Title:
SUBSTRATE-BONDED METALLIC CATALYST AND PROCESS FOR PRODUCING THE SAME
Document Type and Number:
WIPO Patent Application WO/2007/023942
Kind Code:
A1
Abstract:
A novel substrate-bonded metallic catalyst which is effective in eliminating problems
associated with the use of metallic catalysts, such as ones concerning the safety
and stability of metallic catalysts, in particular, organometallic complex
catalysts, the removal of trace metals present in reaction products, and waste-liquid
treatment. Also provided are: a process for producing a substrate having a metal
compound bonded to the surface thereof, characterized by fixing sulfur atoms
to the substrate surface, subsequently further bonding a metal compound to this
substrate surface, and then heating the substrate in an organic solvent; a substrate
produced by the process; a substrate-bonded metallic catalyst comprising the
substrate; a use of the substrate as a substrate-bonded metallic catalyst; and
a process for producing an organic compound with the substrate-bonded metallic
catalyst.
Inventors:
NISHIDA ATSUSHI (JP)
ARISAWA MITSUHIRO (JP)
TSUKAMOTO SHIRO (JP)
SHIMODA MASAHIKO (JP)
ARISAWA MITSUHIRO (JP)
TSUKAMOTO SHIRO (JP)
SHIMODA MASAHIKO (JP)
Application Number:
PCT/JP2006/316725
Publication Date:
March 01, 2007
Filing Date:
August 25, 2006
Export Citation:
Assignee:
UNIV CHIBA NAT UNIV CORP (JP)
NAT INST FOR MATERIALS SCIENCE (JP)
NISHIDA ATSUSHI (JP)
ARISAWA MITSUHIRO (JP)
TSUKAMOTO SHIRO (JP)
SHIMODA MASAHIKO (JP)
NAT INST FOR MATERIALS SCIENCE (JP)
NISHIDA ATSUSHI (JP)
ARISAWA MITSUHIRO (JP)
TSUKAMOTO SHIRO (JP)
SHIMODA MASAHIKO (JP)
International Classes:
B01J31/26; B01J37/02; B01J37/06; B01J37/08; C07C67/343; C07C69/618; C07B61/00
Foreign References:
| JP2004130258A | 2004-04-30 |
Other References:
TAKAMIYA I. ET AL.: "GaAs Kiban Tanjigata Shinki Pd Shokubai no Kaihatsu to Yuki Gosei Hanno eno Oyo (Development of Novel Palladium Catalyst Supported on GaAs Substrate and in Application to Organic Synthesis)", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 85, no. 1, 11 March 2005 (2005-03-11), pages 776, XP003008655
TAKAMIYA I. ET AL.: "Shinki GaAs Tanjigata Palladium Shokubai no Gosei to Kino", CATSJ MEETING TORONKAI A KOEN YOKOSHU, vol. 94, 2004, pages 452, XP003008656
TAKAMIYA I. ET AL.: "Novel Palladium Catalyst Supported on GaAs (001) Passivated by Ammonium Sulfide", CHEMISTRY LETTERS, vol. 33, no. 9, 2004, pages 1208 - 1209, XP003008657
ARISAWA M. ET AL.: "Development of a Method for Preparing a Highly Reactive and Stable, Recyclable and Environmentally Benign Organopalladium Catalyst Supported on Sulfur-Terminated Gallium Arsenide(001): A Three-Component Catalyst, {Pd}-S-GaAs(001), and its Properties", ADVANCED SYNTHESIS & CATALYSIS, vol. 348, no. 9, June 2006 (2006-06-01), pages 1063 - 1070, XP003008658
TAKAMIYA I. ET AL.: "Shinki GaAs Tanjigata Palladium Shokubai no Gosei to Kino", CATSJ MEETING TORONKAI A KOEN YOKOSHU, vol. 94, 2004, pages 452, XP003008656
TAKAMIYA I. ET AL.: "Novel Palladium Catalyst Supported on GaAs (001) Passivated by Ammonium Sulfide", CHEMISTRY LETTERS, vol. 33, no. 9, 2004, pages 1208 - 1209, XP003008657
ARISAWA M. ET AL.: "Development of a Method for Preparing a Highly Reactive and Stable, Recyclable and Environmentally Benign Organopalladium Catalyst Supported on Sulfur-Terminated Gallium Arsenide(001): A Three-Component Catalyst, {Pd}-S-GaAs(001), and its Properties", ADVANCED SYNTHESIS & CATALYSIS, vol. 348, no. 9, June 2006 (2006-06-01), pages 1063 - 1070, XP003008658
Attorney, Agent or Firm:
SAEKI, Norio (Aminosan Kaikan Building 15-8, Nihonbashi 3-chom, Chuo-ku Tokyo 27, JP)
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