Title:
TRIPTYCENE DERIVATIVE USEFUL AS MATERIAL FOR FORMING SELF-ASSEMBLED FILM, METHOD FOR PRODUCING SAID DERIVATIVE, FILM PRODUCED USING SAID DERIVATIVE, AND METHOD FOR PRODUCING SAID FILM
Document Type and Number:
WIPO Patent Application WO/2014/111980
Kind Code:
A1
Abstract:
The present invention provides: a Janus-type triptycene derivative which is represented by general formula [I] and is useful as a material for a self-assembled monomolecular film; a Janus-type triptycene derivative which is represented by general formula [II] and can be used as a raw material for the production of the aforementioned derivative; and methods respectively for producing the derivatives. The present invention also provides: a film-forming material containing the Janus-type triptycene derivative; a self-assembled film produced using the material; a solid substrate having the film formed on the surface thereof; and a method for producing the film. (In the formulae, X represents a linker group such as an oxygen atom; R1 represents a long-chain group; Z represents a hydrogen atom or any one of various functional groups which is located at the terminal; and R2 represents a hydrogen atom or any one of various substituents.)
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Inventors:
FUKUSHIMA TAKANORI (JP)
SHOJI YOSHIAKI (JP)
SHOJI YOSHIAKI (JP)
Application Number:
PCT/JP2013/004952
Publication Date:
July 24, 2014
Filing Date:
August 21, 2013
Export Citation:
Assignee:
JAPAN SCIENCE & TECH AGENCY (JP)
International Classes:
C07C59/72; B01J19/00; C07C37/84; C07C39/17; C07C39/42; C07C43/20; C07C43/225; C07C47/575; C07C69/712; C07C217/74; C07C217/80; C07C255/52; C07C309/65; C07D209/48; C07D333/18; C07F7/18; H01L21/312; H01L21/336; H01L29/78
Other References:
AKITO NISHINAKA ET AL.: "Janus-gata Triptycene o Platform to suru Denshi Oyobi Hikari Kassei Kinodan no Ko Mitsudo Shusekika", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY YOSHISHU, 5 September 2012 (2012-09-05), pages 216
AKITO NISHINAKA ET AL.: "Janus-gata Triptycene o Platform to suru Denshi Oyobi Hikari Kassei Kinodan no Ko Mitsudo Shusekika", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY POSTER BUNSHO, 19 September 2012 (2012-09-19)
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Design", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY YOSHISHU, 5 September 2012 (2012-09-05)
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Design", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY POSTER BUNSHO, 19 September 2012 (2012-09-19)
YOSHIAKI SHOJI ET AL.: "Janus-gata Triptycene: Kinodan no Seimitsu katsu Ko Mitsudo Shusekika o Kano ni suru Han'yosei Bunshi Platform no Kaihatsu", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY YOSHISHU, 5 September 2012 (2012-09-05), pages 30 - 31
YOSHIAKI SHOJI ET AL.: "Janus-gata Triptycene: Kinodan no Seimitsu katsu Ko Mitsudo Shusekika o Kano ni suru Han'yosei Bunshi Platform no Kaihatsu", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY KOTO HAPPYO BUNSHO, 19 September 2012 (2012-09-19)
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Kaihatsu", CSJ: THE CHEMICAL SOCIETY OF JAPAN SHUKI JIGYO, DAI 2 KAI CSJ KAGAKU FESTA 2012 PROGRAM ยท KOEN YOKOSHU, 26 September 2012 (2012-09-26), pages 266
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Kaihatsu", CSJ: THE CHEMICAL SOCIETY OF JAPAN SHUKI JIGYO, DAI 2 KAI CSJ KAGAKU FESTA 2012 POSTER BUNSHO, 16 October 2012 (2012-10-16)
TAKANORI FUKUSHIMA ET AL.: "Nijigen Shusekikano o Yusuru Bunshi Building Block no Kaihatsu", FUCHI KENKYUSHO-KAN ALLIANCE 'JISEDAI ELECTRONICS' GROUP (G1) BUNKAKAI (YAMAGATA UNIVERSITY JOINT SYMOPSIUM, 5 August 2013 (2013-08-05), pages 32
YOSHIAKI SHOJI ET AL.: "Nijigen Shusekika ni yoru Centimeter Scale no Tankesshojo Bunshi Usumaku no Keisei", FUCHI KENKYUSHO-KAN ALLIANCE 'JISEDAI ELECTRONICS' GROUP (G1) BUNKAKAI (YAMAGATA UNIVERSITY JOINT SYMPOSIUM, 5 August 2013 (2013-08-05), pages 78
MARKETA RYBACKOVA ET AL.: "Synthesis of Highly Symmetrical Triptycene Tetra- and Hexacarboxylates", SYNTHESIS, vol. 10, 2007, pages 1554 - 1558
MIRIAM E. ROGERS ET AL.: "Symmetrically Trisubstituted Triptycenes", J. ORG. CHEM., vol. 51, no. 17, 1986, pages 3308 - 3314
HELMUT QUAST ET AL.: "ESR-spektroskopischer Nachweis intramolekularer Wechselwirkungen in Radikalkationen von Poly(a-methoxy)triptycenen", CHEMISCHE BERICHTE, vol. 119, no. 3, 1986, pages 1016 - 1038
GLEN A. RUSSE LL ET AL.: "Radical Anions of Triptycene Bis- and Tris (quinones)", J. AM. CHEM. SOC., vol. 103, no. 6, 1981, pages 1560 - 1561
JINXUAN LIU ET AL.: "Deposition of Metal-Organic Frameworks by Liquid-Phase Epitaxy: The Influence of Substrate Functional Group Density on Film Orientation", MATERIALS, vol. 5, 2012, pages 1581 - 1592
DANIEL ORRIN HUTCHINS ET AL.: "Effects of self- assembled monolayer structural order, surface homogeneity and surface energy on pentacene morphology and thin film transistor device performance", JOURNAL OF MATERIALS CHEMISTRY C: MATERIALS FOR OPTICAL AND ELECTRONIC DEVICES, vol. 1, no. 1, 2013, pages 101 - 113
ADAM J. WOLPAW ET AL.: "Synthesis of self- orienting triptycene adsorbates for STM investigations", TETRAHEDRON LETTERS, vol. 44, no. 41, 2003, pages 7613 - 7615
AKITO NISHINAKA ET AL.: "Janus-gata Triptycene o Platform to suru Denshi Oyobi Hikari Kassei Kinodan no Ko Mitsudo Shusekika", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY POSTER BUNSHO, 19 September 2012 (2012-09-19)
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Design", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY YOSHISHU, 5 September 2012 (2012-09-05)
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Design", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY POSTER BUNSHO, 19 September 2012 (2012-09-19)
YOSHIAKI SHOJI ET AL.: "Janus-gata Triptycene: Kinodan no Seimitsu katsu Ko Mitsudo Shusekika o Kano ni suru Han'yosei Bunshi Platform no Kaihatsu", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY YOSHISHU, 5 September 2012 (2012-09-05), pages 30 - 31
YOSHIAKI SHOJI ET AL.: "Janus-gata Triptycene: Kinodan no Seimitsu katsu Ko Mitsudo Shusekika o Kano ni suru Han'yosei Bunshi Platform no Kaihatsu", DAI 23 KAI SYMPOSIUM ON PHYSICAL ORGANIC CHEMISTRY KOTO HAPPYO BUNSHO, 19 September 2012 (2012-09-19)
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Kaihatsu", CSJ: THE CHEMICAL SOCIETY OF JAPAN SHUKI JIGYO, DAI 2 KAI CSJ KAGAKU FESTA 2012 PROGRAM ยท KOEN YOKOSHU, 26 September 2012 (2012-09-26), pages 266
NORIYA SHIMIZU ET AL.: "Nijigen Bunshi Shusekitai no Kochiku e Muketa Janus-gata Triptycene Yudotai no Kaihatsu", CSJ: THE CHEMICAL SOCIETY OF JAPAN SHUKI JIGYO, DAI 2 KAI CSJ KAGAKU FESTA 2012 POSTER BUNSHO, 16 October 2012 (2012-10-16)
TAKANORI FUKUSHIMA ET AL.: "Nijigen Shusekikano o Yusuru Bunshi Building Block no Kaihatsu", FUCHI KENKYUSHO-KAN ALLIANCE 'JISEDAI ELECTRONICS' GROUP (G1) BUNKAKAI (YAMAGATA UNIVERSITY JOINT SYMOPSIUM, 5 August 2013 (2013-08-05), pages 32
YOSHIAKI SHOJI ET AL.: "Nijigen Shusekika ni yoru Centimeter Scale no Tankesshojo Bunshi Usumaku no Keisei", FUCHI KENKYUSHO-KAN ALLIANCE 'JISEDAI ELECTRONICS' GROUP (G1) BUNKAKAI (YAMAGATA UNIVERSITY JOINT SYMPOSIUM, 5 August 2013 (2013-08-05), pages 78
MARKETA RYBACKOVA ET AL.: "Synthesis of Highly Symmetrical Triptycene Tetra- and Hexacarboxylates", SYNTHESIS, vol. 10, 2007, pages 1554 - 1558
MIRIAM E. ROGERS ET AL.: "Symmetrically Trisubstituted Triptycenes", J. ORG. CHEM., vol. 51, no. 17, 1986, pages 3308 - 3314
HELMUT QUAST ET AL.: "ESR-spektroskopischer Nachweis intramolekularer Wechselwirkungen in Radikalkationen von Poly(a-methoxy)triptycenen", CHEMISCHE BERICHTE, vol. 119, no. 3, 1986, pages 1016 - 1038
GLEN A. RUSSE LL ET AL.: "Radical Anions of Triptycene Bis- and Tris (quinones)", J. AM. CHEM. SOC., vol. 103, no. 6, 1981, pages 1560 - 1561
JINXUAN LIU ET AL.: "Deposition of Metal-Organic Frameworks by Liquid-Phase Epitaxy: The Influence of Substrate Functional Group Density on Film Orientation", MATERIALS, vol. 5, 2012, pages 1581 - 1592
DANIEL ORRIN HUTCHINS ET AL.: "Effects of self- assembled monolayer structural order, surface homogeneity and surface energy on pentacene morphology and thin film transistor device performance", JOURNAL OF MATERIALS CHEMISTRY C: MATERIALS FOR OPTICAL AND ELECTRONIC DEVICES, vol. 1, no. 1, 2013, pages 101 - 113
ADAM J. WOLPAW ET AL.: "Synthesis of self- orienting triptycene adsorbates for STM investigations", TETRAHEDRON LETTERS, vol. 44, no. 41, 2003, pages 7613 - 7615
Attorney, Agent or Firm:
SAEKI, NORIO (JP)
Norio Saeki (JP)
Norio Saeki (JP)
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