Title:
USE OF LITHIUM SECONDARY ELECTROCHEMICAL CELLS CONTAINING A BLEND OF A LITHIUM NICKEL OXIDE AND A LITHIUM MANGANESE IRON PHOSPHATE FOR AUTOMOTIVE APPLICATIONS
Document Type and Number:
WIPO Patent Application WO/2021/259991
Kind Code:
A3
Abstract:
The use of a blend of a lithium nickel oxide and a lithium manganese iron phosphate as an active material composition in the cathode of a lithium secondary electrochemical cell for automotive applications, such as hybrid and electric vehicles. This blend allows decreasing the porosity of a lithium manganese iron phosphate-based cathode. It also allows improving the detectability of a gas release in the cell in case of an abnormal operation of the cell. It allows lowering the cell impedance at a low state of charge, typically less than 30 %, and reducing the impedance increase of the cell during the cell lifespan.
Inventors:
TESSIER CÉCILE (FR)
BERNARD PATRICK (FR)
KAMEN NECHEV (US)
MARGEZ CARINE (US)
CHEN XILIN (US)
GOUSSET CÉDRIC (FR)
HERREYRE SYLVIE (FR)
BERNARD PATRICK (FR)
KAMEN NECHEV (US)
MARGEZ CARINE (US)
CHEN XILIN (US)
GOUSSET CÉDRIC (FR)
HERREYRE SYLVIE (FR)
Application Number:
PCT/EP2021/067124
Publication Date:
April 14, 2022
Filing Date:
June 23, 2021
Export Citation:
Assignee:
ACCUMULATEURS FIXES (FR)
International Classes:
H01M4/36; H01M4/131; H01M4/136; H01M4/525; H01M4/58; H01M4/02
Foreign References:
| FR3036538A1 | 2016-11-25 | |||
| EP2357693A1 | 2011-08-17 | |||
| US20140138591A1 | 2014-05-22 | |||
| US20160149205A1 | 2016-05-26 | |||
| US20150017499A1 | 2015-01-15 | |||
| US20160315355A1 | 2016-10-27 | |||
| US20150333323A1 | 2015-11-19 |
Other References:
HEUBNER C. ET AL: "Recent insights into the electrochemical behavior of blended lithium insertion cathodes: A review", ELECTROCHIMICA ACTA, vol. 269, 2 March 2018 (2018-03-02), AMSTERDAM, NL, pages 745 - 760, XP055803661, ISSN: 0013-4686, DOI: 10.1016/j.electacta.2018.02.165
LEE JEONG-SEON ET AL: "Blended cathode materials for all-solid-state Li-ion batteries", JOURNAL OF ALLOYS AND COMPOUNDS, vol. 781, 7 December 2018 (2018-12-07), pages 553 - 559, XP085591513, ISSN: 0925-8388, DOI: 10.1016/J.JALLCOM.2018.12.025
SUN GUIYAN ET AL: "Synergistic Effect between LiNi 0.5 Co 0.2 Mn 0.3 O 2 and LiFe 0.15 Mn 0.85 PO 4 /C on Rate and Thermal Performance for Lithium Ion Batteries", APPLIED MATERIALS & INTERFACES, vol. 10, no. 19, 24 April 2018 (2018-04-24), US, pages 16458 - 16466, XP055897627, ISSN: 1944-8244, DOI: 10.1021/acsami.8b02102
ZHAO XINXIN ET AL: "LiNi 0.5 Co 0.2 Mn 0.3 O 2 -LiMn 0.6 Fe 0.4 PO 4 Mixture with Both Excellent Electrochemical Performance and Low Cost as Cathode Material for Power Lithium Ion Batteries", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 165, no. 2, January 2018 (2018-01-01), pages A142 - A148, XP055897273, ISSN: 0013-4651, DOI: 10.1149/2.0431802jes
QIN WANG ET AL: "A facile method of improving the high rate cycling performance of LiNi1/3Co1/3Mn1/3O2cathode material", JOURNAL OF ALLOYS AND COMPOUNDS, ELSEVIER SEQUOIA, LAUSANNE, CH, vol. 686, 25 November 2016 (2016-11-25), pages 267 - 272, XP029701859, ISSN: 0925-8388, DOI: 10.1016/J.JALLCOM.2016.06.017
LEE JEONG-SEON ET AL: "Blended cathode materials for all-solid-state Li-ion batteries", JOURNAL OF ALLOYS AND COMPOUNDS, vol. 781, 7 December 2018 (2018-12-07), pages 553 - 559, XP085591513, ISSN: 0925-8388, DOI: 10.1016/J.JALLCOM.2018.12.025
SUN GUIYAN ET AL: "Synergistic Effect between LiNi 0.5 Co 0.2 Mn 0.3 O 2 and LiFe 0.15 Mn 0.85 PO 4 /C on Rate and Thermal Performance for Lithium Ion Batteries", APPLIED MATERIALS & INTERFACES, vol. 10, no. 19, 24 April 2018 (2018-04-24), US, pages 16458 - 16466, XP055897627, ISSN: 1944-8244, DOI: 10.1021/acsami.8b02102
ZHAO XINXIN ET AL: "LiNi 0.5 Co 0.2 Mn 0.3 O 2 -LiMn 0.6 Fe 0.4 PO 4 Mixture with Both Excellent Electrochemical Performance and Low Cost as Cathode Material for Power Lithium Ion Batteries", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 165, no. 2, January 2018 (2018-01-01), pages A142 - A148, XP055897273, ISSN: 0013-4651, DOI: 10.1149/2.0431802jes
QIN WANG ET AL: "A facile method of improving the high rate cycling performance of LiNi1/3Co1/3Mn1/3O2cathode material", JOURNAL OF ALLOYS AND COMPOUNDS, ELSEVIER SEQUOIA, LAUSANNE, CH, vol. 686, 25 November 2016 (2016-11-25), pages 267 - 272, XP029701859, ISSN: 0925-8388, DOI: 10.1016/J.JALLCOM.2016.06.017
Attorney, Agent or Firm:
HIRSCH & ASSOCIES (FR)
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