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Title:
UNSATURATED (METH)ACRYLATE ESTERS CONTAINING EPOXIDIZED CYCLIC GROUP AND PROCESS FOR PREPARING THEM
Document Type and Number:
WIPO Patent Application WO1998028286
Kind Code:
A3
Abstract:
Process of making compounds of the formula wherein R1=(C1-C6) alkyl; X=O, S, NH; R2=divalent saturated organic group; Y=O, S, NH, ester; R3=cyclic moiety containing oxirane group; comprising reacting a compound of the formula wherein R4 is a cyclic moiety containing C=C group with hydrogen peroxide in the presence of (a) tungstic acid, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst; polymers of compounds of formula I; and compounds of formula I except for compounds wherein R4 is a dicyclopentenyl epoxide, Y is O, R2 is -CH2CH2-, X is O, and R1 is H or methyl.

Inventors:
CESKA GARY W (US)
FAN MINGXIN (US)
HORGAN JAMES (US)
Application Number:
PCT/EP1997/007286
Publication Date:
August 13, 1998
Filing Date:
December 22, 1997
Export Citation:
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Assignee:
SARTOMER CO INC (US)
CRAY VALLEY SA (FR)
CESKA GARY W (US)
FAN MINGXIN (US)
HORGAN JAMES (US)
International Classes:
B01J31/24; B01J31/34; C07D301/12; C07D303/16; C07D303/24; C07D303/40; C08F20/32; C08G59/24
Domestic Patent References:
WO1995031512A11995-11-23
WO1995000560A11995-01-05
Foreign References:
DE1418698A11968-10-10
US3230202A1966-01-18
EP0479166A11992-04-08
EP0468840A21992-01-29
DE3602254A11987-07-30
EP0109273A11984-05-23
EP0434546A11991-06-26
DE3916035A11989-11-30
EP0604364A21994-06-29
EP0733637A11996-09-25
EP0735066A21996-10-02
EP0392029A11990-10-17
Other References:
DATABASE WPI Week 9023, Derwent World Patents Index; AN 90-174259, XP002066023
DATABASE CHEM. ABS. REGISTRY American Chemical Society; XP002066022
CHEMICAL ABSTRACTS, vol. 116, no. 10, 9 March 1992, Columbus, Ohio, US; abstract no. 84740, XP002066020
DATABASE WPI Week 9251, Derwent World Patents Index; AN 92-420422, XP002066024
DATABASE WPI Week 9343, Derwent World Patents Index; AN 93-339772, XP002066025
Y. FORT ET AL., TETRAHEDRON, vol. 48, no. 24, 1992, OXFORD GB, pages 5099 - 5110, XP002066250
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