TITLE

SOLAR CELL ENCAPSULANT LAYERS WITH ENHANCED STABILITY AND ADHESION FIELD OF THE INVENTION The present invention relates to solar cell modules comprising encapsulant layers with enhanced stability and adhesion. BACKGROUND OF THE INVENTION

As a renewable energy resource, the use of solar cell modules is rapidly expanding. With increasingly complex solar cell modules, also referred to as photovoltaic modules, comes an increased demand for enhanced functional encapsulant materials. Solar cell (photovoltaic) modules are units that convert light energy into electrical energy. Typical or conventional construction of a solar cell module consists of at least 5 structural layers, which are constructed in the following order starting from the top (i.e., the light-receiving side): (1) an incident layer or front-sheet, (2) a front-sheet (or first) encapsulant layer, (3) a voltage-generating layer (or solar cell(s)), (4) a back-sheet (second) encapsulant layer, and (5) a backing layer. The function of the incident layer is to provide a transparent protective window that will allow sunlight into the solar cell(s). The incident layer is typically a glass plate or a thin polymeric film (such as a fluoropolymer or polyester film), but could conceivably be any material that is transparent to sunlight.

The encapsulant layers are designed to encapsulate and protect the fragile solar cell(s). Generally, a solar cell module will incorporate at least two encapsulant layers sandwiched around the voltage-generating layer. The optical properties of the front-sheet encapsulant layer must be such that light can be effectively transmitted to the voltage-generating layer. Over the years, a wide variety of polymeric interlayers have been developed to be used as encapsulant layers. In general, these polymeric interlayers must possess a combination of characteristics including very high optical clarity, low haze, high impact resistance, shock absorbance, excellent ultraviolet (UV) light resistance, good long term thermal stability, excellent adhesion to glass and other solar cell laminate layers, low UV light transmittance, low moisture absorption, high moisture resistance,

excellent long term weatherability, among other requirements. Widely used encapsulant materials include complex, multicomponent compositions based on poly(ethylene-co-vinyl acetate) (EVA), acid copolymers of α-olefιns and α,β-ethylenically unsaturated carboxylic acids, ionomers derived from partially or fully neutralized acid copolymers of α-olefins and α,β-ethylenically unsaturated carboxylic acids, polyvinyl acetal) (e.g., polyvinyl butyral) (PVB)), thermoplastic polyurethane (TPU), polyvinylchloride (PVC), linear low density polyethylenes, polyolefϊn block elastomers, ethylene acrylate copolymers (e.g., poly(ethylene-co-methyl acrylate) and poly(ethylene-co-butyl acrylate)), silicone elastomers, epoxy resins, and the like.

Poly(ethylene-co-vinyl acetate) compositions suffer the shortcomings of low adhesion to the other components incorporated within the solar cell module, low creep resistance during the lamination process and end-use and low weathering and light stability. These shortcomings have generally been overcome through the formulation of adhesion primers, peroxide curing agents, and thermal and UV stabilizer packages into the poly(ethylene-co-vinyl acetate) compositions, which complicates the sheet production and ensuing lamination processes. A more recent development has been the use of higher modulus ionomers within solar cell construction. See, e.g., JP S56-116047; JP H2-94574(A); US 5,476,553; US 5,478,402; US 5,733,382; US 5,741 ,370; US 5,762,720; US 5,986,203; US 6,114,046; US 6,353,042; US 6,319,596; US 6,320,116; US 6,586,271 ; US 6,690,930; US 2003-0000568; and Baum, Bernard, et. al., Solar

Collectors, Final Report, DOE/CS/35359-T1 (DE84011480), DOE6081.1, Contract No. AC4-78CS35359 (Springbom Laboratories, Inc.), June, 1983. None of the ionomer compositions disclosed in the above mentioned references fulfill all the requirements for a solar cell encapsulant layer, and there is a continuing need for solar cell encapsulant layers which provide adequate protection to the solar cell, have a long lifetime within the end- use and provide even greater levels of adhesion to the other solar cell laminate layers, preferably without the use of adhesion primers to simplify

the producing processes. The present invention provides tailored solar cell encapsulant sheets meeting all these requirements.

SUMMARY OF THE INVENTION

In one aspect, the invention is a solar cell module prepared from an assembly comprising: (i) a first encapsulant layer, (ii) a solar cell layer comprising one or a plurality of electronically interconnected solar cells and having a light-receiving surface and a rear surface, and (iii) an optional second encapsulant layer, wherein a) the first encapsulant layer has a total thickness of about 1 to about 20 mils (about 0.003 - about 0.51 mm); b) the first encapsulant layer comprises at least one surface layer comprising an ionomer composition derived from a partially or fully neutralized acid copolymer of an α-olefin and about 18 to about 25 wt% of an α,β-ethylenically unsaturated carboxylic acid, based on the total weight of the copolymer; c) the first encapsulant layer is positioned next to the light-receiving surface of the solar cell layer; and d) the optional second encapsulant layer, when present, is positioned next to the rear surface of the solar cell layer.

In a further aspect, the invention is a solar cell module prepared from an assembly consisting essentially of, from top to bottom, (i) an incident layer made of transparent material, (ii) a first encapsulant layer, (iii) a solar cell layer comprising one or a plurality of electronically interconnected solar cells, (iv) optionally, a second encapsulant layer, (v) a back-sheet, wherein the first encapsulant layer has a total thickness of about 0.1 to about 20 mils (0.003-0.51 mm) and comprises at least one surface layer comprising an ionomer composition derived from an acid copolymer of an α-olefin and about 18 to about 25 wt% of an α,β- ethylenically unsaturated carboxylic acid, based on the total weight of the copolymer, and wherein the acid copolymer is about 10% to about 100% neutralized with one or more metallic ions based on a total carboxylic acid content.

In a yet further aspect, the invention, is a process of manufacturing a solar cell module comprising: (i) providing an assembly comprising, from top to bottom, an incident layer, a first encapsulant layer, a solar cell layer comprising one or a plurality of electronically interconnected solar cells, an

optional second encapsulant layer, and a back-sheet and (H) laminating the assembly to form the solar cell module, wherein the first encapsulant layer has a total thickness of about 0.1 to about 20 mils (about 0.003 - about 0.51 mm) and comprises at least one surface layer comprising an ionomer composition derived from a partially or fully neutralized acid copolymer of an α-olefin and about 18 to about 25 wt% of an α,β- ethylenically unsaturated carboxylic acid, based on the total weight of the copolymer.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cross-sectional view of one embodiment of the solar cell module 20, which comprises from top to bottom an incident layer 16, a first encapsulant layer 10, a solar cell layer 12, an optional second encapsulant layer 14, and a backing layer 18.

DETAILED DESCRIPTION OF THE INVENTION To the extent permitted, all publications, patent applications, patents, and other references mentioned herein are incorporated by reference in their entirety.

The materials, methods, and examples herein are illustrative only and the scope of the present invention should be judged only by the claims.

DEFINITIONS

The following definitions apply to the terms as used throughout this specification, unless otherwise limited in specific instances.

Unless stated otherwise, all percentages, parts, ratios, etc., are by weight.

When an amount, concentration, or other value or parameter is given as either a range, preferred range or a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. Where a range of numerical values is recited herein, unless otherwise stated, the range is intended to include the endpoints thereof, and all integers and fractions within the range.

When the term "about" is used in describing a value or an end-point of a range, the disclosure should be understood to include the specific value or end-point referred to.

In the present application, the terms "sheet" and "film" are used in their broad sense interchangeably.

SOLAR CELL MODULES OR LAMINATES

In one aspect, the present invention is a solar cell module or a solar cell laminate comprising a first encapsulant layer, a solar cell layer, and an optional second encapsulant layer, wherein (i) the first encapsulant layer has a total thickness of about 0.1 to about 20 mils (about 0.003 - about 0.51 mm) and comprises at least one surface layer comprising a high-acid ionomer composition which is derived from a partially or fully neutralized acid copolymer of an α-olefin and greater than or equal to about 18 wt% of an α, β-ethylenically unsaturated carboxylic acid based on the total weight of the copolymer, (ii) the solar cell layer comprises one or a plurality of electronically interconnected solar cells and has two opposite surfaces, a light-receiving surface and a rear surface, and (iii) the first and the optional second encapsulant layers are laminated to each of the two opposite surfaces of the solar cell layer. In a preferred embodiment, the first encapsulant layer is laminated to the light-receiving surface of the solar cell layer and the optional second encapsulant layer is laminated to the rear surface of the encapsulant layer.

In one particular embodiment, as illustrated in Figure 1, the solar cell module 20 of the present invention may further comprise (i) a transparent incident layer 16, such as a layer of glass, wherein the incident layer 16 is laminated to the first encapsulant layer 10 and away from the solar cell layer 12, and (ii) a backing layer 18, which is laminated to the rear surface of the solar cell layer 12b or, when the optional second encapsulant layer 14 is present, laminated to the second encapsulant layer 14 and away from the solar cell layer 12.

Also within the scope of the present invention, the solar cell modules may further comprise one or more additional encapsulant layers and/or other additional layers of films or sheets.

I. The First Encapsulant Layer:

The first encapsulant layer may be a single-layer or multilayer film or sheet comprising at least one surface layer derived from the high-acid ionomer composition described above. By multilayer, it is meant that the encapsulant layer may be a bi-layer, tri-layer, or include even more layers. The other layers may be formed from any suitable material. Suitable material that may be used as the other layers include, but are not limited to, poly(ethylene-co-vinyl acetates), polyvinyl acetal) (including acoustic grade polyvinyl acetals)), thermoplastic polyurethanes, polyvinylchlorides, linear low density polyethylenes (e.g., metallocene catalyzed linear low density polyethylenes), polyolefϊn block elastomers, ethylene acrylate ester copolymers (e.g., poly(ethylene-co-methyl acrylates) and poly(ethylene-co-butyl acrylates)), acid copolymers of α-olefins and α, β-ethylenically unsaturated carboxylic acids, ionomers derived from partially or fully neutralized acid copolymers of α-olefms and α, β-ethylenically unsaturated carboxylic acids, silicone elastomers, epoxy resins and combinations thereof. By "an acoustic polyvinyl acetal)", it is meant a polyvinyl acetal) composition having a glass transition temperature (Tg) of 23 ⁰ C or less. In a particular embodiment, where the encapsulant layer is in a multilayer form, both surface layers comprises the high-acid ionomer compositions as described above to provide increased levels of adhesion. I.I The High-acid Ionomer Composition: The high-acid ionomer composition used here is derived from a partially or fully neutralized parent acid copolymer of an α-olefin and greater than or equal to about 18 wt% of an α, β-ethylenically unsaturated carboxylic acids based on the total weight of the copolymer. Such high- acid ionomer compositions provide an encapsulant layer with enhanced adhesion, clarity, percent light transmission and other physical properties. Preferably, the parent acid copolymer is produced from an α-olefin and about 18 to about 25 wt%, or more preferably, about 18 to about 23 wt%, or yet more preferably, about 20 to about 23 wt% of an α, β-ethylenically unsaturated carboxylic acid, based on the total weight of the copolymer.

The α-olefins used herein incorporate from 2 to 10 carbon atoms. The α-olefins may be selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 3-methyl-i-butene, 4-methyl-1-pentene, and the like and mixtures thereof. Preferably, the α-olefin is ethylene.

The α, β-ethylenically unsaturated carboxylic acids used herein may be selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid, maleic anhydride, fumaric acid, monomethyl maleic acid, and mixtures thereof. Preferably, the α, β-ethylenically unsaturated carboxylic acids are selected from the group consisting of acrylic acid, methacrylic acid and mixtures thereof.

The parent acid copolymer used herein may optionally independently contain polymerized residues of other unsaturated comonomers. Specific examples of preferable other unsaturated comonomers include, but are not limited to, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, butyl acrylate, butyl rnethacrylate, isobutyl acrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, octyl acrylate, octyl methacrylate, undecyl acrylate, undecyl methacrylate, octadecyl acrylate, octadecyl methacrylate, dodecyl acrylate, dodecyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isobomyl acrylate, isobomyl methacrylate, lauryl acrylate, lauryl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, glycidyl acrylate, glycidyl methacrylate, poly(ethylene glycol) aery late, poly(ethylene glycol)methacrylate, poly(ethylene glycol) methyl ether acrylate, poly(ethylene glycol) methyl ether methacrylate, poly(ethylene glycol) behenyl ether acrylate, poly(ethylene glycol) behenyl ether methacrylate, poly(ethylene glycol) 4-nonylphenyl ether acrylate, poly(ethylene glycol) 4-nonylphenyl ether methacrylate, poly(ethylene glycol) phenyl ether acrylate, poly(ethylene glycol) phenyl ether methacrylate, dimethyl maleate, diethyl maleate, dibutyl maleate, dimethyl fumarate, diethyl fumarate, dibutyl fumarate, dimenthyl fumarate and the like and mixtures thereof. Preferably, the other unsaturated comonomers are independently selected from the group

consisting of, methyl acrylate, methyl methacrylate, butyl acrylate, butyl methacrylate, glycidyl methacrylate and mixtures thereof. Preferably, the parent acid copolymers used here independently contain up to about 50 wt% of polymerized residues of the other unsaturated comonomer, based on the total weight of the copolymer. More preferably, the parent acid copolymers used here independently contain up to about 30 wt%, or up to about 20 wt%, of polymerized residues of the other unsaturated comonomers. The parent acid copolymers may be polymerized as disclosed, for example, in US 3,404,134, US 5,028,674, US 6,500,888 and US 6,518,365.

It is noted that the encapsulant layer comprised of the high-acid ionomers exhibits improved toughness compared to what would be expected of a shaped article comprising a higher acid content. It is believed that the improved toughness is due to the lower melt index (Ml) of the base parent acid copolymers prior to neutralization. The parent acid copolymer that is used here as the base for the high-acid ionomer preferably has a Ml of less than 60 g/10 min, or less than 55 g/10 min, or less than 50 g/10 min, or less than 35 g/10 min, at 190 ⁰ C with a load of 2160 g, using test methods ISO 1133 and ASTM D1238. To form the high-acid ionomers, the parent acid copolymers are neutralized from about 10% to about 100% with metallic ions based on the total carboxylic acid content. Preferably, the parent acid copolymers are neutralized with metallic ions at a level of about 10% to about 50%, or about 20% to about 40%. The metallic ions may be monovalent, divalent, trivalent, multivalent, or mixtures of ions having the same or different valencies. Exemplary monovalent metallic ions include, but are not limited to, sodium, potassium, lithium, silver, mercury, copper, and the like and mixtures thereof. Exemplary divalent metallic ions include, but are not limited to, beryllium, magnesium, calcium, strontium, barium, copper, cadmium, mercury, tin, lead, iron, cobalt, nickel, zinc, and the like and mixtures thereof. Exemplary trivalent metallic ions include, but are not fimited to, aluminum, scandium, iron, yttrium, and the like and mixtures thereof. Exemplary multivalent metallic ions include, but are not limited to, titanium, zirconium, hafnium, vanadium, tantalum, tungsten, chromium,

cerium, iron, and the like and mixtures thereof. Notably, when the metallic ion is multivalent, complexing agents, such as stearate, oleate, salicylate, and phenolate radicals are included, as disclosed within US Patent No. 3,404,134. Preferably, the metallic ion may be selected from the group consisting of sodium, lithium, magnesium, zinc, aluminum, and mixtures thereof. More preferably, the metallic ion may be selected from the group consisting of sodium, zinc, and mixtures thereof. Most preferably, the metallic ion is zinc. The parent acid copolymers used here may be neutralized as disclosed, for example, in US Patent No. 3,404,134. The high-acid ionomers used herein preferably have a Ml less than about 10 g/10 min, or less than about 5 g/10 min, or less than about 3 g/10 min, as measured by ASTM method D1238 at 19O ⁰ C. The high-acid ionomers used here also preferably have a flexural modulus greater than about 40,000 psi, or greater than about 50,000 psi, or greater than about 60,000 psi, as measured by ASTM method D638. I. Il Additives:

The high-acid ionomer compositions used herein may further contain additives which effectively reduce the melt flow of the resin, to the limit of producing thermoset films or sheets. The use of such additives will enhance the upper end-use temperature and reduce creep of the encapsulant layer and laminates of the present invention, both during the lamination process and the end-uses thereof. Typically, the maximum end-use temperature will be increased by 20 ⁰ C to 70 ⁰ C. In addition, laminates produced from such materials will be fire resistant. By reducing the melt flow of the thermoplastic films or sheets of the present invention, the material will have a reduced tendency to melt and flow out of the laminate and therefore less likely to serve as additional fire fuel. Specific examples of melt flow reducing additives include, but are not limited to, organic peroxides, such as 2,5-dimethylhexane-2,5-dihydroperoxide, 2,5- dimethyl-2,5-di(tert-betylperoxy)hexane-3, di-tert-butyl peroxide, tert- butylcumyl peroxide, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane, dicumyl peroxide, alpha, alpha'-bis(tert-butyl-peroxyisopropyl)benzene, n-butyl-4,4- bis(tert-butylperoxy)valerate, 2,2-bis(tert-butylperoxy)butane, 1 ,1-bis(tert- butyl-peroxy)cyclohexane, 1,1-bis(tert-butylperoxy)-3,3,5-trimethyl-

cyclohexane, tert-butyl peroxybenzoate, benzoyl peroxide, and the like and mixtures or combinations thereof. The organic peroxide may decompose at a temperature of about 100 ⁰ C or higher to generate radicals. Preferably, the organic peroxides have a decomposition temperature which affords a half life of 10 hours at about 7O ⁰ C or higher to provide improved stability for blending operations. Typically, the organic peroxides will be added at a level of about 0.01 to about 10 wt% based on the total weight of composition. If desired, initiators, such as dibutyltin dilaurate, may be used. Typically, initiators are added at a level of about 0.01 to about 0.05 wt% based on the total weight of composition. If desired, inhibitors, such as hydroquinone, hydroquinone monomethyl ether, p-benzoquinone, and methylhydroquinone, may be added for the purpose of enhancing control to the reaction and stability. Typically, the inhibitors would be added at a level of less than about 5 wt% based on the total weight of the composition. However, for the sake of process simplification and ease, it is preferred that the encapsulant layer used herein does not incorporate cross-linking additives, such as the abovementioned peroxides.

It is understood that the high-acid ionomer compositions used herein may further contain any suitable additive(s). Such exemplary additives include, but are not limited to, plasticizers, processing aides, flow enhancing additives, lubricants, pigments, dyes, flame retardants, impact modifiers, nucleating agents to increase crystallinity, antiblocking agents such as silica, thermal stabilizers, hindered amine light stabilizers (HALS), UV absorbers, UV stabilizers, dispersants, surfactants, chelating agents, coupling agents, adhesives, primers, reinforcement additives, such as glass fiber, fillers and the like.

Thermal stabilizers are well disclosed within the art. Any thermal stabilizer will find utility within the invention. General classes of thermal stabilizers include, but are not limited to, phenolic antioxidants, alkylated monophenols, alkylthiomethylphenols, hydroquinones, alkylated hydroquinones, tocopherols, hydroxylated thiodiphenyl ethers, alkylidenebisphenols, O-, N- and S-benzyl compounds, hydroxybenzylated malonates, aromatic hydroxybenzyl compounds, triazine compounds,

aminic antioxidants, aryl amines, diaryl amines, polyaryl amines, acylaminophenols, oxamides, metal deactivators, phosphites, phosphonites, benzylphosphonates, ascorbic acid (vitamin C), compounds which destroy peroxide, hydroxylamines, nitrones, thiosynergists, benzofuranones, indolinones, and the like and mixtures thereof. The high- acid ionomer compositions used here may comprise up to about 10 wt%, or up to about 5 wt%, or up to about 1 wt% of the thermal stabilizers, based on the total weight of the composition.

UV absorbers are well disclosed within the art. Any UV absorber will find utility within the invention. Preferable general classes of UV absorbers include, but are not limited to, benzotriazoles, hydroxybenzophenones, hydroxyphenyl triazines, esters of substituted and unsubstituted benzoic acids, and the like and mixtures thereof. The high-acid ionomer compositions used here may comprise up to about 10 wt%, or up to about 5 wt%, or up to about 1 wt%, of the UV absorbers, based on the total weight of the composition.

Generally, HALS are disclosed to be secondary, tertiary, acetylated, N-hydrocarbyloxy substituted, hydroxy substituted N-hydrocarbyloxy substituted, or other substituted cyclic amines which further incorporate steric hindrance, generally derived from aliphatic substitution on the carbon atoms adjacent to the amine function. Essentially any HALS may find utility within the invention. The high-acid ionomer compositions used here may comprise up to about 10 wt%, or up to about 5 wt%, or up to about 1 wt%, of HALS, based on the total weight of the composition. Silane coupling agents may be added in the high-acid ionomer compositions to enhance the adhesive strengths. Specific examples of the silane coupling agents include, but are not limited to, gamma- chloropropylmethoxysilane, vinyltriethoxysilane, vinyltris(beta- methoxyethoxy)silane, gamma-methacryloxypropylmethoxysilane, vinyltriacetoxysilane, gamma-glycidoxypropyltrimethoxysilane, gamma- glycidoxypropyltriethoxysilane, beta-(3,4- epoxycyclohexyl)ethyltrimethoxysilane, vinyltrichlorosilane, gamma- mercaptopropylmethoxysilane, gamma-aminopropyltriethoxysilane, N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, and the like

and mixtures thereof. These silane coupling agent materials may be used at a level of up to about 5 wt%, or about 0.001 to about 5 wt%, based on the total weight of the composition.

Ul I. Thickness: Typically, the first encapsulant layer used herein has a total thickness of about 0.1 to about 20 mils (about 0.003 - about 0.51 mm). The thinner solar cell encapsulant films, for example, with a total thickness of about 0.1 to about 5 mils (0.003-0.13 mm), are generally utilized within flexible solar cell laminates. On the other hand, the thicker solar cell encapsulant sheets, for example, with a total thickness of about 10 to about 20 mils (about 0.25 - about 0.51 mm), are generally utilized within rigid solar cell laminates. The thickness of the individual sub-layer components which make up the total multilayer encapsulant layer is not critical and may be independently varied depending on the particular application. Preferably, the high-acid ionomer surface layers are minimized in thickness. Preferably, the thickness of the high-acid ionomer surface layers are independently equal to or less than about 5 mils (0.13 mm), or equal to or less than about 3 mils (0.08 mm), or equal to or less than about 2 mils (0.05 mm), or equal to or less than about 1 mil (0.03 mm).

UV. Manufacture:

The encapsulant layers described above may be produced through any process. The encapsulant layer may be produced through the use of preformed ionomer and other layer films and sheets, laminates thereof, extrusion coated multilayer films or sheets, co-extrusion casting and blown film processes. Generally, the films or sheets are produced through extrusion casting or blown film processes. I. V. Advantages: Within the safety glass glazing art, the conditioning of polyvinyl butyral) and ionomeric interlayers is known and practiced to provide the highest adhesion possible to provide the attributes commonly associated with safety glass. Conditioning of ionomeric solar cell encapsulant layers has not been disclosed within the art and can explain the generally recognized need to use adhesives and primers to provide the desired level

of adhesion between the encapsulant layer and the other solar cell laminate layers. The encapsulant layer described above provides many desirable benefits to the overall solar cell laminate and the process to produce the solar cell laminate. First, the at least one surface layer which comprises the high-acid ionomer composition provides significant enhancement in adhesion to the other solar cell laminate layers, especially to the rigid support layers (e.g., the glass layer) without the need for the incorporation of adhesion promoters and additives or the need for the application of primers to the glass or other solar cell laminate layers. The at least one high-acid ionomer surface layer also makes the multilayer encapsulant layer tack-free and prevents it from blocking when rolled or stacked in storage or when manipulated during the production of the solar cell laminates. Moreover, the presence of the at least one surface layer that is made of zinc-neutralized, high-acid content ionomers further reduces the impact of adhesion of the encapsulant layer when it is conditioned at high relative humidity (RH) environments. These surprising attributes of the encapsulant layers will provide the highly desirable ability for laminators to significantly reduce or avoid complicated solar cell encapsulant layer conditioning or storage processes, thereby greatly simplifying the overall solar cell lamination process.

In addition, when the encapsulant layer is in a multilayer form, it relegates the preferable soft, low modulus layers, which have a tendency to block and stick, to the inner layer. On the other hand, as the ionomeric layers tend to be rigid and have a high modulus, the incorporation of the other layer(s) substantially enhances the overall flexibility of the encapsulant layer and lowers the modulus to provide adequate physical shock protection for the fragile solar cell components.

In a preferable embodiment, none of the layers contained within the multilayer solar cell encapsulant layer are cross-linked to avoid the complication of formulating the resin compositions with, for example, peroxide cross-linking agents, and therefore produce curable encapsulant sheets.

As a further benefit, the expensive stabilizers, such as the UV absorbers, may be concentrated in one or both of one or both of the

ionomeric surface layers, where the lowest overall concentration can most efficiently protect the overall multilayer encapsulant film or sheet and, in turn, the solar cell laminate.

H. The Optional Second Encapsulant Layer and Other Additional Encapsulant Layers:

. The optional second encapsulant layer or any other additional encapsulant layers comprised in the solar cell laminate of the invention may be derived from any type of suitable material. Preferably, the optional second encapsulant layer 14 is derived from poly(ethylene-co-vinyl acetates), polyvinyl acetal) (including acoustic grade polyvinyl acetals)), thermoplastic polyurethanes, polyvinylchlorides, linear low density polyethylenes (e.g., metallocene catalyzed linear low density polyethylenes), polyolefin block elastomers, ethylene acrylate ester copolymers (e.g., poly(ethylene-co-methyl acrylates) and poly(ethylene-co- butyl acrylates)), acid copolymers of α-olefins and σ, β-ethylenically unsaturated carboxylic acids, ionomers derived from partially or fully neutralized acid copolymers of α-olefins and α, β-ethylenically unsaturated carboxylic acids, silicone elastomers, or epoxy resins. More preferably, the optional second encapsulant layer has the same composition as the first encapsulant layer.

The thickness of the optional second encapsulant layer or any other additional encapsulant layers is not critical and may be independently varied depending on the particular application. The thickness of the optional second encapsulant layer may range from about 1 to about 120 mils (about 0.03 - about 3 mm), or about 1 to about 40 mils (about 0.03 - about 1 mm) , or about 1 to about 20 mils (about 0.03 - about 0.51 mm). III. Surface Roughness of the Encapsulant Layers:

The encapsulant layers used here may have smooth or roughened surfaces. Preferably, the encapsulant layer has one or bother surfaces roughened to facilitate the de-airing of the laminates through the laminate process. The efficiency of the solar cell laminate is related to the appearance and transparency of the transparent front-sheet portion of the solar cell laminate and is an important feature in assessing the desirability of using the laminate. As described above, the front portion of the solar

cell laminate includes the top incident layer, the solar cell(s) and the encapsulant layer and any other layers laminated between the incident layer and the solar cell layer. One factor affecting the appearance of the front portion of the solar cell laminate is whether the laminate includes trapped air or air bubbles between these layers. Providing channels for the escape of air and removing air during lamination is a known method for obtaining laminates with acceptable appearance. For example, this can be effected by mechanically embossing or by melt fracture during extrusion followed by quenching so that the roughness is retained during handling.

IV. Solar Cells:

Solar cells are commonly available on an ever increasing variety as the technology evolves and is optimized. Within the invention, a solar cell is meant to include any article which can convert light into electrical energy. Typical art examples of the various forms of solar cells include, but are not limited to, single crystal silicon solar cells, polycrystal silicon solar cells, microcrystal silicon solar cells, amorphous silicon based solar cells, copper indium selenide solar cells, compound semiconductor solar cells, dye sensitized solar cells, and the like. The most common types of solar cells include multi-crystalline solar cells, thin film solar cells, compound semiconductor solar cells and amorphous silicon solar cells.

Thin film solar cells are typically produced by depositing several thin film layers onto a substrate, such as glass or a flexible film, with the layers being patterned so as to form a plurality of individual cells which are electrically interconnected to produce a suitable voltage output.

Depending on the sequence in which the multi-layer deposition is carried out, the substrate may serve as the rear surface or as a front window for the solar cell module. By way of example, thin film solar cells are disclosed in US 5,512,107; US 5,948,176; US 5,994,163; US 6,040,521; US 6,137,048; and US 6,258,620. Examples of thin film solar cell modules are those that comprise cadmium telluride or CIGS, (Cu(ln-Ga)(SeS)2), thin film cells.

V. Incident Layers. Backing Layers, and Other Layers:

The solar cell module of the invention may further comprise one or more sheet layers or film layers to serve as the incident layer, the backing layer, and other additional layers. The sheet layers, such as the incident and backing layers used herein, may be formed of glass, plastic (e.g., polycarbonate, acrylics, polyacrylate, cyclic polyolefins, ethylene norbornene polymers, polystyrene, poiyamides, polyesters, fluoropolymers), metal (e.g., aluminum, steel, galvanized steel), or ceramic plates. Glass may serve as the incident layer and the supportive backing layer may be derived from glass, rigid plastic sheets or metal sheets.

The term "glass" is meant to include not only window glass, plate glass, silicate glass, sheet glass, low iron glass, tempered glass, tempered CeO-free glass, and float glass, but also includes colored glass, specialty glass which includes ingredients to control, for example, solar heating, coated glass with, for example, sputtered metals, such as silver or indium tin oxide, for solar control purposes, E-glass, Toroglass, Solex® glass (PPG Industries, Pittsburgh, PA) and the like. Such specialty glasses are disclosed in US 4,615,989; US 5,173,212; US 5,264,286; US 6,150,028; US 6,340,646; US 6,461 ,736; and US 6,468,934. The type of glass to be selected for a particular laminate depends on the intended use.

The film layers, such as the incident, backing, and other layers, used herein may be metal (e.g., aluminum) or polymeric. Preferable polymeric film materials include poly(ethylene terephthalate) (PET), polycarbonate, polypropylene, polyethylene, polypropylene, cyclic polyloefins, norbornene polymers, polystyrene, syndiotactic polystyrene, styrene-acrylate copolymers, acrylonitrile-styrene copolymers, poly(ethylene naphthalate), polyethersulfone, polysulfone, nylons, poly(urethanes), acrylics, cellulose acetates, cellulose triacetates, cellophane, vinyl chloride polymers, polyvinylidene chloride, vinylidene chloride copolymers, fluoropolymers, polyvinyl fluoride, polyvinylidene fluoride, polytetrafluoroethylene, ethylene-tetrafluoroethylene copolymers and the like. Most preferably, the polymeric film is bi-axially oriented poly(ethylene terephthalate) film, aluminum foil, or a fluoropolymer film,

such as Tedlar® or Tefzel® films (E. I. du Pont de Nemours and Company, Wilmington, DE (DuPont)). The polymeric film used herein may also be a multi-layer laminate material, such as a fluoropolymer/polyester/fluoropolymer (e.g., Tedlar® film/polyester film/Tedlar® film) laminate material or a fluoropolymer/polyester/EVA laminate material.

The thickness of the polymeric film is not critical and may be varied depending on the particular application. Generally, the thickness of the polymeric film will range from about 0.1 to about 10 mils (about 0.003 - about 0.26 mm), or from about 1 to about 4 mils (about 0.03 - about 0.1 mm).

The polymeric film is preferably sufficiently stress-relieved and shrink-stable under the coating and lamination processes. Preferably, the polymeric film is heat stabilized to provide low shrinkage characteristics when subjected to elevated temperatures (i.e. less than 2% shrinkage in both directions after 30 min at 150 ⁰ C).

The films used herein may serve as the incident layer 16 (such as the fluoropolymer or poly(ethylene terephthalate) film) or the backing layer 18 (such as the fluoropolymer, aluminum foil, or poly(ethylene terephthalate) film). The films may also be included in the solar cell module 20 as dielectric layers or a barrier layers, such as oxygen or moisture barrier layers.

If desired, a layer of non-woven glass fiber (scrim) may be included in the solar cell laminate 20 to facilitate de-airing during the lamination process or to serve as a reinforcement for the encapsulant layer(s). The use of such scrim layers within solar cell laminates is disclosed within US 5,583,057; US 6,075,202; US 6,204,443; US 6,320,115; US 6,323,416; and EP 0 769 818. Vl. Adhesives and Primers: When even greater adhesion is desired, one or both surfaces of any of the component layers of the solar cell laminates may be treated to enhance the adhesion to other laminate layers. This treatment may take any form known within the art, including adhesives (e.g., silanes), primers (e.g., poly(alkyl amines)), flame treatments (see e.g., US 2,632,921 ;

US 2,648,097; US 2,683,894; and US 2,704,382), plasma treatments (see e.g., US 4,732,814), electron beam treatments, oxidation treatments, corona discharge treatments, chemical treatments, chromic acid treatments, hot air treatments, ozone treatments, ultraviolet light treatments, sand blast treatments, solvent treatments, and the like and combinations thereof. For example, a thin layer of carbon may be deposited on one or both surfaces of the polymeric film through vacuum sputtering as disclosed in US 4,865,711. Or, as disclosed in US 5,415,942, a hydroxy-acrylic hydrosol primer may be coated on poly(ethylene terephthalate) films to serve as an adhesion-promoting primer .

Any suitable adhesive or primer maybe used here. The thickness of the adhesive/primer coating may be less than 1 mil (0.03 mm), or less than 0.4 mil (0.01 mm), or less than 0.1 mil (0.003 mm). In a particular embodiment, the adhesive or primer is a silane that incorporates an amine function. Specific examples of such materials include, but are not limited to, gamma-aminopropyltriethoxysilane, N-beta- (aminoethyl)-garnma-aminopropyl-trimethoxysilane, and the like and mixtures thereof. Commercial examples of such materials include, SILQUEST ^® A-1100 Silane (GE Silicones, Friendly, WV) and

DOW CORNING ^® Z-6020 Silane (Dow Corning Corporation, Midland, Ml).

The adhesives may be applied through melt processes or through solution, emulsion, dispersion, and the like coating processes. One of ordinary skill in the art will be able to identify appropriate process parameters based on the composition and process used for the coating formation. For example, the adhesive or primer composition can be cast, sprayed, air knifed, brushed, rolled, poured or printed or the like onto the surface. Generally the adhesive or primer is diluted into a liquid medium prior to application to provide uniform coverage over the surface. The liquid media may function as a solvent for the adhesive or primer to form solutions or may function as a non-solvent for the adhesive or primer to form dispersions or emulsions. Adhesive coatings may also be applied by spraying the molten, atomized adhesive or primer composition onto the

surface. Such processes are disclosed within the art for wax coatings in, for example, US 5,078,313; US 5,281,446; and US 5,456,754. VII. Solar Cell Laminate Constructions: ^•

Notably, specific solar cell laminate constructions include, but are not limited to, those derived from the following pre-lamination assemblies (from the light receiving side to the back side):

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/glass;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/ fluoropolymer film (e.g., Tedlar® film);

• fluoropolymer film/high-acid ionomer sheet/solar cell/high- acid ionomer sheet/glass;

• Tedlar® film/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/fluoropolymer film; • glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/polyester (e.g., PET) film;

• fluoropolymer film/high-acid ionomer sheet/solar cell/high- acid ionomer sheet/polyester film;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/barrier coated film/high-acid ionomer sheet/glass;

• glass/ionomer sheet/solar cell/high-acid ionomer sheet/barrier coated film/high-acid ionomer sheet/fluoropolymer film;

• fluoropolymer film/high-acid ionomer sheet/barrier coated film/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/barrier coated film/high-acid ionomer sheet/fluoropolymer film;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/aluminum stock; • fluoropolymer film/high-acid ionomer sheet/solar cell/high- acid ionomer sheet/aluminum stock;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/galvanized steel sheet;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/polyester film/high-acid ionomer sheet/aluminum stock;

• fluoropolymer film/high-acid ionomer sheet/solar cell/high- acid ionomer sheet/polyester film/high-acid ionomer sheet/aluminum stock;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/P ET film/high-acid ionomer sheet/galvanized steel sheet;

• fluoropolymer film/high-acid ionomer sheet/solar cell/high- acid ionomer sheet/PET film/high-acid ionomer sheet/galvanized steel sheet;

• glass/high-acid ionomer sheet/solar cell/acoustic polyvinyl butyral) sheet/glass;

• glass/high-acid ionomer sheet/solar cell/poly(vinyl butyral) sheet/ fluoropolymer film;

• fluoropolymer film/ionomer sheet/solar cell/high-acid ionomer sheet/glass;

• fluoropolymer film/high-acid ionomer sheet/solar cell/acid copolymer sheet/ fluoropolymer film; • glass/high-acid ionomer sheet/solar cell/ethylene vinyl acetate sheet/PET film;

• fluoropolymer film/high-acid ionomer sheet/solar cell/poly(ethylene-co-methyl acrylate) sheet/polyester film;

• glass/poly(ethylene-co-butyl acrylate) sheet/solar cell/high- acid ionomer sheet/barrier coated fiim/poly(ethylene-co-butyl acrylate) sheet/glass;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/ fluoropolymer/polyester/fluoropolymer tri-layer film;

• Tedlar® film/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/fluoropolymer polyester/fluoropolymer tri-layer film;

• glass/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/ fluoropolymer/polyester/EVA tri-layer film;

• Tedlar® film/high-acid ionomer sheet/solar cell/high-acid ionomer sheet/fluoropolymer/polyester/fluoropolymer tri-layer film; and the like, and wherein the term "high-acid ionomer sheet" is used to refer to an encapsulant sheet layer having at least one surface layer comprising a high-acid ionomer composition described above. MANUFACTURE QF SOLAR CELL MODULE OR LAMINATE

In a further embodiment, the present invention is a process of manufacturing a solar cell laminate described above. The solar cell laminates of the invention may be produced through autoclave and non-autoclave processes, as described below. For example, the component layers of the solar cell laminates may be laid up in a vacuum lamination press and laminated together under vacuum with heat and standard atmospheric or elevated pressure. In a typical autoclave process, a glass sheet, a first encapsulant layer, a solar cell, an optional second encapsulant layer, a Tedlar® film, and a cover glass sheet are laminated together under heat and pressure and a vacuum (e.g., 689-711 mmHg) to remove air. Preferably, the glass sheet has been washed and dried. A typical glass type is 90 mil (2.3 mm) thick annealed low iron glass. In an exemplary process, the laminate assembly is placed into a bag capable of sustaining a vacuum ("a vacuum bag"), drawing the air out of the bag using a vacuum line or other means of pulling a vacuum on the bag, sealing the bag while maintaining the vacuum, placing the sealed bag in an autoclave at a pressure of about 200 psi and a temperature of about 130 ⁰ C -180 ⁰ C ₁ or about 120 ⁰ C - 160 ⁰ C, or about 135°C - 160 ⁰ C, or about 145°C - 155 ⁰ C, for about 10 - 50 min, or about 20 - 45 min, or about 20 - 40 min, or about 25 - 35 min. A vacuum ring may be substituted for the vacuum bag. One type of vacuum bags is disclosed within US 3,311 , 517. Any air trapped within the laminate assembly may be removed through a nip roll process. For example, the laminate assembly may be heated in an oven at a temperature of about 80 ⁰ C - 120 ⁰ C, or about 90°C - 100 ⁰ C, for about 30 minutes. Thereafter, the heated laminate assembly is passed through a set of nip rolls so that the air in the void spaces

between the solar cell outside layers, the solar cell and the encapsulant layers may be squeezed out, and the edge of the assembly sealed. This process may provide the final solar cell laminate or may provide what is referred to as a pre-press assembly, depending on the materials of construction and the exact conditions utilized.

The pre-press assembly may then be placed in an air autoclave where the temperature is raised to about 120 ⁰ C - 16O ⁰ C, or about 135°C - 16O ⁰ C, and pressure to about 100 - 300 psig, or about 200 psig. These conditions are maintained for about 15-60 min, or about 20-50 min, after which, the air is cooled while no more air is added to the autoclave. After about 20 min of cooling, the excess air pressure is vented and the solar cell laminates are removed from the autoclave. This should not be considered limiting. Essentially any lamination process may be used here.

The laminates of the invention may also be produced through non- autoclave processes. Such non-autoclave processes are disclosed, for example, within US 3,234,062; US 3,852,136; US 4,341,576; US 4,385,951 ; US 4,398,979; US 5,536,347; US 5,853,516; US 6,342,116; US 5,415,909; US 2004/0182493; EP 1 235 683 B1; WO 91/01880; and WO 03/057478 A1. Generally, the non-autoclave processes include heating the laminate assembly or the pre-press assembly and the application of vacuum, pressure or both. For example, the pre-press may be successively passed through heating ovens and nip rolls.

If desired, the edges of the solar cell laminate may be sealed to reduce moisture and air intrusion and their potentially degradation effect on the efficiency and lifetime of the solar cell by any means disclosed within the art. General art edge seal materials include, but are not limited to, butyl rubber, polysulfide, silicone, polyurethane, polypropylene elastomers, polystyrene elastomers, block elastomers, styrene-ethylene- butylene-styrene (SEBS), and the like.

EXAMPLES

The following Examples and Comparative Examples are intended to be illustrative of the present invention, and are not intended in anyway to limit the scope of the present invention. The solar cell interconnections

are omitted from the examples below to clarify the structures, but any common art solar cell interconnections may be utilized within the invention. METHODS

I. Compressive Shear Strength Test: Compressive Shear Strength was determined through the method disclosed within US 6,599,630. In particular, six 1 x 1 in (25 x 25 mm) chips were sawed from the laminate. The chips are conditioned in a room controlled at a temperature of 23°C + 2°C and a relative humidity of 50% + 1% for one hour prior to testing. The compressive shear strength of the chip was determined using jig shown in Figure 1 of US 6,599,630. The chip was placed on the cut-out on the lower half of the jig, and the upper half was then placed on top of the chip. A cross-head was lowered at the rate of 0.1 in/min (2.5 mm/min) until it contacts the upper piece of the device. As the cross-head continues to travel downward, one piece of glass of the chip began to slide relative to the other. The compressive shear strength of the chip was the shear stress required to cause adhesive failure. The precision of this test was such that one standard deviation is typically 6% of the average result of six chips.

II. Pummel Adhesion Test: For each test, a portion of the laminate, typically having dimensions of 15 x 30 cm, was subjected to the pummel test. First, this portion of the laminate was cooled for 8 hours at a temperature of -18 ⁰ C. It was then held in a pummel testing machine at a 45° angle to a supporting table. A force was evenly applied over a 10 x 15 cm area of the sample with a 450 g flathead hammer at a predetermined rate until the glass became pulverized. Once the glass pulverized, the glass remaining glued to the polymeric interlayer was compared with a list of formal standards. These standards comprise a scale ranging from 0 to 10 and are given as follows:

Percent Of The Surface Of The

Polvmeric Sheet That Came Pummel Values

Unqlued Durinq Breakinq

100 0

90 1

80 2

70 3

60 4

50 5

40 6

30 7

20 8

10 9

0 10

The pummel test was performed on both surfaces of the laminated glass and a pummel value recorded for each surface tested. In general, good impact performance is attained at a pummel adhesion of greater than 5 for each surface, i.e., 5+5.

Hl. Extrusion Cast of Polymeric Sheets:

The polymeric sheets used in Examples 1-42 were extruded as follows. The polymeric resins were fed into a 1.5 in (3.8 cm) diameter Killion extruder with a temperature profile as follows:

Extruder Temperature

Zone ( ⁰ C)

Feed Ambient

Zone 1 160

Zone 2 200

Zone 3 200

Block 210

Die 210

Polymer throughput was controlled by adjusting the screw speed to 70 rpm. The extruder fed a 14 in (35.6 cm) "coathanger" die with a

nominal gap of 0.038 in (0.1 cm). The as cast sheet was fed into a three roll stack consisting of a 6 in (15.2 cm) diameter rubber nip roll covered with a Teflon® release film and two 12 in (30.5 cm) diameter polished chrome chill rolls held at a temperature of 10 ⁰ C - 15 ⁰ C. The nominally 0.038 in (0.1 cm) thick sheet was then wound onto cardboard cores at a rate of 3.3 feet/min (1 m/min).

IV. Preparation of Glass Laminates:

The glass laminates in Examples 1-42, 55-63, 105-112, 126-133, and 155-170 were prepared in the following manner. Prior to lamination, the polymeric sheets were either "not conditioned", which means that the polymeric sheets were subject to lamination as received, or conditioned, which means that the polymeric sheets were allowed to sit in an environment with a particular relative humidity for five days at a temperature of 22.2 ⁰ C. During lamination, a pre-press assembly of an annealed float glass sheet layer, a polymeric sheet layer, a thin Teflon® film layer, and an annealed float cover glass layer were laid up. The prepress assembly was then placed into a vacuum bag and heated to 90 ⁰ C - 100 ⁰ C for 30 min to remove any air contained between glass and polymeric layers of the pre-press assembly. The pre-press assembly was then subjected to autoclaving at 135 ⁰ C for 30 min in an air autoclave to a pressure of 200 psig (14.3 bar). The air is then cooled while no more air is added to the autoclave. After 20 min of cooling and the air temperature reaches less than about 50 ⁰ C, the excess pressure was vented, the assembly removed from the autoclave, and the Teflon® film and cover glass sheet removed to provide the desired laminate.

V. Preparation of Embossed Sheet Structures:

The embossed sheet structures used in Examples 43-54, 113-117, and 134-138 were prepared on a 24 in (61 cm) wide Sano multilayer coextrusion line equipped with embossing rolls utilizing common art sheet formation processes. This essentially entailed the use of an extrusion line consisting of a twin-screw extruder with a sheet die feeding melt into a calendar roll stack. The calendar rolls have an embossed surface pattern engraved into the metal surface which imparts to varying degrees a reverse image of the surface texture onto the polymer melt as it passes

between and around the textured rolls. Both surfaces of the sheet were embossed with a pattern with the following characteristics:

Mound average depth 21 + 4 μm

Mound peak depth 25 + 5 μm Pattern frequency/mm 2

Mound width 0.350 + 0.02 mm

Valley width 0.140 + 0.02 mm

Surface roughness, Rz, can be expressed in microns by a 10-point average roughness in accordance with ISO-R468 of the International Organization for Standardization. Roughness measurements were made using a stylus-type profilometer (Surfcom 1500A manufactured by Tokyo Seimitsu Kabushiki Kaisha of Tokyo, Japan) as described in ASME B46.1-1995 using a trace length of 26 mm. ARp and ARt, and the area kurtosis were measured by tracing the roughness over a 5.6 mm x 5.6 mm area in 201 steps using the Perthometer Concept system manufactured by Mahr GmbH, Gottingen, Germany. The sheets typically have an Rz in the range of from about 15 to about 25 μm.

VI. Preparation of Laminate Structures:

The laminate structures comprising embossed sheet structures disclosed in Examples 43-54, 64-104, 118-125, 139-154 and Comparative Example CE1 were prepared as follows. Each component layers of the laminate structures were stacked to form the pre-laminate assemblies. The pre-laminate assemblies were then placed within- a vacuum bag, which was sealed and placed into an oven at room temperature (25°C + 5°C). A vacuum was then applied to remove the air from the vacuum bag. While maintaining the application of the vacuum, the vacuum bag was heated at 135 ⁰ C for 1 hour. The vacuum was then discontinued and the vacuum bag removed from the oven, allowed to cool to room temperature (25°C + 5 ⁰ C). The laminate structures were therefore produced and removed from the vacuum bag.

VII. Compression Molding of Polymeric Plaques:

The polymeric plaques in Examples 55-60, 62, and 63 were prepared through compression molding on a Carver Melt Press. The compression molding was conducted at a temperature of 190 ⁰ C and a

pressure of 20,000 psi. The plaques were then cooled to room temperature over approximately 30 min and packaged in moisture barrier packaging.

VIII. Extrusion of Polymeric Pellets: In Examples 59, 60, and 62, a variety of polymeric compositions were dry blended and compounded on an 1 in (2.5 cm) Killion single screw extruder, which had a melt temperature of approximately 200 ⁰ C and a rate of 2.5 Ib/hr (1.1 kg/hr). The screw speed was 47-70 rpm and the rear zone temperature was 12O ⁰ C - 17O ⁰ C, depending on the composition. The adapter pressure was 400 to 800 psi and power consumption was about 2.5 to 3 amps. The typical extruder barrel temperature profile was as follows:

Rear (Feed Hopper) Zone: 120 to 17O ⁰ C

Mid Zone: 199 to 203 ⁰ C Front Zone: 200 to 202 ⁰ C

Adapter: 200 to 201 ⁰ C

A single strand was passed through a water bath and pelletized to form small pellets. The pellets were purged with nitrogen overnight at room temperature and then sealed in a moisture barrier package. EXAMPLES 1-21

The ionomer sheets comprising one of the ionomers listed in Table 1 were produced by extrusion cast. Examples 1- 21 were glass laminates of a layer of annealed float glass sheet (6 in x 12 in (152 mm x 305 mm) x 2.5 mm) and a layer of one of the ionomer sheets listed in Table 1 (6 in x 12 in x 30 mils (152 x 305 x 0.76 mm)), wherein the tin sides of the glass layers were in contact with the sheets. These glass laminates were then subjected to 180° degree peel strength adhesion testing using an INSTRUMENTORS, Inc., Model SP-102B-3M90 SLIP/PEEL Tester at a rate of 1 in/min (2.5 cm/min). The results are noted below within Table 1 , wherein "ND" denotes "not determined".

Table 1

Peel Adhesion

Not ^' After Conditioning At

Example Material Conditioned <8% RH 23% RH 50% RH

(lbs/in) (lbs/in.) (lbs/in) (lbs/in)

1 lonomer 1 1.4 6.2 5.3 3.2

2 lonomer 2 ND 4.1 3.0 3.6

3 lonomer 3 ND 4.7 4.6 1.8

4 lonomer 4 ND 4.8 3.7 3.1

5 lonomer 5 1.8 4.2 3.8 1.9

6 lonomer 5 ND 8.4 3.7 3.2

7 lonomer 6 ND 8.7 8.4 4.9

8 lonomer 7 ND 12.2 7.1 5.8 g lonomer 8 ND 13.3 10.9 5.5

10 lonomer 9 ND 12.9 11.9 4.6

11 lonomer 10 ND 19.6 13.4 11.1

12 lonomer 11 ND 1.9 ND 0.9

13 lonomer 12 ND 4.0 ND 1.0

14 lonomer 13 ND 4.3 4.0 2.8

15 lonomer 14 ND 5.9 6.8 2.9

16 lonomer 15 ND 8.5 ND 3.2

17 lonomer 16 3.8 12.4 11.7 9.1

18 lonomer 17 4.0 6.9 8.1 8.4

19 lonomer 18 9.6 13.1 12.3 12.2

20 lonomer 19 ND 7.3 7.3 6.7

21 lonomer 20 ND 14.3 ND 10.8 lonomer 1 was a polytethylene-co-methacrylic acid) containing 19 wt% of methacrylic acid that is 37% neutralized with sodium ion and having a Ml of 2.6 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). lonomer 1 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 2 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 34.5% neutralized with sodium ion and having a Ml of 0.5 g/10 miπ (19O ⁰ C ₁ ISO 1133, ASTM D1238). lonomer 2 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C, SSO 1133, ASTM D1238).

• lonomer 3 was a po^ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 32.5% neutralized with sodium ion and having a Ml of 0.6 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 3 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238).

• lonomer 4 was a polyfethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 31.1% neutralized with sodium ion and having a Ml of 0.8 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 4 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 5 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacryiic acid that is 29% neutralized with sodium ion and having a Ml of 0.9 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 5 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 6 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 24% neutralized with sodium ion and having a Ml of 1.5 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 6 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 7 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 22.4% neutralized with sodium ion and having a Ml of 1.8 g/10 min (19O ⁰ C ₁ ISO 1133, ASTM D1238). lonomer 7 was prepared from the corresponding poly(ethylene-co-methacryltc acid) having a Ml of 29 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 8 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 22.1% neutralized with sodium ion and having a Ml of 2.2 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 8 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 9 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 17.9% neutralized with sodium ion and having a Ml of 2.7 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 9 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 10 was a poly(ethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 14.6% neutralized with sodium ion and having a Ml of 4.16 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 10 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 29 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238).

• lonomer 11 was a poly(ethylene-co-methacrylic acid) containing 22.1 wt% of methacrylic acid that is 41.1% neutralized with sodium ion and having a Ml of 0.73 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 11 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• lonomer 12 was a poly(ethylene-co-methacrylic acid) containing 22.1 wt% of methacrylic acid that is 37.3% neutralized with sodium ion and having a Ml of 1.1 g/10 min (19O ⁰ C ₁ ISO 1133, ASTM D1238). lonomer 12 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C ₁ ISO 1133, ASTM D1238).

• lonomer 13 was a poly(ethylene-co-methacrylic acid) containing 22.1 wt% of methacrylic acid that is 30.3% neutralized with sodium ion and having a Ml of 2.26 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 13 was prepared from the corresponding poly (ethylene-co-methacry lie acid) having a Ml of 60 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 14 was a poly(ethylene-co-methacrylic acid) containing 22.1 wt% of methacrylic acid that is 26.0% neutralized with sodium ion and having a Ml of 3.34 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). lonomer 14 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 15 was a poly(ethylene-co-methacrylic acid) containing 22.1 wt% of methacrylic acid that is 24.8% neutralized with sodium ion and having a Ml of 3.95 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). lonomer 15 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (190 ⁰ C, ISO 1133, ASTM D 1238).

• lonomer 16 was a poly(ethylene-co-methacrylic acid) containing 19.0 wt% of methacrylic acid that is 37.0% neutralized with zinc ion and having a Ml of 1.8 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). lonomer 16 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 17 was a polytethylene-co-methacrylic acid) containing 19.0 wt% of methacrylic acid that is 36.0% neutralized with zinc ion and having a Ml of 1.3 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238). lonomer 17 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 18 was a polyfethylene-co-methacrylic acid) containing 19.0 wt% of methacrylic acid that is 32.0% neutralized with zinc ion and having a Ml of 3.1 g/10 miπ (19O ⁰ C ₁ ISO 1133, ASTM D1238). lonomer 18 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 19 was a poly(ethylene-co-methacrylic acid) containing 20.0 wt% of methacrylic acid that is 34.0% neutralized with zinc ion and having a Ml of 1.0 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). lonomer 19 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 20 was a polyfethylene-co-methacrylic acid) containing 21.5 wt% of methacrylic acid that is 32.0% neutralized with zinc ion and having a Ml of 1.3 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 20 was prepared from the corresponding poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min (19O ⁰ C ₁ ISO I ISS ₁ ASTM D^SS).

EXAMPLES 22-42

Examples 22-42 were glass laminates similar to those of Examples 1-21 except that the air sides of the glass sheets were in contact with the ionomer sheets. The laminates were also subject to 180 degree peel strength adhesion testing using an INSTRUMENTORS, Inc., Model

SP-102B-3M90 SLIP/PEEL Tester at a rate of 1 in/min (2.5 cm/min). The results are noted below within Table 2, wherein "ND" denotes "not determined".

Table 2

Peel Adhesion

After Conditioning At

Example Material <8% RH 23% RH 50% RH

(lbs/in) (lbs/in) (lbs/in)

22 lonomer 1 4.9 4.3 1.8

23 lonomer 2 2.3 1.8 2.2

24 lonomer 3 2.4 3.6 0.9

25 lonomer 4 3.6 2.4 1.3

26 lonomer 5 2.7 2.0 1.2

27 lonomer 5 8.0 2.9 2.1

28 lonomer 6 5.7 5.1 3.0

29 lonomer 7 9.0 4.2 4.0

30 lonomer 8 7.3 6.4 3.3

31 lonomer 9 11.0 8.8 2.9

32 lonomer 10 14.1 7.9 5.5

33 lonomer 11 2.0 ND 0.4

34 lonomer 12 2.2 ND 0.6

35 lonomer 13 3.8 1.6 2.7

36 lonomer 14 6.0 4.9 1.9

37 lonomer 15 7.9 ND 2.1

38 lonomer 16 6.2 10.7 6.2

39 lonomer 17 2.7 6.3 8.0

40 lonomer 18 15.2 6.4 8.2

41 lonomer 19 5.4 5.6 6.2

42 lonomer 20 12.2 ND 6.3

EXAMPLES 43-54 AND COMPARATIVE EXAMPLE CE 1

Examples 43-54 and comparative example CE 1 were tri-layer sheet structures with embossed surface layers (Table 3).

Table 3

Tri-layer Sheet Structures Outer Layers Inner Layer

Example 1 mil (0.026 mm) thick 18 mils (0.4 mm) thick

43 lonomer 1 lonomer 21

44 lonomer 17 lonomer 21

45 lonomer 22 lonomer 21

CE 1 lonomer 21 EBA 1

46 lonomer 1 EBA 1

47 lonomer 17 EBA 1

48 lonomer 22 EBA 1

• lonomer 21 was a poly(ethylene-co-methacrylic acid) containing 15 wt% of methacrylic acid that is 21% neutralized with zinc ion and having a Ml of 5 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). • lonomer 22 was a polyfethylene-co-methacrylic acid) containing 19 wt% of methacrylic acid that is 39% neutralized with zinc ion and having a Ml of 4 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• EBA 1 was a poly(ethylene-co-n-butyl acrylate) containing 27 wt% of n-butyl acrylate and having a Ml of 4 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). A variety of laminate structures (4 x 4 in (102 x 102 mm)) comprising the embossed sheet structures listed in Table 3 were produced to demonstrate various solar cell structures. The laminate structures included "glass/tri-layer sheet structure/glass", "fluoropolymerfilm/tri-layer sheet structure/glass", "aluminum sheet/tri-layer sheet structure/glass", "aluminum film/tri-layer sheet structure" and "glass/tri-layer sheet structure". The glass used was 1/8 in (3.2 mm) thick Starphire® glass sheet (PPG Industries, Pittsburgh, PA); the fluoropolymer film was 1.5 in (0.38 mm) thick corona surface treated Tedlar® grade WH15BL3 (DuPont); and the aluminum sheet was 1/8 in (3.2 mm) thick and was 5052 alloyed with 2.5 wt% magnesium and conformed to Federal specification QQ-A-250/8 and ASTM B209.

In addition, 6 x 12 in (152 x 305 mm) laminates comprising one of the embossed sheets listed in Table 3 and one from the group consisting of Starphire® glass sheet, Tedlar® grade WH15BL3, and aluminum sheet were prepared, and subject to peel adhesion tests using test method

ASTM D3330. The results are listed in Table 4 where the term "lock up" denotes that the "substrate'V'tri-layer sheet structure" interface did not fail and the term "ND" denotes "not determined".

Tabfe 4

Peel Adhesion

Embossed Glass/ Tedlar®/ Aluminum/

Example Sheet Exp. Sheet Exp. Sheet Exp. Sheet Exp.

(lbs/in) (lbs/in) Hbs/in)

49 43 11.6 lock up 9.0

50 44 9.3 lock up 7.7

51 45 12.1 lock up ND

52 46 4.8 lock up 5.9

53 47 7.1 10.4 ND

54 48 4.2 lock up ND

EXAMPLE 55

A polymeric plaque (6 in x 7 in x 40 mils (152 x 178 x 1.02 mm)) were produced through compression molding from a copoly(ethylene-co- methacrylic acid) containing 21.4 wt% of methacrylic acid that was 31 % neutralized with sodium. The glass laminate of Example 55 had the structure of glass/polymeric plaque/glass, wherein the two glass layer were made of 6 in x 7 in (152 mm x 178 mm) x 2.5 mm clear annealed float glass plates and the tin sides of the glass plates were in contact with the polymeric plaque. It was found to have a compressive shear strength of 5095 psi and a pummel adhesion at an average of 7.

EXAMPLE 56

A polymeric plaque (6 in x 7 in x 40 mils (152 x 178 x 1.02 mm)) were produced through compression molding from a copoly(ethylene-co- methacrylic acid) containing 21.4 wt% of methacrylic acid that was 32% neutralized with zinc. The glass laminate of Example 56 had the structure of glass/polymeric plaque/glass, wherein the two glass layer were made of 6 in x 7 in (152 mm x 178 mm) x 2.5 mm clear annealed float glass plates and the tin sides of the glass plates were in contact with the polymeric plaque. It was found to have a compressive shear strength of 5338 psi and a pummel adhesion at an average bf 8. EXAMPLE 57

A polymeric plaque (6 in x 7 in x 40 mils (152 x 178 x 1.02 mm)) were produced through compression molding from a copoly(ethylene-co- methacrylic acid) containing 21.4 wt% of methacrylic acid that was 31% neutralized with sodium. The glass laminate of Example 57 had the structure of glass/polymeric plaque/glass, wherein the two glass layer were made of 6 in x 7 in (152 mm x 178 mm) x 2.5 mm clear annealed float glass plates and the air sides of the glass plates were in contact with the polymeric plaque. It was found to have a compressive shear strength of 4742 psi and a pummel adhesion at an average of 5. EXAMPLE 58

A polymeric plaque (6 in x 7 in x 40 mils (152 x 178 x 1.02 mm)) were produced through compression molding from a copoly(ethylene-co- methacrylic acid) containing 21.4 wt% of methacrylic acid that was 32% neutralized with zinc. The glass laminate of Example 58 had the structure of glass/polymeric plaque/glass, wherein the two glass layer were made of 6 in x 7 in (152 mm x 178 mm) x 2.5 mm clear annealed float glass plates and the air sides of the glass plates were in contact with the polymeric plaque. It was found to have a compressive shear strength of 5027 psi and a pummel adhesion at an average of 8.

EXAMPLE 59

In this Example, polymeric pellets were prepared from a polymeric composition consisting of 1) 99.60 wt% of polyXethylene-co-methacrylic acid) which contains 21.4 wt% of methacrylic acid that is 29% neutralized with sodium, 2) 0.30 wt% of Tinuvin® 326 stabilizer (CAS Number 3896- 11-5, Ciba Special Chemicals, Tarrytown, NY (Ciba)), and 3) 0.10 wt% of Irganox® 1010 stabilizer (CAS Number 6683-19-8, Ciba). 6 x 7 x 25 in (152 x 178 x 0.64 mm) polymeric plaques were then produced from these polymeric pellets. Example 59 was a glass laminate of a 12 in x 12 in (305 mm x 305 mm) x 2.5 mm annealed float glass plate and the polymeric plaque prepared above. It was found to have a 90° peel strength of 1.5 Ib/in at a peel rate of 1 in/min (2.5 cm/min), and a 90° peel strength of 1.5 Ib/in at a peel rate of 2 in/min (5.1 cm/min). EXAMPLE 60

In this Example, polymeric pellets were prepared from a polymeric composition consisting of 1) 99.60 wt% of poly(ethylene-co-methacrylic acid) containing 21.4 wt% of methacrylic acid that is 32% neutralized with zinc, 2) 0.30 wt% of Tinuvin® 328 stabilizer (CAS Number 25973-55-1, Ciba), and 3) 0.10 wt% of HP-136® stabilizer (CAS Number 181314-48-7, Ciba). 6 in x 7 in x 25 mil (152 mm x 178 mm x 0.64 mm) polymeric plaques were then produced from these polymeric pellets.

The glass laminate of Example 60 comprised a 12 in x 12 in (305 mm x 305 mm) x 2.5 mm annealed float glass plate and the polymeric plaque prepared above. It was found to have a 90° peel strength of 1.5 Ib/in at a peel rate of 9.2 in/min (23.4 cm/min), and a 90° peel strength of 10.1 Ib/in at a peel rate of 2 in/min (5.1 cm/min). EXAMPLE 61

Example 61 was a glass laminate having the structure of glass/polymeric plaque interlayer/glass, wherein the polymeric plaque interlayer was made of three layers of 2 in x 2 in x 25 mils (51 x 51 x 0.64 mm) plaques prepared from the polymeric composition in Example 60, and the two glass layers were made of two 2 in x 2 in (5.1 mm x 5.1 mm) x 2.5 mm pieces of annealed gloat glass plate.

EXAMPLE 62

In this Example, polymeric pellets were prepared from a polymeric composition consisting of 1) 99.70 wt% of po^ethylene-co-methacrylic acid) containing 21.4 wt% of methacrylic acid that is 32% neutralized with zinc and 2) 0.30 wt% of Chimassorb® 944 FD stabilizer (CAS Number 71878-19-8, Ciba). 152 mm x 178 mm x 0.64 mm thick polymeric plaques were then produced from these polymeric pellets through compression molding.

Example 62 was a glass laminate between a layer of the polymeric plaque and a layer of 12 in x 12 in (305 mm x 305 mm) x 2.5 mm annealed float glass plate. EXAMPLE 63

In this Example, 6 in x 7 in x 40 mils (152 x 178 x 1.02 mm) thick polymeric plaque was produced from a copoly(ethylene-co-methacrylic acid) containing 21.4 wt% of methacrylic acid that was 32% neutralized with zinc through compression molding.

Example 63 was a glass laminate composed of a layer of the polymeric plaque and a layer of 6 in x 6 in (152 mm x 152 mm) x 2.5 mm annealed float glass plate, wherein the polymeric plaque was conditioned at 5% RH at a temperature of 22.2°C overnight prior to lamination and the tin side of the glass plate was in contact with the polymeric plaque.

The glass laminate of Example 63 was then subjected to 90° peel strength adhesion testing using an INSTRUMENTORS, Inc., Model SP-102B-3M90 SLIP/PEEL Tester. The laminate was peeled at rates of 1 in/min (2.5 cm/min) and 2 in/min (5.1 cm/min). They were found to have a peel adhesion of greater than 30 lbs/in. EXAMPLES 64-70

As listed in Table 5, Examples 64-66 are ionomer films produced through a blown film process commonly known within the art.

Table 5

Monolayer Film Structures

Example Material Thickness

64 lonomer 16 1 mil (0.03 mm)

65 lonomer 19 2 mils (0.05 mm)

66 lonomer 20 3 mils (0.08 mm)

As listed in Table 6, Examples 67-70 are 12 x 12 in (305 x 305 mm) solar cell laminate structures comprising one of the ionomer films of Examples 64-66. For those laminates which include a flexible film as an outer layer, a glass cover sheet (3 mm thick) is added to the laminate structure and then removed after the lamination process. Table 6

Solar Cell Laminate Structures

Example Layer 1 Layer 2 Layer 3 Layer 4 Layer 5 67 FPF Example 64 Solar CeIM Example 64 FPF

68 FPF Example 65 Solar Cell 2 Example 65 ALF

69 FPF Example 66 Solar Cell 3 Example 66 FPF 7TJ FPF Example 66 Solar Cell 4 Example 64 ALF

• ALF is an aluminum sheet (3.2 mm thick) that is 5052 alloyed with 2.5 wt% of magnesium and conforms to Federal specification QQ-A-250/8 and ASTM B209.

• FPF is a corona surface treated Tedlar® film grade WH15BL3 (1.5 mils (0.038 mm) thick), a product of the DuPont Corporation.

• Solar Cell 1 is a 10 x 10 in (254 x 254 mm) amorphous silicon photovoltaic device comprising a stainless steel substrate (125 μm thick) with an amorphous silicon semiconductor layer (US 6,093,581 , Example 1 ).

• Solar Cell 2 is a 10 x 10 in (254 x 254 mm) copper indium diselenide (CIS) photovoltaic device (US 6,353,042, column 6, line 19).

• Solar Cell 3 is a 10 x 10 in (254 x 254 mm) cadmium telluride (CdTe) photovoltaic device (US 6,353,042, column 6, line 49). • Solar Cell 4 is a silicon solar cell made from a 10 x 10 in (254 x 254 mm) polycrystalline EFG-grown wafer (US 6,660,930, column 7, line 61). EXAMPLES 71-81

As listed in Table 7, Examples 71-75 are bi-layer film structures produced through a blown film process, as is commonly known within the art.

Table 7

Bi-layer Film Structures Layer 1 Layer 2

Example (Thickness) (Thickness)

71 lonomer 16 EBA 2

(0.5 mil (0.013 mm)) (2 mil (0.05 mm)) 72 lonomer 19 EVA 1

(1 mil (0.03 mm)) (3 mil (0.08 mm)) 73 lonomer 20 EMA 1

(0.7 mil (0.018 mm) (2 mil (0.05 mm) 74 ACR 1 lonomer 20

(0.5 mil (0.013 mm)) (2 mil (0.05 mm)) 75 lonomer 22 lonomer 21

(1 mil (0.03 mm)) (3 mil (0.08 mm))

• ACR 1 is a poly(ethylene-co-methacrylic acid) containing 12 wt% of methacrylic acid and having a Ml of 1 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238).

• EBA 2 is a poly(ethylene-co-n-butyl acrylate) containing 30 wt% of n-butyl acrylate and having a Ml of 1 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238).

• EMA 1 is a poly(ethylene-co-methyl acrylate) containing 30 wt% of methyl acrylate.

• EVA 1 is a formulated composition of poly(ethylene-co-vinyl acetate) containing 32 wt% of vinyl acetate content.

As listed in Table 8, Examples 76-81 are solar cell laminate structures comprising the bi-layer film structures in Table 7.

Table 8

Solar Cell Laminate Structures

Example Layer 1 Laver 2 Laver 3 Laver 4 Laver 5

76 FPF Example 71 Solar Cell 1 Example 71 FPF

77 FPF Example 72 Solar Cell 2 Example 72 ALF

78 FPF Example 73 Solar Cell 3 Example 73 FPF

79 FPF Example 73 Solar Cell 4 Example 72 FPF

80 FPF Example 74 Solar Cell 1 Example 74 ALF

81 FPF Example 75 Solar Cell 4 Example 75 FPF

EXAMPLES 82-93

As listed in Table 9, Examples 82-87 tri-layer film structures produced through a blown film process, as commonly known within the art. Table 9 Tri-layer Film Structures

Outer Layers ' Inner Layer

Example (Thickness) (Thickness)

82 Ionomer 17 EBA 1

(0.5 mil (0.013 mm)) (2 mil (0.05 mm)) 83 Ionomer 19 EEA

(1 mil (0.03 mm)) (3 mil (0.08 mm))

84 lonomer 20 EMA 2

(0.7 mil (0.018 mm) (2 mil (0.05 mm)

85 ACR 2 lonomer 20 (0.5 mil (0.013 mm) (2 mil (0.05 mm))

86 lonomer 19 lonomer 21

(1 mil (0.03 mm)) (3 mil (0.08 mm))

87 lonomer 20 EVA 1 (0.5 mils, (0.013 mm)) (3 mils. (0.08 mm)) • ACR 2 is a poly(ethylene-co-methacrylic acid) containing 19 wt% of methacrylic acid and having a Ml of 2 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238).

• lonomer 6 is a poly(ethylene-co-methacrylic acid) containing 21 wt% of methacrylic acid that is 30% neutralized with zinc ion and having a Ml of 1 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238). • EEA is a poly(ethylene-co-ethyl acrylate) containing 32 wt% of ethyl acrylate and having a Ml of 0.4 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238).

• EMA 2 is a poly(ethylene-co-methyl acrylate) containing 35 wt% of methyl acrylate and having a Ml of 0.7 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238). As listed in Table 10, Examples 88-93 are 12 x 12 in (305 x 305 mm) solar cell laminate structures comprising the tri-layer film structures of Examples 82-87.

Table 10

Solar Cell Laminate Structures

Example Layer 1 Laver 2 Laver 3 Laver 4 Laver 5

88 FPF Example 82 Solar Cell 1 Example 82 FPF

89 FPF Example 83 Solar Cell 2 Example 83 ALF

90 FPF Example 84 Solar Cell 3 Example 84 FPF

91 FPF Example 85 Solar Cell 4 Example 85 FPF

92 FPF Example 86 Solar Cell 1 Example 86 FPF

93 FPF Example 87 Solar Cell 4 Example 87 ALF

EXAMPLES 94-104

As listed in Table 11, Examples 84-96 are monolayer sheet structures having embossed surface layers.

Table 11

Monolayer Sheet Structures.

Example Material Thickness

94 lonomer 16 10 mil (0.25 mm)

95 lonomer 19 15 mil (0.38 mm)

96 lonomer 20 20 mil (0.51 mm)

As listed in Table 12, Examples 97-104 are solar cell laminate structures produced in a manner similar to that is used in preparing the laminate structures in Examples 43-54.

Table 12

Solar Cell Laminate Structures

Example Layer 1 Layer 2 Layer 3 Layer 4 Layer 5

97, 105 Glass 1 Example 94 Solar Cell 1 Example 94 Glass 1

98, 106 Glass 2 Example 95 Solar Cell 2 Example 95 Glass 2

99, 107 FPF Example 96 Solar Cell 3 Example 96 ALF

100, 108 Glass 2 Example 94 Solar Cell 2 EBA 3 ALF

101, 109 Glass 1 Example 95 Solar Cell 4 EVA 2 ALF

102, 110 FPF Example 96 Solar CeIM ACR 3 ALF

110033,, 111111 GGllaassss 11 EExxaammppllee 9944 Solar CeIM PVB Glass 3

104, 112 Glass 1 Example 95 Solar Cell 4 lonomer 23 Glass 2

• ACR 3 is a 20 mil (0.51 mm) thick embossed sheet of a poly(ethylene-co- methacrylic acid) containing 15 wt% of methacrylic acid and having a Ml of 5.0 g/10 min (19O ⁰ C, ISO 1133, ASTM D1238). • EBA 3 is a formulated composition based on po!y(ethylene-co-butyl acrylate) containing 20 wt% of butyl acrylate based on the weight of the total copolymer in the form of 20 mil (0.51 mm) thick sheet.

• EVA 2 is SC50B, believed to be a formulated composition based on poly(ethylene-co-vinyl acetate) in the form of 20 mil (0.51 mm) thick sheet, (Hi-Sheet Industries, JP).

• Glass 1 is Starphire® glass (3.2 mm thick).

• Glass 2 is a clear annealed float glass plate layer (2.5 mm thick).

• Glass 3 is a Solex® solar control glass (3.0 mm thick).

• lonomer 23 is a 90 mil (2.25 mm) thick embossed sheet of a poly(ethylene-co- methacrylic acid) containing 18 wt% of methacrylic acid that is 30% neutralized with zinc ion and having a Ml of 1 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238). lonomer 23 is prepared from a poly(ethylene-co-methacrylic acid) having a Ml of 60 g/10 min.

• PVB is B51V, believed to be a formulated composition based on polyvinyl butyral) in the form of a 20 mil (0.51 mm) thick sheet (DuPont).

EXAMPLES 105-112

As listed in Table 12, Examples 105-112 are solar cell laminate structures prepared in a manner similar to that was used in preparing the glass laminates in Examples 1-42. For those laminates which include a flexible film as an outer layer, a glass cover sheet (3 mm thick) is added to the laminate structure and then removed after the lamination process.

Layers 1 and 2 constitute the incident layer of the solar cell laminate and Layers 4 and 5 constitute the back layer of the solar cell laminate. EXAMPLES 113-125

As listed in Table 13, Examples 113-117 are bi-layer sheet structures with embossed surface layers. Table 13

Bi-layer Sheet Structures

Layer 1 Layer 2

Example (Thickness) (Thickness)

1 13 Ionomer 16 EBA 1

(0.5 mil (0.013 mm)) (19 mil (0.48 mm))

1 14 Ionomer 19 EVA 1

(1 mil (0.03 mm)) (19 mil (0.48 mm))

1 15 lonomer 20 EMA 1

(0.7 mil (0.018 mm) (13 mil (0.33 mm)

1 16 ACR 1 lonomer 20

(0.5 mil (0.013 mm)) (18 mil (0.4 mm))

117 lonomer 22 lonomer 21 (1 mil (0.03 mm)) (19 mil (0.48 mm)) • ACR 2 is a poly(ethylene-co-methacrylic acid) containing 19 wt% of methacrylic acid and having a Ml of 2 g/10 min (190 ⁰ C ₁ ISO 1133, ASTM D1238). As listed in Table 14, Examples 118-125 are solar cell laminate structures produced in a manner similar to that is used in preparing the laminate structures in Examples 43-54. For those Examples where it is possible, the ionomeric surface of the bi-layer sheet is in contact with a glass surface. Layers 1 and 2 constitute the incident layer of the solar cell, laminate and Layers 4 and 5 constitute the back layer of the solar cell laminate.

Table 14

Solar Cell Laminate Structures.

Example Layer 1 Layer 2 Layer 3 Layer 4 Layer 5

118, 126 Glass 1 Example 113 Solar CeIM Example 113 Glass 1 119, 127 Glass 2 Example 114 Solar Cell 2 Example 114 Glass 2

120. 128 FPF Example 115 Solar Cell 3 Example 115 ALF

121. 129 Glass 2 Example 117 Solar Cell 2 EBA 3 ALF

122. 130 Glass 1 Example 114 Solar Cell 4 EVA 2 ALF

123. 131 FPF Example 116 Solar Cell 1 ACR 3 ALF 124, 132 Glass 1 Example 115 Solar Cell 1 PVB A Glass 3

125, 133 Glass 1 Example 117 Solar Cell 4 Ionomer 24 Glass 2

• lonomer 24 is a 20 mil (0.51 mm) thick embossed sheet of a poly(ethylene-co- methacrylic acid) containing 22 wt% of methacrylic acid that is 26% neutralized with zinc ion and having a Ml of 0.75 g/10 min (190 ⁰ C, ISO 1133, ASTM D1238). lonomer 24 is prepared from a poly(ethylene-co-methacrylic acid) having a Ml of

60 g/10 min.

• PVB A is an acoustic polyvinyl butyral) sheet including 100 parts per hundred (pph) polyvinyl butyral) with a hydroxyl number of 15 plasticized with 48.5 pph plasticizer tetraethylene glycol diheptanoate prepared similarly to disclosed within WO 2004/039581.

EXAMPLES 126-133

As listed in Table 14, Examples 126-133 are 12 x 12 in (305 x 305 mm) solar cell laminate structures produced in a manner similar to that is used in preparing the solar cell laminates of Examples 105-112. For those laminate structures where it is possible, the ionomeric surface of the bi- layer sheet is in contact with a glass surface. Layers 1 and 2 constitute the incident layer of the solar cell laminate and Layers 4 and 5 constitute the back layer of the solar cell laminate.

EXAMPLES 134-154 As listed in Table 15, Examples 134-138 are tri-layer film structures with embossed surface layers.

Table 15

Tri-layer Film Structures Outer Layers Inner Layer

Example (Thickness) (Thickness) 134 lonomer 18 EBA 2

(0.5 mil (0.013 mm)) (19 mil (0.48 mm))

135 lonomer 19 EEA 1

(1 mil (0.03 mm)) (18 mil (0.4 mm))

136 lonomer 20 EMA 2

(0.7 mil (0.018 mm) (13 mil (0.33 mm)

137 lonomer 20 lonomer 21

(0.5 mil (0.013 mm)) (19 mil (0.48 mm))

138 lonomer 19 EVA 1

(1 mil (0.03 mm)) π8 miU0.4 mm)) As listed in Table 16, Examples 139-154 are 12 x 12 in (305 x 305 mm) solar cell laminate structures produced in a manner similar to that was used in preparing the laminates in Examples 43-54. Layers 1 and 2 constitute the incident layer of the solar cell laminate and Layers 4 and 5 constitute the back layer of the solar cell laminate.

Table 16

Solar Cell Laminate Structures.

Example Laver 1 Laver 2 Laver 3 Laver 4 Laver 5

139, 155 Glass 1 Example 134 Solar Cell 1 Example 134 Glass 1

140, 156 Glass 2 Example 135 Solar Cell 2 Example 135 Glass 2

141, 157 Glass 1 Example 136 Solar Cell 3 Example 136 Glass 2

142, 158 Glass 1 Example 137 Solar Cell 4 Example 137 Glass 2

143, 159 Glass 1 Example 138 Solar Cell 1 Example 138 ALF

144, 160 Glass 2 Example 134 Solar Cell 2 EBA 3 ALF

145, 161 Glass 2 Example 135 Solar Cell 3 EMA 3 ALF

146, 162 Glass 1 Example 136 Solar Cell 4 EVA 2 ALF

147, 163 FPF Example 137 Solar Cell 1 PVB ALF

148, 164 FPF Example 137 Solar Cell 2 Example 138 ALF

149, 165 Glass 1 lonomer 24 Solar Cell 1 Example 138 Glass 3

150, 166 Glass 1 Example 137 Solar Cell 4 lonomer 23 Glass 2

151, 167 Glass 1 Example 134 Solar Cell 1 PVB A Glass 2

151, 168 Glass 2 Example 135 Solar Cell 4 PVB S Glass 2

153, 169 FPF Example 137 Solar Cell 1 Example 136 Glass 2

154. 170 Glass 1 ExamDle 137 Solar Cell 1 Example 134 Glass 3

• EMA 3 is a formulated composition based on poly(ethylene-co-methyl acrylate) containing 20 wt% of methyl acrylate based on the weight of the total copolymer in the form of 20 mil (0.51 mm) thick sheet.

• PVB S is a 20 mil (0.51 mm) thick stiff polyvinyl butyral) sheet prepared similarly to that disclosed in Example 2, WO 03/078160.

EXAMPLES 155-170

As listed in Table 16, Examples 155-170 are 12 x 12 in (305 x 305 mm) solar cell laminate structures produced in a manner similar to that is used in preparing the laminates of in Example 105-112. Layers 1 and 2 constitute the incident layer of the solar cell laminate and Layers 4 and 5 constitute the back layer of the solar cell laminate.