USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS

WIPO Patent Application WO2002088289

A3

Use of metal complex compounds of formula (1): [L>nmp<]?z>Yq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18 alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl;-N(R13)-NR'13R"13 wherein R13, R'13 and R"13 are as defined above for R13; -NR14R15 or -N<+>R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

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SCHLINGLOFF GUNTHER (CH)
WIEPRECHT TORSTEN (DE)
BACHMANN FRANK (DE)
DANNACHER JOSEPH (CH)
DUBS MARIE-JOSEE (FR)
HAZENKAMP MENNO (CH)
RICHTER GRIT (DE)
SCHMIDT BRIGITTE (DE)
SCHNEIDER ALBERT (DE)
WEINGARTNER PETER (CH)

PCT/EP2002/004572

February 27, 2003

April 25, 2002

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CIBA SC HOLDING AG (CH)
SCHLINGLOFF GUNTHER (CH)
WIEPRECHT TORSTEN (DE)
BACHMANN FRANK (DE)
DANNACHER JOSEPH (CH)
DUBS MARIE-JOSEE (FR)
HAZENKAMP MENNO (CH)
RICHTER GRIT (DE)
SCHMIDT BRIGITTE (DE)
SCHNEIDER ALBERT (DE)
WEINGARTNER PETER (CH)

A01N25/00; A01N59/00; B01J31/18; B01J31/22; C07B61/00; C07D213/30; C07D213/61; C07D213/68; C07D213/70; C07D213/74; C07D213/53; C07D213/77; C07D301/12; C07F1/08; C07F7/28; C07F13/00; C07F15/02; C07F15/04; C07F15/06; C11D3/39; C11D3/395; D06L3/02; D06L4/10; D06L4/12; D06P5/02; D06P5/15; D21C9/10; D21C9/16; B01J23/34; (IPC1-7): C11D3/39; B01J31/18; D21C9/10; D21C9/16; C07D213/70; C07D213/61; C07D213/77; C07D213/74; C07D213/30; C07D301/12; C07F13/00

WO2001046368A2	2001-06-28
WO1999056699A2	1999-11-11
WO1991019730A1	1991-12-26
WO2000066536A1	2000-11-09

FR2677766A1	1992-12-18
US4960895A	1990-10-02
EP0867428A1	1998-09-30
DE4316180A1	1994-11-17

DATABASE CROSSFIRE BEILSTEIN BEILSTEIN INSTITUT ZUR FOERDERUNG DER CHEMISCHEN WISSENSCHAFTEN, FRANKFURT AM MAIN, DE; 7 March 2000 (2000-03-07), LOWE ET AL., XP002221615
DATABASE CROSSFIRE BEILSTEIN BEILSTEIN INSTITUT ZUR FOERDERUNG DER CHEMISCHEN WISSENSCHAFTEN, FRANKFURT AM MAIN, DE; 23 October 1991 (1991-10-23), CONSTABLE ET AL., XP002221616
DATABASE CROSSFIRE BEILSTEIN BEILSTEIN INSTITUT ZUR FOERDERUNG DER CHEMISCHEN WISSENSCHAFTEN, FRANKFURT AM MAIN, DE; 15 July 1998 (1998-07-15), CHERNEGA ET AL., XP002221617
DATABASE CROSSFIRE BEILSTEIN BEILSTEIN INSTITUT ZUR FOERDERUNG DER CHEMISCHEN WISSENSCHAFTEN, FRANKFURT AM MAIN, DE; 7 March 2000 (2000-03-07), LOWE ET AL., XP002221618
DATABASE CROSSFIRE BEILSTEIN BEILSTEIN INSTITUT ZUR FOERDERUNG DER CHEMISCHEN WISSENSCHAFTEN, FRANKFURT AM MAIN, DE; 7 March 2000 (2000-03-07), LOWE ET AL., XP002221619

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