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Title:
SHOWERHEAD ASSEMBLY WITH RECURSIVE GAS CHANNELS
Document Type and Number:
WIPO Patent Application WO/2023/283375
Kind Code:
A1
Abstract:
Embodiments of showerheads are provided herein. In some embodiments, a showerhead assembly includes a chill plate comprising a gas plate and a cooling plate having an aluminum-silicon foil interlayer disposed therebetween for diffusion bonding the gas plate to the cooling plate and a heater plate comprising a first plate, a second plate, and a third plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the cooling plate for diffusion bonding the first plate to the cooling plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the second plate for diffusion bonding the first plate to the second plate, and wherein an aluminum-silicon foil interlayer is disposed between the second plate and the third plate for diffusion bonding the second plate to the third plate.

Inventors:
BEHNKE JOSEPH FREDERICK (US)
WAKABAYASHI REYN TETSURO (US)
WONG CARLATON (US)
FRANKLIN TIMOTHY JOSEPH (US)
SOMMERS JOSEPH F (US)
Application Number:
PCT/US2022/036413
Publication Date:
January 12, 2023
Filing Date:
July 07, 2022
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
APPLIED MATERIALS INC (US)
International Classes:
H01J37/32
Foreign References:
KR20170073757A2017-06-29
US20170365443A12017-12-21
US20150170977A12015-06-18
US20130337654A12013-12-19
JP2008001923A2008-01-10
US20220093362A12022-03-24
Attorney, Agent or Firm:
PATEL, Ronak A. et al. (US)
Download PDF:
Claims:
Claims:

1. A showerhead assembly for use in a substrate processing chamber, comprising: a chill plate comprising a gas plate and a cooling plate having an aluminum- silicon foil interlayer disposed therebetween for diffusion bonding the gas plate to the cooling plate; and a heater plate comprising a first plate, a second plate, and a third plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the cooling plate for diffusion bonding the first plate to the cooling plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the second plate for diffusion bonding the first plate to the second plate, and wherein an aluminum-silicon foil interlayer is disposed between the second plate and the third plate for diffusion bonding the second plate to the third plate.

2. The showerhead assembly of claim 1 , further comprising a top plate, wherein an aluminum-silicon foil interlayer is disposed between the top plate and the gas plate for diffusion bonding the top plate to the gas plate.

3. The showerhead assembly of claim 1 , further comprising a bottom plate, wherein an aluminum-silicon foil interlayer is disposed between the cooling plate and the bottom plate for diffusion bonding the cooling plate to the bottom plate.

4. The showerhead assembly of claim 3, wherein an aluminum-silicon foil interlayer is disposed between the bottom plate and the first plate for diffusion bonding the bottom plate to the first plate.

5. The showerhead assembly of claim 1 , wherein the aluminum-silicon foil interlayer used for diffusion bonding the gas plate to the cooling plate, for diffusion bonding the first plate to the cooling plate, for diffusion bonding the first plate to the second plate, and for diffusion bonding the second plate to the third plate, has about 80 weight percent aluminum and about 20 weight percent silicon.

6. The showerhead assembly of claim 5, wherein the aluminum-silicon foil interlayer used for diffusion bonding the gas plate to the cooling plate, for diffusion bonding the first plate to the cooling plate, for diffusion bonding the first plate to the second plate, and for diffusion bonding the second plate to the third plate, is at or near a eutectic compound.

7. The showerhead assembly of any of claims 1 to 6, wherein the chill plate further comprises: a plurality of recursive gas paths disposed therein that are fluidly independent from each other and one or more cooling channels disposed therein, wherein each of the plurality of recursive gas paths is fluidly coupled to a single gas inlet extending to a first side of the chill plate and a plurality of gas outlets extending to a second side of the chill plate; and wherein the heater plate includes one or more heating elements disposed therein, a plurality of first gas distribution holes extending from a top surface thereof to a plurality of plenums that are fluidly independent disposed within the heater plate, the plurality of first gas distribution holes corresponding with the plurality of gas outlets of the chill plate, and a plurality of second gas distribution holes extending from the plurality of plenums to a lower surface of the heater plate.

8. The showerhead assembly of claim 7, further comprising an upper electrode coupled to the heater plate and having a plurality of third gas distribution holes extending from a top surface thereof at locations corresponding to locations of the plurality of second gas distribution holes of the heater plate to a lower surface of the upper electrode.

9. The showerhead assembly of claim 8, further comprising a first thermal gasket sheet disposed between the chill plate and the heater plate and a second thermal gasket sheet disposed between the heater plate and the upper electrode.

10. The showerhead assembly of claim 7, wherein the plurality of recursive gas paths are disposed along two layers of the chill plate.

11. The showerhead assembly of claim 7, wherein the gas plate has a first side coupled to a top plate and a second side coupled to the cooling plate, and a bottom plate coupled to the cooling plate on a side opposite the gas plate, wherein at least one of the plurality of recursive gas paths is disposed on the first side and the second side of the gas plate, and wherein the one or more cooling channels are disposed in the cooling plate.

12. The showerhead assembly of claim 7, wherein each of the plurality of recursive gas paths have a substantially equal flow path from the single gas inlet to each gas outlet of the plurality of gas outlets.

13. The showerhead assembly of claim 7, wherein the one or more heating elements of the heater plate define two or more heating zones of the showerhead assembly.

14. The showerhead assembly of claim 7, wherein the first plate has a plurality of channels to accommodate the one or more heating elements, wherein the second plate is coupled to the first plate to cover the plurality of channels, and the third plate is coupled to the second plate on a side opposite the first plate, and wherein the third plate has a second plurality of channels that define the plurality of plenums.

15. The showerhead assembly of claim 7, wherein the plurality of recursive gas paths include four recursive gas paths and the plurality of plenums includes four plenums to define four gas distribution zones at a lower surface of the showerhead assembly.

16. A process chamber, comprising: a chamber body defining an interior volume therein; a substrate support disposed in the interior volume to support a substrate; and the showerhead assembly of any of claims 1 to 6 disposed in the interior volume opposite the substrate support.

17. The process chamber of claim 16, wherein the chill plate further comprises: a plurality of recursive gas paths disposed therein that are fluidly independent from each other and one or more cooling channels disposed therein, wherein each of the plurality of recursive gas paths is fluidly coupled to a single gas inlet extending to a first side of the chill plate and a plurality of gas outlets extending to a second side of the chill plate; and wherein the heater plate includes one or more heating elements disposed therein, a plurality of first gas distribution holes extending from a top surface thereof to a plurality of plenums that are fluidly independent disposed within the heater plate, the plurality of first gas distribution holes corresponding with the plurality of gas outlets of the chill plate, and a plurality of second gas distribution holes extending from the plurality of plenums to a lower surface of the heater plate.

18. The process chamber of claim 17, wherein an aluminum-silicon foil interlayer is disposed between the bottom plate and the first plate for diffusion bonding the bottom plate to the first plate.

19. The process chamber of claim 16, wherein the plurality of recursive gas paths are disposed along two layers of the chill plate.

20. A method of manufacture for a showerhead assembly for use in a substrate processing chamber, comprising: providing an aluminum-silicon foil interlayer between a gas plate of a chill plate and a cooling plate of the chill plate and diffusion bonding the gas plate to the cooling plate; providing an aluminum-silicon foil interlayer between a first plate of a heater plate and the cooling plate and diffusion bonding the first plate to the cooling plate; providing an aluminum-silicon foil interlayer between the first plate and a second plate of the heater plate and diffusion bonding the first plate to the second plate; and providing an aluminum-silicon foil interlayer between the second plate and a third plate of the heater plate and diffusion bonding the second plate to the third plate.

Description:
SHOWERHEAD ASSEMBLY WITH RECURSIVE GAS CHANNELS

FIELD

[0001] Embodiments of the present disclosure generally relate to substrate processing equipment, and more specifically, showerheads for use with substrate processing equipment.

BACKGROUND

[0002] Conventional showerhead assemblies utilized in semiconductor process chambers (e.g., deposition chambers, etch chambers, or the like) typically include a single gas inlet that is fluidly coupled to a plurality of gas outlets to provide multiple gas injection points into a process volume. The multiple gas injection points provide more even flow distribution over a substrate being processed in the process chamber. The inventors have observed that using weldments to split the single gas inlet into the plurality of gas outlets may cause leaking and serviceability issues. In addition, using weldments to split the single gas inlet into the plurality of gas outlets may undesirably increase an overall thickness of the showerhead assembly.

[0003] Accordingly, the inventors have provided embodiments of improved showerhead assemblies.

SUMMARY

[0004] Embodiments of showerheads for use in a substrate processing chamber are provided herein. In some embodiments, a showerhead assembly for use in a substrate processing chamber includes a chill plate comprising a gas plate and a cooling plate having an aluminum-silicon foil interlayer disposed therebetween for diffusion bonding the gas plate to the cooling plate and a heater plate comprising a first plate, a second plate, and a third plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the cooling plate for diffusion bonding the first plate to the cooling plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the second plate for diffusion bonding the first plate to the second plate, and wherein an aluminum-silicon foil interlayer is disposed between the second plate and the third plate for diffusion bonding the second plate to the third plate.

[0005] In some embodiments, a process chamber includes a chamber body defining an interior volume therein, a substrate support disposed in the interior volume to support a substrate, and a showerhead assembly disposed in the interior volume opposite the substrate support, wherein the showerhead assembly comprises a chill plate comprising a gas plate and a cooling plate having an aluminum-silicon foil interlayer disposed therebetween for diffusion bonding the gas plate to the cooling plate and a heater plate comprising a first plate, a second plate, and a third plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the cooling plate for diffusion bonding the first plate to the cooling plate, wherein an aluminum-silicon foil interlayer is disposed between the first plate and the second plate for diffusion bonding the first plate to the second plate, and wherein an aluminum-silicon foil interlayer is disposed between the second plate and the third plate for diffusion bonding the second plate to the third plate.

[0006] In some embodiments, a method of manufacture for a showerhead assembly for use in a substrate processing chamber includes providing an aluminum-silicon foil interlayer between a gas plate of a chill plate and a cooling plate of the chill plate and diffusion bonding the gas plate to the cooling plate, providing an aluminum-silicon foil interlayer between a first plate of a heater plate and the cooling plate and diffusion bonding the first plate to the cooling plate, providing an aluminum-silicon foil interlayer between the first plate and a second plate of the heater plate and diffusion bonding the first plate to the second plate, and providing an aluminum-silicon foil interlayer between the second plate and a third plate of the heater plate and diffusion bonding the second plate to the third plate.

[0007] Other and further embodiments of the present disclosure are described below.

BRIEF DESCRIPTION OF THE DRAWINGS

[0008] Embodiments of the present disclosure, briefly summarized above and discussed in greater detail below, can be understood by reference to the illustrative embodiments of the disclosure depicted in the appended drawings. However, the appended drawings illustrate only typical embodiments of the disclosure and are therefore not to be considered limiting of scope, for the disclosure may admit to other equally effective embodiments.

[0009] Figure 1 depicts a schematic side view of a process chamber in accordance with some embodiments of the present disclosure.

[0010] Figure 2 depicts a cross-sectional view of a showerhead assembly in accordance with some embodiments of the present disclosure.

[0011] Figure 3 depicts a top view of a gas plate of a showerhead assembly in accordance with some embodiments of the present disclosure.

[0012] Figure 4 depicts a bottom view of a gas plate of a showerhead assembly in accordance with some embodiments of the present disclosure.

[0013] Figure 5 depicts a cross-sectional bottom view of a chill plate of a showerhead assembly in accordance with some embodiments of the present disclosure.

[0014] Figure 6 depicts a cross-sectional top view of a heater plate of a showerhead assembly in accordance with some embodiments of the present disclosure.

[0015] Figure 7 depicts a cross-sectional top view of a heater plate of a showerhead assembly in accordance with some embodiments of the present disclosure.

[0016] To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. The figures are not drawn to scale and may be simplified for clarity. Elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.

DETAILED DESCRIPTION

[0017] Embodiments of showerhead assemblies for use in a process chamber are provided herein. The showerhead assembly is configured to facilitate a flow of process gas to a substrate being processed within the processing chamber. In some embodiments, the showerhead assembly is configured to operate for high power applications. The showerhead assembly includes a heater plate configured to heat the showerhead assembly. The showerhead assembly includes a chill plate having cooling channels therethrough to cool the showerhead assembly. The showerhead assembly includes one or more recursive gas paths that extend from a single gas inlet to a plurality of gas outlets. In some embodiments, the one or more recursive gas paths are advantageously disposed in the chill plate to minimize a thickness of the showerhead assembly.

[0018] In at least some embodiments, the chill plate comprises a gas plate and a cooling plate having an at or near eutectic aluminum-silicon foil interlayer disposed therebetween for aiding diffusion bonding the gas plate to the cooling plate. Additionally, the heater plate comprises a first plate, a second plate, and a third plate, wherein an at or near eutectic aluminum-silicon foil interlayer is disposed between the first plate and the cooling plate for aiding diffusion bonding the first plate to the cooling plate, and an at or near eutectic aluminum-silicon foil interlayer is disposed between one or more of the first plate, the second plate, and the third plate for aiding diffusion bonding the one or more of the first plate, the second plate, and the third plate to each other.

[0019] Figure 1 depicts a schematic side view of a portion of a process chamber in accordance with some embodiments of the present disclosure. In some embodiments, the process chamber is an etch processing chamber. However, other types of processing chambers configured for different processes can also use or be modified for use with embodiments of the showerhead assemblies described herein.

[0020] The process chamber 100 is a vacuum chamber which is suitably adapted to maintain sub-atmospheric pressures within an interior volume 120 during substrate processing. The process chamber 100 includes a chamber body 106 having sidewalls and a bottom wall. The chamber body 106 is covered by a lid 104 and the chamber body 106 and the lid 104, together, define the interior volume 120. The chamber body 106 and lid 104 may be made of metal, such as aluminum. The chamber body 106 may be grounded via a coupling to ground 115. [0021] A substrate support 124 is disposed within the interior volume 120 to support and retain a substrate 122, such as a semiconductor wafer, for example, or other such substrate as may be electrostatically retained. The substrate support 124 may generally comprise a pedestal 128 and a hollow support shaft 112 for supporting the pedestal 128. The pedestal 128 may include an electrostatic chuck 150. The electrostatic chuck 150 comprises a dielectric plate having one or more electrodes 154 disposed therein. The hollow support shaft 112 provides a conduit to provide, for example, backside gases, process gases, fluids, coolants, power, or the like, to the pedestal 128.

[0022] The substrate support 124 is coupled to a chucking power supply 140 and RF sources (e.g., RF bias power supply 117 or RF plasma power supply 170) to the electrostatic chuck 150. In some embodiments, a backside gas supply 142 is disposed outside of the chamber body 106 and supplies heat transfer gas to the electrostatic chuck 150. In some embodiments, the RF bias power supply 117 is coupled to the electrostatic chuck 150 via one or more RF match networks 116. In some embodiments, the substrate support 124 may alternatively include AC or DC bias power.

[0023] The process chamber 100 is also coupled to and in fluid communication with a gas supply 118 which may supply one or more process gases to the process chamber 100 for processing the substrate 122 disposed therein. A showerhead assembly 132 is disposed in the interior volume 120 opposite the substrate support 124. In some embodiments, the showerhead assembly 132 is coupled to the lid 104. The showerhead assembly 132 and the substrate support 124 partially define a processing volume 144 therebetween. The showerhead assembly 132 includes a plurality of openings to distribute the one or more process gases from the gas supply 118 into the processing volume 144. The showerhead assembly 132 includes a chill plate 138 to control a temperature of the showerhead assembly 132 and holes/channels (described in more detail below) to provide a gas flow path through the chill plate 138. The showerhead assembly 132 includes a heater plate 141 coupled to the chill plate 138. The heater plate 141 includes one or more heating elements disposed or embedded therein to control a temperature of the showerhead assembly 132 and include holes/channels (described in more detail below) to provide a gas flow path through the heater plate 141. In some embodiments, the showerhead assembly 132 includes an upper electrode 136 coupled to the heater plate 141. The upper electrode 136 is disposed in the interior volume 120 opposite the substrate support 124. The upper electrode 136 is coupled to one or more power sources (e.g., RF plasma power supply 170) to ignite the one or more process gases. In some embodiments, the upper electrode 136 comprises single crystal silicon or other silicon containing material.

[0024] A liner 102 is disposed in the interior volume 120 about at least one of the substrate support 124 and the showerhead assembly 132 to confine a plasma therein. In some embodiments, the liner 102 is made of a suitable process material, such as aluminum or a silicon-containing material. The liner 102 includes an upper liner 160 and a lower liner 162. The upper liner 160 may be made of any of the materials mentioned above. In some embodiments, the lower liner 162 is made of the same material as the upper liner 160. In some embodiments, the upper liner 160 includes a stepped inner surface that corresponds with a stepped outer surface 188 of the upper electrode 136.

[0025] The lower liner 162 includes a plurality of radial slots 164 arranged around the lower liner 162 to provide a flow path of the process gases to a pump port 148 (discussed below). In some embodiments, the liner 102, along with the showerhead assembly 132 and the pedestal 128, at least partially define the processing volume 144. In some embodiments, an outer diameter of the showerhead assembly 132 is less than an outer diameter of the liner 102 and greater than an inner diameter of the liner 102. The liner 102 includes an opening 105 corresponding with a slit 103 in the chamber body 106 for transferring the substrate 122 into and out of the process chamber 100.

[0026] In some embodiments, the liner 102 is coupled to a heater ring 180 to heat the liner 102 to a predetermined temperature. In some embodiments, the liner 102 is coupled to the heater ring 180 via one or more fasteners 158. A heater power source 156 is coupled to one or more heating elements in the heater ring 180 to heat the heater ring 180 and the liner 102. [0027] The process chamber 100 is coupled to and in fluid communication with a vacuum system 114, which includes a throttle valve and a vacuum pump, used to exhaust the process chamber 100. The pressure inside the process chamber 100 may be regulated by adjusting the throttle valve and/or vacuum pump. The vacuum system 114 may be coupled to a pump port 148.

[0028] In some embodiments, the liner 102 rests on a lower tray 110. The lower tray 110 is configured to direct a flow of the one or more process gases and processing by-products from the plurality of radial slots 164 to the pump port 148. In some embodiments, the lower tray 110 includes an outer sidewall 126, an inner sidewall 130, and a lower wall 134 extending from the outer sidewall 126 to the inner sidewall 130. The outer sidewall 126, the inner sidewall 130, and the lower wall 134 define an exhaust volume 184 therebetween. In some embodiments, the outer sidewall 126 and the inner sidewall 130 are annular. The lower wall 134 includes one or more openings 182 (one shown in Figure 1) to fluidly couple the exhaust volume 184 to the vacuum system 114. The lower tray 110 may rest on or be otherwise coupled to the pump port 148. In some embodiments, the lower tray 110 includes a ledge 152 extending radially inward from the inner sidewall 130 to accommodate a chamber component, for example, the pedestal 128 of the substrate support 124. In some embodiments, the lower tray 110 is made of a conductive material such as aluminum to provide a ground path.

[0029] In operation, for example, a plasma may be created in the processing volume 144 to perform one or more processes. The plasma may be created by coupling power from a plasma power source (e.g., RF plasma power supply 170) to a process gas via one or more electrodes (e.g., upper electrode 136) near or within the interior volume 120 to ignite the process gas and create the plasma. A bias power may also be provided from a bias power supply (e.g., RF bias power supply 117) to the one or more electrodes 154 within the electrostatic chuck 150 to attract ions from the plasma towards the substrate 122.

[0030] A plasma sheath can bend at an edge of the substrate 122 causing ions to accelerate perpendicularly to the plasma sheath. The ions can be focused or deflected at the substrate edge by the bend in the plasma sheath. In some embodiments, the substrate support 124 includes an edge ring 146 disposed about the electrostatic chuck 150. In some embodiments, the edge ring 146 and the electrostatic chuck 150 define a substrate receiving surface. The edge ring 146 may be coupled to a power source, such as RF bias power supply 117 or a second RF bias power supply (not shown) to control and/or reduce the bend of the plasma sheath.

[0031] Figure 2 depicts a cross-sectional view of a showerhead assembly 132 in accordance with some embodiments of the present disclosure. The showerhead assembly 132 includes the chill plate 138 having one or more cooling channels 204 disposed or embedded therein. The showerhead assembly 132 includes the heater plate 141 coupled to the chill plate 138. The heater plate 141 includes one or more heating elements 208 disposed or embedded therein. The one or more heating elements 208 may be arranged in one or more heating zones to provide independent temperature control to two or more gas zones of the showerhead assembly 132. The one or more heating elements 208 are coupled to one or more power supplies 290. The showerhead assembly 132 includes a plurality of gas flow paths that are fluidly independent from each other and extend through the showerhead assembly 132. In some embodiments, the chill plate 138 is made of aluminum. In some embodiments, the heater plate 141 is made of aluminum.

[0032] The chill plate 138 includes a plurality of recursive gas paths 206 disposed therein that are fluidly independent from each other and corresponding to the two or more gas zones of the showerhead assembly 132. For example, the plurality of recursive gas paths 206 may comprise two, three, or four recursive gas paths (two recursive gas paths depicted in Figures 3 and 4). Each of the plurality of recursive gas paths 206 is fluidly coupled to a single gas inlet extending to a first side 218 of the chill plate 138 and a plurality of gas outlets 248 extending to a second side 224 of the chill plate 138. Each of the recursive gas paths 206 may comprise a substantially equal flow path (/.e., substantially equal axial length and cross- sectional area) from the single gas inlet to each gas outlet of the plurality of gas outlets 248. In some embodiments, a substantially equal flow path may comprise lengths that are within 10% of each other. The substantially equal flow path advantageously provides more uniform gas distribution through the showerhead assembly 132 and into the processing volume 144.

[0033] In some embodiments, the plurality of recursive gas paths 206 are disposed about the chill plate 138 along a common plane (i.e., a single layer). In some embodiments, at least one of the plurality of recursive gas paths 206 are disposed about the chill plate 138 along two or more planes (i.e., two or more layers), where connecting channels (such as connecting channels 220) couple multiple layers of the plurality of recursive gas paths 206. The two or more layers advantageously allow for increased volume for the plurality of recursive gas paths 206 to extend within the chill plate 138 as compared to a single layer. Figure 2 depicts at least one of the plurality of recursive gas paths 206 disposed along two planes.

[0034] In some embodiments, the chill plate 138 comprises one or more plates coupled together. As depicted in Figure 2, in some embodiments, the chill plate 138 includes a gas plate 230 having a first side 238 coupled to a top plate 228 and a second side 240 coupled to a cooling plate 232. A bottom surface of the top plate 228 is coupled to a top surface of the gas plate 230 via one or more bonding processes, e.g., brazing, diffusion bonding, etc. For example, in at least some embodiments, the bottom surface of the top plate 228 is coupled to the top surface of the gas plate 230 using an at or near eutectic (e.g., 577° C) aluminum-silicon foil interlayer 229 (interlayer 229) for aiding diffusion bonding. In at least some embodiments, the interlayer 229 can have a thickness of about 1 mil to about 10 mil. Additionally, a bottom surface of the gas plate 230 is coupled to a top surface of the cooling plate 232 also using the interlayer 229 for aiding diffusion bonding. The cooling plate 232 is coupled to a bottom plate 234 on a side of the cooling plate 232 opposite the gas plate 230. A bottom surface of the cooling plate 232 can be coupled to a top surface of the bottom plate 234 using the interlayer 229 for aiding diffusion bonding. Similarly, a bottom surface of the bottom plate 234 can be coupled to one or more of the plates of the heater plate 141 , as described in greater detail below.

[0035] In at least some embodiments, the interlayer 229 used for diffusion bonding the above-described plates to each other can be the same or different. For example, a weight percent of aluminum to silicon used for the interlayer 229 can vary between different plates. For example, in at least some embodiments, the interlayer 229 used for diffusion bonding the bottom surface of the top plate 228 to the top surface of the gas plate 230 can have about 88 weight percent aluminum and about 12 weight percent silicon. Similarly, the interlayer 229 used for diffusion bonding the bottom surface of the gas plate 230 to the top surface of the cooling plate 232 can have about 80 weight percent aluminum and about 20 weight percent silicon, while the interlayer 229 used for diffusion bonding the bottom surface of the cooling plate 232 to the top surface of the bottom plate 234 can have about 88 weight percent aluminum and about 12 weight percent silicon.

[0036] The one or more cooling channels 204 are disposed along a bottom surface 242 of the cooling plate 232. In some embodiments, the plurality of recursive gas paths 206 are disposed on at least one of the first side 238 and the second side 240 of the gas plate 230. In some embodiments, one or more of the plurality of recursive gas paths 206 are disposed on both the first side 238 and the second side 240 in embodiments where the plurality of recursive gas paths 206 are disposed in the chill plate 138 along two layers. In such embodiments, recursive gas paths that lie along two layers include connecting channels 220 that fluidly couple the two layers. In embodiments where the recursive gas paths 206 are disposed along more than two layers, the gas plate 230 may comprise two or more plates coupled together. The bottom plate 234 includes openings that at least partially define the plurality of gas outlets 248.

[0037] In some embodiments, a first gas inlet 212 extends from the first side 218 of the chill plate 138 (/.e., upper surface of top plate 228) to a first recursive gas path 310 (see Figure 3) of the plurality of recursive gas paths 206. In some embodiments, a second gas inlet 216 extends from the first side 218 of the chill plate 138 to a second recursive gas path 330 (see Figure 3) of the plurality of recursive gas paths 206.

[0038] In some embodiments, each of the plurality of recursive gas paths 206 are coupled to the gas supply 118. The gas supply can be configured to provide one or more process gases to any one or more of the recursive gas paths. For example, in some embodiments, the gas supply 118 is configured to provide a single process gas to each of the first recursive gas path 310 and the second recursive gas path 330. In some embodiments, the gas supply 118 is configured to provide a first process gas or gaseous mixture to one or more the first recursive gas path 310 and the second recursive gas path 330 and a second process gas or gaseous mixture to a remainder of the first recursive gas path 310 and the second recursive gas path 330. In some embodiments, the gas supply 118 is configured to provide different process gases or gaseous mixtures to each of the recursive gas paths.

[0039] The heater plate 141 includes one or more heating elements 208. In some embodiments, the heater plate 141 includes a plurality of first gas distribution holes 252 extending from a top surface 250 thereof to a plurality of plenums 256 that are fluidly independent and disposed in the heater plate 141. A plurality of second gas distribution holes 254 extend from the plurality of plenums 256 to a lower surface 258 of the heater plate to provide a gas flow path through the heater plate 141. In some embodiments, the plurality of second gas distribution holes 254 comprises more holes than the plurality of first gas distribution holes 252 to more uniformly disperse the one or more process gases into the processing volume 144.

[0040] The plurality of first gas distribution holes 252 are aligned with the plurality of gas outlets 248 of the chill plate 138. In some embodiments, the plurality of plenums 256 correspond with the plurality of recursive gas paths 206. In some embodiments, the showerhead assembly 132 includes the upper electrode 136 coupled to the heater plate 141. The upper electrode 136 includes a plurality of third gas distribution holes 274 extending from a top surface 276 thereof at locations corresponding to locations of the plurality of second gas distribution holes 254 of the heater plate 141 to a lower surface 278 of the upper electrode 136. In some embodiments, the plurality of third gas distribution holes 274 have a diameter of about 10 mils to about 50 mils. The upper electrode 136, the heater plate 141 , and the chill plate 138 may be coupled together via fasteners, spring tensioners, or the like.

[0041] In some embodiments, each of the plurality of gas flow paths through the showerhead assembly 132 that are fluidly independent from each other extends through the chill plate 138 via a respectively gas inlet on the first side 218 of the chill plate 138 to a recursive flow path within the chill plate 138 to a respective plurality of gas outlets (e.g., the gas outlets 248) that extend to the second side 224 of the chill plate 138, through the heater plate 141 via respective holes of the plurality of first gas distribution holes 252, a respective plenum of the plurality of plenums 256, and respective holes of the plurality of second gas distribution holes 254, and through the upper electrode 136 via the plurality of third gas distribution holes 274. For example, a first gas flow path extends from the plurality of gas outlets 248 associated with the first recursive gas path 410 through corresponding ones of the first gas distribution holes 252 and into a first plenum of the plurality of plenums 256. Similarly, a second gas flow path extends from the plurality of gas outlets 248 associated with the second recursive gas path 330, through corresponding ones of the first gas distribution holes 252 and into a second plenum of the plurality of plenums 256.

[0042] In some embodiments, the heater plate 141 comprises one or more plates coupled together. In some embodiments, the heater plate 141 includes a first plate 262 coupled to a second plate 264. As noted above, a bottom surface of the bottom plate 234 can be coupled to one or more plates of the heater plate 141. For example, in at least some embodiments, the bottom surface of the bottom plate 234 can be coupled to a top surface of the first plate 262 using the interlayer 229 for aiding diffusion bonding. Alternatively, if the bottom plate 234 is not used, the bottom surface of the cooling plate 232 can be coupled to the top surface of the first plate 262 using the interlayer 229 for aiding diffusion bonding. Additionally, in at least some embodiments, a bottom surface of the first plate 262 can be coupled to a top surface of the second plate 264 using the interlayer 229 for aiding diffusion bonding. The one or more heating elements 208 are disposed in a plurality of channels 268. In some embodiments, the plurality of channels 268 are disposed in the first plate 262. In some embodiments, the plurality of channels 268 are disposed in the second plate 264. In some embodiments, the plurality of channels 268 are defined by both the first plate 262 and the second plate 264. In some embodiments, the first plate 262 and the second plate 264 both include the plurality of channels 268. In some embodiments, a third plate 266 is coupled to the second plate 264 on a side of the second plate 264 opposite the first plate 262. In at least some embodiments, a bottom surface of the second plate 264 can be coupled to a top surface of the third plate 266 using the interlayer 229 for aiding diffusion bonding. In some embodiments, the third plate 266 includes a second plurality of channels 272 that define the plurality of plenums 256. As noted above, the interlayer 229 used for diffusion bonding the first to the third plates to each other can be the same or different, e.g., using the above-described aluminum to silicon weight percentages.

[0043] One or more optional thermal gaskets can be disposed between the chill plate 138 and the heater plate 141 to provide enhanced thermal coupling therebetween and a compression interface. For example, in some embodiments, a first thermal gasket sheet 280 is disposed between the chill plate 138 and the heater plate 141 to provide enhanced thermal coupling therebetween and a compression interface. In some embodiments, a second thermal gasket sheet 282 is disposed between the heater plate 141 and the upper electrode 136 to provide enhanced thermal coupling therebetween and a compression interface. The first thermal gasket sheet 280 includes a plurality of openings corresponding with locations of the plurality of first gas distribution holes 252 of the heater plate 141. The second thermal gasket sheet 282 includes a plurality of openings corresponding with locations of the plurality of second gas distribution holes 254 of the heater plate 141. The first thermal gasket sheet 280 and the second gasket sheet 281 are made of a thermally and electrically conductive sheet of material. In some embodiments, the first thermal gasket sheet 280 and the second gasket sheet 281 comprise a polymer material. In some embodiments, the first thermal gasket sheet 280 and the second gasket sheet 281 comprise an elastomer and metal sandwich structure.

[0044] Figure 3 depicts a top view of the gas plate 230 of the chill plate 138 in accordance with some embodiments of the present disclosure. Figure 4 depicts a bottom view of the gas plate 230 in accordance with some embodiments of the present disclosure. The gas plate 230 depicted in Figures 3 and 4 has the plurality of recursive gas paths 206 disposed along two layers of the gas plate 230. Figure 3 depicts embodiments of a first layer 300 of the plurality of recursive gas paths 206. Figure 4 depicts embodiments of a second layer 400 of the plurality of recursive gas paths 206. [0045] Each of the plurality of recursive gas paths 206 may be disposed in at least one of the first layer 300 and the second layer 400. In some embodiments, one or more of the plurality of recursive gas paths 206 extend from the second layer 400 to the first layer 300 and back to the second layer 400. In some embodiments, the first gas inlet 212 extends to the first layer 300 and is fluidly coupled to a first recursive gas path 310 disposed in both the first layer 300 and the second layer 400. In some embodiments, the first recursive gas path 310 branches out from the first gas inlet 212 one or more times in the first layer 300 to a plurality of ends corresponding with connecting channels 220A that fluidly couple the multiple layers of the first recursive gas path 310. In some embodiments, the first recursive gas path 310 branches out one time to two ends corresponding with two connecting channels 220A.

[0046] In some embodiments, in the second layer 400, the first recursive gas path 310 branches out one or more times from each of the connecting channels 220A to a plurality of first ends 415. In some embodiments, the first recursive gas path 310 branches out once from each connecting channel 220A in the second layer 400 to form four first ends 415. In some embodiments, the plurality of first ends 415 are symmetrically disposed about the gas plate 230. In some embodiments, the plurality of first ends 415 lie at regular intervals along an imaginary circle. In some embodiments, the first recursive gas path 310 includes annular extending portions and radial extending portions in the second layer 400. The plurality of second ends 435 are aligned with a first subset 248A of the plurality of gas outlets 248 of the chill plate 138. In some embodiments, the first recursive gas path 310 branches out two times from each connecting channel 220A in the second layer 400 to form eight first ends 415.

[0047] In some embodiments, a second recursive gas path 330 extends from the second gas inlet 216 to the second layer 400, to the first layer 300, and then back to the second layer 400. As such, the second recursive gas path 330 may be disposed in both the first layer 300 and the second layer 400. In some embodiments, the second recursive gas path 330 branches out from the second gas inlet 216 one or more times in the second layer 400 to a plurality of ends corresponding with connecting channels 220C that fluidly couple the multiple layers of the second recursive gas path 330. In some embodiments, the second recursive gas path 330 branches out once to form two ends corresponding with two connecting channels 220C.

[0048] In some embodiments, in the first layer 300, the second recursive gas path 330 branches out one or more times from each of the connecting channels 220C to ends corresponding with connecting channels 220D. In some embodiments, the second recursive gas path 330 branches out one time from each of the connecting channels 220C to form four ends corresponding with four connecting channels 220D.

[0049] In some embodiments, in the second layer 400, the second recursive gas path 330 branches out one or more times from each of the connecting channels 220D to a plurality of second ends 435. In some embodiments, the second recursive gas path 330 branches out once from each connecting channel 220D in the second layer 400 to form a total of eight second ends 435. In some embodiments, the plurality of second ends 435 are symmetrically disposed about the gas plate 230. In some embodiments, the plurality of second ends 435 are disposed at regular intervals along an imaginary circle. In some embodiments, the second recursive gas path 330 includes annular extending portions and radial extending portions in the second layer 400. The plurality of second ends 435 are aligned with a second subset 248B of the plurality of gas outlets 248 of the chill plate 138. In some embodiments, the second recursive gas path 330 is disposed radially outward from the first recursive gas path 310. In some embodiments, the second recursive gas path 330 branches out twice from each connecting channel 220D in the second layer 400 to form sixteen second ends 435.

[0050] Figure 5 depicts a cross-sectional bottom view of a chill plate 138 of a showerhead assembly 132 in accordance with some embodiments of the present disclosure. In some embodiments, the plurality of gas outlets 248 are disposed along concentric circles of the chill plate 138. In some embodiments, the plurality of gas outlets 248 are disposed at regular intervals along concentric circles of the chill plate 138. In some embodiments, gas outlets of the plurality of gas outlets 248 at each concentric circle correspond with a different gas distribution zone of the showerhead assembly 132. In some embodiments, the showerhead assembly 132 comprises two gas distribution zones, wherein the first zone is a radially innermost zone and the second zone is the radially outermost zone. In some embodiments, the showerhead assembly 132 comprises four zones, where the first zone is a radially innermost zone, the second zone is radially outward of the first zone, the third zone is radially outward of the second zone, and the fourth zone is a radially outermost zone and is radially outward of the third zone.

[0051] In some embodiments, the one or more cooling channels 204 includes one cooling channel having an inlet 510 for supplying a coolant therethrough and an outlet 520 to provide a return path for the coolant. In some embodiments, the one or more cooling channels 204 extend proximate each zone. In some embodiments, the one or more cooling channels 204 are arranged in a spiral pattern.

[0052] Figure 6 depicts a cross-sectional top view of a heater plate 141 of a showerhead assembly 132 in accordance with some embodiments of the present disclosure. The one or more heating elements 208 may extend about the heater plate 141 in any suitable pattern for heating the heater plate 141. In some embodiments, the one or more heating elements 208 are two or more heating elements defining two or more respective heating zones of the showerhead assembly 132. In some embodiments, the one or more heating elements 208 include a first heating element 610 proximate a center of the heater plate 141. In some embodiments, the one or more heating elements 208 include a second heating element 620 disposed radially outward of the first heating element 610. In some embodiments, the second heating element 620 extends radially outward beyond a radially outermost set 612 of the plurality of first gas distribution holes 252

[0053] Figure 7 depicts a cross-sectional top view of the heater plate 141 along a plane of the plurality of plenums 256 in accordance with some embodiments of the present disclosure. In some embodiments, the plurality of plenums 256 correspond with a plurality of gas distribution zones. In some embodiments, the plurality of plenums 256 comprise two plenums corresponding with the two gas distribution zones. In some embodiments, the plurality of plenums 256 comprise four plenums corresponding with four gas distribution zones. In some embodiments, a first plenum 720 is fluidly coupled to a first subset 252A of the first gas distribution holes 252 that are associated with the first recursive gas path 310. In some embodiments, a second plenum 740 is fluidly coupled to a second subset 252B of the plurality of first gas distribution holes 252 that are associated with the second recursive gas path 330. The first plenum 720 is fluidly coupled with a first subset 254A of the plurality of second gas distribution holes 254. The second plenum 740 is fluidly coupled with a second subset 254B of the plurality of second gas distribution holes 254. The plurality of second gas distribution holes 254 are evenly distributed within each plenum. The first plenum 720 and the second plenum 740 may include a plurality of walls 702 to direct gas flow from the plurality of first gas distribution holes 252 to the plurality of second gas distribution holes 254 in each plenum. In some embodiments, the plurality of walls 702 have a polygonal cross-sectional shape. In some embodiments, the plurality of walls 702 are curved. In some embodiments, the plurality of second gas distribution holes 254 comprise more than 100 holes in the plurality of plenums 256. In some embodiments, the plurality of second gas distribution holes 254 are arranged in concentric circles. In some embodiments, the second gas distribution holes 254 within each concentric circle are disposed at regular intervals along the respective concentric circle. Each plenum of the plurality of plenums 256 can include one or more concentric circle of second gas distribution holes 254. In some embodiments, the plurality of second gas distribution holes 254 have a diameter of about 10 mils to about 50 mils.

[0054] While the foregoing is directed to embodiments of the present disclosure, other and further embodiments of the disclosure may be devised without departing from the basic scope thereof.