricating oil composition comprising the booster additive package composition of Example 1 (with substantially no additional phosphorus-containing anti-wear component and with substantially no additional detergent component) exhibited metal-on-metal friction characteristics that would be too low for CVT transmissions in which metal-on-metal (e.g., steel-on-steel) friction characteristics should be adequately high (e.g., a coefficient of friction, μ, of at least 0.110, and optionally not greater than 0.140, under LFW-1 standard test conditions at a sliding speed of about 0.125 m/s, a temperature of about 110℃, and at an applied load of about 1.1kN (~250 lbs)). LFW-1 standard test conditions are well known to the ordinary skilled artisan, and similar testing conditions are disclosed in the JASO M358 (2005) standard test method. Under such conditions/testing, the rejuvenated used lubricating oil composition comprising the booster additive package composition of Example 1 exhibited a μ less than 0.100, whereas the rejuvenated used lubricating oil composition comprising the booster additive package composition of Example 2, as well as the used lubricating oil composition itself (without any booster package) and the fresh (fully formulated) lubricating oil composition, exhibited μ values of ~0.122, ~0.120, and ~0.122, respectively. Thus, while the booster additive package composition of Example 1 may be useful in extending ASD lifetime in transmission/drivetrain setups without significant metal-on-metal friction (e.g., non-CVT drivetrains, such as wet clutch, dual clutch, manual, automatic, and the like), its low metal-on-metal friction coefficient can render it relatively undesirable in CVT applications. Fresh Lubricant Samples A-B, Used Lubricant Samples C-F, and Examples 3-12 [0128] In these Examples, the booster additive package compositions of Examples 3-12 were combined with (“diluted” by) either a fully-formulated fresh lubricating oil composition (Fresh Lubricant Sample A or B) or a lubricating oil composition (Used Lubricant Sample C, D, E, or F) that had been used by being run in a continuously-variable transmission (CVT) of a vehicle for at least 25,000 kilometers (Used Lubricant Samples C, D, E, and F were collected from, respectively: a mid-size vehicle with a 4-cylinder transmission that had been run for ~51,000 kilometers; a mid-size vehicle with a 4-cylinder transmission that had been run for ~25,000 kilometers; a dyno unit test on a 4-cylinder transmission that had been simulated run for ~50,000 kilometers; and a small SUV vehicle with a V6 transmission that had been run for ~85,000 kilometers). Before being used (i.e., when factory-filled into their respective vehicles), the “diluent” (fresh or used) lubricating oil compositions contained the following components of an additive package (suspension-stable), with the remainder of the composition comprising mostly a Group III lubricating oil basestock, optionally with a minor amount of Group IV lubricating oil basestock and optionally with a minor amount of a viscosity modifier: an anti-wear additive, an ashless dispersant, an overbased calcium detergent, at least two friction modifiers (at least one of which being an anti-shudder durability (ASD) friction modifier), a corrosion inhibitor, at least two additional antioxidants (other than the components mentioned), and a diluent (e.g., a lubricating oil basestock of appropriate viscosity). The components of each of the used lubricating oil compositions (Used Lubricant Sample C, D, E, or F), after their respective use levels, obviously exhibited differing contents of phosphorus, calcium, and boron (i.e., each as measured in accordance with ASTM D5185), depending upon the extent and severity of use (e.g., level of degradation) and/or other cause that would result in reduction of such elemental content levels in the used lubricating oil compositions. Table 6 below describes the P, Ca, and B contents of the various used lubricant samples, as well as a baseline level of their anti- shudder durability (ASD) lifetimes, measured as-used by themselves, with no booster package added, according to the modified JASO M349 test method under constant torque conditions using a Dynax™ D0535-23H fiber plate, as described hereinabove. For reference, a typical ASD lifetime range for a fresh fully-formulated CVT lubricant oil composition (e.g., Fresh Lubricant Sample A or B) can be from about 65 to about 80 hours – indeed, though not enumerated in Table 6, the ASD lifetimes (according to the constant torque method) of Fresh Lubricant Sample A and Fresh Lubricant Sample B were measured to be 65 hours and 75 hours, respectively. Table 6. Elemental ppm by mass Used Sample C Used Sample D Used Sample E Used Sample F phosphorus 233 294 275 219 [0129] After being used for the requisite mileage, booster additive package compositions of Examples 3-12 were added to a fresh or a used lubricating oil composition (Fresh Lubricant Sample A or B, or Used Lubricant Sample C, D, E, or F). The booster additive package compositions of Examples 3-14 are shown in Tables 7-8 below, relative to the content of like components in the respective fresh and/or used lubricating oil compositions. Table 7. Component Ex.3 Ex.4 Ex.5 Ex.6 Ex.7 Ex.8 structure (I) com ounds ~50% ~50% ~100% ~100% ~50% ~100% Table 8. Component Ex.9 Ex.10 Ex.11 Ex.12 Ex.13 Ex.14 structure (I) com ounds ~50% ~100% ~100% ~50% ~50% ~50% [0130] A combinatorial matrix of experiments for establishing ASD lifetime and ASD lifetime increase (in both hours and percent increase above the “Diluent” ASD lifetime) for combinations of booster packages according to the present disclosure and either fresh or used lubricating oil compositions described herein is shown in Table 9 below. In addition, though graphics are not shown, each of the combinations of booster package and lubricant sample (diluent) from Table 8 above were tested during the ASD lifetime measurements and were found to have a μ(5) that was no more than 40% below (and optionally no more than 10% above) the μ(5) for the used lubricant samples and that was no more than 30% below (and optionally no more than 10% above) the μ(5) for the fresh lubricant samples. Table 9. ASD lifetime ASD lifetime increase Booster Package (X) “Diluent” (Y) Treat rate (X:Y) [hrs] [hrs] (% abv Diluent) [0131] In order to ensure that a rejuvenated lubricating oil composition satisfies the various different friction performances in transmission/drivetrain systems, dynamic friction characteristics of the rejuvenated lubricating oil compositions can advantageously be controlled to be superior or comparable to (e.g., within reasonable variation from) those of the “used” lubricating oil compositions, before the booster additive package is introduced, and perhaps even ideally returned at or near the fresh version of the fully formulated lubricating oil composition before use. These dynamic frictional properties can be indicative of drivetrain performance during steady state operational conditions, and, generally, a negative slope in the dynamic Mu-V profile is desirable. However, in addition, static friction and/or relatively low-speed dynamic (near-static) friction levels may also be controlled to be superior or comparable to those of the “used” lubricating oil compositions, before the booster additive package is introduced, and perhaps even ideally returned at or near the fresh version of the fully formulated lubricating oil composition before use. These static and/or near-static frictional properties can be indicative of torque capacity of the (typically non-metal, e.g., paper) clutch system. If the static/near-static friction is too high, significant wear can occur; if too low, the “stick” portion of the stick-slip friction that causes the clutch to engage with other transmission/drivetrain components can be insufficient to transfer the torque, also resulting in inferior operation. There are intimate correlations between low-speed dynamic friction and static friction in that high static friction generally coincides with high low-speed dynamic friction and affects the slope of the Mu-V curve (e.g., ideally retaining it as negative). Therefore, a particularly advantageous goal of lubricant oil composition rejuvenation is to control low-speed dynamic friction and static friction to both be within an operational window, while simultaneously controlling dynamic friction behavior to yield a negative (or approximately zero) slope. [0132] The disclosures of all patents, articles and other materials described herein are hereby incorporated, in their entirety, into this specification by reference. A description of a composition comprising, consisting of, or consisting essentially of multiple specified components, as presented herein and in the appended claims, should be construed to also encompass compositions made by admixing said multiple specified components. The principles, preferred embodiments and modes of operation of the present invention have been described in the foregoing specification. What applicants submit is their invention, however, is not to be construed as limited to the particular embodiments disclosed, since the disclosed embodiments are regarded as illustrative rather than limiting. Changes may be made by those skilled in the art without departing from the spirit of the invention.
Next Patent: POLYPEPTIDE TERMINAL BINDERS AND USES THEREOF