Technical Field

The invention relates to a biopolymeric composite disinfectant composition supported with flower shaped silver - plant hydrosol hybrid nanoparticles.

The invention relates in particular to a biopolymer supported vegan and ecological disinfectant composition comprising flower shaped silver plant hydrosol hybrid nanoparticles and production method thereof in providing personal hygiene in the general and public areas with the health sector being in the first place, in the process of making personal and medical textile and glass products antimicrobially effective. The invention relates to disinfectant substance obtained by bringing together biopolymer of herbal origin and herbal synthesis silver hybrid nanoparticles in its composition.

Prior Art

Currently used hygienic formulations comprise totally synthetic origined, toxic, chemical substances harmful to human and environmental health. This kind of synthetic chemicals adversely affect human and environmental health. In the existing formulations, quaternary ammonium compounds, chlorhexidine, iodine compounds or alcohol based iodine, iodophores, para - chloro - metha - xylenol (PCMX), hexachlorophene and octenidin dihydrochloride, chlorine derivatives, etc. are used in providing antimicrobial efficacy.

As a result of this, the developed products cause respiratory toxicity and sensitivity on the skin, allergy and irritation. The fact that skin protective, softener and humidifiers added to the formulations in order to overcome this problem are synthetic chemicals threatens human health in an increasing manner.

In prior art, in the compositions which are being used as nanotechnological disinfectants, silver (Ag) nanoparticles obtained by chemical or physical synthesis are being used to stabilizer the active matter. Stability issues emerge in prior art because of the chemical and physical methods used in reducing silver to nanosize In this case, since the desired antimicrobial efficacy cannot be provided only by the active matter composed of silver, a chemical and potent active matter is being added to the composition with silver being used as the stabilizer. Therefore, silver directly being the active matter is avoided. Chemical reduction by using organic solvent or water is the most common technique in the production of silver nanoparticles (AgNPs). As reducing agent, generally boron hydride (borohydride), sodium dodecyl sulfate, sodium citrate, ascorbate polyols, NaBH4, N2H4 and N, N - dimethylformamide are used. In the end, colloidal silver subjected to chemical processing and diameter thereof reduced to nano level is being obtained. A great majority of chemical reducing reactions require high heat shock application. For obtaining chemical Ag ⁺ in thermal way, m - hydroxyl benzaldehyde (m - hydroxy benzaldehyde), hydrazine and dextrose are used together as the reducing agent. Therefore, morphology of the nanoparticles is effected by the value of temperature applied during the synthesis. Furthermore, sodium formaldehyde sulfoxylate is being used too as the secondary reducing agent. And in another method, glucose and gluconic acid are being used. Among the alternative methods, method of subjecting to X - ray radiation in which ethylene glycol - water mixture is used can be mentioned. In this method, nanoparticles are obtained by using UV rays. Especially for the synthesis of factory - made silver nanoparticles, pyrolysis technique too implemented at high temperature and pressure in furnaces set at 720 C is another known method. For this method Ag / Mg O mixture is needed, and in the final stage ammonium chloride (NH4CI) solution is used to remove the MgO.

For example, in application number EP2309863B1 , the concentrate to prepare the disinfectant and methods for manufacturing thereof are disclosed. The invention relates to an aqueous concentrate which will be stable during storage, and is for preparing a disinfectant. The concentrate comprises the following: hydrogen peroxide at a concentration between 30 % and 70 % by volume of the final concentrate; colloidal silver at a concentration between 150 and 1000 ppm by weight of the final concentration; a stabilizer selected from the group consisting of gum arabic, gelatine, guar gum, carrageenan, pectin and combinations thereof; the concentration of the stabilizer is between 10 and 100 ppm by weight of the final concentrate; and phosphoric acid to adjust the pH value of the concentrate at 3 or lower. And in application number EP3184492B1 , the invention falls among the antiseptic formulations including the disinfectants targeted to disinfection of water for health and hygiene; and for disinfection of water especially in swimming pools and in other artificial reservoirs; for health and hygienic purification of rooms, household equipment, furniture, home appliances and industrial devices and also rinse and waste water. An antiseptic formulation encompasses both silver and also particles of very small size encompassing silver chloride. An antiseptic formulation can encompass additionally at least one amphoteric surfactant. In order for disinfection of water to be implemented, very small sized particles encompassing silver and silver chloride are added into the water at least once.

And in national patent application number TR2016 I 20278, a solution comprising colloidal silver is disclosed. This invention relates in general to a kind of water which has been developed for the purpose of elimination of ailments such as healing of wounds, skin beauty (anti aging), disinfectant, elimination of pathogens in the body and comprising colloidal silver which offers advantages while not harming useful bacteria with respect to synthetic antibiotics.

Consequently, in compositions produced by the known methods, there are silver nanoparticles obtained by one or a few of the techniques explained above. Also, in the existing methods, it is necessary to add the surfactant to the medium during chemical synthesis silver for the stabilization of nanoparticles. Conversely, in the existing methods it has been determined that silver alone cannot provide the desired antimicrobial effect. Therefore, in the existing methods, as active matter, chemical substances (such as benzalconium chloride, Hydrogen peroxide, Alcohol, Chlorhexydine digluconate) are selected to be used as silver stabilizer. The compositions of the existing methods have been supported with substances of synthetic or chemical origin which could be risky as far as human and environmental health are concerned. Furthermore, the cost of silver nanoparticles with chemical synthesis depending on the chemical required for the application, in other words energy requirement varies. Time spent in the processes is long. In the composition of the invention, the requirement for additional chemicals has been eliminated since silver is present as the sole and effective active matter, in has been obtained by herbal synthesis, and being supported with biopolymers of herbal origin. In the existing products used for space and vehicle odor, attaining the odor, and chemicals such as Tween 20, Tween 80 used in the ingredient during uniform distribution and remaining stable are harmful to human health.

Also, in the existing products comprising silver, yellow, brown, black staining is being observed on the applied surfaces. It has been necessary to perform an improvement in the related technical field due to the negativities narrated above and because of the inadequacy of existing solutions on the subject.

Brief Description of the invention

The present invention relates to a herbal synthesis flower shaped silver nanostructured biopolymer supported disinfectant composition and its method of production which meet the above mentioned requirements, which eliminate all disadvantages and which offer some additional advantages.

The prioritized object of the invention is to provide solution to eliminate the problems which will adversely affect the human and environmental health in use according to the formulations with chemical matter content that are used in the existing technique since in the composition of the invention herbal synthesis flower shaped silver nanoparticles are supported with biopolymers. In order to provide this solution, the mixture consisting of silver, distilled water, hydrosols of rose, lavender, jasmine, cherry flower, laurel, peppermint, olibanum plants, and L - lactic acid as the pH adjuster, cellulose and starch as herbal polymer have been used in the invention.

Another object of invention is to set forth that chemical substances are not required to be used as reducers and stabilizers as in the prior art thanks to the sufficiency of the usage of plant hydrosols in obtaining the nanoparticles.

Another object of invention is to reduce production cost and energy requirements in the elimination of pathogen microbes from the environment by the composition of the invention with herbal synthesis, and to facilitate production stages. By the use of plant hydrosols, the surface area of the hybrid structure comprising flower shaped silver nanoparticles and high antimicrobial efficacy against gram positive and gram negative bacteria is being provided. Another object of invention is to reduce production costs by the use of pure extracts obtained from plants in the composition as odor agent; it has been provided to make aromatizing harmless in terms of human health.

Another object of invention is to set forth that chemicals such as Tween - 20 are not required for the uniform distribution and stability of the agents which odorise the composition.

Another object of invention is to provide to offer distinctive good odor to the composition and to obtain disinfectants of different odors other than the contribution to flower shaped hybrid nanostructure synthesis by the use of rose, lavender, jasmine, cherry flower, laurel, and peppermint olibanum.

Another object of invention is to set forth a disinfectant composition which does not harm the respiratory system and which does not cause allergy on the skin thanks to obtaining flower shaped silver nanoparticles hybrid structure with herbal synthesis. It can be applied to all kinds of environments in which the human being is in touch with, and it is environmentally friendly.

Another object of invention is to provide effective adsorption without requiring one or more chemical binders in antibacterial textile and glass products by the biopolymer supported structure of the flower shaped silver nanohybrid structure.

Another object of invention is to enable antibacterial textile and glass products to possess high wash resistance.

Another object of invention is to set forth a disinfectant which can be applied in different ways such as spraying, immersion, direct application to the surface by means of reducing the pure silver used to nanosize, and which does not leave stains on the surface. The fact that nitrate form of silver is being used in the nanosilver compositions of the prior art causes leaving stains on the surface over which the final product has been applied.

Another object of invention is to set forth that an environmentally friendly method energy requirements of which has been reduced by the use of organic acids can be utilized when obtaining aqueous solution from the silver used in 999.9 purity.

In order to achieve the objects mentioned above, the invention is a herbal biopolymeric a disinfectant composition produced from rice husk and sunflower pomace having herbal synthesis, flower shaped silver hybrid nanostructure; and it comprises individuals or combinations selected from the group comprising Hydrosol comprising Lavender - Olibanum, Hydrosol comprising Rose - Olibanum, Hydrosol comprising Jasmine - Olibanum, Hydrosols comprising Cherry flower - Olibanum, Hydrosol comprising Laurel - Olibanum, Hydrosol comprising Peppermint - Olibanum; L - lactic acid, Biopolymer, Silver, Distilled water, preferably at least one odor agent. The odor agent mentioned here is individuals or combinations selected from the group comprising rose, lavender, jasmine, cherry flower, laurel, peppermint hydrosols.

According to one embodiment of the invention, individuals or combinations selected from the group comprising Hydrosol comprising Lavender - Olibanum, Hydrosol comprising Rose - Olibanum, Hydrosol comprising Jasmine - Olibanum, Hydrosol comprising Cherry flower - Olibanum, Hydrosol comprising Laurel - Olibanum, Hydrosol comprising Peppermint - Olibanum 3.2 - 3.5 % by weight comprise L - lactic acid 1 .5 - 2.5 % by weight; Biopolymer 3.3 - 3.7 % by weight; Silver 0.037 - 0.052 % by weight; Distilled water 66 - 84 % by weight; odor agent 7.7 - 24 % by weight.

According to one embodiment of the invention, individuals or combinations selected from the group comprising Hydrosol comprising Lavender - Olibanum, Hydrosol comprising Rose - Olibanum, Hydrosol comprising Jasmine - Olibanum, Hydrosol comprising Cherry flower - Olibanum, Hydrosol comprising Laurel - Olibanum, Hydrosol comprising Peppermint - Olibanum 3.45 % by weight comprise L - lactic acid 2 % by weight, 3.5 % Biopolymer by weight, 0.050 % Silver, Distilled water 81 % by weight, Odor agent 10 % by weight.

In order to accomplish the above mentioned objects, the invention relates to a disinfectant composition production method comprising Herbal synthesis, flower shaped silver hybrid nanostructured herbal biopolymer; and comprises the process steps of :

Obtaining hydrosols by brewing rose, lavender, jasmine, cherry flower, laurel, peppermint plants separately,

Preparation of the solution with pure silver, acetic acid and hydrogen peroxide, Obtaining the combined plant hydrosolin PBS by adding one of Rose, lavender, jasmine, cherry flower, laurel, peppermint plants in an amount equal to Olibanum plant,

Synthesizing flower shaped organic - inorganic hybrid nanostructure by adding silver solution to PBS and plant hydrosols,

Obtaining starch as the biopolymer raw material from rice and its husks,

Obtaining biopolymer raw material cellulose from sunflower stem and face pomace,

Providing Herbal Biopolymer synthesis,

Combining the obtained flower shaped silver hybrid nanostructures and herbal biopolymer, adding preferably at least one odor agent, distilled water as solvent, adjusting the pH to the range of 3 to 6 by L - lactic acid.

Structural and characteristic features of the invention and all of its advantages will be understood more clearly by means of the detailed description given below and therefore it should be appreciated by considering this detailed description.

Brief Description of Figures

Figure 1 is the SEM view of the flower shaped nanohybrid structure.

Detailed Description of the Invention

In this detailed description, disinfectant composition of the invention and production method thereof are described aimed at only better understanding of the subject and without forming any limiting effects.

The invention relates to a biopolymeric composite disinfectant composition and production method thereof supported with herbal synthesis flower shaped silver hybrid nanoparticles.

The disinfectant composition of the invention in its most fundamental form comprises individuals or combinations selected from the group comprising rose leaves, lavender flower and leaves, jasmine flower and leaves, cherry flower, laurel leaves, peppermint leaves and stem, olibanum resin hydrosols, and herbal biopolymer supported with silver nanoparticles, and distilled water. The content of the disinfectant composition of the invention is given in Table 1 . Table"! . The content of the disinfectant composition of the invention

Rose Plant (Rosa damascena) is known by its antiseptic property, it is used in wound and skin cleansing. It is frequently used in inflammatory diseases with mouth and throat wound being in the first place. Recently, it is among the most preferred products in skin care. In the composition of the invention, synthesis of organic - inorganic hybrid nanostructure is being provided by the use of high quality pure rose water which is liberated by the extraction of rose leaves. Ingredients in the leaves of rose such as geraniol, citronella are being used in reducing silver to nanosize and in obtaining organic - inorganic flower shaped hybrid structure. Also, a pleasant odor is obtained in the composition by the use of rose water in the specified ratio.

Lavender plant extract (Lavandula angustifolia) has the features of reducing stress and anxiety, eliminating nervousness, alleviating pain, disinfecting head skin and the skin, preventing acne, increasing blood circulation. It is good for dermal problems such as eczema, acne. Synthesis of organic - inorganic hybrid nanostructure is being provided by the use of high quality pure lavender water which is liberated by the extraction of lavender leaves. Also, a pleasant odor is obtained in the composition by the use of lavender water in the specified ratio.

Jasmine (Jasminum officinale L.) flower is used in the treatment of influenza and common cold by means of the antiviral and anti bacterial feature it includes. Synthesis of organic - inorganic hybrid nanostructure is being provided by the use of high quality pure jasmine water which is obtained from jasmine flower. Also, a pleasant odor is obtained in the composition by the use of jasmine flower water in the specified ratio.

Cherry flower (Prunes serrulata) aids in nourishing and protecting the skin by means of its vitamin E content. Synthesis of organic - inorganic hybrid nanostructure is being provided by the use of high quality pure cherry flower water which is obtained from cherry flower. Also, a pleasant odor is obtained in the composition by the use of cherry flower water in the specified ratio.

Laurel leaf extract (Laurus nobilis) has antiseptic and antiviral effect, and it has wound healing effect. Synthesis of organic - inorganic hybrid nanostructure is being provided by the use of high quality extract which is obtained from laurel leaves. Also, a pleasant odor is obtained in the composition by the use of laurel leaf hydrosol in the specified ratio.

Peppermint leaves and stem (Mentha piperita) include rosmarinic acid which is a structure effective against infections, it has been used in the composition for obtaining flower shaped hybrid nanostructure and as odor agent. The peppermint kind used in the composition is known to be effective in hepatic disease viruses such as HSV - 1 and HSV - 2 because of the high ratio of menthol it comprises. Olibanum (Boswellia carterii) resin comprises ester and acidic ingredients, and its antimicrobial feature is high. In the composition of the invention, it provides obtaining flower shaped organic - inorganic hybrid structure by being combined plant hydrosols the ratios given in the table.

Silver is commonly used in photography industry, electronics, coin manufacturing, making ornaments and jewelleries, alloys, dentistry. It is also being used in artificial raining, in making mirror taints, computer relay contacts, in making cells. Pure silver (999.9) is also used in obtaining acetic acid, paints and photography substances. Likewise, silver in powder form is being used in new ceramic type coating to make glass and wood electrically conductive.

Silver is a very powerful antibacterial, and it has very little toxic effect. For this purpose, it is used excessively in the field of medicine and textile.

The disinfectant composition of the invention production method in its most fundamental form comprises the following process steps; i. preparation of solution with pure silver, acetic acid and hydrogen peroxide, ii. Obtaining plant hydrosol by adding one of Olibanum (Boswellia carterii) and Rose (Rosa damascena), lavender (Lavandula angustifolia), jasmine (Jasminum officinale L.), cherry flower (Prunes serrulata), laurel (Laurus nobilis), peppermint (Mentha piperita) plants into PBS (phosphate buffered solution) which has been prepared in suitable concentration, iii. Mixing silver solution prepared in process step number “i” to the solution prepared in process step number “ii”, iv. Obtaining starch to be used in obtaining biopolymer from rice and its husk, v. Obtaining cellulose to be used in obtaining biopolymer from sunflower face and stem pomace, vi. Combining the substances prepared in process steps number “iv” and “v” with the mixture obtained in process step number (iii), vii. Obtaining hydrosols of individuals selected from Rose (Rosa damascena), lavender (Lavandula angustifolia), jasmine (Jasminum officinale L.), cherry flower (Prunes serrulata), laurel (Laurus nobilis), peppermint (Mentha piperita) plants separately in distilled water, viii. Addition of one of the individuals selected from plants obtained in process step number (viii) to the biopolymeric mixture prepared in process step number “vii” and mixing the same, ix. Completion of volume of the mixture obtained in process step number “viii” to the desired amount with distilled water and adjusting the pH to 3 - 6 with L - Lactic acid.

In the preparation of a preferred embodiment of the invention, 1 number of lightproof glass bottle having a lid and septum and 1 1 numbers of lightproof glass bottle having a lid are used.

450 - 550 grams of Rose plant are put in glass bottle number 1 , 500 - 700 grams of ice are added over it and mixed in a magnetic mixer continuously at 100 - 150 rpm. When the ice melts completely, it is mixed for 30 - 40 minutes at 55 - 65 ‘C at 100 - 150 rpm by increasing its heat slowly in the magnetic mixer, it is treated in the ultrasonic device for 10 - 15 minutes. At the end of the period of time, it is centrifuged at 4000 - 5000 rpm for 20 minutes. The obtained Rose hydrosol is stored at + 4 ID.

450 - 550 grams of Lavender plant are put in glass bottle number 2, 400 - 500 grams of ice are added over it and mixed in a magnetic mixer continuously at 100 - 150 rpm. When the ice melts completely, it is mixed for 30 - 40 minutes at 55 - 65 ‘C at 100 - 150 rpm by increasing its heat slowly in the magnetic mixer, it is treated in the ultrasonic device for 10 - 15 minutes. At the end of the period of time, it is centrifuged at 4000 - 5000 rpm for 20 minutes. The obtained Lavender hydrosol is stored at + 4 ID.

450 - 550 grams of Jasmine plant are put in glass bottle number 3, 800 - 1000 ml of distilled water are added over it and it is brewed at 55 - 65 <C at 100 - 150 rpm for 30 - 35 minutes, and it is treated in the ultrasonic device for 10 - 15 minutes. At the end of the period of time, it is centrifuged at 4000 - 5000 rpm for 20 minutes. The obtained hydrosol is stored at + 4 ID.

400 - 500 grams of Cherry flower are put in glass bottle number 4, 800 - 1000 ml of distilled water are added over it and brewed in a magnetic mixer at 65 - 70 ‘C at 100 - 150 rpm for 30 - 40 minutes, at the end of the period of time it is treated in the ultrasonic device at 30 <0 for 10 - 15 minutes. At the end of the period of time, it is centrifuged at 4000 - 5000 rpm for 20 minutes. The obtained hydrosol is stored at + 4 3.

400 - 500 grams of Laurel leaves are put in glass bottle number 5, 800 - 1000 ml of distilled water are added over it and brewed in a magnetic mixer at 70 - 80 <0 at 100

- 150 rpm for 30 - 40 minutes, at the end of the period of time it is treated in the ultrasonic device at 30 <0 for 10 - 15 minutes. At the end of the period of time, it is centrifuged at 4000 - 5000 rpm for 20 minutes. The obtained hydrosol is stored at + 4 T .

400 - 500 grams of Peppermint leaves are put in glass bottle number 6, 600 - 800 ml of distilled water are added over it and brewed in a magnetic mixer at 70 - 80 D at 100 - 150 rpm for 30 - 40 minutes, at the end of the period of time it is treated in the ultrasonic device at 30 <0 for 10 - 15 minutes. At the end of the period of time, it is centrifuged at 4000 - 5000 rpm for 20 minutes. The obtained hydrosol is stored at + 4 <0.

Pure silver granules (solid) in the ratio of 5 - 7 grams by weight are weighed into lightproof glass bottle number 7 having a lid and septum, and treated with equal ratios of acetic acid and hydrogen peroxide for 3 - 5 minutes; its volume is completed to 1000 ml with distilled water.

Into glass bottle number 8 having a lid, 200 - 300 ml of PBS solution at pH=7.4 are admitted, 10 - 15 grams of Olibanum plant and one of the Rose (Rosa damascena), lavender (Lavandula angustifolia), jasmine (Jasminum officinale L.), cherry flower (Prunes serrulata), laurel (Laurus nobilis), peppermint (Mentha piperita) plants at equal amount are added, mixed at 40 - 50 O at 80 - 100 rpm and brewed for 30 - 40 minutes, at the end of the period of time the mixture is filtered through filter paper and stored at + 4 <0.

Into bottle number 9 having a lid, solution prepared in bottle number 8 is taken, silver solution in bottle number 7 is added over it in the ratio in the table (0.037 - 0.052 %), vortexed for 10 - 20 seconds and treated in the ultrasonic device for 2 - 5 minutes. Into bottle number 10 having a lid, 50 - 100 grams of washed rice and its husks are put, 3 % citric acid is added over it and it is left at 80 <0 for 40 - 60 minutes. At the end of the period of time it is centrifuged at 4500 - 5500 rpm for 20 - 25 minutes, its pH is adjusted to 7 and stored at + 4 ^< C.

Into glass bottle number 1 1 having a lid, 200 - 400 grams of sunflower stem and face pomace are put, 800 - 1000 ml of distilled water are added over it. It is heated at 80 - 90 <0 at 50 - 70 rpm for 30 - 45 minutes; s mashed with a laboratory type blender for 1 - 3 minutes; left at ultrasonification device for 10 - 15 minutes and stored at + 4 ^< C.

Into bottle number 12; 0.34 grams of the substance in bottle number 1 1 is taken, 1 % citric and 1 % L - lactic acid are added over it, mixed for 20 - 25 minutes; 15 ml of the substance in bottle number 10 are added over it, mixed at 80 - 90 <0 at 200 - 250 rpm for 1 - 2 hours; organic - inorganic nanohybrid structure in bottle number 9 is added to the mixture and mixed for 20 - 30 minutes. Then, one of the plant hydrosols in bottles number 1 , 2, 3, 4, 5 and 6, and distilled water are added at the ratios given in the Table, mixed at 400 - 550 rpm for 20 - 30 minutes. Its pH is adjusted with L - lactic acid. Acetic acid and hydrogen peroxide do not have a role in reducing silver to nanosize in the final product. They have been added only to solubilize granular silver of 999.9 purity. Since desired amount of silver solution prepared as stock is admitted and used, and since both of them are in organic structure and being reduced during the course of the process, acetic acid and hydrogen peroxide do not exist in the final product.

In the method of obtaining the composition of the invention, since all of the reducing, stabilizing agents and polymers are composed of herbal raw materials, the solution of avoiding negative results which can effect human and environmental health according to formulations with synthetic content used in prior art is proposed. In order to provide this solution, individual selected from rose leaves, lavender, jasmine, cherry flower, laurel, peppermint, olibanum plant hydrosols or combinations thereof, and herbal biopolymer, distilled water, L - lactic acid and silver have been used in the invention.

In the method of obtaining the composition of the invention, by the synergistic effect which said plants create; Reducing ionic pure silver to 5 - 10 nm size has been provided;

Maintaining the obtained composition stable for a long time has been provided;

Antimicrobial effect of the composition has been enhanced,

Production time has been shortened,

In imparting antimicrobial feature to textile and glass products performing coating without requiring chemical binder has been provided;

Wash resistance of textile and glass products which have attained antimicrobial feature has been provided.

In the method of obtaining the composition of the invention, by using pure silver;

Active matter with antimicrobial effect has been obtained; (silver CAS No : 7442 - 22 - 4),

Yellow, brown, black staining problem on the applied surfaces has been eliminated.

With the active content of the disinfectant composition of the invention, antibacterial, antiviral and anti fungal effects are provided. Results of the efficacy of the disinfectant composition of the invention are given in Table 1 .

Tablel : Antimicrobial efficacy tests of herbal synthesis flower shaped silver hybrid nanostructure The disinfectant composition of the invention comprises 5 - 10 nm herbal synthesis flower shaped silver hybrid nanostructure, and its BET report output is given as a chart.

Chart 1 : Nanoparticle surface area analysis report (BET)

Summary Report

Surface Area

Single point surface area at P I Po=0.299141472 : 156.2584 m ² 1 g

BET Surface Area : 154.4047 m ² / g

Langmuir Surface Area : 357.7420 m ² 1 g t - Plot External Surface Area : 201 .5669 m ² 1 g

BJH Adsorption cumulative surface area of pores between 17.000 A and 3000.000 A width : 128.913 m ² / g

Pore Volume t - Plot micropore volume : - 0.019883 cm ³ 1 g

BJH Adsorption cumulative volume of pores between 17.000 A and 3000.000 A width : 0.079199 cm ³ 1 g

Pore Size

BJH Adsorption average pore width (4V/A) : 24.574 A

In this manner, the product can be used as broad effect antimicrobial substance for different purposes. Herbal synthesis disinfectant composition of the invention for providing personal hygiene with general and public areas, especially the health sector being in the first place will be used :

• In dentistry and dental hospitals; in the disinfection of implant and prosthesis surfaces, • In social areas; in the disinfection of schools, nurseries, kindergartens, sports halls, hotels, job sites and mosques;

• In the disinfection of mass transportation and private vehicles;

• In homes; in providing hygiene of living areas and personal hygiene,

• In the disinfection of air conditioning and ventilation systems;

• In drug industry; against bacteria resistant to existing antibiotics,

• In food sector; in providing hygiene of packaging and food hygiene,

• In the disinfection of public area floor surfaces;

• In the disinfection of hospital floor surfaces;

• In the disinfection of intensive care room, surgery room, delivery room;

• In the disinfection of medical equipment;

• In the disinfection of public areas such as schools, mosques, municipality buildings, hospitals, subways, buses;

• playgrounds; In the disinfection of areas wherein children are present such as kindergartens, playgrounds, nurseries;

• In the disinfection of military, personal care and public areas;

• animal farms; to provide disinfection of animals and the workers,

• vehicle cleaning; in the cleaning of glasses, in removal of all kinds of dust or dirt on the wheel rim and vehicle surface, in the cleaning of seats in the car and places like ceiling, etc.,

• food packaging and storage; in providing hygiene conditions in food packagings or storage areas;

• personal care; in care products such as wet wipes, diapers, soaps, hand disinfectants, tooth pastes, creams, etc.; - it prevents formation of bacteria which tend to produce in diapers or wet wipes. It prevents decay on the teeth especially when used inside tooth paste and treats the wounds inside the mouth - cosmetics; in the field of cosmetics as an antimicrobial for products such as lipsticks, blushers, eye shadows in which bacteria grow in time depending on the usage;

• in pool hygiene; - it is mentioned by the doctors that chlorous disinfectants trigger some health problems, and increase middle ear ailment especially in children. And in pool disinfection having biological nanoparticles such health problems are not encountered. Also, infectious diseases such as mycosis which are possible to develop in pools do not show up -

• sterile areas; in the sterilization of places such as hospitals and drug production areas;

• airlines; in the disinfection of airplanes, passenger waiting halls, ground services offices;

• In obtaining antimicrobial products in textile and glass industries.

In usage, for floor surface disinfection, sufficient amount of composition is sprayed, distributed to the surface with the aid of a cloth by rubbing, it does not require rinsing. And for environment disinfection, sufficient amount of product is applied by spraying or with the aid of ULV device. The environment can be used a few minutes after the application, it does not require ventilation. For tool and equipment disinfection, the materials are left inside the product which is put into the immersion container, taken out and dried a few minutes later or the product is applied over the tools and equipment in the form of direct spraying and left to dry. Additional chemical binder in textile coatings is not required. It does not require rinsing. The composition of the invention can be applied as needed depending on the microbic load of the environment.