COMPOSITIONS CONTAINING SAME AND THEIR USE

This invention relates to copolymers of vinyl acetate, latex compositions containing such copolymers, elements containing such copolymers and to a method of making such elements.

The use of photographic film supports such as cellulose acetate film in radiation-sensitive elements is well known. Organic solvents which cause photographic film support to swell have been used in coating polymer layers on such supports.

The swelling promotes adhesion between the polymer layer and the support.

There are several disadvantages to using organic solvents in coating polymer layers on photographic film supports. Elaborate and costly machinery is required to prevent escape of organic solvent vapors into the environment. In addition, such solvents are costly, are generally flammable and frequently cause the support to curl. It is possible to control curl, but not without sacrificing coating versatility or expending additional energy.

Organic solven -water mixtures have been considered for use in coating polymer layers on photographic film supports. The use of such solvent mixtures requires recovery procedures for the organic solvents to prevent their escape into the enviroment. The presence of water complicates such recovery.

It is necessary for layers such as subbing layers that are coated on photographic film supports to withstand normal photographic alkaline processing without undergoing significant changes in adhesion or other properties. Also, from an economic

standpoint, it is important for film scrap such as perforations and waste film from manufacturing operations to be capable of conversion back to an uiicoated condition. Such uncoated scrap can then be redissolved and reused in support manufacture.

The use of vinyl acetate copolymers in layers that are used to adhere hydrophilic layers such as gelatin containing layers to photographic film supports is well-known. For example, U.S. Patent 3,615,557, issued October 26, 1971, discloses the use of a tri-component copolymer of vinyl acetate, a lower alkyl acrylate and an unsaturated acid in such an adhesion promoting layer, commonly referred to in the photographic art as a subbing layer. Unfortunately, vinyl acetate copolymers of the type described in U.S. Patent 3,615,557 cannot be easily removed from the photographic film support by conventional alkaline recovery processes.

The problem of this invention is to provide a copolymer that can be easily coated to form a layer on a photographic film support, for example, a subbing layer, that withstands alkaline photographic processing and can be readily removed in a conventional alkaline recovery process. This problem is solved with a copolymer that comprises recurring polymerized units of:

(A) 20 to 85 weight percent vinyl acetate monomer,

(B) 5 to 65 weight percent acrylate or methacrylate monomer,

(C 5 to 50 weight percent methacrylic acid monomer, and (DJ 0.5 to 15 weight percent cationically charged vinyl monomer.

The copolymers of this invention can be prepared and coated in the form of a stable latex composition comprising an aqueous continuous phase having particles of the copolymer dispersed therein. This avoids the use of an organic solvent or an organic solvent-water mixture in coating operations and the disadvantages described previously herein. Furthermore, such latex compositions can be "loaded" with hydrophobic compounds, simply referred to as hydrophobes, by conventional techniques such as those disclosed in U.S. Patents 4,214,047, issued July 22, 1980, and 4,199,363, issued April 22, 1980. In these loaded latex compositions a desired hydrophobe is absorbed in, dissolved in, dispersed in or adsorbed to the copolymer particles of the latex compositions. These loaded latex compositions provide a convenient means for achieving uniform dispersion of a hydrophobe that is normally insoluble in an aqueous medium, within a hydrophilic colloid layer or aqueous medium. This feature of the invention is particularly useful in the photographic art for forming uniform dispersions of hydrophobes such as hydrophobic photographic addenda. From the foregoing description, it is evident that this invention provides a latex composition comprising an aqueous continuous phase having dispersed therein particles of copolymer comprising units (A) - (D) . This invention also provides an element comprising a photographic film support and a layer comprising a copolymer comprising units (A) - (D) .

Further, this invention provides an element comprising a photographic film support, a radiation- sensitive layer and a subbing layer comprising a copolymer comprising units (A; - (D).

C tFI ^'

In addition, this invention provides a method of coating a support with an aqueous latex coating composition comprising dispersed particles of a copolymer comprising units (A) - (D) . The copolymers of this invention are conveniently prepared as a latex by known emulsion polymerization techniques. Such techniques can be used to provide linear addition copolymers comprising random recurring polymerized units (A)-(D). Suitable techniques are disclosed in . P. Sorenson and T. W. Campbell "Preparative Methods of Polymer Chemistry", 2nd Edition, N.Y., N.Y., Wiley (1968) and M. P. Stevens "Polymer Chemistry - an Introduction", Addison-Wesley Publishing Co., Reading, Mass. (1975).

The polymers are conveniently prepared by: a) dissolving a surfactant and a polymerization catalyst in deoxygenated water, b) mixing the solution of a) with a mixture consisting of from 20 to 85 weight percent vinyl acetate monomer, 5 to 65 weight percent acrylate or methacrylate monomer, 5 to 50 weight percent methacyclic acid monomer and 0.5 to 15 weight percent cationically charged vinyl monomer, c) adding a solution of surfactant and polymerization catalyst prepared as in a) to a reaction vessel. d) adjusting the pH of the solution in the reaction vessel to between 3 and 4, e) heating the reaction vessel, f) adding the mixture of b) to the reaction vessel over a period of about 1 hour, g) continuing the reaction for at least 1 more hour, and

h) cooling the reaction vessel and filtering the contents to obtain a latex composition compris¬ ing dispersed particles of copolymer of this invention. Component A of the copolymer of this invention is polymerized vinyl acetate. This polymerized unit comprises 20 to 85, often at least 50 and preferably 50 to 60 weight percent of the copolymer. Monomers useful in forming component B of the copolymer of this invention are acrylate and methacrylate monomers. Polymerized unit B comprises 5 to 65, often 10 to 25 and preferably 15 to 25 weight percent of the copolymer. These monomers are well known organic esters of acrylic or methacrylic acid and are capable of copoly erizing with vinyl acetate. Examples of such acrylates include methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, a yl acrylate, 2-ethylhexyl acrylate, octyl acrylate, t-octyl acrylate, 2-methoxyethyl acrylate, 2-butoxyethyl acrylate, 2-phenoxyethyl acrylate, chloroethyl acrylate, cyanoethyl acrylate, dime hylaminoethyl acrylate, benzyl acrylate, methoxybenzyl acrylate, furfuryl acrylate, tetrahydrofurfuryl acrylate and phenyl acrylate. Examples of such methacrylates include methyl methacrylate, ethyl methacrylate, propyl methacrylate, isopropyl methacrylate, butyl methacrylate, amyl methacrylate, hexyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, chlorobenzyl methacrylate, octyl methacrylate, N-ethyl-N-phenylaminoethyl methacrylate, 2-methoxyethyl methacrylate, 2-(3-phenylpropyloxy)- ethyl methacrylate, dimethylaminophenoxyethyl methacrylate, furfuryl methacrylate,

tetrahydrofurfuryl methacrylate, phenyl methacrylate, cresyl methacrylate and naphthyl methacrylate.

Component C is polymerized methacrylic acid monomer. This unit comprises 5 to 50, often 10 to 30 and preferably 15 to 25 weight percent of the copolymer. Upon polymerization methacrylic acid yields a substantially water-insoluble polymeric component C. This insures a high degree of incorporation of the polymerized methacrylic acid monomer into the insoluble particles of copolymer in an aqueous latex composition. This composition is stable and can be easily coated. The acid groups of the polymerized monomer of component C make the copolymer soluble in alkaline recovery process solutions. As illustrated in the following Example 4, the substitution of methacrylic acid monomer by a polymerizable vinyl monomer containing similar acid groups such as acrylic acid does not impart the required solubility to the copolymer in an alkaline recovery process.

Component D is a polymerized unit of cationically charged vinyl monomer, i.e. a vinyl monomer that contains a cationic group. Component D comprises 0.5 to 15, often 1 to 10, and preferably 2 to 10 weight percent of the copolymer. Examples of such monomers include N-(2-methacryloyloxyethyl) - N,N,N-trimethylammonium methosulfate, N,N,N- trimethyl-N-vinylbenzylammonium chloride and N-(3-methacrylamidoproρyl)-N,N,N-trimethylammonium chloride. As illustrated, in following Example 4, a comparable copolymer which does not contain polymerized unit (D) forms an unstable latex composition which has poor coating characteristics and forms a coating that cannot be easily removed during photographic film support recovery operations.

Surfactants that can be used in the aforementioned procedure to prepare the copolymers of this invention include hexadecyltrimethylammonium bromide which is representive of cationic surfactants and Igepal CO-73CF' (an ethoxylated nonyl-phenol, GAF Corporation, U.S.A.) which is representative of non-ionic surfactants. Useful catalysts include 2,2'-azobis(2-amidinopropane ^• hydrochloride) , 2,2'-azobis(2-methylproρio- nitrile) and hydrogen peroxide.

The copolymers of this invention have both anionic and cationic characteristics due to the poly¬ merized units present therein. Accordingly, they are not sufficiently soluble in solvents typically employed to determine molecular weights of copolymers by conventional methods such as gel permeation chro atography. However, such copolymers do exhibit glass transition temperatures (Tg) that are in the range of about 10 to 70°C, often 10 to 60°C and preferably 30 to 50°C. These glass transition temperatures can be determined using conventional differential thermal analysis, preferably by the use of a "differential scanning calorimeter" (DSC) . A detailed description of this analytical method can be found in "Thermal

Analysis", Vol. I of the series "Techniques and Methods of Polymer Evaluation", edited by P. E. Slade and L. T. Jenking, Marcel Dekker, New York, 1966. Examples of copolymers made according to the previously described method are set forth in the following Table I.

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Table I

Copolymer No. Name Weight Percent 1 Poly[vinyl ace ate-co-tetrahydrofurfuryl 55/20/20/5 methacrylate-co-methacrylic acid-co-N-(2 methacryloyloxy)ethyl-N,N,N-trimethyl- ammonium methosulfate]

Poly[vinyl acetate-co-tetrahydrofurfuryl 65/20/10/5 methyacrylate-co-methacrylic acid-co-N-(2 methacryloyloxy)ethyl-N,N,N-trimethylammonium methosulfate]

Poly[vinyl acetate-co-n-butyl acrylate-co- 60/20/15/5 methacrylic acid-co-N-(2-methacryloyloxy)ethyl- N,N,N-trimethylammonium methosulfate]

I

Poly[vinyl acetate-co-tetrahydrofurfuryl 55/20/20/5 00 methyacrylate-co-methacrylic acid-co-N-(3- methacrylamidopropyl)-N,N,N-trime hyl- ammonium chloride]

Poly(vinyl acetate-co-tetrahydrofurfuryl 55/20/20/5 methacrylate-co-methacrylic acid-co- N,N,N-trimethyl-N-vinylbenzylammonium chloride)

Polytvinyl acetate-co- ethoxyethyl acrylate- 60/20/15/5 co-methacrylic acid-co-N-(2-methacryloyloxy)- ethyl-N,N,N-trime hylammonium methosulfate]

An important feature of this invention relates to the use of loaded latex compositions to form uniform dispersions of hydrophobes, as described in U.S. Patents 4,214,047 and 4,199,363.

Accordingly, although loaded latex compositions are known, a detailed description of this feature of the invention, including the manner of forming the loaded latex composition is believed to be appropriate.

10 The hydrophobe to be loaded is dissolved in a water-miscible organic solvent. An aqueous latex consisting essentially of water as a continuous phase and loadable copolymer particles as a dispersed phase is then blended into the

₁₅ water-miscible organic solvent containing the hydrophobe. Blending is undertaken so that the hydrophobe remains in solution and the loadable copolymer particles remain dispersed. That is, separation of the hydrophobe or coagulation of the

2 _Q copolymer particles is avoided. By avoiding such separation or coagulation, a two-phase mixture is established in which the mixture of water-miscible organic solvent and water constitutes a continuous phase and the copolymer particles constitute a _j r. discontinuous phase. Initially, the hydrophobe is within the water-miscible organic solvent. In the two phase mixture resulting from blending, the hydrophobe is brought into intimate association with both the continuous and the dispersed phases. The

, ₀ hydrophobe is then free to distribute itself between these phases based on its relative solubilities therein. Dilution of the water-miscible organic solvent with water by blending has the effect of reducing the affinity of the hydrophobe for the c continuous phase. Thus, the introduction of water

has the effect of driving or shifting the equilibrium distribution of the hydrophobe away from the continuous phase and toward the dispersed phase. The presence of water (or an increased amount of water, if some water was initially present in the water-miscible organic solvent) causes the hydrophobe to redistribute itself between the continuous and dispersed phases. In this way a portion of the hydrophobe becomes dispersed or dissolved in the copolymer particles, so that the particles become loaded with hydrophobe. This loading procedure requires that the hydrophobe remain dissolved until associated with the copolymer particle. In most instances all the water desired to dilute the water-miscible organic solvent and shift the equilibrium distribution of the hydrophobe is present in the aqueous latex during initial blending. Where it is desired to introduce additional water, as where a concentrated latex is employed, additional water is blended with the loaded latex composition resulting from the initial step of blending. The additional water has the effect of further reducing the affinity of the hydrophobe for the continuous phase. This further drives or shifts the equilibrium distribution of the hydrophobe away from the continuous phase toward the dispersed phase and further contributes to loading the copolymer particles with hydrophobe. While blending of water and loadable copolymer particles with the water-miscible organic solvent containing hydrophobe dissolved therein results in significant loading of the hydrophobe into the particles, a substantial portion of the hydrophobe remains in the continuous phase dissolved

in the water-miscible organic solvent. Further loading of the hydrophobe into the polymer particles can be achieved by removing water-miscible organic solvent from the continuous phase. This has the effect of further increasing the affinity of the hydrophobe for the dispersed phase. It is preferred to remove a major portion, in other words, at least about half, of the water-miscible organic solvent. This drives or shifts the equilibrium distribution of the hydrophobe away from the continuous phase toward the dispersed phase. A still higher proportion of hydrophobe becomes dissolved or dispersed in the copolymer particles so that their loading is further increased. It is unnecessary to practice all of the loading steps indicated above following initial blending and loading. For certain applications the loaded latex composition resulting from initial blending and loading is used directly, or the loaded copolymer particles can be separated from the continuous phase and used directly.

The water-miscible organic solvents useful in the practice of this loading process are those which: a. , can be dissolved in (i.e., are "miscible" with) distilled water at 20°C to the extent of at least about 20 parts by volume of solvent in 80 parts by volume of water; b. have boiling points (at atmospheric pressure) above about -10°C; c. do not detrimentally react chemically with aqueous latexes containing the loadable copolymer particles which are useful in the practice of this process; and

d. do not dissolve more than about 5 weight percent of such loadable copolymer particles in the aqueous latex at 20°C. Examples of such useful water-miscible organic solvents are water-miscible alcohols, ketones and amides (e.g. acetone, ethyl alcohol, methyl alcohol, isopropyl alcohol, dimethylformamide, methyl ethyl ketone) , tetrahydrofuran, N-methyl-2-pyrrolidone, dimethyl sulfoxide and mixtures thereof. The latices employed in the practice of the latex loading process consist essentially of water as a continuous phase and loadable copolymer particles as a dispersed phase. These loadable copolymer particles meet the following Loadable Particle Test.

Loadable Particle Test

At 25°C, the loadable copolymer particles being tested are (a) capable of forming a latex with water at a copolymer particle concentration of from 10 to 20 percent by weight, based on total weight of the latex, and (b) when 100 ml of the latex is mixed with an equal volume of the water-miscible organic solvent to be employed in forming the loaded polymeric latex composition desired, stirred and allowed to stand for 10 minutes, exhibit no observable coagulation of the copolymer particles.

The latex is characterized in that the loadable copolymer particles are generally highly dispersed as compared to coupler solvent and similar hydrophobic particle dispersions in photographic hydrophilic colloid coatings. The loadable copolymer particles exhibit an average diameter less than approximately 0.2 micrometer, generally from 0.002 to 0.2, preferably from 0.02 to 0.08 micrometer. Although some swelling can occur during

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loading, the loaded copolymer particles typically fall within these same ranges of average diameters. The loadable copolymer particles form at least 2 percent by weight of the aqueous latex and preferably form at least 10 percent by weight thereof. Preferably the aqueous latex contains 20 percent by weight or less of the loadable polymer particles.

The hydrophobes employed in the latex composition are essentially insoluble in distilled water at 25°C. Preferably the dissolved concentration of hydrophobe in water under these conditions is less than 0.5 percent by weight, based on the weight of the water. Any such hydrophobe also can be dissolved in a liquid consisting of one or a mixture of water-miscible organic solvents . Preferably the hydrophobe is soluble in a concentration of at least 5 percent by weight, based on the total weight of the water-miscible organic solvent and dissolved hydrophobe. In practice, minor amounts of essentially diluent materials, such as minor amounts of water commonly entrained in water-miscible solvents, are associated with the blended hydrophobe and water-miscible organic solvent. However, the hydrophobe and water-miscible organic solvent or solvents are chosen so that additional materials, such as pH modifiers or other modifiers e.g. acid or alkali, are not required to dissolve the hydrophobe. Preferred hydrophobes used to form loaded latex compositions are hydrophobic photographic addenda such as those used to perform coupling, silver halide development, oxidized developer scavenging, spectral sensitizing or desensitizing, diffusion transfer dye image-forming and visible or

ultraviolet light absorbing functions when incorporated in a radiation-sensitive element such as a silver halide photographic element. Other hydrophobic photographic addenda include those used in silver halide photographic elements as brighteners, antistats, antioxidants, silver halide solvents and bleachable dyes in silver-dye-bleach imaging processes. Hydrophobic photographic addenda which have been conventionally introduced into hydrophillic colloid layers of photographic elements in coupler-solvent and similar high boiling organic solvent droplets are ideally suited for use in the loaded latex compositions described herein. Generally the amount of hydrophobe present in intimate association with the copolymer particles of the latex is from 1:40 to 3:1 in terms of a weight ratio of hydrophobe to loadable copolymer. It is preferred that the weight ratio be from 1:10 to 2:1, optimally from 1:5 to 1:1. Generally the proportion of aqueous copolymer latex added to water-miscible organic solvent containing hydrophobe is maintained in the volume ratio of 1:4 to 20:1, preferably 1:1 to 10:1. Not all of the water added, however, need be present in the aqueous copolymer latex. It is contemplated that a portion of the water which might be blended in such latex is added subsequent to blending the aqueous latex and water-miscible organic solvent. Where it is desired to coat hydrophilic colloid layers, as in photographic applications and elements, the copolymer particles, loadable or loaded, of the latex, are chosen to be readily dispersible in a hydrophilic colloid composition. This is accomplished by employing particles

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consisting essentially of loadable copolymers of the type described herein. This allows the hydrophilic colloid composition to be uniformly blended with the loadable or loaded latex composition. The resulting hydrophilic colloid containing latex composition is then coated onto a suitable substrate, such as a conventional photographic film support. Water and, if any is present, water-miscible organic solvent are then removed from the coating so that a solid hydrophilic colloid coating results. Depending upon the specific photographic application, the hydrophilic coating containing the copolymer particles is the sole coating on the support, it is an undercoat, an interlayer or an overcoat. In one useful embodiment the copolymer particles are incorporated into a subbing layer on one or both surfaces of a photographic film support. The subbing layer or layers can be overcoated with a suitable hydrophobic layer, e.g. a layer comprising poly(methyl methacrylate)..

The latex compositions, loaded or unloaded, with or without a hydrophilic colloid, are coated as layers on one or both sides of a photographic film support. Examples of such supports are cellulose acetate film, cellulose nitrate film, polyvinyl acetal film, polycarbonate film, polystyrene film and polyester film. The copolymer latex compositions can be coated using conventional techniques. It is specifically contemplated to coat the film-forming copolymer compositions of the invention using coating hoppers and other apparatus conventionally employed in the photographic arts for forming single or multiple coatings on photographic film supports. Useful coating techniques and supports are described in the Product Licensing

Index, Vol. 92, pages 107-110, December, 1971, and the publications referred to therein.

Radiation-sensitive layers are well-known in the art. Radiation-sensitive materials that can be used in the radiation-sensitive layers used in this invention include photographic silver halides such as silver chloride, silver bromide, silver bromoiodide, silver chlorobromide, silver chloroiodide, silver chlorobromoiodide, and mixtures thereof. Often, these layers are photographic emulsion layers that contain a hydrophilic colloid. Illustrative examples of such colloids are proteins such as gelatin, protein derivatives, cellulose derivatives, polysaccharides such as starch, sugars such as dextran, plant gums, and synthetic polymers such as polyvinyl alcohol, polyacrylamide and polyvinylpyrrolidone. Conventional addenda such as antifoggants, stabilizers, sensitizers, development modifiers, developing agents, hardeners, plasticizers and coating aids, can also be included in the radiation-sensitive layers. The elements described herein can be unsensitized photographic film support, film sensitized with a black-and-white photographic emulsion, elements designed for reversal color processing, negative color elements, color print materials, and the like. Photographic silver halide emulsions, preparations, addenda, and processing techniques useful for such elements are described, for example, in Research Disclosure publication 17643, December, 1978, pp. 22-31.

The following Examples are presented to illustrate the practice of this invention. Example 1:

A copolymer of this invention (Copolymer 1 of Table I) can be prepared using the emulsion

^" -^ ^•

polymerization technique described herein. To illustrate, an aqueous solution of

0.33 g of hexadecyltrimethylammonium bromide surfactant, 0.167 g of Igepal CO-730^ surfactant and 0.70 g of 2,2'azobis(2-amidinoρropane) dihydrochloride in 100 g of deoxygenated water was prepared in a tank. 55 g of vinyl acetate, 22.2 g of 90 percent active (20 g of polymerizable monomer) tetrahydrofurfuryl methacrylate, 20 g of methacrylic- acid and 5 g of N-(2-methacryloyloxyethyl)N,N,N- trimethylammonium methosulfate were added to the aqueous solution with stirring.

A mixture was prepared in a reaction vessel by dissolving 0.67 g of hexadecyltrimethylammonium bromide surfactant and 0.33 g of Igepal CO-730 in

460 g deoxygenated water. The pH of the mixture was adjusted to 3-4 with aqueous hydrochloric acid. The contents of the tank were added to the reaction vessel over a 60 minute period. The reaction was continued at 68°C for 4 hours. The thus formed latex was cooled and filtered. The composition of the copolymer was confirmed by elemental analysis and its Tg was 39°C. Example 2 The copolymers of this invention can be used to make loaded latex compositions that form layers which exhibit excellent adhesion to photographic film support. To illustrate, the copolymer latex prepared as in Example 1 was loaded with a photographically useful hydrophobe as described in Examples 11 or 12 of U.S. Patent 4,199,363, issued April 22, 1980. The loaded latex composition was then coated on unsubbed cellulose acetate photographic film support at a dry total

2 coverage of 66 mg/m . This loaded latex layer was

then overcoated with a solution of ρoly(methyl methacrylate) in acetone/n-butanol (95/5) wt./wt. at a total dry coverage of 770 mg/m .

Performance Tests Adhesion of both the single layer coated from the aqueous latex and the overcoated 2-layer system to the support were excellent, as shown by a cross-hatch adhesion test. In this test, elements coated with the layer or layers were scored to the cellulose acetate film support with a razor blade in a cross-hatch pattern. Transparent adhesive tape was firmly applied and then ripped away. No portion of the coated single layer or the 2-layer system were removed by the tape. The element containing the overcoated

2-layer system was soaked in a conventional metol-hydroquinone alkaline photographic developer, pH 10.2, at 38°C for 10 minutes. There was no effect on the properties or appearance of either the poly(methyl methacrylate) overcoat or the underlayer formed from the aqueous copolymer latex of this invention.

To illustrate the support recovery feature of this invention, the element was treated with Q.14& aqueous NaOH for 30 minutes at 95°C. Both the overcoat layer and the underlayer containing the hydrophobe were quantitatively removed. The overcoat came off as dust-like, insoluble, non-tacky particles or flakes which were easily filtered away from the film support. The underlayer dissolved and was easily filtered away from the film support. The remaining support was dissolved in methylene chloride/methyl alcohol (95/5) wt./wt. to give a clear dope, free of particulate matter. The dope was cast to give a clear film. No residual

copoly er, hydrophobe or overcoat could be detected spectrally.

Similar layer removal is obtained with elements in which either the loaded latex single coated layer or the overcoated 2-layer system is on one side of the cellulose acetate film support and the other side of the support is coated with an exposed and processed radiation-sensitive layer of gelatino-silver bromoiodide photographic emulsion. Example 3:

A variety of photographic film supports can be used in the practice of this invention. To illustrate, the copolymer latex loaded with a hydrophobe as described in Example 2 was coated on subbed poly(ethylene terephthalate) film support at a dry total coverage of 66 mg/m ² . The layer was then overcoated with an aqueous latex of pol (methyl methacrylate) at a total dry coverage of 770 mg/m ² . Resorcinol was used as a coalescing aid. Adhesion of both of these coated layers was excellent, as shown by the cross-hatch adhesion test described in Example 2. Example 4

Additional copolymers of this invention were prepared as aqueous latex compositions using the emulsion polymerization technique described in Example 1. These copolymers are identified in the following Table II as Copolymers 1-13.

To illustrate the need for the cationically charged vinyl monomer in the copolymers of this invention, comparable copolymers were prepared using the same technique but without such monomer. These comparative copolymers are identified in the following Table II as Copolymers C-l to C-4.

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To illustrate that the methacrylic acid monomer cannot be replaced by a polymerizable vinyl monomer such as acrylic acid, a comparable copolymer in which acrylic acid was used in place of methacrylic acid was also prepared. This copolymer is identified in the following Table II as C-5.

The structure of each of the copolymers in Table II are verified by elemental analysis and each of these copolymers have a glass transition temperature (Tg) in the range of 10°C to 60°C.

Table II

Copolymer No. Name Weight Percent 1 Polyfvinyl acetate-co-tetrahydrofurfuryl meth¬ acrylate-co-methacrylic acid-co-2-(methacryloyl- oxy)ethyltrimethylammonium methosulfate] 68/20/10/2

2 65/20/10/5 3 64/20/15/1 4 60/22/15/3 5 59/20/20/1 6 55/20/20/5 7 Poly[vinyl acetate-co-n-butyl acrylate-co- methacrylic acid-co-2-(methacryloyloxy)- N> ethyltrimethylammonium methosulfate] 64/20/15/1

8 II 60/22/15/3

9 II 55/20/20/5

10 II 50/20/25/5

11 45/20/30/5

12 Poly[vinyl acetate-co-n-butyl methacrylate- co-methacrylic acid-co-2-(methacryloyloxy) ^■ ethyltrimethylammonium methosulfate] 55/20/20/5

13 Poly[vinyl acetate-co-ethyl acrylate-co-

Table II (Cont'd)

Copolymer No. Name Weight Percent C-l Poly(vinyl acetate-co-tetrahydrofurfuryl methacrylate-co-methacrylic acid) 85/10/5

C-2 Poly(vinyl acetate-co-tetrahydrofurfuryl methacrylate-co-methacrylic acid) 82.5/10/7.5

C-3 Poly(vinyl acetate-co-tetrahydrofurfuryl methacrylate-co-methacrylic acid) 80/10/10

C-4 Poly(vinyl acetate-co-n-butyl acrylate-co- methacrylic acid 75/20/5 r-o

C-5 Poly[vinyl acetate-co-tetrahydrofurfuryl methacrylate-co-acrylic acid-co-2-(methacryl- oyloxy)ethyltrimethylammonium methosulfate] 55/20/20/5

The copolymer latex compositions containing

Copolymers 1-13 and C-l to C-5 were loaded with photographically useful hydrophobe and coated on unsubbed cellulose acetate photographic film at a

2 dry total coverage of 66 mg/m , as described in

Example 2. The loaded latex layers were then overcoated with a solution of poly(methyl methacrylate), also as described in Example 2. The coated layers exhibited excellent adhesion when

10 subjected to the cross-hatch adhesion test described previously herein.

To illustrate the photographic process- ability and support recovery features of this invention, each of the coated elements was treated

₁ _ with metol-hydroquinone alkaline photographic developer and aqueous sodium hydroxide solution as described in Example 2, except that the concentration of the aqueous sodium hydroxide solution was increased to 0.175%.

20 The elements containing layers of

Copolymers 1-13 showed no adverse effects from treatment with the metol-hydroquinone alkaline photographic developer and were satisfactorily removed from the cellulose acetate film support by y r. the treatment with the aqueous sodium hydroxide solution. The coatings were essentially completely removed by the treatment for Copolymers 3-13 in which the polymerized methacrylic acid content was 15 weight percent or greater. Coatings with on Copolymers 1 and 2 which contain 10 weight percent methacrylic acid were removed to the extent of at least 65 percent. Essentially complete removal of coatings of Copolymers 1 and 2 could easily be achieved by increasing the sodium hydroxide

9. r. concentration above 0.175 percent or lengthening the

ti e beyond 30 minutes in the 95°C recovery operation. Furthermore, the aqueous latex compositions of Copolymers 1-13 were stable, as illustrated by the fact that they formed no objectionable amount of precipitate in the pan of a simulated dip pan coating hopper. In contrast, Copolymers C-1 through C-4 formed aqueous latex compositions which were unstable and formed heavy precipitates in the pan of the simulated hopper. Also, no more than about 35 percent of the coatings formed with Copolymers C-1, C-2 and C-4 were removed in the treatment with aqueous sodium hydroxide. In the case of Copolymer C-5, only about 20 percent of the coating was removed in the treatment with aqueous sodium hydroxide solution.

Similar good latex stability and acceptable layer removal are obtained with poly[vinyl acetate-co-methyl aerylate-co-methacrylie acid-co-2-(methacryloyloxy)ethyltri- methylammonium methosulfate], 64/20/15/1 and poly[vinyl acetate-co-methyl methacrylate-co- methacrylic acid-co-2-(methacryloyloxy)ethyl¬ trimethylammonium methosulfate], 55/20/20/5 of this invention.

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