In color or full-color organic electroluminescent (EL) displays, also known as organic light-emitting diode (OLED) displays or devices, having an array of colored pixels such as red, green, and blue color pixels (commonly referred to as RGB pixels), precision patterning of the color-producing organic EL media is required to produce the RGB pixels. The basic EL device has in common an anode, a cathode, and an organic EL medium sandwiched between the anode and the cathode. The organic EL medium may consist of one or more layers of organic thin films, where one of the layers is primarily responsible for light generation or electroluminescence. This particular layer is generally referred to as the emissive layer of the organic EL medium. Other organic layers present in the organic EL medium may provide electronic transport functions primarily and are referred to as either the hole transport layer (for hole transport) or electron transport layer (for electron transport). In forming the RGB pixels in a full-color organic EL display panel, it is necessary to devise a method to precisely pattern the emissive layer of the organic EL medium or the entire organic EL medium.

Typically, electroluminescent pixels are formed on the display by shadow masking techniques, such as shown in US-A-5,742, 129. Although this has been effective, it has several drawbacks. It has been difficult to achieve high resolution of pixel sizes using shadow masking. Moreover, there are problems of alignment between the substrate and the shadow mask, and care must be taken that pixels are formed in the appropriate locations. When it is desirable to increase the substrate size, it is difficult to manipulate the shadow mask to form appropriately positioned pixels. A further disadvantage of the shadow mask method is that the

mask holes can become plugged with time. Plugged holes on the mask lead to the undesirable result of non-functioning pixels on the EL display.

A method for patterning high-resolution organic EL displays has been disclosed in US-A-5,851, 709 by Grande and others. This method is comprised of the following sequences of steps: 1) providing a substrate having opposing first and second surfaces; 2) forming a light-transmissive, heat- insulating layer over the first surface of the substrate; 3) forming a light-absorbing layer over the heat-insulating layer; 4) providing the substrate with an array of openings extending from the second surface to the heat-insulating layer; 5) providing a transferable, color-forming, organic donor layer formed on the light- absorbing layer; 6) precision aligning the donor substrate with the display substrate in an oriented relationship between the openings in the substrate and the corresponding color pixels on the device; and 7) employing a source of radiation for producing sufficient heat at the light-absorbing layer over the openings to cause the transfer of the organic layer on the donor substrate to the display substrate. A problem with the Grande and others approach is that patterning of an array of openings on the donor substrate is required. This creates many of the same problems as the shadow mask method, including the requirement for precision mechanical alignment between the donor substrate and the display substrate. A further problem is that the donor pattern is fixed and cannot be changed readily.

Using an unpatterned donor substrate and a precision light source, such as a laser, can remove some of the difficulties seen with a patterned donor.

Littman and Tang (US-A-5,688, 551) teach the patternwise transfer of organic EL material from an unpatterned donor sheet to an EL substrate. A series of patents by Wolk and others (US-A-6,114, 088; US-A-6,140, 009; US-A-6,214, 520; and US-A- 6,221, 553) teaches a method that can transfer the luminescent layer of an EL device from a donor element to a substrate by heating selected portions of the donor with a laser beam.

Such a donor sheet works well for preparing small OLED devices.

It can become difficult to handle for larger (greater than 15 cm) OLED devices or

when a single manufacturing step prepares multiple OLED devices. Typical donor support material is supplied in roll form. One of the problems in handling an unrolled donor substrate is that it must be held relatively flat and wrinkle-free during organic coating, laser transfer, and transport. It is difficult to coat such a donor substrate evenly when it is not completely flat.

It is therefore an object of the present invention to provide a way of handling an unrolled donor substrate such that it is held relatively flat and wrinkle- free during organic coating, laser transfer, and transport.

This object is achieved by a method for tensioning unrolled donor substrate to facilitate transfer of organic material to form a layer on the unrolled donor substrate, comprising the steps of : a) delivering of a portion of the unrolled donor substrate from a roll to a frame disposed in an organic coating chamber, such frame defining an aperture ; b) engaging the unrolled donor substrate and tensioning such material using a first clamp assembly associated with the frame; c) coating the tensioned donor substrate with an organic layer in the organic coating chamber; and d) cutting the unrolled tensioned portion of donor substrate into a sheet before or after it has been coated with organic material.

This object is also achieved by a method for tensioning unrolled donor substrate coated with at least one organic layer to facilitate transfer of organic material to an OLED substrate from the unrolled donor substrate, comprising the steps of : a) delivering of a portion of the unrolled donor substrate from a roll to a frame; b) engaging the unrolled donor substrate and tensioning such material using a first clamp assembly associated with the frame; c) cutting the unrolled tensioned portion of donor substrate into a sheet.

In the present invention, an unrolled donor substrate material that can be coated with an organic layer either before or after unrolling is handled to facilitate the transfer of the organic layer onto an OLED substrate. It is an advantage of this method/apparatus that it maintains the tension of an unrolled donor substrate when a portion of the unrolled donor substrate is cut into a sheet, thus maintaining the donor free of wrinkles and sag. It is a further advantage that this tension can be maintained throughout further steps in the process. It is a further advantage that this tension can be maintained with no clamps or obstructions above the top surface, thus leaving this surface unobstructed for further operations. It is a further advantage that attachment of the unrolled donor substrate to the frame can be automated easily.

FIG. 1 shows a top view of a frame designed in accordance with this invention; FIG. 2 shows a side view of the above frame in use with an unrolled donor substrate prior to being clamped; FIG. 3a shows a side view of the above frame showing an intermediate position between unclamped and clamped conditions; FIG. 3b shows a side view of the above frame showing the clamp assembly engaging the unrolled donor substrate; FIG. 4 is a block diagram showing the steps involved in one embodiment of a method according to the present invention; FIG. 5 is a block diagram showing the steps involved in another embodiment of a method according to the present invention; and FIG. 6 is a cross-sectional view of a coated donor substrate prepared according to the present invention.

Turning now to FIG. 1, there is shown a top view of part of one embodiment of an apparatus for tensioning an unrolled donor substrate to facilitate transfer of organic material to an OLED substrate. Such apparatus includes a frame 10 designed in accordance with this invention. Frame 10 defines aperture 12. Aperture 12 can be a coating aperture to facilitate coating of an organic layer, as described by Boroson and others Aperture 12 can also facilitate transfer of an

organic layer to an OLED substrate, as described by Boroson and others and Phillips and others Frame 10 includes spring-biased member 14, and also includes clamp bases that are not visible in this particular orientation. Moveable members 22 and 26 are attached to frame 10.

Turning now to FIG 2, there is shown a side view of one embodiment of an apparatus 8 for tensioning an unrolled donor substrate to facilitate transfer of organic material to an OLED substrate. The apparatus 8 includes a roll of donor substrate, a means for cutting an unrolled portion of the donor substrate into a sheet, and a device disposed relative to a coating chamber and which includes a frame, a means for unrolling and delivering a portion of the donor substrate, and a means for engaging the unrolled donor substrate, all of which will be further described.

The apparatus 8 includes roll 32 of donor substrate 38. Donor substrate 38 is a donor support material for OLED manufacture, and has been described before, for example, by Tang and others in commonly assigned US-A- 5,904, 961. Donor substrate 38 can be made of any of several materials which meet at least the following requirements: the donor substrate 38 must be sufficiently flexible and possess adequate tensile strength to tolerate precoating steps and roll-to-roll or stacked-sheet transport of the support. Donor substrate 38 must be capable of maintaining the structural integrity during the light-to-heat- induced transfer step while pressurized on one side, and during any preheating steps contemplated to remove volatile constituents such as water vapor.

Additionally, donor substrate 38 must be capable of receiving on one surface a relatively thin coating of organic material, and of retaining this coating without degradation during anticipated storage periods of the coated support. Substrate materials meeting these requirements include, for example, metal foils, certain plastic foils which exhibit a glass transition temperature value higher than a support temperature value anticipated to cause transfer of the transferable organic materials of the coating on the support, and fiber-reinforced plastic foils. While selection of suitable substrate materials can rely on known engineering approaches, it will be appreciated that certain aspects of a selected substrate

material merit further consideration when configured as a useful donor support.

For example, the donor substrate 38 can require a multistep cleaning and surface preparation process prior to precoating with transferable organic material. If the substrate material is a radiation-transmissive material, the incorporation into the support or onto a surface thereof, of a radiation-absorptive material can be advantageous to more effectively heat the substrate material and to provide a correspondingly enhanced transfer of transferable organic donor material from the substrate material to the OLED device, when using a flash of radiation from a suitable flash lamp or laser light from a suitable laser. The radiation-absorptive material is capable of absorbing radiation in a predetermined portion of the spectrum and producing heat. Radiation-absorptive material can be a dye such as the dyes specified in commonly assigned US-A-5,578, 416, a pigment such as carbon, or a metal such as nickel, chromium, titanium, and so forth.

Donor substrate 38 can be uncoated, or can be coated with one or more organic layers. If coated, unrolled donor substrate 30 tensioned by frame 10 can be used to facilitate transfer of organic material to an OLED substrate. If coated, unrolled donor substrate 30 tensioned by frame 10 can be coated with an organic layer by coating apparatus 52, and subsequently used to facilitate transfer of organic material to an OLED substrate. Alternatively, unrolled donor substrate 30 can be tensioned by frame 10 in another location, then moved into coating chamber 50 for coating with an organic layer, then moved into a laser thermal transfer chamber for transfer of the organic material to an OLED substrate. The laser thermal transfer chamber and coating chamber 50 can be the same chamber, as described by Boroson and others. By OLED substrate, it is meant a substrate commonly used for preparing OLED displays, for example, active-matrix low- temperature polysilicon TFT substrate. The OLED substrate can either be light transmissive or opaque, depending on the intended direction of light emission.

The light transmissive property is desirable for viewing the EL emission through the OLED substrate. Transparent glass or plastic are commonly employed in such cases. For applications where the EL emission is viewed through the top electrode, the transmissive characteristic of the bottom support is immaterial, and

therefore can be light transmissive, light absorbing or light reflective. OLED substrates for use in this case include, but are not limited to, glass, plastic, semiconductor materials, ceramics, and circuit board materials.

The tensioning apparatus 8 further includes a device 58. Device 58 is disposed in organic coating chamber 50 that includes coating apparatus 52, the latter of which can be disposed above or below device 58. Coating apparatus 52 can be an apparatus that provides coating by any of several well known coating methods, for example, curtain coating, spraying, gravure coating, spin coating, evaporation, and sputtering. This can include vapor deposition apparatus such as that described in US-A-6,237, 529, or any other apparatus capable of coating the materials in a vacuum. The exact nature of coating apparatus 52 will depend on various factors, including the conditions within coating chamber 50 and the nature of donor substrate 38. Device 58 includes frame 10, which as noted defines aperture 12. Frame 10 includes tensioning mechanism 42, which comprises first clamp assembly 16 and spring 28. First clamp assembly 16 includes spring-biased member 14 provided in frame 10 and moveable member 22. Spring-biased member 14 is moveable along a path defined by channel 56. Spring 28 is in engagement with spring-biased member 14 via pressure against frame 10 and urges spring-biased member 14 in first direction 40 along a path defined by channel 56.

Device 58 further includes feed rollers 36 or other means for unrolling and delivering a portion of donor substrate 38 from the roll 32 to device 58 including frame 10 so that a portion of donor substrate 38 is unrolled and disposed over aperture 12 as unrolled donor substrate 30. Device 58 further includes a means for engaging unrolled donor substrate 30 and causing the material to be engaged with first clamp assembly 16 to tension unrolled donor substrate 30. Initial tension can be provided by an associated means or device, such as articulated clamp 25. Articulated clamp 25 can grasp the portion of donor substrate 38 that has been delivered by feed rollers 36 and further deliver it so that donor substrate 38 is disposed over aperture 12. Those skilled in the art will understand that a variety of means will serve the same purpose, for example

articulated rollers, multiple edge rollers, or manual tension. Feed rollers 36 can deliver donor substrate 38 completely over aperture 12 by pushing it providing that the substrate has sufficient stiffness. A means of pulling such as articulated clamp 25 has the additional advantage of providing tension until clamp assembly 16 engages the donor substrate 38.

Spring-biased member 14 includes clamp base 20, which in this embodiment is a groove. Moveable member 22 is designed to fit into clamp base 20 so as to firmly engage a flexible sheet, for example, unrolled donor substrate 30, and allow spring-biased member 14 to tension the material. When the material is properly tensioned, unrolled donor substrate 30 can be coated if necessary with an organic layer from coating apparatus 52 in coating chamber 50.

Apparatus 8 further includes knife 34 or other means for cutting the unrolled portion of donor substrate 38 into a sheet after it has been properly tensioned. Such a cutting step can be effected before or after the unrolled portion of donor substrate 38 has been coated with organic material by coating apparatus 52 in coating chamber 50.

Apparatus 8 can further include a second clamp assembly 18 formed at least in part in frame 10, which comprises clamp base 24 and moveable member 26, and which is functionally similar to first clamp assembly 16 except that second clamp assembly 18 does not include a spring-biased member. First clamp assembly 16 and second clamp assembly 18 define clamp bases 20 and 24, respectively, as corresponding grooves in this embodiment. Moveable members 22 and 26 are two spaced apart members that are both moveable, via slots 46 and 48, respectively, from a disengaged position as shown into engagement with unrolled donor substrate 30, thus forcing unrolled donor substrate 30 into corresponding clamp bases 20 and 24, respectively. In other embodiments, moveable members 22 and 26 can be attached by other means to frame 10 or can be separate.

It will be understood that the exact shape, size, and material composition of clamp bases 20 and 24 and moveable members 22 and 26 will depend upon a number of factors, including the composition, thickness, and

flexibility of the donor substrate material one desires to hold in the frame.

Moveable members 22 and 26 can be formed from a compliant material, for example, rubber, so as to better fit into clamp bases 20 and 24, respectively.

Turning now to FIG. 3a, there is shown a side view of a portion of the above frame 10 showing the moveable member 22 which has been moved from a disengaged position to a lowered position so as to engage unrolled donor substrate 30 over the groove of clamp base 20 of clamp assembly 16. In this embodiment, spring-biased member 14 has also been forced into the frame 10 in opposition to the urging of spring 28, that is spring 28 has been compressed or preloaded. It is important that spring-biased member 14 not be compressed completely against frame 10 so as to ensure that tensioning of unrolled donor substrate 30 will be provided entirely by the pressure of spring 28. Thus a gap 44 must be maintained.

Turning now to FIG. 3b, there is shown a side view of a portion of the above frame 10 showing that moveable member 22 has further moved into engagement with unrolled donor substrate 30 and forcing the unrolled donor substrate 30 into the groove that is clamp base 20 of clamp assembly 16. It will be understood that moveable member 22 and unrolled donor substrate 30 are meant to fit snugly into clamp base 20 and are not shown as snug in FIG. 3b for clarity of illustration.

By a similar process, unrolled donor substrate 30 can be engaged with the second clamp assembly 18, that is, moveable member 26 shown in FIG. 2 can be moved from a disengaged position into engagement with unrolled donor substrate 30, forcing such material into the groove that is clamp base 24 of clamp assembly 18. Spring-biased member 14 will then tension unrolled donor substrate 30 in frame 10 by the urging of spring 28, thus forming tensioned donor substrate 54, which can also be termed the unrolled tensioned portion of the donor substrate.

Tensioned donor substrate 54 can then facilitate the transfer of organic material by preventing sagging or wrinkling in a transfer apparatus such as disclosed by Phillips and others.

Turning now to FIG. 4, there is shown a block diagram showing the steps in one embodiment of a method for tensioning unrolled donor substrate to facilitate coating of organic material on the unrolled donor substrate. At the start (Step 60), feed rollers 36 and/or other means for unrolling and delivering a portion of donor substrate 38 such as articulated clamp 25 delivers a portion of unrolled donor substrate 30 from roll 32 to frame 10 disposed in organic coating chamber 50 (Step 62) such that unrolled donor substrate 30 is disposed over aperture 12.

Spring 28 is preloaded by compressing spring-biased member 14 toward frame 10 (Step 63). Compressing spring-biased member 14 can be done by an actuator in an apparatus into which frame 10 can fit. Once unrolled donor substrate 30 is completely fed, the two spaced apart moveable members 22 and 26 are moved from a disengaged position into engagement with unrolled donor substrate 30 so that unrolled donor substrate 30 is forced into first and second clamp assemblies 16 and 18. Specifically, the leading edge of moveable member 22 is lowered (Step 64) and engages unrolled donor substrate 30 in first clamp assembly 16 (Step 66), after which the delivery means (for example, articulated clamp 25) can be released (Step 67). In a like manner, the trailing edge of moveable member 26 is lowered (Step 68) and engages unrolled donor substrate 30 in second clamp assembly 18 (Step 70). Preloaded spring 28 is released (Step 72), that is spring- biased member 14 is no longer restrained against the urging of spring 28, as unrolled donor substrate 30 is now tensioned by the clamp assemblies 16 and 18 associated with frame 10. Coating apparatus 52 then coats tensioned donor substrate 54 with an organic layer in organic coating chamber 50 (Step 74). Knife 34 or other means for cutting the unrolled portion of donor substrate 38 then cuts the unrolled tensioned portion of donor substrate into a sheet (Step 76). The process then ends (Step 78).

It will be understood that variations in the order of these steps is possible while providing the same result. For example, the preloading of spring 28 (Step 63) can occur concurrently with the engaging of moveable member 22 against clamp base 20 (Step 66). Cutting the tensioned donor substrate 54 into a

sheet (Step 76) can occur before or after coating it with an organic layer (Step 74), and the coating step (Step 74) can be left out entirely.

Turning now to FIG. 5, there is shown a block diagram showing the steps in another embodiment of a method for tensioning unrolled donor substrate, in this case to facilitate transfer of organic material to an OLED substrate from the unrolled donor substrate in a laser thermal transfer chamber. At the start (Step 60), feed rollers 36 and/or other means for unrolling and delivering a portion of donor substrate 38 such as articulated clamp 25 delivers a portion of unrolled donor substrate 30 from roll 32 to frame 10 disposed in organic coating chamber 50 (Step 62) such that unrolled donor substrate 30 is disposed over aperture 12.

Spring 28 is preloaded by compressing spring-biased member 14 toward frame 10 (Step 63). Compressing spring-biased member 14 can be done by an actuator in an apparatus into which frame 10 can fit. Once unrolled donor substrate 30 is completely fed, the two spaced apart moveable members 22 and 26 are moved from a disengaged position into engagement with unrolled donor substrate 30 so that unrolled donor substrate 30 is forced into first and second clamp assemblies 16 and 18. Specifically, the leading edge of moveable member 22 is lowered (Step 64) and engages unrolled donor substrate 30 in first clamp assembly 16 (Step 66), after which the delivery means (for example articulated clamp 25) can be released (Step 67). In a like manner, the trailing edge of moveable member 26 is lowered (Step 68) and engages unrolled donor substrate 30 in second clamp assembly 18 (Step 70). Preloaded spring 28 is released (Step 72), that is spring- biased member 14 is no longer restrained against the urging of spring 28, as unrolled donor substrate 30 is now tensioned by the clamp assemblies 16 and 18 associated with frame 10. Knife 34 or other means for cutting the unrolled portion of donor substrate 38 then cuts the unrolled tensioned portion of donor substrate into a sheet (Step 76). The tensioned donor substrate 54 can then be used in a laser transfer process to transfer organic material from tensioned donor substrate 54 to an OLED substrate in a laser thermal transfer chamber (Step 77).

Turning now to FIG. 6, there is shown a cross-sectional view of an example of coated donor substrate 80 prepared by this method. Coated donor

substrate 80 includes donor substrate 38. In this example, coated donor substrate 80 also includes optional radiation-absorptive layer 82. Coated donor substrate 80 also includes organic layer 84, which was coated in Step 74.

Organic layer 84 can include any organic material used in the formation of an OLED device. A typical OLED device can contain the following layers, usually in this sequence: an anode, a hole-injecting layer, a hole- transporting layer, a light-emitting layer, an electron-transporting layer, and a cathode. The organic material can include a hole-injecting material, a hole- transporting material, an electron-transporting material, a light-emitting material, a host material, or a combination of any of these materials. These materials are described below.

Hole-Injecting (HI) Material While not always necessary, it is often useful that a hole-injecting layer be provided in an organic light-emitting display. The hole-injecting material can serve to improve the film formation property of subsequent organic layers and to facilitate injection of holes into the hole-transporting layer. Suitable materials for use in the hole-injecting layer include, but are not limited to, porphyrinic compounds as described in US-A-4,720, 432, and plasma-deposited fluorocarbon polymers as described in US-A-6,208, 075 B1. Alternative hole-injecting materials reportedly useful in organic EL devices are described in EP 0 891 121 Al and EP 1,029, 909 Al.

Hole-Transport HTl Material Hole-transport materials useful as coated material are well known to include compounds such as an aromatic tertiary amine, where the latter is understood to be a compound containing at least one trivalent nitrogen atom that is bonded only to carbon atoms, at least one of which is a member of an aromatic ring. In one form the aromatic tertiary amine can be an arylamine, such as a monoarylamine, diarylamine, triarylamine, or a polymeric arylamine. Exemplary monomeric triarylamines are illustrated by Ilupfel and others US-A-3,180, 730.

Other suitable triarylamines substituted with one or more vinyl radicals and/or

comprising at least one active hydrogen containing group are disclosed by Brantley and others US-A-3,567, 450 and US-A-3,658, 520.

A more preferred class of aromatic tertiary amines are those which include at least two aromatic tertiary amine moieties as described in US-A- 4,720, 432 and US-A-5,061, 569. Such compounds include those represented by structural Formula (A). wherein Ql and Q2 are independently selected aromatic tertiary amine moieties and G is a linking group such as an arylene, cycloalkylene, or alkylene group of a carbon-to-carbon bond. In one embodiment, at least one of Q or Q2 contains a polycyclic fused ring structure, for example, naphthalene. When G is an aryl group, it is conveniently a phenylene, biphenylene, or naphthalene moiety.

A useful class of triarylamines satisfying structural Formula (A) and containing two triarylamine moieties is represented by structural Formula (B): where: Ri and R2 each independently represents a hydrogen atom, an aryl group, or an alkyl group or Rl and R2 together represent the atoms completing a cycloalkyl group; and R3 and R4 each independently represents an aryl group, which is in turn substituted with a diary substituted amino group, as indicated by structural Formula (C):

wherein R5 and R6 are independently selected aryl groups. In one embodiment, at least one of R5 or R6 contains a polycyclic fused ring structure, for example, a naphthalene.

Another class of aromatic tertiary amines are the tetraaryldiamines.

Desirable tetraaryldiamines include two diarylamino groups, such as indicated by Formula (C), linked through an arylene group. Useful tetraaryldiamines include those represented by Formula (D). wherein: each Are is an independently selected arylene group, such as a phenylene or anthracene moiety; n is an integer of from 1 to 4; and Ar, R7, R8, and R9 are independently selected aryl groups.

In a typical embodiment, at least one of Ar, R7, R8, and R9 is a polycyclic fused ring structure, for example, a naphthalene.

The various alkyl, alkylene, aryl, and arylene moieties of the foregoing structural Formulae (A), (B), (C), (D), can each in turn be substituted.

Typical substituents include alkyl groups, alkoxy groups, aryl groups, aryloxy groups, and halogen such as fluoride, chloride, and bromide. The various alkyl and alkylene moieties typically contain from about 1 to 6 carbon atoms. The cycloalkyl moieties can contain from 3 to about 10 carbon atoms, but typically contain five, six, or seven ring carbon atoms, for example, cyclopentyl, cyclohexyl, and cycloheptyl ring structures. The aryl and arylene moieties are usually phenyl and phenylene moieties.

The hole-transporting layer can be formed of a single or a mixture of aromatic tertiary amine compounds. Specifically, one may employ a triarylamine, such as a triarylamine satisfying the Formula (B), in combination with a tetraaryldiamine, such as indicated by Formula (D). When a triarylamine is employed in combination with a tetraaryldiamine, the latter is positioned as a layer interposed between the triarylamine and the electron-injecting and transporting layer. Illustrative of useful aromatic tertiary amines are the following: 1,1-Bis (4-di-p-tolylaminophenyl) cyclohexane 1,1-Bis (4-di-p-tolylaminophenyl)-4-phenylcyclohexane 4,4'-Bis (diphenylamino) quadriphenyl Bis (4-dimethylamino-2-methylphenyl)-phenylmethane N, N, N-Tri (p-tolyl) amine 4- (di-p-tolylamino)-4'- [4 (di-p-tolylamino)-styryl] stilbene N, N, N', N'-Tetra-p-tolyl-4-4'-diaminobiphenyl N, N, N', N'-Tetraphenyl-4,4'-diaminobiphenyl N, N, N', N'-Tetra-l-naphthyl-4, 4'-diaminobiphenyl N, N, N', N'-Tetra-2-naphthyl-4, 4'-diaminobiphenyl N-Phenylcarbazole 4,4'-Bis [N- (1-naphthyl)-N-phenylamino] biphenyl 4,4'-Bis [N- (l-naphthyl)-N- (2-naphthyl) amino] biphenyl 4,4"-Bis [N- (l-naphthyl)-N-phenylamino] p-terphenyl 4,4'-Bis [N- (2-naphthyl)-N-phenylamino] biphenyl 4,4'-Bis [N- (3-acenaphthenyl)-N-phenylamino] biphenyl 1,5-Bis [N- (l-naphthyl)-N-phenylamino] naphthalene 4,4'-Bis [N- (9-anthryl)-N-phenylamino] biphenyl 4,4"-Bis [N- (l-anthryl)-N-phenylamino]-p-terphenyl 4,4'-Bis [N- (2-phenanthryl)-N-phenylamino] biphenyl 4,4'-Bis [N- (8-fluoranthenyl)-N-phenylamino] biphenyl 4,4'-Bis [N- (2-pyrenyl)-N-phenylamino] biphenyl 4,4'-Bis [N- (2-naphthacenyl)-N-phenylamino] biphenyl 4,4'-Bis [N- (2-perylenyl)-N-phenylamino] biphenyl

4,4'-Bis [N- (l-coronenyl)-N-phenylamino] biphenyl 2,6-Bis (di-p-tolylamino) naphthalene 2,6-Bis [di- (1-naphthyl) amino] naphthalene 2,6-Bis [N- (l-naphthyl)-N- (2-naphthyl) amino] naphthalene N, N, N', N'-Tetra (2-naphthyl)-4, 4"-diamino-p-terphenyl 4,4'-Bis {N-phenyl-N- [4- (l-naphthyl)-phenyl] amino} biphenyl 4,4'-Bis [N-phenyl-N- (2-pyrenyl) amino] biphenyl 2,6-Bis [N, N-di (2-naphthyl) amine] fluorene 1,5-Bis [N- (l-naphthyl)-N-phenylamino] naphthalene Another class of useful hole-transporting materials includes polycyclic aromatic compounds as described in EP 1 009 041 A2. In addition, polymeric hole-transporting materials can be used such as poly (N-vinylcarbazole) (PVK), polythiophenes, polypyrrole, polyaniline, and copolymers such as poly (3,4-ethylenedioxythiophene)/poly (4-styrenesulfonate), also called PEDOT/PSS.

Light-Emitting Material Light-emitting materials useful as the organic material are well known. Such donor materials can comprise components to make a light-emitting layer in an OLED device. As more fully described in US-A-4,769, 292 and US-A- 5, 935, 721, the light-emitting layer (LEL) of the organic EL element comprises a luminescent or fluorescent material where electroluminescence is produced as a result of electron-hole pair recombination in this region. The donor material and the light-emitting layer produced from it can be comprised of a single material, but more commonly consists of two or more components, for example, a host material doped with a light-emitting guest compound or compounds where light emission comes primarily from the dopant and can be of any color. The host materials in the light-emitting layer can be an electron-transporting material, as defined below, a hole-transporting material, as defined above, or another material that supports hole-electron recombination. The dopant is usually chosen from highly fluorescent dyes, but phosphorescent compounds, for example, transition metal complexes as described in WO 98/55561, WO 00/18851, WO 00/57676, and WO

00/70655 are also useful. Dopants are typically coated as 0.01 to 10 % by weight into the host material.

An important relationship for choosing a dye as a dopant is a comparison of the bandgap potential which is defined as the energy difference between the highest occupied molecular orbital and the lowest unoccupied molecular orbital of the molecule. For efficient energy transfer from the host to the dopant molecule, a necessary condition is that the band gap of the dopant is smaller than that of the host material.

Host and emitting molecules known to be of use include, but are not limited to, those disclosed in US-A-4,768, 292; US-A-5,141, 671; US-A- 5,150, 006; US-A-5,151, 629; US-A-5,294, 870; US-A-5,405, 709; US-A-5,484, 922; US-A-5,593, 788; US-A-5,645, 948; US-A-5,683, 823; US-A-5,755, 999; US-A- 5,928, 802; US-A-5,935, 720; US-A-5,935, 721; and US-A-6, 020,078.

Metal complexes of 8-hydroxyquinoline and similar derivatives (Formula E) constitute one class of useful host compounds capable of supporting electroluminescence, and are particularly suitable for light emission of wavelengths longer than 500 nm, for example, green, yellow, orange, and red. wherein: M represents a metal; n is an integer of from 1 to 3; and Z independently in each occurrence represents the atoms completing a nucleus having at least two fused aromatic rings.

From the foregoing it is apparent that the metal can be monovalent, divalent, or trivalent metal. The metal can, for example, be an alkali metal, such as lithium, sodium, or potassium; an alkaline earth metal, such as magnesium or calcium; or an earth metal, such as boron or aluminum. Generally any

monovalent, divalent, or trivalent metal known to be a useful chelating metal can be employed.

Z completes a heterocyclic nucleus containing at least two fused aromatic rings, at least one of which is an azole or azine ring. Additional rings, including both aliphatic and aromatic rings, can be fused with the two required rings, if required. To avoid adding molecular bulk without improving on function the number of ring atoms is usually maintained at 18 or less.

Illustrative of useful chelated oxinoid compounds are the following: CO-1 : Aluminum trisoxine [alias, tris (8-quinolinolato) aluminum (III)] CO-2 : Magnesium bisoxine [alias, bis (8-quinolinolato) magnesium (II)] CO-3 : Bis [benzo {f}-8-quinolinolato] zinc (II) CO-4 : Bis (2-methyl-8-quinolinolato) aluminum (III)-.-oxo-bis (2-methyl-8- quinolinolato) aluminum (III) CO-5 : Indium trisoxine [alias, tris (8-quinolinolato) indium] CO-6 : Aluminum tris (5-methyloxine) [alias, tris (5-methyl-8- quinolinolato) aluminum (III)] CO-7 : Lithum oxine [alias, (8-quinolinolato) lithium (I)] CO-8 : Gallium oxine [alias, tris (8-quinolinolato) gallium (III)] CO-9: Zirconium oxine [alias, tetra (8-quinolinolato) zirconium (IV)] Derivatives of 9, 10-di-(2-naphthyl) anthracene (Formula F) constitute one class of useful hosts capable of supporting electroluminescence, and are particularly suitable for light emission of wavelengths longer than 400 nm, for example, blue, green, yellow, orange or red.

wherein: Rl, R2, R3, and R4 represent one or more substituents on each ring where each substituent is individually selected from the following groups: Group 1: hydrogen, or alkyl of from 1 to 24 carbon atoms; Group 2: aryl or substituted aryl of from 5 to 20 carbon atoms; Group 3: carbon atoms from 4 to 24 necessary to complete a fused aromatic ring of anthracenyl; pyrenyl, or perylenyl; Group 4: heteroaryl or substituted heteroaryl of from 5 to 24 carbon atoms as necessary to complete a fused heteroaromatic ring of furyl, thienyl, pyridyl, quinolinyl or other heterocyclic systems; Group 5: alkoxylamino, alkylamino, or arylamino of from 1 to 24 carbon atoms; and Group 6: fluorine, chlorine, bromine or cyano.

Benzazole derivatives (Formula G) constitute another class of useful hosts capable of supporting electroluminescence, and are particularly suitable for light emission of wavelengths longer than 400 nm, for example blue, green, yellow, orange or red. wherein: n is an integer of 3 to 8 ; ZisO, NRorS ; R and R'are individually hydrogen; alkyl of from 1 to 24 carbon atoms, for example, propyl, t-butyl, heptyl, and the like; aryl or hetero-atom substituted aryl of from 5 to 20 carbon atoms for example phenyl and naphthyl, furyl, thienyl, pyridyl, quinolinyl and other heterocyclic systems; or halo such as chloro, fluoro; or atoms necessary to complete a fused aromatic ring;

L is a linkage unit consisting of alkyl, aryl, substituted alkyl, or substituted aryl, which conjugately or unconjugately connects the multiple benzazoles together.

An example of a useful benzazole is 2,2', 2"- (1, 3,5- phenylene) tris [1-phenyl-1 H-benzimidazole].

Desirable fluorescent dopants include derivatives of anthracene, tetracene, xanthene, perylene, rubrene, cumarin, rhodamine, quinacridone, dicyanomethylenepyran compounds, thiopyran compounds, polymethine compounds, pyrilium and thiapyrilium compounds, and carbostyryl compounds.

Illustrative examples of useful dopants include, but are not limited to, the following : 0, OH /I I \ N \ F/ \ N \ \ N//\ N// L8 L8 R1 R1 R2 N R2 /\ N R2/\ wN R2 R1 0 A X N R2 N R2 N \ O' N \ O'\ o J X R1 R2 X R1 R2 L9 O H H L23 O H H L10 O H Methyl L24 O H Methyl Lll O Methyl H L25 O Methyl H L12 O Methyl Methyl L26 O Methyl Methyl L13 O H t-butyl L27 O H t-butyl L14 O t-butyl H L28 O t-butyl H L15 O t-butyl t-butyl L29 O t-butyl t-butyl L16 S H H L30 S H H L17 S H Methyl L31 S H Methyl L18 S Methyl H L32 S Methyl H L19 S Methyl Methyl L33 S Methyl Methyl L20 S H t-butyl L34 S H t-butyl L21 S t-butyl H L35 S t-butyl H L22 S t-butyl t-butyl L36 S t-butyl t-butyl NC CN NC CN I I I I R R N ,/\ N \ __j L37 phenyl L41 phenyl L38 methyl L42 methyl L39 t-butyl L43 t-butyl L40 mesityl L44 mesityl / nui 2 NI \N 2 L46 - 3 L45 La. s

Other organic emissive materials can be polymeric substances, for example, polyphenylenevinylene derivatives, dialkoxy-polyphenylenevinylenes, poly-para-phenylene derivatives, and polyfluorene derivatives, as taught by Wolk and others in commonly assigned US-A-6,194, 119 B1 and references therein.

Electron-Transport CET) Material Preferred electron-transport materials for use in organic EL devices of the present invention are metal chelated oxinoid compounds, including chelates of oxine itself (also commonly referred to as 8-quinolinol or 8-hydroxyquinoline).

Such compounds help to inject and transport electrons and exhibit both high levels of performance and are readily fabricated in the form of thin films. Exemplary of contemplated oxinoid compounds are those satisfying structural Formula (E), previously described.

Other electron-transporting materials include various butadiene derivatives as disclosed in US-A-4,356, 429 and various heterocyclic optical brighteners as described in US-A-4,539, 507. Benzazoles satisfying structural Formula (I) are also useful electron-transporting materials.

Other electron-transport materials can be polymeric substances, for example, polyphenylenevinylene derivatives, poly-para-phenylene derivatives, polyfluorene derivatives, polythiophenes, polyacetylenes, and other conductive polymeric organic materials such as those listed in Handbook of Conductive Molecules and Polymers, Vols. 1-4, H. S. Nalwa, ed. , John Wiley and Sons, Chichester (1997).

In some instances, one organic layer 84 can include two or more different organic materials. For example, a single layer can serve the function of supporting both light emission and electron transportation, and will therefore include emissive material and electron-transporting material. Other embodiments that include two or more organic layers 84 are also possible.

Coated donor substrate 80 can be used in a patternwise transfer of organic material from tensioned donor substrate 54 to an OLED substrate.

Other features of the invention are included below.

The method wherein the moveable members are made of compliant material.

The method further including using laser transfer to transfer organic material from the tensioned donor substrate to an OLED substrate.

The apparatus wherein the moveable members are made of compliant material.