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Title:
TRIALKOXYSILANES, METHOD FOR PRODUCING A CATHODE LINER WITH A SILANE SUBSTRATE, AND AN OXIDE CAPACITOR WITH SUCH A CATHODE LINER
Document Type and Number:
WIPO Patent Application WO/2013/022385
Kind Code:
A3
Abstract:
Trialkoxysilanes of general formula (I), where R1-Si(OAlk)3, R2=R3=H R2=R3=--OCH2CH2O-, R'=-Si(OAlk)3 R2=R3=--OCH2CH2O-, R1=-CH-N-CH2CH2CH2Si(OAlk)3, are proposed as silicon-containing additives for the formation of a monolayer on the surface of a tantalum anode made from compressed tantalum powder. A method for producing a cathode liner from a polymer electrolyte is described, which involves applying 8 (eight) layers of a polyethylenedioxythiophene-based polymerizing compound onto sections consisting of oxidized porous valve-metal anodes, with hardening and shaping and the subsequent washing of the sections in deionized water being carried out after every four layers, said method being characterized in that a trialkoxysilane of the general formula according to claim 1 is first applied to the sections by means of impregnating the sections with a 5% solution of, for example, triethoxy-2-thienylsilane in ethanol for 5 minutes at a temperature of 25±5°C and drying is subsequently carried out in two stages: at room temperature for 15 minutes, and in a drying oven at a temperature of 110±5°C for 15-20 minutes. An oxide capacitor with a solid electrolyte is proposed, which contains a section consisting of a porous valve-metal anode (1), on the surface of which the following are consecutively formed: an oxide layer (2) which constitutes a dielectric, a silane monolayer (3), a cathode liner produced using the method according to claim 2 and being in the form of a polyethylenedioxythiophene-based polymer coating (4), a carbon layer (5) which constitutes a cathode intermediate coating, a silver-containing layer (6) which constitutes a cathode contact layer, and a casing (7) produced, for example, by moulding a section into a plastic or by flooding the section with an epoxy compound.

Inventors:
ABASHEV GEORGIJ GEORGIEVICH (RU)
MASALEV ALEKSEJ ALEKSANDROVICH (RU)
CHESNOKOV JURIJ ALEKSANDROVICH (RU)
LEBEDEV VIKTOR PETROVICH (RU)
STEPANOV ALEKSANDR VIKTOROVICH (RU)
KONYSHEV VLADIMIR SERGEEVICH (RU)
OSORGINA IRINA VIKTOROVNA (RU)
KICHIGIN VLADIMIR IVANOVICH (RU)
SHAVKUNOV SERGEJ PAVLOVICH (RU)
SHKLJAEVA ELENA VIKTOROVNA (RU)
Application Number:
PCT/RU2012/000647
Publication Date:
May 30, 2013
Filing Date:
August 09, 2012
Export Citation:
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Assignee:
FEDERAL NOE G BJUDZHETNOE OBRAZOVATEL NOE UCHREZHDENIE VYSSHEGO PROSESSIONAL NOGO OBRAZOVANIJA PERM (RU)
OTKRYTOE AKCIONERNOE OBWESTVO ELECOND (RU)
International Classes:
C07F7/18; C07D333/10; H01G9/02
Foreign References:
US20070072362A12007-03-29
EP2309524A12011-04-13
Other References:
TINGTING XU ET AL.: "Self-assembled thienylsilane molecule as interfacial layer for ZnO nanowire/polymer hybrid system", JOURNAL OF PHOTONICS FOR ENERGY, vol. 1, January 2011 (2011-01-01), pages 011107/1 - 011107/9
Attorney, Agent or Firm:
ONORIN, Alexandr Anatolievich (patentny otdelul. Bukireva, 1, Perm 0, RU)
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