Title:
REVERSE PHOTOCHROMIC COMPOUND
Document Type and Number:
WIPO Patent Application WO/2018/143239
Kind Code:
A1
Abstract:
Conventional reverse photochromic compounds have difficulty in sensing light in a visible light region of 600 nm or more used in medical applications, etc. The present invention addresses the problem of providing a reverse photochromic compound and polymer which are highly sensitive even to light of 600 nm or more. The present invention pertains to a compound or the like represented by general formula (1) (wherein, R1 and R4 each independently represent a hydrogen atom or the like, R2, R3, and R5 each independently represent an alkyl group or the like, R6 represents a group having a polymerizable unsaturated group, a carboxy group, an alkoxycarbonyl group, or the like, R31 and R32 each independently represent an alkoxy group or the like, R33 and R34 each independently represent a hydrogen atom or the like, Y1 represents an oxygen atom or a sulfur atom, An- represents an anion, n1-n3 represent a specific integer, and R1 and R2, R3 and R4, and/or R33 and R34 may form an alkylene group.)
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Inventors:
KATOH RYUZI (JP)
ENOKI MASAMI (JP)
NEMOTO KAZUKI (JP)
SUZUKI KATSUFUMI (JP)
MURASE TETSUJI (JP)
IMAZEKI SHIGEAKI (JP)
ENOKI MASAMI (JP)
NEMOTO KAZUKI (JP)
SUZUKI KATSUFUMI (JP)
MURASE TETSUJI (JP)
IMAZEKI SHIGEAKI (JP)
Application Number:
PCT/JP2018/003112
Publication Date:
August 09, 2018
Filing Date:
January 31, 2018
Export Citation:
Assignee:
FUJIFILM WAKO PURE CHEMICAL CORP (JP)
UNIV NIHON (JP)
UNIV NIHON (JP)
International Classes:
C07D405/06; C08F20/36; C09K9/02
Foreign References:
| JPH09124654A | 1997-05-13 | |||
| JP2000219687A | 2000-08-08 | |||
| US5919608A | 1999-07-06 | |||
| JP2001115154A | 2001-04-24 | |||
| JPH07206858A | 1995-08-08 | |||
| JPH09124654A | 1997-05-13 | |||
| JP2012017442A | 2012-01-26 |
Other References:
YUAN, LIN ET AL.: "A Unique Class of Near-Infrared Functional Fluorescent Dyes with Carboxylic-Acid-Modulated Fluorescence ON/OFF Switching: Rational Design, Synthesis, Optical Properties, Theoretical Calculations, and Applications for Fluorescence Imaging in Living Animals", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, no. 2, 2012, pages 1200 - 1211, XP055530679, ISSN: 0002-7863
TOLMACHEV, A. I. ET AL.: "Synthesis, electronic structure, and absorption spectra of the merocyanines derived from pyranes and benzopyranes", DYES AND PIGMENTS, vol. 74, no. 2, 2007, pages 348 - 356, XP005871158, ISSN: 0143-7208
HARRIS, D. KRISTI ET AL.: "Dual-use chromophores for photorefractive and irreversible photochromic applications", APPLIED OPTICS, vol. 40, no. 17, 2001, pages 2895 - 2901, XP001103068, ISSN: 0003-6935
GARCIA-AMOROS, JAUME ET AL.: "Plasmonic Activation of a Fluorescent Carbazole-Oxazine Switch", CHEMISTRY-A EUROPEAN JOURNAL, vol. 20, no. 33, 23 July 2014 (2014-07-23), pages 10276 - 10284, XP055614058, ISSN: 0947-6539, DOI: 10.1002/chem.201403509
NEMOTO, KAZUKI ET AL.: "Merocyanine blue dye exhibiting photochromic behavior", PROGRAM AND LECTURE PROCEEDINGS OF JOINT MEETING OF THE TOHOKU AREA CHEMISTRY SOCIETIES, vol. 2017, September 2017 (2017-09-01), pages 96, XP9515692
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, no. 2, 2012, pages 1200
See also references of EP 3578556A4
TOLMACHEV, A. I. ET AL.: "Synthesis, electronic structure, and absorption spectra of the merocyanines derived from pyranes and benzopyranes", DYES AND PIGMENTS, vol. 74, no. 2, 2007, pages 348 - 356, XP005871158, ISSN: 0143-7208
HARRIS, D. KRISTI ET AL.: "Dual-use chromophores for photorefractive and irreversible photochromic applications", APPLIED OPTICS, vol. 40, no. 17, 2001, pages 2895 - 2901, XP001103068, ISSN: 0003-6935
GARCIA-AMOROS, JAUME ET AL.: "Plasmonic Activation of a Fluorescent Carbazole-Oxazine Switch", CHEMISTRY-A EUROPEAN JOURNAL, vol. 20, no. 33, 23 July 2014 (2014-07-23), pages 10276 - 10284, XP055614058, ISSN: 0947-6539, DOI: 10.1002/chem.201403509
NEMOTO, KAZUKI ET AL.: "Merocyanine blue dye exhibiting photochromic behavior", PROGRAM AND LECTURE PROCEEDINGS OF JOINT MEETING OF THE TOHOKU AREA CHEMISTRY SOCIETIES, vol. 2017, September 2017 (2017-09-01), pages 96, XP9515692
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, no. 2, 2012, pages 1200
See also references of EP 3578556A4
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